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Limit state analysis of rigid retaining structures against seismically induced passive failure in heterogeneous soils
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作者 Jianfeng Zhou Changbing Qin 《Journal of Rock Mechanics and Geotechnical Engineering》 SCIE CSCD 2024年第3期1095-1105,共11页
Soils are not necessarily uniform and may present linearly varied or layered characteristics,for example the backfilled soils behind rigid retaining walls.In the presence of large lateral thrust imposed by arch bridge... Soils are not necessarily uniform and may present linearly varied or layered characteristics,for example the backfilled soils behind rigid retaining walls.In the presence of large lateral thrust imposed by arch bridge,passive soil failure is possible.A reliable prediction of passive earth pressure for the design of such wall is challenging in complicated soil strata,when adopting the conventional limit analysis method.In order to overcome the challenge for generating a kinematically admissible velocity field and a statically allowable stress field,finite element method is incorporated into limit analysis,forming finiteelement upper-bound(FEUB)and finite-element lower-bound(FELB)methods.Pseudo-static,original and modified pseudo-dynamic approaches are adopted to represent seismic acceleration inputs.After generating feasible velocity and stress fields within discretized elements based on specific criteria,FEUB and FELB formulations of seismic passive earth pressure(coefficient K_(P))can be derived from work rate balance equation and stress equilibrium.Resorting to an interior point algorithm,optimal upper and lower bound solutions are obtained.The proposed FEUB and FELB procedures are well validated by limit equilibrium as well as lower-bound and kinematic analyses.Parametric studies are carried out to investigate the effects of influential factors on seismic K_(P).Notably,true solution of K_(P) is well estimated based on less than 5%difference between FEUB and FELB solutions under such complex scenarios. 展开更多
关键词 Retaining wall passive earth pressure EARThQUAKES Finite-element limit-analysis methods
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LFM Radar Source Passive Localization Algorithm Based on Range Migration
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作者 Dandan Li Deyi Wang Hao Huan 《Journal of Beijing Institute of Technology》 EI CAS 2024年第2期130-140,共11页
Traditional single-satellite passive localization algorithms are influenced by frequency and angle measurement accuracies,resulting in error estimation of emitter position on the order of kilometers.Subsequently,a sin... Traditional single-satellite passive localization algorithms are influenced by frequency and angle measurement accuracies,resulting in error estimation of emitter position on the order of kilometers.Subsequently,a single-satellite localization algorithm based on passive synthetic aper-ture(PSA)was introduced,enabling high-precision positioning.However,its estimation of azimuth and range distance is considerably affected by the residual frequency offset(RFO)of uncoopera-tive system transceivers.Furthermore,it requires data containing a satellite flying over the radia-tion source for RFO search.After estimating the RFO,an accurate estimation of azimuth and range distance can be carried out,which is difficult to achieve in practical situations.An LFM radar source passive localization algorithm based on range migration is proposed to address the dif-ficulty in estimating frequency offset.The algorithm first provides a rough estimate of the pulse repetition time(PRT).It processes intercepted signals through range compression,range interpola-tion,and polynomial fitting to obtain range migration observations.Subsequently,it uses the changing information of range migration and an accurate PRT to formulate a system of nonlinear equations,obtaining the emitter position and a more accurate PRT through a two-step localization algorithm.Frequency offset only induces a fixed offset in range migration,which does not affect the changing information.This algorithm can also achieve high-precision localization in squint scenar-ios.Finally,the effectiveness of this algorithm is verified through simulations. 展开更多
关键词 passive localization range migration residual frequency offset
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Detection of UAV Target Based on Continuous Radon Transform and Matched Filtering Process for Passive Bistatic Radar
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作者 Luo Zuo Yuefei Yan +6 位作者 Jun Wang Xin Sang Yan Wang Dongming Ge Lihao Ping Zhihai Wang Congsi Wang 《Journal of Beijing Institute of Technology》 EI CAS 2024年第1期9-18,共10页
Long-time integration technique is an effective way of improving target detection performance for unmanned aerial vehicle(UAV)in the passive bistatic radar(PBR),while range migration(RM)and Doppler frequency migration... Long-time integration technique is an effective way of improving target detection performance for unmanned aerial vehicle(UAV)in the passive bistatic radar(PBR),while range migration(RM)and Doppler frequency migration(DFM)may have a major effect due to the target maneuverability.This paper proposed an innovative long-time coherent integration approach,regarded as Continuous Radon-matched filtering process(CRMFP),for low-observable UAV target in passive bistatic radar.It not only mitigates the RM by collaborative research in range and velocity dimensions but also compensates the DFM and ensures the coherent integration through the matched filtering process(MFP).Numerical and real-life data following detailed analysis verify that the proposed method can overcome the Doppler mismatch influence and acquire comparable detection performance. 展开更多
关键词 passive bistatic radar unmanned aerial vehicle long-time coherent integration Radon-matched filtering process
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Low-energy-consumption temperature swing system for CO_(2) capture by combining passive radiative cooling and solar heating
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作者 Ying-Xi Dang Peng Tan +3 位作者 Bin Hu Chen Gu Xiao-Qin Liu Lin-Bing Sun 《Green Energy & Environment》 SCIE EI CAS CSCD 2024年第3期507-515,共9页
Temperature-swing adsorption(TSA)is an effective technique for CO_(2) capture,but the temperature swing procedure is energy-intensive.Herein,we report a low-energy-consumption system by combining passive radiative coo... Temperature-swing adsorption(TSA)is an effective technique for CO_(2) capture,but the temperature swing procedure is energy-intensive.Herein,we report a low-energy-consumption system by combining passive radiative cooling and solar heating for the uptake of CO_(2) on commercial activated carbons(CACs).During adsorption,the adsorbents are coated with a layer of hierarchically porous poly(vinylidene fluoride-co-hexafluoropropene)[P(VdF-HFP)HP],which cools the adsorbents to a low temperature under sunlight through radiative cooling.For desorption,CACs with broad absorption of the solar spectrum are exposed to light irradiation for heating.The heating and cooling processes are completely driven by solar energy.Adsorption tests under mimicked sunlight using the CACs show that the performance of this system is comparable to that of the traditional ones.Furthermore,under real sunlight irradiation,the adsorption capacity of the CACs can be well maintained after multiple cycles.The present work may inspire the development of new temperature swing procedures with little energy consumption. 展开更多
关键词 CO_(2)capture Solar heating passive radiative cooling Temperature swing adsorption
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Coarse-fine joint target parameter estimation method based on AN-RSC in OFDM passive radar
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作者 WANG Chujun WAN Xianrong +1 位作者 YI Jianxin CHENG Feng 《Journal of Systems Engineering and Electronics》 SCIE CSCD 2024年第2期339-349,共11页
In this paper,we study the accuracy of delay-Doppler parameter estimation of targets in a passive radar using orthogonal frequency division multiplexing(OFDM)signal.A coarse-fine joint estimation method is proposed to... In this paper,we study the accuracy of delay-Doppler parameter estimation of targets in a passive radar using orthogonal frequency division multiplexing(OFDM)signal.A coarse-fine joint estimation method is proposed to achieve better estimation accuracy of target parameters without excessive computational burden.Firstly,the modulation symbol domain(MSD)method is used to roughly estimate the delay and Doppler of targets.Then,to obtain high-precision Doppler estimation,the atomic norm(AN)based on the multiple measurement vectors(MMV)model(MMV-AN)is used to manifest the signal sparsity in the continuous Doppler domain.At the same time,a reference signal compensation(RSC)method is presented to obtain highprecision delay estimation.Simulation results based on the OFDM signal show that the coarse-fine joint estimation method based on AN-RSC can obtain a more accurate estimation of target parameters compared with other algorithms.In addition,the proposed method also possesses computational advantages compared with the joint parameter estimation. 展开更多
关键词 passive radar orthogonal frequency division multiplexing(OFDM)signal atomic norm(AN) parameter estimation
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The Effects of Thickness and Location of PCMon the Building’s Passive Temperature-Control–A Numerical Study
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作者 Zhengrong Shi JieRen +1 位作者 Tao Zhang Yanming Shen 《Energy Engineering》 EI 2024年第3期681-702,共22页
Building energy consumption and building carbon emissions both account for more than 20%of their total national values in China.Building employing phase change material(PCM)for passive temperature control shows a prom... Building energy consumption and building carbon emissions both account for more than 20%of their total national values in China.Building employing phase change material(PCM)for passive temperature control shows a promising prospect in meeting the comfort demand and reducing energy consumption simultaneously.However,there is a lack of more detailed research on the interaction between the location and thickness of PCM and indoor natural convection,as well as indoor temperature distribution.In this study,the numerical model of a passive temperature-controlled building integrating the developed PCM module is established with the help of ANSYS.In which,the actual weather condition of Beijing city is set as the boundary conditions and the indoor natural convection is simulated with the consideration of radiation model.The effects of PCM’s thickness and location on the internal temperature field are analyzed and discussed.The results show that the room could maintain within the human comfort temperature range with the longest ratio of 94.10%and the shortest ratio of 51.04%as integrating PCM.In comparison,the value is only 26.70%without PCM.The room’s maximum temperature fluctuation can also be improved;it could be lowered by 64.4%compared to the normal condition.When the quantity of PCM is sufficient,further increasing the PCM amount results in a temperature fluctuation reduction of less than 0.1°C and does not increase the comfort time.Placing PCM on the wall induces an apparent variation in indoor temperature along the vertical direction.Conversely,placing PCM on the roof can lead to a heat transfer rate difference of up to seven times.The optimal placement of PCM depends on the difference between the environmental and phase change temperatures.If the difference is positive,placing PCM on the roof is more effective;conversely,the opposite holds.According to the results over the entire cycle,PCM application on vertical walls yields better performance.The significant difference in natural convection caused by the same thickness of PCM but different application positions,coupled with the influence of air movement on the melting and solidification of PCM,further impacts indoor temperature fluctuations and comfort.This study can provide guidance for the application location and thickness of PCM,especially for scenarios where temperature regulation is required at a specific time. 展开更多
关键词 Phase change materials passive temperature regulation numerical simulation temperature field
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Equalization Reconstruction Algorithm Based on Reference Signal Frequency Domain Block Joint for DTMB-Based Passive Radar
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作者 Shuai Ma Zeqi Yang +2 位作者 Hua Zhang Yiheng Liu Xiaode Lyu 《Journal of Beijing Institute of Technology》 EI CAS 2024年第1期41-53,共13页
Channel equalization plays a pivotal role within the reconstruction phase of passive radar reference signals.In the context of reconstructing digital terrestrial multimedia broadcasting(DTMB)signals for low-slow-small... Channel equalization plays a pivotal role within the reconstruction phase of passive radar reference signals.In the context of reconstructing digital terrestrial multimedia broadcasting(DTMB)signals for low-slow-small(LSS)target detection,a novel frequency domain block joint equalization algorithm is presented in this article.From the DTMB signal frame structure and channel multipath transmission characteristics,this article adopts a unconventional approach where the delay and frame structure of each DTMB signal frame are reconfigured to create a circular convolution block,facilitating concurrent fast Fourier transform(FFT)calculations.Following equalization,an inverse fast Fourier transform(IFFT)-based joint output and subsequent data reordering are executed to finalize the equalization process for the DTMB signal.Simulation and measured data confirm that this algorithm outperforms conventional techniques by reducing signal errors rate and enhancing real-time processing.In passive radar LSS detection,it effectively suppresses multipath and noise through frequency domain equalization,reducing false alarms and improving the capabilities of weak target detection. 展开更多
关键词 passive radar frequency domain equalization reference signal reconstruction digital terrestrial multimedia broadcasting(DTMB)
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The Economic Demands on the Method of Founding a Passive Brick House on Foamed Glass Granulate
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作者 Marek Jašek 《Journal of Civil Engineering and Architecture》 2024年第5期218-222,共5页
The cost of acquisition of a passive house is a little higher than that of a conventional house.Proper design of a passive house should include not only thermal protection and stability of the construction,but it must... The cost of acquisition of a passive house is a little higher than that of a conventional house.Proper design of a passive house should include not only thermal protection and stability of the construction,but it must also take into account the price demands on each of the proposed structures and solution of details.The paper deals with the financial comparison of the traditional method of a foundation on the foundation strips of plain concrete and the modern method of founding a passive house as brick construction on the reinforced concrete slab base with a compact subsoil layer of thermal insulation in the form of granules of foamed glass. 展开更多
关键词 passive house financial comparison granules of foamed glass
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重放攻击下多智能体系统H_(∞)一致性PID控制
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作者 宋金波 董宏丽 +1 位作者 申雨轩 侯男 《控制理论与应用》 EI CAS CSCD 北大核心 2024年第4期658-666,共9页
本文针对一类带有加性噪声和乘性噪声的离散多智能体系统,研究重放攻击下多智能体系统的H_(∞)一致性比例-积分-微分(PID)控制问题.首先,根据智能体的测量输出设计状态观测器,对智能体的状态进行有效估计,观测器设计过程中考虑了系统测... 本文针对一类带有加性噪声和乘性噪声的离散多智能体系统,研究重放攻击下多智能体系统的H_(∞)一致性比例-积分-微分(PID)控制问题.首先,根据智能体的测量输出设计状态观测器,对智能体的状态进行有效估计,观测器设计过程中考虑了系统测量输出从传感器传输到观测器过程中受到重放网络攻击的影响.然后,利用智能体与其邻居智能体的估计状态差设计PID控制器.利用李雅普诺夫稳定性理论和代数图论,证明在该控制策略下,多智能体系统在重放攻击存在的情况下达到预期的H_(∞)性能指标.最后,利用线性矩阵不等式(LMI)方法求解观测器和控制器增益,利用数值仿真验证了所设计的观测器和PID控制器的有效性. 展开更多
关键词 多智能体 重放攻击 PID控制 h_(∞)性能 观测器
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NH_(3)SO_(3)改性稀土尾矿催化剂NH_(3)-SCR脱硝活性及SO_(2)/H_(2)O耐受性能研究
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作者 焦坤灵 焦晓云 +3 位作者 刘佳杰 汪思瀛 李娜 武文斐 《稀有金属与硬质合金》 CAS CSCD 北大核心 2024年第2期32-37,75,共7页
采用球磨、微波焙烧方法制备了不同质量分数NH_(3)SO_(3)改性稀土尾矿NH_(3)-SCR脱硝催化剂。通过BET、SEM-EDS、XRD、NH_(3)-TPD、H_(2)-TPR分析了催化剂脱硝活性及SO_(2)/H_(2)O耐受性能。结果表明:NH_(3)SO_(3)改性使催化剂脱硝活性... 采用球磨、微波焙烧方法制备了不同质量分数NH_(3)SO_(3)改性稀土尾矿NH_(3)-SCR脱硝催化剂。通过BET、SEM-EDS、XRD、NH_(3)-TPD、H_(2)-TPR分析了催化剂脱硝活性及SO_(2)/H_(2)O耐受性能。结果表明:NH_(3)SO_(3)改性使催化剂脱硝活性得到了显著提高,10%NH_(3)SO_(3)改性催化剂在300~350℃脱硝活性可达90%左右。SO_(2)/H_(2)O共同作用可将10%NH_(3)SO_(3)改性催化剂脱硝活性提高至97%,其促进作用保持了良好的稳定性,且具有可逆性。NH_(3)SO_(3)改性稀土尾矿后,催化剂比表面积、酸性位点及强度增加,表面活性物质分散度更高,弱化了尾矿矿物晶型,提高了催化剂吸附能力和氧化还原能力,从而提高催化脱硝活性,同时具备优良的SO_(2)/H_(2)O耐受性。 展开更多
关键词 Nh_(3)SO_(3)改性 稀土尾矿 催化剂 Nh_(3)-SCR脱硝 SO_(2)/h_(2)O耐受性能 脱硝活性
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添加剂H_(2)对SNCR脱硝特性的影响
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作者 刘平 王林伟 +3 位作者 李天硕 左言骏 刘猛 段钰锋 《电力科技与环保》 2024年第2期108-115,共8页
在管式炉上探讨了选择性非催化还原的脱硝特性,分析了有无气体添加剂H_(2)在不同氨氮比(normalized stoichiometric ratio,NSR)下的N_(2)O、NO、NH_(3)、SO_(2)的排放特性及其随温度的变化规律。分析结果表明:无添加剂的情况下,在温度87... 在管式炉上探讨了选择性非催化还原的脱硝特性,分析了有无气体添加剂H_(2)在不同氨氮比(normalized stoichiometric ratio,NSR)下的N_(2)O、NO、NH_(3)、SO_(2)的排放特性及其随温度的变化规律。分析结果表明:无添加剂的情况下,在温度870℃、NSR为2.0时,NO最大还原效率为90%;N_(2)O生成浓度和NO还原效率的变化趋势接近,NSR越大,NO还原效率越高,N_(2)O排放浓度越大;NO还原温度窗口与N_(2)O生成的温度窗口基本上吻合。氨逃逸量在低于750℃时,明显增大,在高于850℃时,趋于0;SO_(2)浓度随温度的升高呈现与氨逃逸相反的变化趋势;随着H_(2)添加量的增大,NO还原温度窗口显著拓宽,且向低温移动,添加后最大NO还原效率超过90%,对应温度为820℃左右;N_(2)O浓度随温度呈先上升后下降的趋势,随H_(2)添加量的增加,低温区的N_(2)O浓度升高,且峰值向低温区移动,温度窗口变宽;氨逃逸量随温度升高先增大后降低,且这种趋势在低温区更明显,反应温度超过850℃,不同添加比下的氨逃逸量趋于0;添加比对SO_(2)浓度的影响在低温和高温段都不明显,SO_(2)浓度与氨逃逸量呈现相反的变化趋势。所述H_(2)添加后的污染物排放规律可为同类研究提供参考。 展开更多
关键词 SNCR 添加剂 h_(2) N_(2)O排放 脱硝特性
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非线性系统无需初始条件预设性能有界H_(∞)容错控制
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作者 李小华 程鸿展 刘辉 《控制理论与应用》 EI CAS CSCD 北大核心 2024年第2期273-282,共10页
针对一类具有外部扰动和传感器故障的非线性系统,本文研究了其自适应预设性能有界H_(∞) 容错控制问题.本文提出一种新的预设性能控制设计方法,使得预设性能函数的选择与系统被约束变量的初始状态完全无关,用一种全新的方式解决了传统... 针对一类具有外部扰动和传感器故障的非线性系统,本文研究了其自适应预设性能有界H_(∞) 容错控制问题.本文提出一种新的预设性能控制设计方法,使得预设性能函数的选择与系统被约束变量的初始状态完全无关,用一种全新的方式解决了传统预设性能方法的控制效果依赖被约束变量初始条件的问题.基于该设计方法和有界H_(∞) 控制方法,在未知系统初始条件的情况下获得了系统的自适应预设性能有界H_(∞) 控制器.本文所设计的控制器能够保证系统中的所有信号都是有界稳定的,系统的输出变量能够被预设性能函数约束,并且对于外部干扰具有很好的抑制作用.最后,仿真结果验证了该控制器的可行性及有效性. 展开更多
关键词 非线性系统 传感器故障 预设性能控制 无需初始条件 有界h_(∞)控制 容错控制
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基于改进粒子群优化权函数的直流微电网H_(∞)控制策略
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作者 马文忠 王源航 +3 位作者 高健壹 李维国 么旻蕊 黄建伟 《现代电力》 北大核心 2024年第3期431-440,共10页
直流微电网中常常含有恒功率负载(constant power loads,CPLs),其负阻抗特性会降低系统的稳定性,造成直流母线电压波动甚至崩溃。因此,首先建立了直流微电网的小信号模型,使用根轨迹法分析了恒功率负载对系统稳定性的影响;其次提出一种... 直流微电网中常常含有恒功率负载(constant power loads,CPLs),其负阻抗特性会降低系统的稳定性,造成直流母线电压波动甚至崩溃。因此,首先建立了直流微电网的小信号模型,使用根轨迹法分析了恒功率负载对系统稳定性的影响;其次提出一种基于混合灵敏度优化的电压控制策略,提升了直流微电网系统的稳定性,并采用改进粒子群优化(particle swarm optimization,PSO)算法对权函数进行了优化,进一步提升了鲁棒控制器的性能;最后采用Matlab/Simulink仿真算例进行验证,仿真结果表明提出的鲁棒控制器减小了母线电压的波动,有效提升了直流微电网系统的稳定性。 展开更多
关键词 直流微电网 稳定性分析 母线电压 h_(∞)控制 粒子群算法
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三阶三次幂非线性混沌电路的自适应反馈控制和H_(∞)控制
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作者 付景超 杨阳 《吉林大学学报(理学版)》 CAS 北大核心 2024年第3期713-720,共8页
针对三阶三次幂非线性混沌电路,研究其控制问题.首先,给出系统的Lyapunov指数和混沌吸引子,验证系统存在复杂的混沌现象;其次,用自适应反馈控制方法和H_(∞)状态反馈控制方法,设计参数已知和参数未知的自适应反馈控制器以及H_(∞)状态... 针对三阶三次幂非线性混沌电路,研究其控制问题.首先,给出系统的Lyapunov指数和混沌吸引子,验证系统存在复杂的混沌现象;其次,用自适应反馈控制方法和H_(∞)状态反馈控制方法,设计参数已知和参数未知的自适应反馈控制器以及H_(∞)状态反馈控制器,将混沌系统状态稳定到平衡点上;最后,通过MATLAB软件进行数值仿真验证控制器的有效性,并对两种控制器的控制效果进行比较. 展开更多
关键词 三次幂非线性混沌电路 自适应反馈控制 h_(∞)状态反馈控制 LYAPUNOV指数
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含时滞的不确定性交直流微电网直流母线电压H_∞控制
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作者 肖伸平 廖世英 +2 位作者 张晓虎 郑湘明 邓博文 《电力自动化设备》 EI CSCD 北大核心 2024年第4期184-189,217,共7页
针对含通信网络延时的不确定性交直流微电网的直流母线电压稳定问题,提出了一种将状态空间法和阻抗分析法相融合的方法,构建具有时滞的范数有界不确定交直流微电网模型。基于系统鲁棒二次稳定的求解,获得了满足H_∞控制性能的时滞无关... 针对含通信网络延时的不确定性交直流微电网的直流母线电压稳定问题,提出了一种将状态空间法和阻抗分析法相融合的方法,构建具有时滞的范数有界不确定交直流微电网模型。基于系统鲁棒二次稳定的求解,获得了满足H_∞控制性能的时滞无关型状态反馈控制器的条件。然后应用S-procedure定理,提出一种降低时滞依赖型Lyapunov方法的泛函构造难度且无须再次求导的方法,引用Wirtinger积分不等式和自由矩阵的积分不等式,得到时滞依赖型的H_∞控制器。仿真分析验证了所提控制方法能在一定的通信延时约束下抑制不确定参数对直流母线电压的影响。 展开更多
关键词 h_∞控制器 交直流微电网 直流母线电压 不确定系统 时滞系统
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新标09CrCuSb耐酸钢的耐50%H_(2)SO_(4)腐蚀性能
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作者 郑健 张佳伟 +3 位作者 袁渊 张成元 黄峰 刘静 《腐蚀与防护》 CAS CSCD 北大核心 2024年第4期8-13,共6页
通过电化学测试和全浸腐蚀试验,研究了不同温度(25,50,60,70℃)条件下新标09CrCuSb耐酸钢在50%H_(2)SO_(4)溶液中的腐蚀行为。结果表明:随着温度从25℃升至70℃,新标09CrCuSb钢的腐蚀速率整体呈现增大趋势,在70℃时,腐蚀速率达到最高,为... 通过电化学测试和全浸腐蚀试验,研究了不同温度(25,50,60,70℃)条件下新标09CrCuSb耐酸钢在50%H_(2)SO_(4)溶液中的腐蚀行为。结果表明:随着温度从25℃升至70℃,新标09CrCuSb钢的腐蚀速率整体呈现增大趋势,在70℃时,腐蚀速率达到最高,为2.70 g/(m^(2)·h),这与随温度升高,腐蚀产物中具有保护性作用的Fe_(3)O_(4)含量减少,无保护作用的FeSO_(4)·H_(2)O含量增加以及锈层中微孔变化有关。另外,由于新标调整了09CrCuSb钢中Cu、Mo、Sn、Sb、W等元素的含量,与旧标09CrCuSb钢相比,阳极维钝电流密度J维钝降低,同等温度条件下,新标09CrCuSb钢的耐蚀性得到较大改善。 展开更多
关键词 新标09CrCuSb耐酸钢 50%h_(2)SO_(4)溶液 腐蚀 温度影响
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H_(2)与氨混燃增强火焰燃烧特性模拟研究
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作者 赵争辉 李航锦 +2 位作者 吴超杭 尹倩倩 王睿坤 《电力科技与环保》 2024年第1期18-27,共10页
氢和氨作为清洁能源受到广泛关注,为深入探究氢-氨混燃的燃烧特性和影响因素,本文借助Chemkin仿真平台建立相关反应模型,以氢-氨混合气体为燃料,空气作为助燃剂,采用Otomo等人提出的一种氨氧化机理对其燃烧过程进行模拟计算,并模拟研究... 氢和氨作为清洁能源受到广泛关注,为深入探究氢-氨混燃的燃烧特性和影响因素,本文借助Chemkin仿真平台建立相关反应模型,以氢-氨混合气体为燃料,空气作为助燃剂,采用Otomo等人提出的一种氨氧化机理对其燃烧过程进行模拟计算,并模拟研究了混合气体的点火延迟时间、层流燃烧速度、绝热燃烧温度、NO排放等燃烧特性随当量比、初始压力以及燃料中H_(2)比例的具体变化规律,对不同工况下的层流火焰结构、H和OH自由基的产率(rate of production,ROP)、NO生成的敏感度进行了化学动力学分析。结果表明:纯氨气体的点火延迟时间长、层流燃烧速度慢,掺氢后燃烧特性均有所改善,且提高了火焰的绝热燃烧温度,但掺氢比例越大,NO排放越多。NO摩尔分数随当量比变化的趋势先增后减,在当量比为0.8左右达到峰值。综合考虑氢-氨混燃的一系列燃烧特性以及掺氢、加压的成本和收益情况,推荐H_(2)占比15%、当量比φ=1.1、压力P=0.2 MPa为氢-氨混合燃烧的最优条件。 展开更多
关键词 h_(2) Nh_(3) 混合燃烧 层流燃烧特性 数值模拟研究
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温度对UNS N08825合金在高含H_(2)S环境中耐腐蚀性能的影响
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作者 李科 李天雷 +5 位作者 张诚 姜流 崔磊 施岱艳 曹晓燕 钟显康 《机械工程材料》 CAS CSCD 北大核心 2024年第4期76-82,共7页
在不同温度(80,90,110,132℃)、高压、高含H2S和高含氯离子环境中对UNS N08825合金进行了72 h浸泡和电化学腐蚀试验,研究了温度对合金耐腐蚀性能的影响,分析了其影响机理。结果表明:在80℃下试验合金几乎不发生腐蚀,90,110,132℃下合金... 在不同温度(80,90,110,132℃)、高压、高含H2S和高含氯离子环境中对UNS N08825合金进行了72 h浸泡和电化学腐蚀试验,研究了温度对合金耐腐蚀性能的影响,分析了其影响机理。结果表明:在80℃下试验合金几乎不发生腐蚀,90,110,132℃下合金表面出现黑色腐蚀产物,并且110,132℃下的腐蚀产物增多且呈疏松多孔特征;随着温度升高,合金表面的点蚀坑数量增多且深度增加,最大点蚀速率和均匀腐蚀速率均增大;随着温度升高,试验合金的自腐蚀电位、电荷转移电阻和钝化膜电阻减小,自腐蚀电流密度增大。当温度低于90℃时,合金表面钝化膜均匀致密,点蚀敏感性低,具有较好的耐腐蚀性能;当温度不低于90℃时,元素硫的水解加剧,合金表面钝化膜发生破坏,点蚀更易发生,耐腐蚀性能变差。 展开更多
关键词 高温高压 UNS N08825合金 h_(2)S 氯离子 电化学 点蚀
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^(10)BF_(3)制备H_(3)^(10)BO_(3)反应进程在线监测
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作者 周文辉 胡石林 +1 位作者 张彦彪 周秀林 《原子能科学技术》 EI CAS CSCD 北大核心 2024年第6期1304-1310,共7页
工业规模生产富集^(10)B的硼酸(H_(3)^(10)BO_(3),^(10)B>19.8%)时需要监测反应的进行程度和判定反应的终点。为解决现有监测方法步骤繁琐、人为误差大、精准度低等问题,本文设计并建造了一套在线监测反应进行程度的实验装置,并采用... 工业规模生产富集^(10)B的硼酸(H_(3)^(10)BO_(3),^(10)B>19.8%)时需要监测反应的进行程度和判定反应的终点。为解决现有监测方法步骤繁琐、人为误差大、精准度低等问题,本文设计并建造了一套在线监测反应进行程度的实验装置,并采用该实验装置对通过富集^(10)B的三氟化硼(^(10)BF_(3),^(10)B>19.8%)与难溶于水的碳酸锶(SrCO_(3))反应制备H_(3)^(10)BO_(3)的实验进行原位、实时、在线监测。测试得到的溶液离子浓度随时间变化的数据曲线可以用c_(t)-c_(1)=c_(0)e^(-kt)公式进行拟合,其拟合系数R^(2)为1.00000。在相同条件下,进行了4次重复性测试实验,得到的4条溶液离子浓度随时间变化的数据曲线用c_(t)-c_(1)=c_(0)e^(-kt)公式拟合,其拟合系数R^(2)都为1.00000,说明用该实验装置进行长时间、多次测试,得到的数据精准度高、误差小、重现性好;且拟合方程的3个参数c1、c0、k的标准偏差(s)均小于0.3%,这说明用c_(t)-c_(1)=c_(0)e^(-kt)方程拟合的精密度高。c_(t)-c_(1)=c_(0)e^(-kt)方程可以用于^(10)BF_(3)制备H_(3)^(10)BO_(3)反应的进行程度监测。实验得到的离子浓度-时间曲线的拟合方程c_(t)-c_(1)=c_(0)e^(-kt)与化学反应的一级动力学方程ct=c_(0)e^(-kt)在表现形式上一致,表明用c_(t)-c_(1)=c_(0)e^(-kt)方程拟合^(10)BF_(3)制备H_(3)^(10)BO_(3)反应的进行程度符合化学反应进行实质,c_(t)-c_(1)=c_(0)e^(-kt)方程能够作为^(10)BF_(3)制备H_(3)^(10)BO_(3)反应进行程度和反应终点的判定依据。^(10)BF_(3)制备H_(3)^(10)BO_(3)较合理的加料方式是难溶固体粉末SrCO_(3)与H2O先混溶,搅拌下形成悬浮液,然后把悬浮液加热至设定温度并保持恒定,再向悬浮液中加入^(10)BF_(3)。在线监测结果表明,^(10)BF_(3)制备H_(3)^(10)BO_(3)需经过3步加羟基脱氟取代反应,其前两步反应是快反应,第3步反应是慢反应,即第3步反应是^(10)BF_(3)制备H_(3)^(10)BO_(3)反应的速率控制步骤。^(10)BF_(3)制备H_(3)^(10)BO_(3)反应为表观化学一级动力学反应。 展开更多
关键词 ^(10)BF_(3) h_(3)^(10)BO_(3) 反应进程 在线监测
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基于TDLAS的H_(2)S气体材料表面吸附特性研究
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作者 金建新 刘威 +3 位作者 宋振明 朱志辉 田冰 彭志敏 《激光与红外》 CAS CSCD 北大核心 2024年第5期710-717,共8页
在H_(2)S气体浓度在线监测过程中,因其具有粘附性强的特点,容易发生管线吸附,从而导致测量结果存在偏差,尤其在痕量H_(2)S检测过程中表现最为明显,所以开展H_(2)S气体管线材料表面吸附特性研究尤为必要。本文基于可调谐二极管激光吸收... 在H_(2)S气体浓度在线监测过程中,因其具有粘附性强的特点,容易发生管线吸附,从而导致测量结果存在偏差,尤其在痕量H_(2)S检测过程中表现最为明显,所以开展H_(2)S气体管线材料表面吸附特性研究尤为必要。本文基于可调谐二极管激光吸收光谱技术(TDLAS),设计并搭建了一套H_(2)S浓度在线测定系统,并对该系统进行了测量性能检验,在此基础上进行了H_(2)S在不锈钢材料表面常温吸附特性探究。实验结果表明,所搭建H_(2)S浓度在线测定系统具有稳定性强、检测限低和灵敏度高的特点,利用此系统可以实现痕量H_(2)S浓度的在线连续测定。经过一系列探究试验,证明了H_(2)S在不锈钢材料表面存在明显且稳定的吸附作用,得出了H_(2)S在不锈钢材料表面的单位面积吸附量在10^(14)(个/cm^(2))量级。实验结果可以为痕量硫化氢在线精准测量提供一定参考。 展开更多
关键词 TDLAS h_(2)S 测量系统 材料表面 吸附特性
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