The distribution and characteristics of seven heavy metals in sediments located in the typical ecological units （eco-units） （e.g., rivers, lakes, and estuaries） of Haihe River Basin were analyzed. The Hakanson pot...The distribution and characteristics of seven heavy metals in sediments located in the typical ecological units （eco-units） （e.g., rivers, lakes, and estuaries） of Haihe River Basin were analyzed. The Hakanson potential ecological risk index was used for ecological risk assessment. The results indicated that the concentration scales of As, Hg, Cr, Cd, Pb, Cu, and Zn in the eco-units were 2.08 to 24.80 mg·g-1, 0.01 to 1135.50 mg·g-1, 28.70 to 152.73mg·g-1, 0.03 to 195765.83mg·g-1, 8.65 to 157.82mg·g-1, 6.47 to 178.61mg·g-1, and 21.09 to 1076.25 mg·g-1, respectively. The maximum concentra- tions of Hg, Cd, and Zn showed higher levels than other water bodies around the world. Hg and Cd have high concentrations in Zhangweinanhe River （1135.50 and 195765.83mg·g-1, respectively） and Haihe Estuary （790.50 and 548.47 mg·g-1, respectively）. According to the ecological factor, Cd and Hg showed very strong ecological risks. The seven heavy metals, namely, Cd, Hg, As, Cr, Pb, Cu, and Zn, exhibited ecological risk levels in descending order. Based on the potential ecological risk index, Luanhe River and Baiyangdian Lake had moderate ecological risks, whereas every site in Zhangweinanhe River and Haihe Estuary had substantial risk levels. The risk order of the typical eco-units are as follows： Zhangweinan River （2278345.68） 〉 Estuary （161914.74） 〉 Luanhe River （191.54）〉Baiyangdian Lake （120.95）. These results provided a scientific basis for water environment improve- ment and risk management of the Haihe River Basin.展开更多
Global ecosystems and public health have been greatly impacted by the accumulation of heavy metal(loid)s in water.Source-specific risk apportionment is needed to prevent and manage potential groundwater contamination ...Global ecosystems and public health have been greatly impacted by the accumulation of heavy metal(loid)s in water.Source-specific risk apportionment is needed to prevent and manage potential groundwater contamination with heavy metal(loid)s.The heavy metal(loid)s contamination status,water quality,ecological risk,and health risk apportionment of the Shule River Basin groundwater are poorly understood.Therefore,field sampling was performed to explore the water quality and risk of heavy metal(loid)s in the groundwater of the Shule River Basin in northwestern China.A total of 96 samples were collected from the study area to acquire data for water quality and heavy metal(loid)s risk.There was noticeable accumulation of ferrum in the groundwater of the Shule River Basin.The levels of pollution were considered to be moderately low,as evaluated by the degree of contamination,heavy metal evaluation index,heavy metal pollution index,and Nemerow pollution index.The ecological risks were also low.However,an assessment of the water quality index revealed that only 58.34%of the groundwater samples had good water quality.The absolute principal component scores-multiple linear regression model was more suited for this study area than the positive matrix factorization model.There were no obvious noncarcinogenic or carcinogenic concerns for all types of receptors according to the values of the total hazard index and total carcinogenic risk.The human activities and the initial geological environment factor(65.85%)was the major source of noncarcinogenic risk(residential children:87.56%;residential adults:87.52%;recreational children:86.77%;and recreational adults:85.42%),while the industrial activity factor(16.36%)was the major source of carcinogenic risk(residential receptors:87.96%;and recreational receptors:68.73%).These findings provide fundamental and crucial information for reducing the health issues caused by heavy metal(loid)s contamination of groundwater in arid areas.展开更多
The resource development and changes of hydrological regime, sediment and water quality in the Mekong River basin have attracted great attentions. This research aimed to enhance the study on transboundary pollution of...The resource development and changes of hydrological regime, sediment and water quality in the Mekong River basin have attracted great attentions. This research aimed to enhance the study on transboundary pollution of heavy metals in this international river. In this study, eight sampling sites were selected to collect the bed sand samples along the mainstream of the Mekong River. In addition, the contents of 5 heavy metal elements and their spatial variability along the mainstream of the river were analyzed. The geoaccumulation index （l^eo） and potential ecological risk analysis were employed to assess heavy metal pol- lution status in the mainstream of the Mekong River. The results show that the average con- tent of the heavy metal elements Zn is 91.43 mg/kg, Pb is 41.85 mg/kg, and As is 21.84 mg/kg in the bed sands of the Upper Mekong River, which are higher than those （Zn 68.17 mg/kg, Pb 28.22 mg/kg, As 14.97 mg/kg） in the Lower Mekong. The average content of Cr in the Lower Mekong is 418.86 mg/kg, higher than that in the Upper Mekong （42.19 mg/kg）. Luang Prabang has a very high Cr concentration with 762.93 mg/kg and Pakse with 422.90 mg/kg. The concentration of Cu in all of the 8 sampling sites is similar, except for in Jiajiu with 11.70 mg/kg and Jiebei with 7.00 mg/kg. The results of the geoaccumulation index reveal that contaminations caused by Zn and Pb while Pb and As are more than those by Zn in Upper Mekong. Cr is the primary pollutant in the Lower Mekong, especially at Luang Prabang and Pakse. Slight pollution with As also occurs in Pakse. The potential ecological risk index indi- cates that the potential ecological risk of heavy metals in the mainstream of the Mekong River is low. We argue that the pollution of water quality and contamination of heavy metals in bed sediment caused by mining of mineral resources or geochemical background values in the Mekong is not transmitted from the Upper to the Lower Mekong because of the reservoir sedimentation and dilution along the river.展开更多
基金This work was supported by the National Natural Science Foundation of China （Grant No. 41271496）, the National Basic Research Program （No. 2006CB403403） of the Ministry of Science and Technology, and the Program for Changjiang Scholars and Innovative Research Team in University of China （No. IRT0809）.
文摘The distribution and characteristics of seven heavy metals in sediments located in the typical ecological units （eco-units） （e.g., rivers, lakes, and estuaries） of Haihe River Basin were analyzed. The Hakanson potential ecological risk index was used for ecological risk assessment. The results indicated that the concentration scales of As, Hg, Cr, Cd, Pb, Cu, and Zn in the eco-units were 2.08 to 24.80 mg·g-1, 0.01 to 1135.50 mg·g-1, 28.70 to 152.73mg·g-1, 0.03 to 195765.83mg·g-1, 8.65 to 157.82mg·g-1, 6.47 to 178.61mg·g-1, and 21.09 to 1076.25 mg·g-1, respectively. The maximum concentra- tions of Hg, Cd, and Zn showed higher levels than other water bodies around the world. Hg and Cd have high concentrations in Zhangweinanhe River （1135.50 and 195765.83mg·g-1, respectively） and Haihe Estuary （790.50 and 548.47 mg·g-1, respectively）. According to the ecological factor, Cd and Hg showed very strong ecological risks. The seven heavy metals, namely, Cd, Hg, As, Cr, Pb, Cu, and Zn, exhibited ecological risk levels in descending order. Based on the potential ecological risk index, Luanhe River and Baiyangdian Lake had moderate ecological risks, whereas every site in Zhangweinanhe River and Haihe Estuary had substantial risk levels. The risk order of the typical eco-units are as follows： Zhangweinan River （2278345.68） 〉 Estuary （161914.74） 〉 Luanhe River （191.54）〉Baiyangdian Lake （120.95）. These results provided a scientific basis for water environment improve- ment and risk management of the Haihe River Basin.
基金This work was supported by the Kunlun Talent Action Plan of Qinghai Province(E140 WX42)National Natural Science Foundation of China(52179026)Strategy for Water Resource Security in Yellow River Sources。
文摘Global ecosystems and public health have been greatly impacted by the accumulation of heavy metal(loid)s in water.Source-specific risk apportionment is needed to prevent and manage potential groundwater contamination with heavy metal(loid)s.The heavy metal(loid)s contamination status,water quality,ecological risk,and health risk apportionment of the Shule River Basin groundwater are poorly understood.Therefore,field sampling was performed to explore the water quality and risk of heavy metal(loid)s in the groundwater of the Shule River Basin in northwestern China.A total of 96 samples were collected from the study area to acquire data for water quality and heavy metal(loid)s risk.There was noticeable accumulation of ferrum in the groundwater of the Shule River Basin.The levels of pollution were considered to be moderately low,as evaluated by the degree of contamination,heavy metal evaluation index,heavy metal pollution index,and Nemerow pollution index.The ecological risks were also low.However,an assessment of the water quality index revealed that only 58.34%of the groundwater samples had good water quality.The absolute principal component scores-multiple linear regression model was more suited for this study area than the positive matrix factorization model.There were no obvious noncarcinogenic or carcinogenic concerns for all types of receptors according to the values of the total hazard index and total carcinogenic risk.The human activities and the initial geological environment factor(65.85%)was the major source of noncarcinogenic risk(residential children:87.56%;residential adults:87.52%;recreational children:86.77%;and recreational adults:85.42%),while the industrial activity factor(16.36%)was the major source of carcinogenic risk(residential receptors:87.96%;and recreational receptors:68.73%).These findings provide fundamental and crucial information for reducing the health issues caused by heavy metal(loid)s contamination of groundwater in arid areas.
基金The National Key Technologies R＆D Program of China during the 12th Five-Year Plan Period, No.2010BAC09B07 National Natural Science Foundation of China, No.U0933604 The Reservoir＇s Train- ing Projects of Yunnan Mid-Youth Scientific Technical Leader, No.2009CI050
文摘The resource development and changes of hydrological regime, sediment and water quality in the Mekong River basin have attracted great attentions. This research aimed to enhance the study on transboundary pollution of heavy metals in this international river. In this study, eight sampling sites were selected to collect the bed sand samples along the mainstream of the Mekong River. In addition, the contents of 5 heavy metal elements and their spatial variability along the mainstream of the river were analyzed. The geoaccumulation index （l^eo） and potential ecological risk analysis were employed to assess heavy metal pol- lution status in the mainstream of the Mekong River. The results show that the average con- tent of the heavy metal elements Zn is 91.43 mg/kg, Pb is 41.85 mg/kg, and As is 21.84 mg/kg in the bed sands of the Upper Mekong River, which are higher than those （Zn 68.17 mg/kg, Pb 28.22 mg/kg, As 14.97 mg/kg） in the Lower Mekong. The average content of Cr in the Lower Mekong is 418.86 mg/kg, higher than that in the Upper Mekong （42.19 mg/kg）. Luang Prabang has a very high Cr concentration with 762.93 mg/kg and Pakse with 422.90 mg/kg. The concentration of Cu in all of the 8 sampling sites is similar, except for in Jiajiu with 11.70 mg/kg and Jiebei with 7.00 mg/kg. The results of the geoaccumulation index reveal that contaminations caused by Zn and Pb while Pb and As are more than those by Zn in Upper Mekong. Cr is the primary pollutant in the Lower Mekong, especially at Luang Prabang and Pakse. Slight pollution with As also occurs in Pakse. The potential ecological risk index indi- cates that the potential ecological risk of heavy metals in the mainstream of the Mekong River is low. We argue that the pollution of water quality and contamination of heavy metals in bed sediment caused by mining of mineral resources or geochemical background values in the Mekong is not transmitted from the Upper to the Lower Mekong because of the reservoir sedimentation and dilution along the river.
