With drilling and seismic data of Transtensional(strike-slip)Fault System in the Ziyang area of the central Sichuan Basin,SW China plane-section integrated structural interpretation,3-D fault framework model building,...With drilling and seismic data of Transtensional(strike-slip)Fault System in the Ziyang area of the central Sichuan Basin,SW China plane-section integrated structural interpretation,3-D fault framework model building,fault throw analyzing,and balanced profile restoration,it is pointed out that the transtensional fault system in the Ziyang 3-D seismic survey consists of the northeast-trending F_(I)19 and F_(I)20 fault zones dominated by extensional deformation,as well as 3 sets of northwest-trending en echelon normal faults experienced dextral shear deformation.Among them,the F_(I)19 and F_(I)20 fault zones cut through the Neoproterozoic to Lower Triassic Jialingjiang Formation,presenting a 3-D structure of an“S”-shaped ribbon.And before Permian and during the Early Triassic,the F_(I)19 and F_(I)20 fault zones underwent at least two periods of structural superimposition.Besides,the 3 sets of northwest-trending en echelon normal faults are composed of small normal faults arranged in pairs,with opposite dip directions and partially left-stepped arrangement.And before Permian,they had formed almost,restricting the eastward growth and propagation of the F_(I)19 fault zone.The F_(I)19 and F_(I)20 fault zones communicate multiple sets of source rocks and reservoirs from deep to shallow,and the timing of fault activity matches well with oil and gas generation peaks.If there were favorable Cambrian-Triassic sedimentary facies and reservoirs developing on the local anticlinal belts of both sides of the F_(I)19 and F_(I)20 fault zones,the major reservoirs in this area are expected to achieve breakthroughs in oil and gas exploration.展开更多
This article aims to develop a head pursuit (HP) guidance law for three-dimensional hypervelocity interception, so that the effect of the perturbation induced by seeker detection can be reduced. On the basis of a no...This article aims to develop a head pursuit (HP) guidance law for three-dimensional hypervelocity interception, so that the effect of the perturbation induced by seeker detection can be reduced. On the basis of a novel HP three-dimensional guidance model, a nonlinear variable structure guidance law is presented by using Lyapunov stability theory. The guidance law positions the interceptor ahead of the target on its tlight trajectory, and the speed of the interceptor is required to be lower than that of the target, A numerical example of maneuvering ballistic target interception verifies the rightness of the guidance model and the effectiveness of the proposed method.展开更多
Summary: A three-dimensional (3D) graphic model of a single-chain Fv (scFv) which was derived from an anti-human placental acidic isoferritin (PAF) monoclonal antibody (MAb) was construct- ed by a homologous protein...Summary: A three-dimensional (3D) graphic model of a single-chain Fv (scFv) which was derived from an anti-human placental acidic isoferritin (PAF) monoclonal antibody (MAb) was construct- ed by a homologous protein-predicting computer algorithm on Silicon graphic computer station. The structure, surface static electricity and hydrophobicity of scFv were investigated. Computer graphic modelling indicated that all regions of scFv including the linker, variable regions of the heavy (VH) and light (VL) chains were suitable. The VH region and the VL region were involved in composing the 'hydrophobic pocket'. The linker was drifted away VH and VL regions. The complementarity determining regions (CDRs) of VH and VL regions surrounded the 'hydrophobic pocket'. This study provides a theory basis for improving antibody affinity, investigating antibody structure and analyzing the functions of VH and VL regions in antibody activity.展开更多
BACKGROUND Esophageal cancer is one of the most common malignant tumors.The three-dimensional quality structure model is a quality assessment theory that includes three dimensions:Structure,process,and results.AIM To ...BACKGROUND Esophageal cancer is one of the most common malignant tumors.The three-dimensional quality structure model is a quality assessment theory that includes three dimensions:Structure,process,and results.AIM To investigate the effects of nursing interventions with three-dimensional quality assessment on the efficacy and disease management ability of patients undergoing esophageal cancer surgery.METHODS In this prospective study,the control group received routine nursing,and the intervention group additionally received a three-dimensional quality assessment intervention based on the above routine care.Self-efficacy and patient disease management abilities were evaluated using the General Self-Efficacy Scale(GSES)and Exercise of Self-Care Agency scale,respectively.IBM SPSS Statistics for Windows,version 17.0,was used for the data processing.RESULTS This study recruited 112 patients who were assigned to the control and experi-mental groups(n=56 per group).Before the intervention,there was no significant difference in GSES scores between the two groups(P>0.05).After the inter-vention,the GSES scores of both groups increased,with the experimental group showing higher values(P<0.05).At the time of discharge and three months after discharge,the scores for positive attitudes,self-stress reduction,and total score of health promotion in the experimental group were higher than those in the control group(P<0.05).CONCLUSION The implementation of a three-dimensional quality structure model for postoperative patients with esophageal cancer can effectively improve their self-management ability and self-efficacy of postoperative patients.展开更多
Large-scale topography, such as a seamount, substantially impacts low-frequency sound propagation in an ocean waveguide, limiting the application of low-frequency acoustic detecting techniques. A three-dimensional(3D)...Large-scale topography, such as a seamount, substantially impacts low-frequency sound propagation in an ocean waveguide, limiting the application of low-frequency acoustic detecting techniques. A three-dimensional(3D) coupledmode model is developed to calculate the acoustic field in an ocean waveguide with seamount topography and analyze the3D effect. In this model, a correction is introduced in the bottom boundary, theoretically making the acoustic field satisfy the energy conservation. Furthermore, a large azimuth angle calculation range is obtained by using the operator theory and higher-order Pade approximation. Additionally, the model has advantages related to the coupling mode and parabolic equation theory. The couplings corresponding to the effects of range-dependent environment are fully considered, and the numerical implementation is kept feasible. After verifying the accuracy and reliability of the model, low-frequency sound propagation characteristics in the seamount environment are analyzed. The results indicate lateral variability in bathymetry can lead to out-of-plane effects such as the horizontal refraction phenomenon, while the coupling effect tends to restore the abnormal sound field and produces acoustic field diffraction behind the seamount. This model effectively considers the effects of the horizontal refraction and coupling, which are proportional to the scale of the seamount.展开更多
The state of the physics of convective clouds and cloud seeding is discussed briefly. It is noted that at the present time there is a transition from the stage of investigation of “elementary” processes in the cloud...The state of the physics of convective clouds and cloud seeding is discussed briefly. It is noted that at the present time there is a transition from the stage of investigation of “elementary” processes in the clouds to the stage of studying the formation of macro- and microstructural characteristics of clouds as a whole, taking into account their system properties. The main directions of the development of cloud physics at the upcoming stage of its development are discussed. The paper points out that one of these areas is the determination of the structure-forming factors for the clouds and the study of their influence on their formation and evolution. It is noted that one of such factors is the interaction of clouds with their surrounding atmosphere, and the main method of studying its role in the processes of cloud formation is mathematical modeling. A three-dimensional nonstationary model of convective clouds is presented with a detailed account of the processes of thermohydrodynamics and microphysics, which is used for research. The results of modeling the influence of the wind field structure in the atmosphere on the formation and evolution of clouds are presented. It is shown that the dynamic characteristics of the atmosphere have a significant effect on the formation of macro- and microstructural characteristics of convective clouds: the more complex the structure of the wind field in the atmosphere (i.e., the more intense the interaction of the atmosphere and the cloud), the less powerful the clouds are formed.展开更多
A three-dimensional off-lattice protein model with two species of monomers, hydrophobic and hydrophilic, is studied. Enligh- tened by the law of reciprocity among things in the physical world, a heuristic quasi-physic...A three-dimensional off-lattice protein model with two species of monomers, hydrophobic and hydrophilic, is studied. Enligh- tened by the law of reciprocity among things in the physical world, a heuristic quasi-physical algorithm for protein structure prediction problem is put forward. First, by elaborately simulating the movement of the smooth elastic balls in the physical world, the algorithm finds low energy configurations for a given monomer chain. An "off-trap" strategy is then proposed to get out of local minima. Experimental results show promising performance. For all chains with lengths 13≤n ≤55, the proposed algorithm finds states with lower energy than the putative ground states reported in literatures. Furthermore, for chain lengths n = 21, 34, and 55, the algorithm finds new low energy configurations different from those given in literatures.展开更多
To dynamically update the shape of orebody according to the knowledge of a structural geologist’s insight,an approach of orebody implicit modeling from raw drillhole data using the generalized radial basis function i...To dynamically update the shape of orebody according to the knowledge of a structural geologist’s insight,an approach of orebody implicit modeling from raw drillhole data using the generalized radial basis function interpolant was presented.A variety of constraint rules,including geology trend line,geology constraint line,geology trend surface,geology constraint surface and anisotropy,which can be converted into interpolation constraints,were developed to dynamically control the geology trends.Combined with the interactive tools of constraint rules,this method can avoid the shortcomings of the explicit modeling method based on the contour stitching,such as poor model quality,and is difficult to update dynamically,and simplify the modeling process of orebody.The results of numerical experiments show that the 3D ore body model can be reconstructed quickly,accurately and dynamically by the implicit modeling method.展开更多
Soil-rock mixture (SRM) is a unique type of geomaterial characterized by a heterogeneous composition and a complicated structure. It is intractable for the continuum-based soil and rock mechanics theories to accurat...Soil-rock mixture (SRM) is a unique type of geomaterial characterized by a heterogeneous composition and a complicated structure. It is intractable for the continuum-based soil and rock mechanics theories to accurately characterize and predict the SRM's mechanical properties. This study reports a novel numerical method incorporating microfocus computed tomography and PFC3D codes to probe the deformation and failure processes of SRM. The three-dimensional (3D) PFC models that represent the SRM's complex structures were built. By simulating the entire failure process in PFC3D, the SRM's strength, elastic modulus and crack growth were obtained. The influence of rock ratios on the SRM's strength, deformation and failure processes, as well as its internal mesoscale mechanism, were analyzed. By comparing simulation results with experimental data, it was verified that the 3D PFC models were in good agreement with SRM's real structure and the SRM's compression process, deformation and failure patterns; its intrinsic mesomechanism can be effectively analyzed based on such 3D PFC models.展开更多
Weft knitted fancy fabrics are widely used in knitted garment design. Due to the complexity of the structures, their modeling and simulation needs to be solved in three-dimensional (3D) CAD developments. In this paper...Weft knitted fancy fabrics are widely used in knitted garment design. Due to the complexity of the structures, their modeling and simulation needs to be solved in three-dimensional (3D) CAD developments. In this paper, 3D loop geometrical models of weft knitted fancy structures, including tuck stitch, jacquard stitch, transfer stitch and fleecy stitch, were developed based on an improved model of plain loop, and their central axes as some 3D space curves were achieved by using Non-Uniform Rational B-Splines (NURBS). The 3D visual simulation programme was written in C++ programming language using OpenGL, which was a function library of 3D graphics. Some examples of weft knitted fancy fabrics were generated and practical application of 3D simulation was discussed.展开更多
The humic acid(HA) sample obtained from the alluvial soil was characterized by elemental composition, pyrolysis gas chromatography-mass spectrometry(Py-GC-MS) and solid-state 13C nuclear magnetic resonance (13C ...The humic acid(HA) sample obtained from the alluvial soil was characterized by elemental composition, pyrolysis gas chromatography-mass spectrometry(Py-GC-MS) and solid-state 13C nuclear magnetic resonance (13C NMR) spectroscopy. There is high fat content and a few nitrogen-containing functional groups in HA. Py-GC-MS demonstrates the characterization and structural identification of HA. One long list of identified pyrolysis products was proposed for the construction of conceptual model of HA. Solid-state 13C NMR data indicate there are higher values of alkyl-C, O-alkyl-C and aryl-C in HA. The elemental composition, structural carbon distribution and L3C NMR spectroscopy of simulated HA are consistent with those of experimental HA. HyperChem was used to simulate the three-dimensional molecular structure of the monomer, which was optimized by the molecular mechanics of the optimized potential for liquid simulations(OPLS) force field and molecular dynamics simulation to get the stable and balanced conformation. The deprotonation process study depicts that the degree of ionization of HA gets deeper, while the electronegativity of HA and the energy of van der Waals(vdW) increase. Moreover, the 3D structure of humic acid with -4 charges is the most stable. The deprotonation process is an endothermic process.展开更多
People currentiy pay attention to a hotspot problem that how industrial production is evaluated and controlled based on sustainable development theory. Quality is one of the important indexes. Two mainstream theories ...People currentiy pay attention to a hotspot problem that how industrial production is evaluated and controlled based on sustainable development theory. Quality is one of the important indexes. Two mainstream theories guide us to realize the industrial sustainable development: mainly the circular economy and sustainable manufacturing are introduced. The basic characteristics of the sustainable manufacturing are introduced, and that quality management is important contents of sustainable development is indicated. Based on circular economy and sustainable manufacture theories, the drawbacks in the existing quality management models are analyzed. The requests that satisfy the big system "environment- society - economy" are summarized to build up a model. A Chinese traditional cultural principle is applied and the relevant contents are sublimated as the platform to set up the model. The new quality management concept models are put forward "T- D- R" three-dimensional structures and "ecological quality loop" model, from which the new quality concepts are formed The paper elaborates the contents and the process of setting up the models. The big quality problems of the system can be handled by the new quality concept and model that are validated in practice.展开更多
In this paper, we make an initial value investigation of the unsteady flow of incompressible viscous fluid between two rigid non-conducting rotating parallel plates bounded by a porous medium under the influence of a ...In this paper, we make an initial value investigation of the unsteady flow of incompressible viscous fluid between two rigid non-conducting rotating parallel plates bounded by a porous medium under the influence of a uniform magnetic field of strength H0 inclined at an angle of inclination α with normal to the boundaries taking hall current into account. The perturbations are created by a constant pressure gradient along the plates in addition to the non-torsional oscillations of the upper plate while the lower plate is at rest. The flow in the porous medium is governed by the Brinkman’s equations. The exact solution of the velocity in the porous medium consists of steady state and transient state. The time required for the transient state to decay is evaluated in detail and the ultimate quasi-steady state solution has been derived analytically. Its behaviour is computationally discussed with reference to the various governing parameters. The shear stresses on the boundaries are also obtained analytically and their behaviour is computationally discussed.展开更多
基金Supported by the Key Project of National Natural Science Foundation of China(42330810).
文摘With drilling and seismic data of Transtensional(strike-slip)Fault System in the Ziyang area of the central Sichuan Basin,SW China plane-section integrated structural interpretation,3-D fault framework model building,fault throw analyzing,and balanced profile restoration,it is pointed out that the transtensional fault system in the Ziyang 3-D seismic survey consists of the northeast-trending F_(I)19 and F_(I)20 fault zones dominated by extensional deformation,as well as 3 sets of northwest-trending en echelon normal faults experienced dextral shear deformation.Among them,the F_(I)19 and F_(I)20 fault zones cut through the Neoproterozoic to Lower Triassic Jialingjiang Formation,presenting a 3-D structure of an“S”-shaped ribbon.And before Permian and during the Early Triassic,the F_(I)19 and F_(I)20 fault zones underwent at least two periods of structural superimposition.Besides,the 3 sets of northwest-trending en echelon normal faults are composed of small normal faults arranged in pairs,with opposite dip directions and partially left-stepped arrangement.And before Permian,they had formed almost,restricting the eastward growth and propagation of the F_(I)19 fault zone.The F_(I)19 and F_(I)20 fault zones communicate multiple sets of source rocks and reservoirs from deep to shallow,and the timing of fault activity matches well with oil and gas generation peaks.If there were favorable Cambrian-Triassic sedimentary facies and reservoirs developing on the local anticlinal belts of both sides of the F_(I)19 and F_(I)20 fault zones,the major reservoirs in this area are expected to achieve breakthroughs in oil and gas exploration.
文摘This article aims to develop a head pursuit (HP) guidance law for three-dimensional hypervelocity interception, so that the effect of the perturbation induced by seeker detection can be reduced. On the basis of a novel HP three-dimensional guidance model, a nonlinear variable structure guidance law is presented by using Lyapunov stability theory. The guidance law positions the interceptor ahead of the target on its tlight trajectory, and the speed of the interceptor is required to be lower than that of the target, A numerical example of maneuvering ballistic target interception verifies the rightness of the guidance model and the effectiveness of the proposed method.
文摘Summary: A three-dimensional (3D) graphic model of a single-chain Fv (scFv) which was derived from an anti-human placental acidic isoferritin (PAF) monoclonal antibody (MAb) was construct- ed by a homologous protein-predicting computer algorithm on Silicon graphic computer station. The structure, surface static electricity and hydrophobicity of scFv were investigated. Computer graphic modelling indicated that all regions of scFv including the linker, variable regions of the heavy (VH) and light (VL) chains were suitable. The VH region and the VL region were involved in composing the 'hydrophobic pocket'. The linker was drifted away VH and VL regions. The complementarity determining regions (CDRs) of VH and VL regions surrounded the 'hydrophobic pocket'. This study provides a theory basis for improving antibody affinity, investigating antibody structure and analyzing the functions of VH and VL regions in antibody activity.
文摘BACKGROUND Esophageal cancer is one of the most common malignant tumors.The three-dimensional quality structure model is a quality assessment theory that includes three dimensions:Structure,process,and results.AIM To investigate the effects of nursing interventions with three-dimensional quality assessment on the efficacy and disease management ability of patients undergoing esophageal cancer surgery.METHODS In this prospective study,the control group received routine nursing,and the intervention group additionally received a three-dimensional quality assessment intervention based on the above routine care.Self-efficacy and patient disease management abilities were evaluated using the General Self-Efficacy Scale(GSES)and Exercise of Self-Care Agency scale,respectively.IBM SPSS Statistics for Windows,version 17.0,was used for the data processing.RESULTS This study recruited 112 patients who were assigned to the control and experi-mental groups(n=56 per group).Before the intervention,there was no significant difference in GSES scores between the two groups(P>0.05).After the inter-vention,the GSES scores of both groups increased,with the experimental group showing higher values(P<0.05).At the time of discharge and three months after discharge,the scores for positive attitudes,self-stress reduction,and total score of health promotion in the experimental group were higher than those in the control group(P<0.05).CONCLUSION The implementation of a three-dimensional quality structure model for postoperative patients with esophageal cancer can effectively improve their self-management ability and self-efficacy of postoperative patients.
基金Project supported by the National Natural Science Foundation of China(Grant No.11804360)the IACAS Frontier Exploration Project(Grant No.QYTS202103)the Key Laboratory Foundation of Acoustic Science and Technology(Grant No.2021-JCJQ-LB-066-08)。
文摘Large-scale topography, such as a seamount, substantially impacts low-frequency sound propagation in an ocean waveguide, limiting the application of low-frequency acoustic detecting techniques. A three-dimensional(3D) coupledmode model is developed to calculate the acoustic field in an ocean waveguide with seamount topography and analyze the3D effect. In this model, a correction is introduced in the bottom boundary, theoretically making the acoustic field satisfy the energy conservation. Furthermore, a large azimuth angle calculation range is obtained by using the operator theory and higher-order Pade approximation. Additionally, the model has advantages related to the coupling mode and parabolic equation theory. The couplings corresponding to the effects of range-dependent environment are fully considered, and the numerical implementation is kept feasible. After verifying the accuracy and reliability of the model, low-frequency sound propagation characteristics in the seamount environment are analyzed. The results indicate lateral variability in bathymetry can lead to out-of-plane effects such as the horizontal refraction phenomenon, while the coupling effect tends to restore the abnormal sound field and produces acoustic field diffraction behind the seamount. This model effectively considers the effects of the horizontal refraction and coupling, which are proportional to the scale of the seamount.
文摘The state of the physics of convective clouds and cloud seeding is discussed briefly. It is noted that at the present time there is a transition from the stage of investigation of “elementary” processes in the clouds to the stage of studying the formation of macro- and microstructural characteristics of clouds as a whole, taking into account their system properties. The main directions of the development of cloud physics at the upcoming stage of its development are discussed. The paper points out that one of these areas is the determination of the structure-forming factors for the clouds and the study of their influence on their formation and evolution. It is noted that one of such factors is the interaction of clouds with their surrounding atmosphere, and the main method of studying its role in the processes of cloud formation is mathematical modeling. A three-dimensional nonstationary model of convective clouds is presented with a detailed account of the processes of thermohydrodynamics and microphysics, which is used for research. The results of modeling the influence of the wind field structure in the atmosphere on the formation and evolution of clouds are presented. It is shown that the dynamic characteristics of the atmosphere have a significant effect on the formation of macro- and microstructural characteristics of convective clouds: the more complex the structure of the wind field in the atmosphere (i.e., the more intense the interaction of the atmosphere and the cloud), the less powerful the clouds are formed.
基金The National Natural Science Founda-tion of China (No.10471051) and the National Basic Research Program (973) of China (No.2004CB318000)
文摘A three-dimensional off-lattice protein model with two species of monomers, hydrophobic and hydrophilic, is studied. Enligh- tened by the law of reciprocity among things in the physical world, a heuristic quasi-physical algorithm for protein structure prediction problem is put forward. First, by elaborately simulating the movement of the smooth elastic balls in the physical world, the algorithm finds low energy configurations for a given monomer chain. An "off-trap" strategy is then proposed to get out of local minima. Experimental results show promising performance. For all chains with lengths 13≤n ≤55, the proposed algorithm finds states with lower energy than the putative ground states reported in literatures. Furthermore, for chain lengths n = 21, 34, and 55, the algorithm finds new low energy configurations different from those given in literatures.
文摘To dynamically update the shape of orebody according to the knowledge of a structural geologist’s insight,an approach of orebody implicit modeling from raw drillhole data using the generalized radial basis function interpolant was presented.A variety of constraint rules,including geology trend line,geology constraint line,geology trend surface,geology constraint surface and anisotropy,which can be converted into interpolation constraints,were developed to dynamically control the geology trends.Combined with the interactive tools of constraint rules,this method can avoid the shortcomings of the explicit modeling method based on the contour stitching,such as poor model quality,and is difficult to update dynamically,and simplify the modeling process of orebody.The results of numerical experiments show that the 3D ore body model can be reconstructed quickly,accurately and dynamically by the implicit modeling method.
基金Acknowledgements The authors gratefully acknowledge the financial support from the State Key Research Development Program of China (Grant No. 2016YFC0600705), the National Natural Science Foundation of China (Grant Nos. 51674251, 51727807, 51374213), the National Natural Science Foundation for Distinguished Young Scholars of China (Grant No. 51125017), the Fund for Creative Research and Development Group Program of Jiangsu Province (Grant No. 2014-27), and the Priority Academic Program Development of Jiangsu Higher Education Institutions (Grant No. PAPD2014), and an open project sponsored by the State Key Labo- ratory for Geomechanics and Deep Underground Engineering (Grant SKLGDUE K1318) for their financial support.
文摘Soil-rock mixture (SRM) is a unique type of geomaterial characterized by a heterogeneous composition and a complicated structure. It is intractable for the continuum-based soil and rock mechanics theories to accurately characterize and predict the SRM's mechanical properties. This study reports a novel numerical method incorporating microfocus computed tomography and PFC3D codes to probe the deformation and failure processes of SRM. The three-dimensional (3D) PFC models that represent the SRM's complex structures were built. By simulating the entire failure process in PFC3D, the SRM's strength, elastic modulus and crack growth were obtained. The influence of rock ratios on the SRM's strength, deformation and failure processes, as well as its internal mesoscale mechanism, were analyzed. By comparing simulation results with experimental data, it was verified that the 3D PFC models were in good agreement with SRM's real structure and the SRM's compression process, deformation and failure patterns; its intrinsic mesomechanism can be effectively analyzed based on such 3D PFC models.
基金Natural Science Foundation of Tianjin,China( No. 11JCYBJC26400) Tianjin High School Scientific and Technology Fund Planning Project,China( No. 20100310)
文摘Weft knitted fancy fabrics are widely used in knitted garment design. Due to the complexity of the structures, their modeling and simulation needs to be solved in three-dimensional (3D) CAD developments. In this paper, 3D loop geometrical models of weft knitted fancy structures, including tuck stitch, jacquard stitch, transfer stitch and fleecy stitch, were developed based on an improved model of plain loop, and their central axes as some 3D space curves were achieved by using Non-Uniform Rational B-Splines (NURBS). The 3D visual simulation programme was written in C++ programming language using OpenGL, which was a function library of 3D graphics. Some examples of weft knitted fancy fabrics were generated and practical application of 3D simulation was discussed.
基金the National Natural Science Foundation of China
文摘The humic acid(HA) sample obtained from the alluvial soil was characterized by elemental composition, pyrolysis gas chromatography-mass spectrometry(Py-GC-MS) and solid-state 13C nuclear magnetic resonance (13C NMR) spectroscopy. There is high fat content and a few nitrogen-containing functional groups in HA. Py-GC-MS demonstrates the characterization and structural identification of HA. One long list of identified pyrolysis products was proposed for the construction of conceptual model of HA. Solid-state 13C NMR data indicate there are higher values of alkyl-C, O-alkyl-C and aryl-C in HA. The elemental composition, structural carbon distribution and L3C NMR spectroscopy of simulated HA are consistent with those of experimental HA. HyperChem was used to simulate the three-dimensional molecular structure of the monomer, which was optimized by the molecular mechanics of the optimized potential for liquid simulations(OPLS) force field and molecular dynamics simulation to get the stable and balanced conformation. The deprotonation process study depicts that the degree of ionization of HA gets deeper, while the electronegativity of HA and the energy of van der Waals(vdW) increase. Moreover, the 3D structure of humic acid with -4 charges is the most stable. The deprotonation process is an endothermic process.
文摘People currentiy pay attention to a hotspot problem that how industrial production is evaluated and controlled based on sustainable development theory. Quality is one of the important indexes. Two mainstream theories guide us to realize the industrial sustainable development: mainly the circular economy and sustainable manufacturing are introduced. The basic characteristics of the sustainable manufacturing are introduced, and that quality management is important contents of sustainable development is indicated. Based on circular economy and sustainable manufacture theories, the drawbacks in the existing quality management models are analyzed. The requests that satisfy the big system "environment- society - economy" are summarized to build up a model. A Chinese traditional cultural principle is applied and the relevant contents are sublimated as the platform to set up the model. The new quality management concept models are put forward "T- D- R" three-dimensional structures and "ecological quality loop" model, from which the new quality concepts are formed The paper elaborates the contents and the process of setting up the models. The big quality problems of the system can be handled by the new quality concept and model that are validated in practice.
文摘In this paper, we make an initial value investigation of the unsteady flow of incompressible viscous fluid between two rigid non-conducting rotating parallel plates bounded by a porous medium under the influence of a uniform magnetic field of strength H0 inclined at an angle of inclination α with normal to the boundaries taking hall current into account. The perturbations are created by a constant pressure gradient along the plates in addition to the non-torsional oscillations of the upper plate while the lower plate is at rest. The flow in the porous medium is governed by the Brinkman’s equations. The exact solution of the velocity in the porous medium consists of steady state and transient state. The time required for the transient state to decay is evaluated in detail and the ultimate quasi-steady state solution has been derived analytically. Its behaviour is computationally discussed with reference to the various governing parameters. The shear stresses on the boundaries are also obtained analytically and their behaviour is computationally discussed.