MXene has been the limelight for studies on electrode active materials,aiming at developing supercapacitors with boosted energy density to meet the emerging influx of wearable and portable electronic devices.Despite i...MXene has been the limelight for studies on electrode active materials,aiming at developing supercapacitors with boosted energy density to meet the emerging influx of wearable and portable electronic devices.Despite its various desirable properties including intrinsic flexibility,high specific surface area,excellent metallic conductivity and unique abundance of surface functionalities,its full potential for electrochemical performance is hindered by the notorious restacking phenomenon of MXene nanosheets.Ascribed to its two-dimensional(2D)nature and surface functional groups,inevitable Van der Waals interactions drive the agglomeration of nanosheets,ultimately reducing the exposure of electrochemically active sites to the electrolyte,as well as severely lengthening electrolyte ion transport pathways.As a result,energy and power density deteriorate,limiting the application versatility of MXene-based supercapacitors.Constructing 3D architectures using 2D nanosheets presents as a straightforward yet ingenious approach to mitigate the fatal flaws of MXene.However,the sheer number of distinct methodologies reported,thus far,calls for a systematic review that unravels the rationale behind such 3D MXene structural designs.Herein,this review aims to serve this purpose while also scrutinizing the structure–property relationship to correlate such structural modifications to their ensuing electrochemical performance enhancements.Besides,the physicochemical properties of MXene play fundamental roles in determining the effective charge storage capabilities of 3D MXene-based electrodes.This largely depends on different MXene synthesis techniques and synthesis condition variations,hence,elucidated in this review as well.Lastly,the challenges and perspectives for achieving viable commercialization of MXene-based supercapacitor electrodes are highlighted.展开更多
为了提升电火花线切割(Wire cut Electric Discharge Machining,WEDM)加工后的TC4钛合金表面质量,减少表面重熔层厚度,采用不同浓度配比(1∶4、1∶6和1∶8)的HF-HNO_(3)酸蚀溶液对钛合金试件进行化学抛光处理。实验结果表明,HF-HNO_(3)...为了提升电火花线切割(Wire cut Electric Discharge Machining,WEDM)加工后的TC4钛合金表面质量,减少表面重熔层厚度,采用不同浓度配比(1∶4、1∶6和1∶8)的HF-HNO_(3)酸蚀溶液对钛合金试件进行化学抛光处理。实验结果表明,HF-HNO_(3)酸蚀溶液能使钛合金重熔层得到显著去除,表面微裂纹得到有效控制;当HF-HNO_(3)酸蚀溶液的浓度配比为1:6时,试件能获得最低的表面粗糙度和最大的表面粗糙度下降率,并且抛光前后钛合金表面元素含量发生了不同程度的变化,Ti、Al和V元素质量分数分别提高了21.5%、41.3%和13.2%,而O、C元素质量分数分别降低了82.5%和33.6%;HF-HNO_(3)酸蚀溶液可显著改善TC4钛合金试件电火花线切割加工后的表面缺陷。钛合金重熔层结构的主要成分与化学抛光后氧化膜的主要成分相似,但与氧化膜的结构不同,这对TC4钛合金试件表面质量提升具有重要意义。展开更多
A new phloretin derivative 1 3-[2-(4-hydroxy-phenyl)-ethyl]-benzo[d] isoxazole-4,6-diol (yield 63%) was synthesized from phloretin by carbonyl nucleophilic addition condensation reaction. Its structure was characteriz...A new phloretin derivative 1 3-[2-(4-hydroxy-phenyl)-ethyl]-benzo[d] isoxazole-4,6-diol (yield 63%) was synthesized from phloretin by carbonyl nucleophilic addition condensation reaction. Its structure was characterized by 1H NMR, 13C NMR and HR-MS. The phloretin, compound 1, resveratrol and acetylated resveratrol were determined by comparing them with paclitaxel. Anti-tumor activity of alcohol on SPC-A1, EC109, A549, MCF-7 and MDA-MB-231 cell lines. Compound 1 showed better antitumor activity than docetaxel against A549 tumor cells.展开更多
基金supported by the Fundamental Research Grant Scheme by Ministry of Higher Education Malaysia(FRGS/1/2021/STG04/XMU/02/1 and FRGS/1/2022/TK09/XMU/03/2)the Xiamen University Malaysia Research Fund(XMUMRF/2023-C11/IENG/0056)。
文摘MXene has been the limelight for studies on electrode active materials,aiming at developing supercapacitors with boosted energy density to meet the emerging influx of wearable and portable electronic devices.Despite its various desirable properties including intrinsic flexibility,high specific surface area,excellent metallic conductivity and unique abundance of surface functionalities,its full potential for electrochemical performance is hindered by the notorious restacking phenomenon of MXene nanosheets.Ascribed to its two-dimensional(2D)nature and surface functional groups,inevitable Van der Waals interactions drive the agglomeration of nanosheets,ultimately reducing the exposure of electrochemically active sites to the electrolyte,as well as severely lengthening electrolyte ion transport pathways.As a result,energy and power density deteriorate,limiting the application versatility of MXene-based supercapacitors.Constructing 3D architectures using 2D nanosheets presents as a straightforward yet ingenious approach to mitigate the fatal flaws of MXene.However,the sheer number of distinct methodologies reported,thus far,calls for a systematic review that unravels the rationale behind such 3D MXene structural designs.Herein,this review aims to serve this purpose while also scrutinizing the structure–property relationship to correlate such structural modifications to their ensuing electrochemical performance enhancements.Besides,the physicochemical properties of MXene play fundamental roles in determining the effective charge storage capabilities of 3D MXene-based electrodes.This largely depends on different MXene synthesis techniques and synthesis condition variations,hence,elucidated in this review as well.Lastly,the challenges and perspectives for achieving viable commercialization of MXene-based supercapacitor electrodes are highlighted.
文摘为了提升电火花线切割(Wire cut Electric Discharge Machining,WEDM)加工后的TC4钛合金表面质量,减少表面重熔层厚度,采用不同浓度配比(1∶4、1∶6和1∶8)的HF-HNO_(3)酸蚀溶液对钛合金试件进行化学抛光处理。实验结果表明,HF-HNO_(3)酸蚀溶液能使钛合金重熔层得到显著去除,表面微裂纹得到有效控制;当HF-HNO_(3)酸蚀溶液的浓度配比为1:6时,试件能获得最低的表面粗糙度和最大的表面粗糙度下降率,并且抛光前后钛合金表面元素含量发生了不同程度的变化,Ti、Al和V元素质量分数分别提高了21.5%、41.3%和13.2%,而O、C元素质量分数分别降低了82.5%和33.6%;HF-HNO_(3)酸蚀溶液可显著改善TC4钛合金试件电火花线切割加工后的表面缺陷。钛合金重熔层结构的主要成分与化学抛光后氧化膜的主要成分相似,但与氧化膜的结构不同,这对TC4钛合金试件表面质量提升具有重要意义。
文摘A new phloretin derivative 1 3-[2-(4-hydroxy-phenyl)-ethyl]-benzo[d] isoxazole-4,6-diol (yield 63%) was synthesized from phloretin by carbonyl nucleophilic addition condensation reaction. Its structure was characterized by 1H NMR, 13C NMR and HR-MS. The phloretin, compound 1, resveratrol and acetylated resveratrol were determined by comparing them with paclitaxel. Anti-tumor activity of alcohol on SPC-A1, EC109, A549, MCF-7 and MDA-MB-231 cell lines. Compound 1 showed better antitumor activity than docetaxel against A549 tumor cells.
