Two possible lower barrier reaction pathways in the reaction HF+HOBOH2O+FBO are predicated by means of MP2 and CCSD(T) (single-point) methods. In the two channels, two stable intermediates are located, and thus, they...Two possible lower barrier reaction pathways in the reaction HF+HOBOH2O+FBO are predicated by means of MP2 and CCSD(T) (single-point) methods. In the two channels, two stable intermediates are located, and thus, they are multi-step channels, which are more favorable in energy than direct single-step reaction pathway predicated by previous theoretical study. Therefore, the two pathways should be main reaction channels in experiments.展开更多
Influence of temperature on egg incubation of the wild Chinese alligator was studied during the summer seasons of 1999 and 2000(July to October and August to September,respectively)at three observation sites, Zhuangto...Influence of temperature on egg incubation of the wild Chinese alligator was studied during the summer seasons of 1999 and 2000(July to October and August to September,respectively)at three observation sites, Zhuangtou of Xuanzhou County,Shuangkeng and Zhongqiao of Jingxian county, Anhui Province. One nest at each of the above sites was monitored, bearing 19,17 and 19 eggs,respectively. According to the width of the band on the eggs, we estimated the dates that the eggs were laid. We recorded both the nest temperature and atmosphere temperature with an automated temperature data logger (HOBO Temp) during the whole observation period.We found that the average nest temperature maintained around 25 26℃ during incubation throughout day and night,within over two thirds of time in each day the nest temperature being higher than the atmosphere temperature. Analysis of our data revealed that alligator nests have buffering effect on the inside temperature. Higher nest temperature (27 30℃)increased the hatching rate. It was also noticed that the hatching rate varied considerably from site to site(between 0 100%). We conclude that climate is an important factor influencing egg hatching in the wild, and prolonged rainy season which caused large temperature fluctuation can decrease the hatching rate of the alligator eggs.展开更多
The vertical distribution of vegetation types along an elevational gradient in mountain areas largely depends on the elevational changes in air temperature and humidity. In this study, we presented the seasonal and di...The vertical distribution of vegetation types along an elevational gradient in mountain areas largely depends on the elevational changes in air temperature and humidity. In this study, we presented the seasonal and diurnal variations in the elevational gradients of air temperature and humidity on the southern and northern slopes in the middle Tianshan Mountain Range using data collected throughout the year via HOBO data loggers. The measurements were conducted at 12 different elevations from 1548 to 3277 m from September 2004 to August 2005. The results showed that the annual mean air temperature decreased along the elevational gradients with temperature lapse rates of(0.71±0.20)°C/100 m and(0.59±0.05)°C/100 m on the northern and southern slopes, respectively. The annual mean absolute humidity significantly decreased with increasing elevation on the northern slope but showed no significant trend on the southern slope. The annual mean relative humidity did not show a significant trend on the northern slope but increased with increasing elevation on the southern slope. The mean air temperature lapse rate exhibited significant seasonal variation, which is steeper insummer and shallower in winter, and this value varied between 0.37°C/100 m and 0.75°C/100 m on the southern slope and between 0.30°C/100 m and 1.02°C/100 m on the northern slope. The mean absolute and relative humidity also exhibited significant seasonal variations on both slopes, with the maximum occurring in summer and the minimum occurring in winter or spring. The monthly diurnal range of air temperature on both slopes was higher in spring than in winter. The annual range of air temperature on the southern slope was higher than that on the northern slope. Our results suggest that significant spatiotemporal variations in humidity and temperature lapse rate are useful when analyzing the relationships between species range sizes and climate in mountain areas.展开更多
The typically sparse or lacking distribution of meteorological stations in mountainous areas inadequately resolves temperature elevation variability. This study presented the diurnal and seasonal variations of the ele...The typically sparse or lacking distribution of meteorological stations in mountainous areas inadequately resolves temperature elevation variability. This study presented the diurnal and seasonal variations of the elevation gradient of air temperature in the northern flank of the western Qinling Mountain range,which has not been thoroughly evaluated. The measurements were conducted at 9 different elevations between 1710 and 2500 m from August 2014 to August 2015 with HOBO Data loggers. The results showed that the annual temperature lapse rates(TLRs) for Tmean,Tmin and Tmax were 0.45?C/100 m,0.44?C/100 m and 0.40?C/100 m,respectively,which are substantially smaller than the often used value of 0.60°C/100 m to 0.65°C/100 m. The TLRs showed no obvious seasonal variations,except for the maximum temperature lapse rate,which was steeper in winter and shallower in spring. Additionally,the TLRs showed significant diurnal variations,with the steepest TLR in forenoon and the shallowest in early morning or late-afternoon,and the TLRs changed more severely during the daytime than night time. The accumulated temperature above 0°C,5°C and 10°C(AT0,AT5 and AT10) decreased at a lapse rate of 112.8?C days/100 m,104.5?C days/100 m and 137.0?C days/100 m,respectively. The monthly and annual mean diurnal range of temperatures(MDRT and ADRT) demonstrated unimodal curves along the elevation gradients,while the annual range of temperature(ART) showed no significant elevation differences. Our results strongly suggest that the extrapolated regional TLR may not be a good representative for an individual mountainside,in particular,where there are only sparse meteorological stations at high elevations.展开更多
基金This work is supported by the National Natural Science Foundation of China (No. 20171015 20171016)+1 种基金 the Natural Science Foundation of Heilongjiang Province (No. E00-16) and the Science Foundation for Excellent Youth of Heilongjiang University (2002
文摘Two possible lower barrier reaction pathways in the reaction HF+HOBOH2O+FBO are predicated by means of MP2 and CCSD(T) (single-point) methods. In the two channels, two stable intermediates are located, and thus, they are multi-step channels, which are more favorable in energy than direct single-step reaction pathway predicated by previous theoretical study. Therefore, the two pathways should be main reaction channels in experiments.
文摘Influence of temperature on egg incubation of the wild Chinese alligator was studied during the summer seasons of 1999 and 2000(July to October and August to September,respectively)at three observation sites, Zhuangtou of Xuanzhou County,Shuangkeng and Zhongqiao of Jingxian county, Anhui Province. One nest at each of the above sites was monitored, bearing 19,17 and 19 eggs,respectively. According to the width of the band on the eggs, we estimated the dates that the eggs were laid. We recorded both the nest temperature and atmosphere temperature with an automated temperature data logger (HOBO Temp) during the whole observation period.We found that the average nest temperature maintained around 25 26℃ during incubation throughout day and night,within over two thirds of time in each day the nest temperature being higher than the atmosphere temperature. Analysis of our data revealed that alligator nests have buffering effect on the inside temperature. Higher nest temperature (27 30℃)increased the hatching rate. It was also noticed that the hatching rate varied considerably from site to site(between 0 100%). We conclude that climate is an important factor influencing egg hatching in the wild, and prolonged rainy season which caused large temperature fluctuation can decrease the hatching rate of the alligator eggs.
基金supported by the National Key R&D Program of China(2017YFA0605101)the National Natural Science Foundation of China(31770489,41273098 and 31621091)
文摘The vertical distribution of vegetation types along an elevational gradient in mountain areas largely depends on the elevational changes in air temperature and humidity. In this study, we presented the seasonal and diurnal variations in the elevational gradients of air temperature and humidity on the southern and northern slopes in the middle Tianshan Mountain Range using data collected throughout the year via HOBO data loggers. The measurements were conducted at 12 different elevations from 1548 to 3277 m from September 2004 to August 2005. The results showed that the annual mean air temperature decreased along the elevational gradients with temperature lapse rates of(0.71±0.20)°C/100 m and(0.59±0.05)°C/100 m on the northern and southern slopes, respectively. The annual mean absolute humidity significantly decreased with increasing elevation on the northern slope but showed no significant trend on the southern slope. The annual mean relative humidity did not show a significant trend on the northern slope but increased with increasing elevation on the southern slope. The mean air temperature lapse rate exhibited significant seasonal variation, which is steeper insummer and shallower in winter, and this value varied between 0.37°C/100 m and 0.75°C/100 m on the southern slope and between 0.30°C/100 m and 1.02°C/100 m on the northern slope. The mean absolute and relative humidity also exhibited significant seasonal variations on both slopes, with the maximum occurring in summer and the minimum occurring in winter or spring. The monthly diurnal range of air temperature on both slopes was higher in spring than in winter. The annual range of air temperature on the southern slope was higher than that on the northern slope. Our results suggest that significant spatiotemporal variations in humidity and temperature lapse rate are useful when analyzing the relationships between species range sizes and climate in mountain areas.
基金funded by the Natural Science Foundation of China (Grant Nos.41630750,41271059)the National Key Basic Research Special Foundation of China (Grant No.2011FY110300)
文摘The typically sparse or lacking distribution of meteorological stations in mountainous areas inadequately resolves temperature elevation variability. This study presented the diurnal and seasonal variations of the elevation gradient of air temperature in the northern flank of the western Qinling Mountain range,which has not been thoroughly evaluated. The measurements were conducted at 9 different elevations between 1710 and 2500 m from August 2014 to August 2015 with HOBO Data loggers. The results showed that the annual temperature lapse rates(TLRs) for Tmean,Tmin and Tmax were 0.45?C/100 m,0.44?C/100 m and 0.40?C/100 m,respectively,which are substantially smaller than the often used value of 0.60°C/100 m to 0.65°C/100 m. The TLRs showed no obvious seasonal variations,except for the maximum temperature lapse rate,which was steeper in winter and shallower in spring. Additionally,the TLRs showed significant diurnal variations,with the steepest TLR in forenoon and the shallowest in early morning or late-afternoon,and the TLRs changed more severely during the daytime than night time. The accumulated temperature above 0°C,5°C and 10°C(AT0,AT5 and AT10) decreased at a lapse rate of 112.8?C days/100 m,104.5?C days/100 m and 137.0?C days/100 m,respectively. The monthly and annual mean diurnal range of temperatures(MDRT and ADRT) demonstrated unimodal curves along the elevation gradients,while the annual range of temperature(ART) showed no significant elevation differences. Our results strongly suggest that the extrapolated regional TLR may not be a good representative for an individual mountainside,in particular,where there are only sparse meteorological stations at high elevations.
