An Intelligent Hazardous Waste Detection and Classification Model Using Ensemble Learning Techniques

Proper waste management models using recent technologies like computer vision,machine learning(ML),and deep learning(DL)are needed to effectively handle the massive quantity of increasing waste.Therefore,waste classification becomes a crucial topic which helps to categorize waste into hazardous or non-hazardous ones and thereby assist in the decision making of the waste management process.This study concentrates on the design of hazardous waste detection and classification using ensemble learning(HWDC-EL)technique to reduce toxicity and improve human health.The goal of the HWDC-EL technique is to detect the multiple classes of wastes,particularly hazardous and non-hazardous wastes.The HWDC-EL technique involves the ensemble of three feature extractors using Model Averaging technique namely discrete local binary patterns(DLBP),EfficientNet,and DenseNet121.In addition,the flower pollination algorithm(FPA)based hyperparameter optimizers are used to optimally adjust the parameters involved in the EfficientNet and DenseNet121 models.Moreover,a weighted voting-based ensemble classifier is derived using three machine learning algorithms namely support vector machine(SVM),extreme learning machine(ELM),and gradient boosting tree(GBT).The performance of the HWDC-EL technique is tested using a benchmark Garbage dataset and it obtains a maximum accuracy of 98.85%.

Problems of Hazardous Waste Storage Facilities in Coal-fired Power Plants and Countermeasures

The hazardous waste produced by coal-fired power plants are large in quantity and variety. It is important for ecological environment protection to properly store hazardous waste in coal-fired power plants. The environmental management of hazardous waste in coal-fired power plants started late, and there are many problems in the construction and management of their storage facilities. In this paper, taking eight typical coal-fired power plants as examples, the present problems of hazardous waste storage facilities in coal-fired power plants are analyzed, and corresponding countermeasures are put forward to solve the main common problems.

Problems of Identification according to National Catalogue of Hazardous Wastes

ldentification work of solid wastes ’ risks is a kind of improvement and amendment for environmental impact assessment document of constructed projectss. ln the research, waste identification is classified as per entrustment source and the characteristics of pol ution accidents are analyzed, with major problems of National Catalogue of Hazardous Wastes and countermeasures proposed.

Simulation research of a counter‑fow rotary kiln hazardous waste incineration system

As industrialization accelerates and the amount of hazardous waste generated gradually increases,the means of disposal of hazardous waste is of increasing concern.In this paper,a 40 t/d counter-fow rotary kiln incineration system owned by a Jiangsu environmental protection company was researched.The software Aspen Plus was used to build the mixed pyrolysis model and the software Fluent was used to build the computational fuid dynamics model of the incineration system.The infuence of the calorifc value of the hazardous waste,the operating temperature and the air supply on the operational efectiveness of the incineration system were analyzed by varying the simulation conditions.The results show that the SO_(x)and NO_(x)content of the product is lower when the operating temperature is above 800℃.The incineration system could only operate above 800℃when the calorifc value of the hazardous waste is not less than 1500 kcal/kg.The incineration system operated best at a primary air velocity of 1.5 m/s.The simulation results in this paper serve as a guide for the operation of counter-fow rotary kiln incineration systems.

Investigation and analysis of hazardous waste in the Three Gorges Area of Chongqing region

This article describes the investigation of hazardous waste (HW) in the Three Gorges Area of Chongqing region, which indicates that by May 2002, the dumped HW therein amounted to 14 600 t and was mainly distributed in five districts and counties with 11 000 t in Fuling, 1 650 t in Fengdu, 950 t in Wanzhou; 630 t in Wushan and 430 t in Yunyang. The total amount was composed of 9 670 t chromic residue, 2 310 t waste oil and residue, 410 t waste (false) fertilizer, 28 t waste chemical medicine, 26 t waste materials and 2 200 t other things including acid residue, waste asbestos, fluorine silicate, pigment, additive, waste acid, alkali, nitric acid, vitriol, lead mud, storage battery, calcium carbide, potassium cyanide, polluted soil, discard dynamite, waste packing barrel of cyanides, etc. In all of the HW, 578 t can be treated by chemical neutralization and stabilization technology such as redox, chemical precipitation, acid and alkali neutralization, etc., and the rest is temporarily untreatble and should be removed and piled at a temporary storage site above the 177 m water level of the dam with an aim to be transported to a future disposal site for innocuous treatment.

Current status and strategy of hazardous waste management in China

This paper deals briefly with the pollution caused by hazardous wastes in China, the hazardous waste management at present and the strategy that should be taken for hazardous waste management in the future. Hazardous waste problem has become one of the important environmental concerns in China. Hazardous waste have resulted in ecological and environmental destruction, caused damage to human health, and restricted economic development. Although a great effort has been devoted to the management of hazardous wastes, there remain many issues in legislation, experience, technology and finance to be solved. Some recommendations are made on the strategic measures for improving the hazardous waste management in China, particularly relating to legislation, technical development and international cooperation.

Current Status of Manufacturing Hazardous Waste in Shanghai

It is difficult to manage the manufacturing hazardous waste (MHW) which is generated from a huge amount of compli- cated sources and causes very serious pollution. Therefore more and more attention has been paid to MHW pollution. Shanghai, as an industrial and economic center and an international metropolis in China, has a vast industrial system spanning a multitude of sectors, which generates MHW not only in a huge magnitude but also in a large variety of types from complicated sources, resulting in severe pollution. In 2003, the production of MHW in Shanghai is about 3.96 × 105 ton, involving 33 indices. Most of MHW in Shanghai is treated and disposed of, but a significant portion is not handled properly and effectively. This paper carries out in-field investigation on the current status of MHW production and treat- ment in Shanghai, and puts forward scientific proposals that Shanghai should facilitate cleaner production and minimize haz- ardous waste; strictly enforce hazardous waste registration system, strengthen monitoring the certified enterprises; strengthen intent disposal center construction and realize hazardous waste reclama- tion; accelerate establishing the technical criteria and the man- agement policy, promote the research and development on the treatment and disposal technology, and strengthen information management, thus realizing integrated management on MHW pollution.

Typical Refractories Design of Rotary Kiln Hazardous Waste Incineration System

This paper summarizes the current situation of China’s industrial hazardous waste treatment,the disposal technology and the characteristics of rotary kiln incineration system,analyzes the refractory lining design of rotary kiln incineration system in China,and puts forward optimization suggestions according to the process characteristics.

A disposal strategy of industrial hazardous wastes in the Three Gorges Region

A large quantity of industrial hazardous wastes (IHWs) accumulates in the Three Gorges Region. This study found that approximately 15 000 t IHWs were piled in the region by October 2001. These IHWs came from various sources and were complex in composition, mostly toxic and difficult to be disposed. IHW is regarded as a potential threat to the ecological environment, water resources and survival of local residents. It is important and indispensable to dispose the waste properly. To meet the regulation requirements on the disposal of IHWs and to minimize environmental effects on the Three Gorges Region, a disposal strategy is proposed, according to which approximately 600 t of the IHWs can be disposed by chemical stabilization, incineration and other treatment measures, and the rest need be stockpiled in safe and reliable places situated above the 177 m impoundment line of the Three Gorges dam.

Sealed model and computation of hazardous waste landfill high voltage DC leakage detection

According to the structural characteristics of hazardous waste landfill and the leakage current model of high voltage DC Landfill leakage detection, a sealed model is established detail. The detection layer of the hazardous waste landfill is considered as a sealed assumed that the source current flows through the leak entirely. The leak is regard and analyzed in space and it is ed as a positive current resource ＋ I located at the current entrance or a negative resource - I located at the current exit, which depends on the placement of the current supply. The electrical potential of an arbitrary in detection layer satisfies Poisson equation. The boundary condition is regarded as a natural bound- ary condition for the high resistivity of high density polyethylene （HDPE） membrane. Based on which a numerical calculation method is developed. Satisfactory agreement between experimental da- ta and simulated data validates the analysis. Parametric studies show that a larger horizontal distance between the power supply electrode and leak and a smaller distance between the detector electrodes and the detected liner are helpful to leak location. More parametric curves show that parameters leaks can be detected effectively with optimum selection of field survey.

Corrosion-resistant Refractory Linings for Hazardous Waste Treatment inRotary Kilns

Mega trends like urbanization,industrialization and growing population drive the demand of daily necessaries and therefore result in increased refractory consumption for waste treatment carried out at elevated temperatures.It is estimated that for burning 1 t of waste about 5.5 kg of refractory materials need to be consumed.In the present study,the corrosion resistance of refractory bricks based on alumina-chromia and alumina-silica was tested by exposing them to slag from hazardous waste incineration.Samples from the cup test were investigated macroscopically and mineralogically.They showed that alumina-chromia bricks had high corrosion resistance when in contact with the tested slags,while alumina-silica bricks containing silicon carbide showed an overall good performance.

Preparation of lithium-ion battery anode materials from graphitized spent carbon cathode derived from aluminum electrolysis

Graphitized spent carbon cathode(SCC)is a hazardous solid waste generated in the aluminum electrolysis process.In this study,a flotation-acid leaching process is proposed for the purification of graphitized SCC,and the use of the purified SCC as an anode material for lithium-ion batteries is explored.The flotation and acid leaching processes were separately optimized through one-way experiments.The maximum SCC carbon content(93wt%)was achieved at a 90%proportion of−200-mesh flotation particle size,a slurry concentration of 10wt%,a rotation speed of 1600 r/min,and an inflatable capacity of 0.2 m^(3)/h(referred to as FSCC).In the subsequent acid leaching process,the SCC carbon content reached 99.58wt%at a leaching concentration of 5 mol/L,a leaching time of 100 min,a leaching temperature of 85°C,and an HCl/FSCC volume ratio of 5:1.The purified graphitized SCC(referred to as FSCC-CL)was utilized as an anode material,and it exhibited an initial capacity of 348.2 mAh/g at 0.1 C and a reversible capacity of 347.8 mAh/g after 100 cycles.Moreover,compared with commercial graphite,FSCC-CL exhibited better reversibility and cycle stability.Thus,purified SCC is an important candidate for anode material,and the flotation-acid leaching purification method is suitable for the resourceful recycling of SCC.

A Sustainable Strategy for Spent Cathode Carbon Blocks Hazardous Waste Recycling Using Binary Molten Salt Thermal Treatment

Waste-to-Energy treatment is a promising path to environment and energy management in the future.This work detailed a binary molten salt thermal treatment methodology for the detoxification of spent cathode carbon block(SCCB)waste and the recycling of carbonaceous materials.The thermal behavior of SCCB and SCCB blended with molten salts was investigated.It was found that the NaCl-Na_(2)CO_(3)binary molten salts significantly contributed to reducing pyrolysis onset temperature by 334.3 K compared to that of SCCB itself(i.e.,activation energy of pyrolysis reaction was reduced from 4.24×10^(5)to 2.30×10^(5)J/mol),thus helping to lower thermal treatment energy consumption.With the addition of binary molten salts,the residue after thermal treatment in a horizontal tube furnace experiment was separated into two layers.The bottom-layer residue was mainly composed of molten salts.The fluorine content in the form of NaF and CaF_(2)of top-layer residue was reduced significantly while the carbon content remained unchanged.Specifically,the leaching concentration of fluoride ion was decreased from 4620 mg/L to 856 mg/L.It is noted that the NaF and CaF_(2)can be removed through water-leaching and hydrothermal acid-leaching methods and thus the carbonaceous materials with a calorific value of 17.5 MJ/kg were obtained.

An ensemble machine learning model to uncover potential sites of hazardous waste illegal dumping based on limited supervision experience

With the soaring generation of hazardous waste(HW)during industrialization and urbanization,HW illegal dumping continues to be an intractable global issue.Particularly in developing regions with lax regulations,it has become a major source of soil and groundwater contamination.One dominant challenge for HW illegal dumping supervision is the invisibility of dumping sites,which makes HW illegal dumping difficult to be found,thereby causing a long-term adverse impact on the environment.How to utilize the limited historic supervision records to screen the potential dumping sites in the whole region is a key challenge to be addressed.In this study,a novel machine learning model based on the positive-unlabeled(PU)learning algorithm was proposed to resolve this problem through the ensemble method which could iteratively mine the features of limited historic cases.Validation of the random forest-based PU model showed that the predicted top 30%of high-risk areas could cover 68.1%of newly reported cases in the studied region,indicating the reliability of the model prediction.This novel framework will also be promising in other environmental management scenarios to deal with numerous unknown samples based on limited prior experience.

Quantitative Assessment of Medical Waste Management in Hamad Medical Corporation—Qatar

A proper waste management system is very important in healthcare facilities because the overall benefit outweighs the cost. In the healthcare sector, hazardous health care waste (HHCW) consists of wastes that are potentially contaminated by dangerous agents. Identification and segregation of HHCW is harbinger for its proper management. The quantitative analysis study on HHCW had not been done in Qatar government hospitals. This study quantitatively analyzed the current practice for HHCW management in Hamad Medical Corporation (HMC), Qatar. The objective of this study is to provide a first comprehensive assessment of hazardous healthcare waste managements in Qatar and offers an opportunity to improve existing practice. This is a retrospective survey study carried out on secondary data collected from the department of occupational health and safety (OHS), HMC. OHS department collects and keeps records of hazardous wastes produced by HMC. Data on the HMC hospitals’ characteristics from 2017 to 2019 were retrieved from Planning and Statistics Authority’s website. World Health Organization (WHO) formula for calculating HHCW generation rate was used to calculate the rate for HMC. Data analysis results show a steady increase in HHCW generation rate in HMC, the generation rate was 2.6 Kg/patient bed/day, 2.8 Kg/patient bed/day and 3.1 Kg/patient bed/day for the years 2017, 2018 and 2019 respectively. There were also significant variations in HHCW generation rates between hospitals. The highest generation rate was 4.64 Kg/patient bed/day recorded for AWH and the lowest was 0.2 Kg/patient bed/day recorded for mental health and both hospitals contributing 23.18% and 0.29% respectively of HHCW in HMC.

Optimal ways of disposal of highly radioactive waste

Multibarrier concepts are commonly proposed for effective isolation of highly radioactive waste (HLW). Present concepts consider the host rock as a barrier by retarding migration of possibly released radionuclides to the biosphere, containers for preventing release of radionuclides, and “buffer clay” embedding the canisters for providing ductility and minimizing the risk of container breakage and for delaying migration of possibly escaping radionuclides. Closer analysis of the isolating functions shows that rock will only serve as a mechanical protection of the “nearfield”, the containers of proposed types can be short-lived, and the surrounding clay will be increasingly permeable and stiffen hence becoming less ductile with time. A different approach, representing an alternative to the common concepts, can be safer and cheaper. It takes the HIPOW copper canister as the only major barrier and a cheap but sufficiently efficient buffer as embedment. The repository can consist of an abandoned copper mine, an option being to place HLW in emptied drifts while mining is still going in not yet exploited parts of the ore body.

Can sealing of rock hosting a repository for highly radioactive waste be relied on?

Multibarrier systems are commonly proposed for effective isolation of highly radioactive waste (HLW). Presently considered concepts take the host rock as a barrier claiming it to retard migration of possibly released radionuclides from HLW containers to the biosphere. This capacity is small unless water-bearing fracture zones intersecting the blasted waste-containing tunnels and excavation-disturbance zones around them can be sealed by grouting and construction of bulkheads, but this is effective only for a very limited period of time as explained in the paper. The disturbed zones thence make the entire repository serve as a continuous hydraulic conductor causing quick transport of released radionuclides up to the biosphere. The dilemma can be solved by accepting the shortcircuiting function of the disturbed zones along the tunnels on the condition that totally tight waste containers be used. Deep holes bored in the site selection phase through the forthcoming repository can be effective pathways for radionuclides unless they are properly sealed. They are small-scale equivalents of tunnels but do not have any excavation damage and can be effectively sealed by using clay and concrete of new types. Applying this principle to very deep boreholes with a diameter of a few decimeters would make it possible to safely store slim, tight HLW canisters for any period of time.

Hydrometallurgical detoxification and recycling of electric arc furnace dust

Electric arc furnace dust(EAFD)is a hazardous waste but can also be a potential secondary resource for valuable metals,such as Zn and Fe.Given the increased awareness of carbon emission reduction,energy conservation,and environmental protection,hydrometallurgical technologies for the detoxification and resource use of EAFD have been developing rapidly.This work summarizes the generation mechanisms,compositions,and characteristics of EAFD and presents a critical review of various hydrometallurgical treatment methods for EAFD,e.g.,acid leaching,alkaline leaching,salt leaching,and pretreatment–enhanced leaching methods.Simultaneously,the phase transformation mechanisms of zinc-containing components in acid and alkali solutions and pretreatment processes are expounded.Finally,two novel combined methods,i.e.,oxygen pressure sulfuric acid leaching combined with composite catalyst preparation,and synergistic roasting of EAFD and municipal solid waste incineration fly ash combined with alkaline leaching,are proposed,which can provide future development directions to completely recycling EAFD by recovering valuable metals and using zinc residue.

Predicting effect factors of dual bag filter system for PCDD/Fs removal from hazardous waste incineration flue gas

The dual bag filter(DBF)system is a new polychlorinated dibenzo-p-dioxins and polychlorinated dibenzofurans(PCDD/Fs)emission control technology that has more efficient(PCDD/Fs)removal performance,a higher activated carbon utilization rate and less activated carbon consumption compared with the traditional single bag filter system.Moreover,few studies have been relevant to the mechanism of the PCDD/Fs removal process in the DBF system,and the selection of operating conditions of the DBF system lacks an academic basis.This study established a PCDD/Fs removal efficiency model of activated carbon injection combined bag filter(ACI+DBF)system for hazardous waste incineration flue gas and predicted the crucial effect factors.New adsorption coefficients k_(1)=532,145 Nm^(3)/(mol s)and k_(2)=45 Nm^(3)/(mol s),and the relationship expression between the number of available adsorption positions of recycled AC(AAC′)and cycle times(n)are proposed in the model.The results verify that the model error was below 5%.In addition,the PCDD/Fs removal efficiency model predicts that in a certain range,the PCDD/Fs removal efficiency increases with increasing activated carbon injection concentration.The best cycle number of activated carbon was less than 3,and the ratio of circulating activated carbon to fresh activated carbon in second bag filter(SBF)should be controlled at 7–8.

Species Transformation of Trace Elements and Their Distribution Prediction in Dyestuff Residue Incineration

The release of heavy metals from the combustion of hazardous wastes is an environmental issue of in-creasing concern.The species transformation characteristics of toxic heavy metals and their distribution are consid-ered to be a complex problem of mechanism.The behavior of hazardous dyestuff residue is investigated in a tubular furnace under the general condition of hazardous waste pyrolysis and gasfication.Data interpretation has been aided by parallel theoretical study based on a thermodynamic equilibrium model based on the principle of Gibbs free en-ergy minimization.The results show that Ni,Zn,Mn,and Cr are more enriched in dyestuff residue incineration than other heavy metals(Hg,As,and Se)subjected to volatilization.The thermodynamic model calculation is used for explaining the experiment data at 800℃ and analyzing species transformation of heavy metals.These results of species transformation are used to predict the distribution and emission characteristics of trace elements.Although most trace element predictions are validated by the measurements,cautions are in order due to the complexity of incineration systems.