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Zinc phthalocyanine as an efficient catalyst for halogen-free synthesis of formamides from amines via carbon dioxide hydrosilylation under mild conditions 被引量:3
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作者 Rongchang Luo Xiaowei Lin +2 位作者 Jing Lu Xiantai Zhou Hongbing Ji 《Chinese Journal of Catalysis》 CSCD 北大核心 2017年第8期1382-1389,共8页
The combination of a zinc phthalocyanine(ZnPc)catalyst and a stoichiometric amount of dimethyl formamide(DMF)provided a simple route to formamide derivatives from amines,CO2,and hydrosilanes under mild conditions.We d... The combination of a zinc phthalocyanine(ZnPc)catalyst and a stoichiometric amount of dimethyl formamide(DMF)provided a simple route to formamide derivatives from amines,CO2,and hydrosilanes under mild conditions.We deduced that formation of an active zinc‐hydrogen(Zn‐H)species promoted hydride transfer from the hydrosilane to CO2.The cooperative activation of the Lewis acidic ZnPc by strongly polar DMF,led to formation of activated amines and hydrosilanes,which promoted the chemical reduction of CO2.Consequently,the binary ZnPc/DMF catalytic system showed excellent yields and superior chemoselectivity,representing a simple and sustainable pathway for the reductive transformation of CO2into valuable chemicals as an alternative to conventional halogen‐containing process. 展开更多
关键词 Carbon dioxide Zinc phthalocyanine Cooperative effect N‐formylation hydrosilanes
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Cationic quaternary ammonium-stabilized Nb oxoclusters catalyze reductive amination of carbon dioxide with hydrosilane 被引量:1
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作者 Yuan Ma Xinjian Wei +3 位作者 Jian Fang Qingpo Peng Wen Xu Zhenshan Hou 《Green Chemical Engineering》 2022年第2期146-156,共11页
The N-formylation of amines with CO_(2)and hydrosilanes is an emerging yet important reaction in fine chemical industry.Herein,we have reported a methyltrioctylammonium cation(TOMA)stabilized Nb oxocluster catalyst th... The N-formylation of amines with CO_(2)and hydrosilanes is an emerging yet important reaction in fine chemical industry.Herein,we have reported a methyltrioctylammonium cation(TOMA)stabilized Nb oxocluster catalyst that can effectively realize two electron reduction of CO_(2)and form C-N bond simultaneously,leading to the corresponding formamides.The oxocluster catalyst exhibits excellent catalytic activity to transform secondary and primary amines into the corresponding formamides,with the conversion ranging from 81.5%to 99.2%under room temperature conditions.Furthermore,the Nb oxocluster catalyst shows the unique characteristics of ionic liquids,and it is highly robust and easy to be recycled for five times with negligible loss of catalytic activity.On the basis of the activity tests and structure characterization of Nb catalysts,it was found that TOMA cation played an important role in modulating the Nb oxocluster with high stability and uniform dispersion.The mechanism studies demonstrate that the formylation reaction proceeds through the formation of silyl formate intermediate rather than carbamate,and the Lewis base site of negative oxygen atoms from polyoxoniobate anions can exert a favorable impact on activation both CO_(2)and Si-H bond of PhSiH 3,allowing that N-formylation reaction proceed smoothly under very mild reaction conditions. 展开更多
关键词 CO_(2) AMINE HYDROSILANE N-FORMYLATION POLYOXONIOBATE
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