This work develops 2-Phenyl-1H-imidazole-1-sulfonate(PHIS)as a multi-functional electrolyte additive for H2O/HF scavenging and film formation to improve the high temperature performance of LiNi_(0.8)Co_(0.1)Mn_(0.1)O_...This work develops 2-Phenyl-1H-imidazole-1-sulfonate(PHIS)as a multi-functional electrolyte additive for H2O/HF scavenging and film formation to improve the high temperature performance of LiNi_(0.8)Co_(0.1)Mn_(0.1)O_(2)/graphite batteries.After 450 cycles at room temperature(25℃),the discharge capacity retentions of batteries with blank and PHIS-containing electrolyte are 56.03%and 94.92%respectively.After 230 cycles at high temperatures(45℃),their values are 75.30%and 88.38%respectively.The enhanced electrochemical performance of the batteries with PHIS-containing electrolyte is supported by the spectroscopic characterization and theoretical calculations.It is demonstrated that this PHIS electrolyte additive can facilitate the construction of the electrode interface films,remove the H2O/HF in the electrolyte,and improve the electrochemical performance of the batteries.This work not only develops a sulfonate-based electrolyte but also can stimulate new ideas of functional additives to improve the battery performance.展开更多
This paper considers the robust per formance design problem of the linear systems with both unmodelled dynamics and real parametric uncertainties. We suggest for the first time that the problem can besolved by the H∞...This paper considers the robust per formance design problem of the linear systems with both unmodelled dynamics and real parametric uncertainties. We suggest for the first time that the problem can besolved by the H∞ mixed sensitivity method. The main idea is as follows: Firstly, the original problem istransformed into the robust per formance design problem for a pure parameter uncertain system. Then, theresulting problem is reduced to a standard H∞ control problem which can be solved by the H∞ state feedbacksynthesis method or Doyle’s "DGKF" algorithm.展开更多
The investigation of Thermal performance in nanofluids and hybrid nanofluids over a curved stretching infinite region strengthens its roots in engineering and industry.Therefore,the comparative thermal analysis in SiO...The investigation of Thermal performance in nanofluids and hybrid nanofluids over a curved stretching infinite region strengthens its roots in engineering and industry.Therefore,the comparative thermal analysis in SiO_(2)–H_(2)O and(MoS_(2)–SiO_(2))–H_(2)O is conducted over curved stretching surface.The model is reduced in the dimensional version via similarity transformation and then treated numerically.The velocity and thermal behavior for both the fluids is decorated against the preeminent parameters.From the analysis,it is examined that the motion of under consideration fluids declines against Fr and.The thermal performance enhances for higher volumetric fraction and.Further,it is noticed that thermal performance prevailed in(MoS_(2)–SiO_(2))–H_(2)O throughout the analysis.Therefore,(MoS_(2)–SiO_(2))–H_(2)O is better for industrial and engineering uses where high heat transfer is required to accomplished different processes of production.展开更多
近年来,阻尼力与位移呈线性关系的新型调谐质量阻尼器(Tuned mass damper, TMD)相继出现,其参数分析优化原理大部分属于动力数值分析缺乏理论参数优化指导。该文对白噪声作用下具有上述特性的TMD,即滞变阻尼调谐质量阻尼器(Hysteretic d...近年来,阻尼力与位移呈线性关系的新型调谐质量阻尼器(Tuned mass damper, TMD)相继出现,其参数分析优化原理大部分属于动力数值分析缺乏理论参数优化指导。该文对白噪声作用下具有上述特性的TMD,即滞变阻尼调谐质量阻尼器(Hysteretic damping tuned mass damper, HD-TMD)进行减振优化研究。总结了HD-TMD的力学机理并推导出相应的结构-HD-TMD系统运动方程;提出适用于HD-TMD的H_(2)优化和性能平衡设计,并通过数值拟合技术得到了最优参数公式和基于容忍度的性能平衡设计流程;以真实可用的变摩擦摆式调谐质量阻尼器(VFP-TMD)为HD-TMD的实际算例,检验所提出的优化方法对风振激励的减振性能影响。结果表明:H_(2)优化和性能平衡设计下的HD-TMD可以提供略优于传统黏滞阻尼TMD的控制效果。H_(2)优化的最优参数能使HD-TMD发挥最大的潜能从而实现最好的减振率,但面临VFP-TMD行程过大导致的摆动非线性问题。性能平衡设计下的最优参数可以控制VFP-TMD行程在线性范围内,同时发挥出良好且稳定的减振控制效果实现双赢。与最优参数公式结果相比,性能平衡设计的峰值减振率和均方差峰值减振率仅损失3.19%和0.74%。展开更多
Lithium-ion batteries(LIBs)featuring a Ni-rich cathode exhibit increased specific capacity,but the establishment of a stable interphase through the implementation of a functional electrolyte strategy remains challengi...Lithium-ion batteries(LIBs)featuring a Ni-rich cathode exhibit increased specific capacity,but the establishment of a stable interphase through the implementation of a functional electrolyte strategy remains challenging.Especially when the battery is operated under high temperature,the trace water present in the electrolyte will accelerate the hydrolysis of the electrolyte and the resulting HF will further erode the interphase.In order to enhance the long-term cycling performance of graphite/LiNi_(0.8)Co_(0.1)Mn_(0.1)O_(2)(NCM811)LIBs,herein,Tolylene-2,4-diisocyanate(TDI)additive containing lone-pair electrons is employed to formulate a novel bifunctional electrolyte aimed at eliminating H_(2)O/HF generated at elevated temperature.After 1000 cycles at 25℃,the battery incorporating the TDI-containing electrolyte exhibits an impressive capacity retention of 94%at 1 C.In contrast,the battery utilizing the blank electrolyte has a lower capacity retention of only 78%.Furthermore,after undergoing 550 cycles at 1 C under45℃,the inclusion of TDI results in a notable enhancement of capacity,increasing it from 68%to 80%.This indicates TDI has a favorable influence on the cycling performance of LIBs,especially at elevated temperatures.The analysis of the film formation mechanism suggests that the lone pair of electrons of the isocyanate group in TDI play a crucial role in inhibiting the generation of H_(2)O and HF,which leads to the formation of a thin and dense interphase.The existence of this interphase is thought to substantially enhance the cycling performance of the LIBs.This work not only improves the performance of graphite/NCM811 batteries at room temperature and high temperature by eliminating H_(2)O/HF but also presents a novel strategy for advancing functional electrolyte development.展开更多
Vanadium oxide cathode materials with stable crystal structure and fast Zn^(2+) storage capabilities are extremely important to achieving outstanding electrochemical performance in aqueous zinc‐ion batteries.In this ...Vanadium oxide cathode materials with stable crystal structure and fast Zn^(2+) storage capabilities are extremely important to achieving outstanding electrochemical performance in aqueous zinc‐ion batteries.In this work,a one‐step hydrothermal method was used to manipulate the bimetallic ion intercalation into the interlayer of vanadium oxide.The pre‐intercalated Cu ions act as pillars to pin the vanadium oxide(V‐O)layers,establishing stabilized two‐dimensional channels for fast Zn^(2+) diffusion.The occupation of Mn ions between V‐O interlayer further expands the layer spacing and increases the concentration of oxygen defects(Od),which boosts the Zn^(2+) diffusion kinetics.As a result,as‐prepared Cu_(0.17)Mn_(0.03)V_(2)O_(5−□)·2.16H_(2)O cathode shows outstanding Zn‐storage capabilities under room‐and lowtemperature environments(e.g.,440.3 mAh g^(−1) at room temperature and 294.3 mAh g^(−1)at−60°C).Importantly,it shows a long cycling life and high capacity retention of 93.4%over 2500 cycles at 2 A g^(−1) at−60°C.Furthermore,the reversible intercalation chemistry mechanisms during discharging/charging processes were revealed via operando X‐ray powder diffraction and ex situ Raman characterizations.The strategy of a couple of 3d transition metal doping provides a solution for the development of superior room‐/lowtemperature vanadium‐based cathode materials.展开更多
基金financially supported by the Scientific and Technological Plan Projects of Guangzhou City(202103040001)。
文摘This work develops 2-Phenyl-1H-imidazole-1-sulfonate(PHIS)as a multi-functional electrolyte additive for H2O/HF scavenging and film formation to improve the high temperature performance of LiNi_(0.8)Co_(0.1)Mn_(0.1)O_(2)/graphite batteries.After 450 cycles at room temperature(25℃),the discharge capacity retentions of batteries with blank and PHIS-containing electrolyte are 56.03%and 94.92%respectively.After 230 cycles at high temperatures(45℃),their values are 75.30%and 88.38%respectively.The enhanced electrochemical performance of the batteries with PHIS-containing electrolyte is supported by the spectroscopic characterization and theoretical calculations.It is demonstrated that this PHIS electrolyte additive can facilitate the construction of the electrode interface films,remove the H2O/HF in the electrolyte,and improve the electrochemical performance of the batteries.This work not only develops a sulfonate-based electrolyte but also can stimulate new ideas of functional additives to improve the battery performance.
文摘This paper considers the robust per formance design problem of the linear systems with both unmodelled dynamics and real parametric uncertainties. We suggest for the first time that the problem can besolved by the H∞ mixed sensitivity method. The main idea is as follows: Firstly, the original problem istransformed into the robust per formance design problem for a pure parameter uncertain system. Then, theresulting problem is reduced to a standard H∞ control problem which can be solved by the H∞ state feedbacksynthesis method or Doyle’s "DGKF" algorithm.
文摘The investigation of Thermal performance in nanofluids and hybrid nanofluids over a curved stretching infinite region strengthens its roots in engineering and industry.Therefore,the comparative thermal analysis in SiO_(2)–H_(2)O and(MoS_(2)–SiO_(2))–H_(2)O is conducted over curved stretching surface.The model is reduced in the dimensional version via similarity transformation and then treated numerically.The velocity and thermal behavior for both the fluids is decorated against the preeminent parameters.From the analysis,it is examined that the motion of under consideration fluids declines against Fr and.The thermal performance enhances for higher volumetric fraction and.Further,it is noticed that thermal performance prevailed in(MoS_(2)–SiO_(2))–H_(2)O throughout the analysis.Therefore,(MoS_(2)–SiO_(2))–H_(2)O is better for industrial and engineering uses where high heat transfer is required to accomplished different processes of production.
文摘近年来,阻尼力与位移呈线性关系的新型调谐质量阻尼器(Tuned mass damper, TMD)相继出现,其参数分析优化原理大部分属于动力数值分析缺乏理论参数优化指导。该文对白噪声作用下具有上述特性的TMD,即滞变阻尼调谐质量阻尼器(Hysteretic damping tuned mass damper, HD-TMD)进行减振优化研究。总结了HD-TMD的力学机理并推导出相应的结构-HD-TMD系统运动方程;提出适用于HD-TMD的H_(2)优化和性能平衡设计,并通过数值拟合技术得到了最优参数公式和基于容忍度的性能平衡设计流程;以真实可用的变摩擦摆式调谐质量阻尼器(VFP-TMD)为HD-TMD的实际算例,检验所提出的优化方法对风振激励的减振性能影响。结果表明:H_(2)优化和性能平衡设计下的HD-TMD可以提供略优于传统黏滞阻尼TMD的控制效果。H_(2)优化的最优参数能使HD-TMD发挥最大的潜能从而实现最好的减振率,但面临VFP-TMD行程过大导致的摆动非线性问题。性能平衡设计下的最优参数可以控制VFP-TMD行程在线性范围内,同时发挥出良好且稳定的减振控制效果实现双赢。与最优参数公式结果相比,性能平衡设计的峰值减振率和均方差峰值减振率仅损失3.19%和0.74%。
基金financially supported by the Scientific and Technological Plan Projects of Guangzhou City(202103040001),P.R.Chinathe Project of Science and Technology Department of Henan Province(222102240074)the Key Research Programs of Higher Education Institutions of Henan Province(24B150009)。
文摘Lithium-ion batteries(LIBs)featuring a Ni-rich cathode exhibit increased specific capacity,but the establishment of a stable interphase through the implementation of a functional electrolyte strategy remains challenging.Especially when the battery is operated under high temperature,the trace water present in the electrolyte will accelerate the hydrolysis of the electrolyte and the resulting HF will further erode the interphase.In order to enhance the long-term cycling performance of graphite/LiNi_(0.8)Co_(0.1)Mn_(0.1)O_(2)(NCM811)LIBs,herein,Tolylene-2,4-diisocyanate(TDI)additive containing lone-pair electrons is employed to formulate a novel bifunctional electrolyte aimed at eliminating H_(2)O/HF generated at elevated temperature.After 1000 cycles at 25℃,the battery incorporating the TDI-containing electrolyte exhibits an impressive capacity retention of 94%at 1 C.In contrast,the battery utilizing the blank electrolyte has a lower capacity retention of only 78%.Furthermore,after undergoing 550 cycles at 1 C under45℃,the inclusion of TDI results in a notable enhancement of capacity,increasing it from 68%to 80%.This indicates TDI has a favorable influence on the cycling performance of LIBs,especially at elevated temperatures.The analysis of the film formation mechanism suggests that the lone pair of electrons of the isocyanate group in TDI play a crucial role in inhibiting the generation of H_(2)O and HF,which leads to the formation of a thin and dense interphase.The existence of this interphase is thought to substantially enhance the cycling performance of the LIBs.This work not only improves the performance of graphite/NCM811 batteries at room temperature and high temperature by eliminating H_(2)O/HF but also presents a novel strategy for advancing functional electrolyte development.
基金National Natural Science Foundation of China,Grant/Award Numbers:52372188,51902090,51922008,520721142023 Introduction of studying abroad talent program,the China Postdoctoral Science Foundation,Grant/Award Number:2019 M652546+3 种基金Xinxiang Major Science and Technology Projects,Grant/Award Number:21ZD001Henan Province Postdoctoral Start‐Up Foundation,Grant/Award Number:1901017Henan Center for Outstanding Overseas Scientists,Grant/Award Number:GZS2018003Overseas Expertise Introduction Project for Discipline Innovation,Grant/Award Number:D17007。
文摘Vanadium oxide cathode materials with stable crystal structure and fast Zn^(2+) storage capabilities are extremely important to achieving outstanding electrochemical performance in aqueous zinc‐ion batteries.In this work,a one‐step hydrothermal method was used to manipulate the bimetallic ion intercalation into the interlayer of vanadium oxide.The pre‐intercalated Cu ions act as pillars to pin the vanadium oxide(V‐O)layers,establishing stabilized two‐dimensional channels for fast Zn^(2+) diffusion.The occupation of Mn ions between V‐O interlayer further expands the layer spacing and increases the concentration of oxygen defects(Od),which boosts the Zn^(2+) diffusion kinetics.As a result,as‐prepared Cu_(0.17)Mn_(0.03)V_(2)O_(5−□)·2.16H_(2)O cathode shows outstanding Zn‐storage capabilities under room‐and lowtemperature environments(e.g.,440.3 mAh g^(−1) at room temperature and 294.3 mAh g^(−1)at−60°C).Importantly,it shows a long cycling life and high capacity retention of 93.4%over 2500 cycles at 2 A g^(−1) at−60°C.Furthermore,the reversible intercalation chemistry mechanisms during discharging/charging processes were revealed via operando X‐ray powder diffraction and ex situ Raman characterizations.The strategy of a couple of 3d transition metal doping provides a solution for the development of superior room‐/lowtemperature vanadium‐based cathode materials.
