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Bird’s-eye view of recycled solid wastes in road engineering
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作者 Zhuangzhuang Liu Tengteng Feng +5 位作者 Xingyi Zhu Jie Gao Kui Hu Meng Guo Fan Gu Feng Li 《Journal of Road Engineering》 2024年第2期93-150,共58页
Recent trends in road engineering have explored the potential of incorporating recycled solid wastes into infrastructures that including pavements,bridges,tunnels,and accessory structures.The utilization of solid wast... Recent trends in road engineering have explored the potential of incorporating recycled solid wastes into infrastructures that including pavements,bridges,tunnels,and accessory structures.The utilization of solid wastes is expected to offer sustainable solutions to waste recycling while enhancing the performance of roads.This review provides an extensive analysis of the recycling of three main types of solid wastes for road engineering purposes:industrial solid waste,infrastructure solid waste,and municipal life solid waste.Industrial solid wastes suitable for road engineering generally include coal gangue,fly ash,blast furnace slag,silica fume,and steel slag,etc.Infrastructure solid wastes recycled in road engineering primarily consist of construction&demolition waste,reclaimed asphalt pavements,and recycled cement concrete.Furthermore,recent exploration has extended to the utilization of municipal life solid wastes,such as incinerated bottom ash,glass waste,electronics waste,plastic waste,and rubber waste in road engineering applications.These recycled solid wastes are categorized into solid waste aggregates,solid waste cements,and solid waste fillers,each playing distinct roles in road infrastructure.Roles of solid waste acting aggregates,cements,and fillers in road infrastructures were fully investigated,including their pozzolanic properties,integration effects to virgin materials,modification or enhancement solutions,engineering performances.Utilization of these materials not only addresses the challenge of waste management but also offers environmental benefits aiming carbon neutral and contributes to sustainable infrastructure development.However,challenges such as variability in material properties,environmental impact mitigation,secondary pollution to environment by leaching,and concerns regarding long-term performance need to be further addressed.Despite these challenges,the recycled solid wastes hold immense potential in revolutionizing road construction practices and fostering environmental stewardship.This review delves into a bird’seye view of the utilization of recycled solid wastes in road engineering,highlighting advances,benefits,challenges,and future prospects. 展开更多
关键词 Road engineering Industrial solid waste Infrastructure solid waste Municipal life waste Recycled materials
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Reasonable design a high-entropy garnet-type solid electrolyte for all-solid-state lithium batteries
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作者 Shiyu Yu Yandi Li +6 位作者 Jiaxin Luo Daming Chen Liang Yang Yaqing Wei De Li Yuanxun Li Yong Chen 《Journal of Energy Chemistry》 SCIE EI CAS CSCD 2024年第9期414-423,共10页
Traditional garnet solid electrolyte(Li_(7)La_(3)Zr_(2)O_(12))suffers from low room temperature ionic conductivity,poor air stability,high sintering temperature and energy consumption.Considering the development prosp... Traditional garnet solid electrolyte(Li_(7)La_(3)Zr_(2)O_(12))suffers from low room temperature ionic conductivity,poor air stability,high sintering temperature and energy consumption.Considering the development prospects of high-entropy materials with high structural disorder and strong component controllability in the field of electrochemical energy storage,herein,a novel high-entropy garnet-type oxide solid electrolyte,Li_(5.75)Ga_(0.25)La_(3)Zr_(0.5)Ti_(0.5)Sn_(0.5)Nb_(0.5)O_(12)(LGLZTSNO)was constructed by partially replacing the Li and Zr sites in Li_(7)La_(3)Zr_(2)O_(12)with Ga and Ti/Sn/Nb elements,respectively.The experimental and density functional theory(DFT)calculation results show that the high-entropy LGLZTSNO electrolyte has preferable room temperature ion conductivity,air stability,interface contact performance with lithium anode,and the ability to suppress lithium dendrites.Thanks to the improvement of electrolyte performance,the critical current density of Li/Ag@LGLZTSNO/Li symmetric cell was increased from 0.42 to 1.57 mA cm^(−2),and the interface area specific impedance(IASR)was reduced from 765.2 to 42.3Ωcm^(2).Meanwhile,the Li/Ag@LGLZTSNO/LFP full cell also exhibits excellent rate performance and cycling performance(148 mA h g^(−1)at 0.1 C and 124 mA h g^(−1)at 0.5 C,capacity retention up to 84.8%after 100 cycles at 0.1 C),showing the application prospects of high-entropy LGLZTSNO solid electrolyte in high-performance all solid state lithium batteries. 展开更多
关键词 Garnet solid electrolyte Dual-site substitution High-entropy all solid-state lithium batteries(ASSLBs)
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From concept to commercialization:A review of tubular solid oxide fuel cell technology 被引量:1
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作者 Ruyan Chen Yuan Gao +4 位作者 Jiutao Gao Huiyu Zhang Martin Motola Muhammad Bilal Hanif Cheng-Xin Li 《Journal of Energy Chemistry》 SCIE EI CAS CSCD 2024年第10期79-109,I0003,共32页
The reduced sealing difficulty of tubular solid oxide fuel cells(SOFCs)makes the stacking of tubular cell groups relatively easy,and the thermal stress constraints during stack operation are smaller,which helps the st... The reduced sealing difficulty of tubular solid oxide fuel cells(SOFCs)makes the stacking of tubular cell groups relatively easy,and the thermal stress constraints during stack operation are smaller,which helps the stack to operate stably for a long time.The special design of tubular SOFC structures can completely solve the problem of high-temperature sealing,especially in the design of multiple single-cell series integrated into one tube,where each cell tube is equivalent to a small electric stack,with unique characteristics of high voltage and low current output,which can significantly reduce the ohmic polarization loss of tubular cells.This paper provides an overview of typical tubular SOFC structural designs both domestically and internationally.Based on the geometric structure of tubular SOFCs,they can be divided into bamboo tubes,bamboo flat tubes,single-section tubes,and single-section flat tube structures.Meanwhile,this article provides an overview of commonly used materials and preparation methods for tubular SOFCs,including commonly used materials and preparation methods for support and functional layers,as well as a comparison of commonly used preparation methods for microtubule SOFCs,It introduced the three most important parts of building a fuel cell stack:manifold,current collector,and ceramic adhesive,and also provided a detailed introduction to the power generation systems of different tubular SOFCs,Finally,the development prospects of tubular SOFCs were discussed. 展开更多
关键词 Tubular solid oxide fuel cell Support material Geometric structure Preparation methods STACK
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Multistate transition and coupled solid-liquid modeling of motion process of long-runout landslide 被引量:1
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作者 Yang Gao Yueping Yin +3 位作者 Bin Li Han Zhang Weile Wu Haoyuan Gao 《Journal of Rock Mechanics and Geotechnical Engineering》 SCIE CSCD 2024年第7期2694-2714,共21页
The recognition,repetition and prediction of the post-failure motion process of long-runout landslides are key scientific problems in the prevention and mitigation of geological disasters.In this study,a new numerical... The recognition,repetition and prediction of the post-failure motion process of long-runout landslides are key scientific problems in the prevention and mitigation of geological disasters.In this study,a new numerical method involving LPF3D based on a multialgorithm and multiconstitutive model was proposed to simulate long-runout landslides with high precision and efficiency.The following results were obtained:(a)The motion process of landslides showed a steric effect with mobility,including gradual disintegration and spreading.The sliding mass can be divided into three states(dense,dilute and ultradilute)in the motion process,which can be solved by three dynamic regimes(friction,collision,and inertial);(b)Coupling simulation between the solid grain and liquid phases was achieved,focusing on drag force influences;(c)Different algorithms and constitutive models were employed in phase-state simulations.The volume fraction is an important indicator to distinguish different state types and solid‒liquid ratios.The flume experimental results were favorably validated against long-runout landslide case data;and(d)In this method,matched dynamic numerical modeling was developed to better capture the realistic motion process of long-runout landslides,and the advantages of continuum media and discrete media were combined to improve the computational accuracy and efficiency.This new method can reflect the realistic physical and mechanical processes in long-runout landslide motion and provide a suitable method for risk assessment and pre-failure prediction. 展开更多
关键词 Long-runout landslide Multistate transition Mixed solid‒liquid flow Post-failure process Numerical simulation
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Boosting oxygen reduction activity and CO_(2) resistance on bismuth ferrite-based perovskite cathode for low-temperature solid oxide fuel cells below 600℃ 被引量:1
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作者 Juntao Gao Zhiyun Wei +5 位作者 Mengke Yuan Zhe Wang Zhe Lü Qiang Li Lingling Xu Bo Wei 《Journal of Energy Chemistry》 SCIE EI CAS CSCD 2024年第3期600-609,I0013,共11页
Developing efficient and stable cathodes for low-temperature solid oxide fuel cells(LT-SOFCs) is of great importance for the practical commercialization.Herein,we propose a series of Sm-modified Bi_(0.7-x)Sm_xSr_(0.3)... Developing efficient and stable cathodes for low-temperature solid oxide fuel cells(LT-SOFCs) is of great importance for the practical commercialization.Herein,we propose a series of Sm-modified Bi_(0.7-x)Sm_xSr_(0.3)FeO_(3-δ) perovskites as highly-active catalysts for LT-SOFCs.Sm doping can significantly enhance the electrocata lytic activity and chemical stability of cathode.At 600℃,Bi_(0.675)Sm_(0.025)Sr_(0.3)FeO_(3-δ)(BSSF25) cathode has been found to be the optimum composition with a polarization resistance of 0.098 Ω cm^2,which is only around 22.8% of Bi_(0.7)Sr_(0.3)FeO_(3-δ)(BSF).A full cell utilizing BSSF25 displays an exceptional output density of 790 mW cm^(-2),which can operate continuously over100 h without obvious degradation.The remarkable electrochemical performance observed can be attributed to the improved O_(2) transport kinetics,superior surface oxygen adsorption capacity,as well as O_(2)p band centers in close proximity to the Fermi level.Moreover,larger average bonding energy(ABE) and the presence of highly acidic Bi,Sm,and Fe ions restrict the adsorption of CO_(2) on the cathode surface,resulting in excellent CO_(2) resistivity.This work provides valuable guidance for systematic design of efficient and durable catalysts for LT-SOFCs. 展开更多
关键词 Low-temperature solid oxide fuel cell Perovskite cathode DFT calculations CO_(2) tolerance
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Microstructural analysis of marl stabilized with municipal solid waste and nano-MgO
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作者 Ali Ohadian Navid Khayat Mehdi Mokhberi 《Journal of Rock Mechanics and Geotechnical Engineering》 SCIE CSCD 2024年第8期3258-3269,共12页
Municipal solid waste(MSW)is accumulating over elapsed time across the world,and it is observed in many projects associated with weak soils,such as marl.Therefore,effective solutions to the environmental problem are e... Municipal solid waste(MSW)is accumulating over elapsed time across the world,and it is observed in many projects associated with weak soils,such as marl.Therefore,effective solutions to the environmental problem are essential.Conventional techniques for stabilizing marl generally use substances such as lime and cement,which could exacerbate pollution.For this,some new stabilizers,e.g.nano-MgO,are used.There are large quantities of marls and MSW in Shiraz City,Iran.The present study aims to evaluate the feasibility of using nano-MgO as a green low-carbon binder to remove MSW from the environment and make construction projects more cost-effective.Consolidated drained shear tests were conducted to evaluate the mechanical behaviors of the nano-MgO treated marl specimens at high normal stresses.The marl specimens containing MSW percentages of 15%,25%,35%,and 45%and nano-MgO percentages of 0.25%,0.5%,0.75%,and 1%,were used.It is found that the marl containing 15%and 25%MSW and 0.5%nano-MgO at 28-d curing can perform cation exchange and form new cementitious products.The soils with merely MSW show good performance due to the removal of the kaolinite and the formation of brucite.However,the soil with 25%MSW and 0.5%nano-MgO shows the same strength enhancement as the specimen with the optimal nano-MgO(0.75%)through the formation of dolomite,with a 20.59%increase in strain energy(SE). 展开更多
关键词 MARL Shear strength MICROSTRUCTURE Nano-MgO Municipal solid waste(MSW)
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Improvement effect of reversible solid solutions Mg_(2)Ni(Cu)/Mg_(2)Ni(Cu)H_(4)on hydrogen storage performance of MgH_(2)
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作者 Yingyan Zhao Zhibing Liu +5 位作者 Jiangchuan Liu Yunfeng Zhu Jiguang Zhang Yana Liu Xiaohui Hu Liquan Li 《Journal of Magnesium and Alloys》 SCIE EI CAS CSCD 2024年第1期197-208,共12页
The hydrogen absorption/desorption kinetic properties of MgH_(2)can be effectively enhanced by doping specific catalysts.In this work,MOFs-derived NiCu@C nanoparticles(~15 nm)with regular core-shell structure were suc... The hydrogen absorption/desorption kinetic properties of MgH_(2)can be effectively enhanced by doping specific catalysts.In this work,MOFs-derived NiCu@C nanoparticles(~15 nm)with regular core-shell structure were successfully prepared and introduced into MgH_(2)(denoted as MgH_(2)-NiCu@C).The onset and peak temperatures of hydrogen desorption of MgH_(2)-11 wt.%NiCu@C are 175.0℃and282.2℃,respectively.The apparent activation energy of dehydrogenated reaction is 77.2±4.5 kJ/mol for MgH_(2)-11 wt.%NiCu@C,which is lower than half of that of the as-milled MgH_(2).Moreover,MgH_(2)-11 wt.%NiCu@C displays great cyclic stability.The strengthening"hydrogen pumping"effect of reversible solid solutions Mg_(2)Ni(Cu)/Mg_(2)Ni(Cu)H_(4)is proposed to explain the remarkable improvement in hydrogen absorption/desorption kinetic properties of MgH_(2).This work offers a novel perspective for the design of bimetallic nanoparticles and beyond for application in hydrogen storage and other energy related fields. 展开更多
关键词 Magnesium hydride Reversible solid solution Core-shell nanoparticles Hydrogen storage performance
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Quantifying Uncertainty in Dielectric Solids’ Mechanical Properties Using Isogeometric Analysis and Conditional Generative Adversarial Networks
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作者 Shuai Li Xiaodong Zhao +1 位作者 Jinghu Zhou Xiyue Wang 《Computer Modeling in Engineering & Sciences》 SCIE EI 2024年第9期2587-2611,共25页
Accurate quantification of the uncertainty in the mechanical characteristics of dielectric solids is crucial for advancing their application in high-precision technological domains,necessitating the development of rob... Accurate quantification of the uncertainty in the mechanical characteristics of dielectric solids is crucial for advancing their application in high-precision technological domains,necessitating the development of robust com-putational methods.This paper introduces a Conditional Generation Adversarial Network Isogeometric Analysis(CGAN-IGA)to assess the uncertainty of dielectric solids’mechanical characteristics.IGA is utilized for the precise computation of electric potentials in dielectric,piezoelectric,and flexoelectric materials,leveraging its advantage of integrating seamlessly with Computer-Aided Design(CAD)models to maintain exact geometrical fidelity.The CGAN method is highly efficient in generating models for piezoelectric and flexoelectric materials,specifically adapting to targeted design requirements and constraints.Then,the CGAN-IGA is adopted to calculate the electric potential of optimum models with different parameters to accelerate uncertainty quantification processes.The accuracy and feasibility of this method are verified through numerical experiments presented herein. 展开更多
关键词 Dielectric solid isogeometric finite element method surrogate model generative adversarial
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Anelasticity to plasticity transition in a model two-dimensional amorphous solid
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作者 尚宝双 《Chinese Physics B》 SCIE EI CAS CSCD 2024年第1期143-147,共5页
Anelasticity, as an intrinsic property of amorphous solids, plays a significant role in understanding their relaxation and deformation mechanism. However, due to the lack of long-range order in amorphous solids, the s... Anelasticity, as an intrinsic property of amorphous solids, plays a significant role in understanding their relaxation and deformation mechanism. However, due to the lack of long-range order in amorphous solids, the structural origin of anelasticity and its distinction from plasticity remain elusive. In this work, using frozen matrix method, we study the transition from anelasticity to plasticity in a two-dimensional model glass. Three distinct mechanical behaviors, namely,elasticity, anelasticity, and plasticity, are identified with control parameters in the amorphous solid. Through the study of finite size effects on these mechanical behaviors, it is revealed that anelasticity can be distinguished from plasticity.Anelasticity serves as an intrinsic bridge connecting the elasticity and plasticity of amorphous solids. Additionally, it is observed that anelastic events are localized, while plastic events are subextensive. The transition from anelasticity to plasticity is found to resemble the entanglement of long-range interactions between element excitations. This study sheds light on the fundamental nature of anelasticity as a key property of element excitations in amorphous solids. 展开更多
关键词 amorphous solid deformation mechanism anelasticity to plasticity transition molecular dynamics simulation
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Construction of a High‑Performance Composite Solid Electrolyte Through In‑Situ Polymerization within a Self‑Supported Porous Garnet Framework 被引量:1
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作者 An‑Giang Nguyen Min‑Ho Lee +1 位作者 Jaekook Kim Chan‑Jin Park 《Nano-Micro Letters》 SCIE EI CAS CSCD 2024年第5期56-70,共15页
Composite solid electrolytes(CSEs)have emerged as promising candidates for safe and high-energy–density solid-state lithium metal batteries(SSLMBs).However,concurrently achieving exceptional ionic conductivity and in... Composite solid electrolytes(CSEs)have emerged as promising candidates for safe and high-energy–density solid-state lithium metal batteries(SSLMBs).However,concurrently achieving exceptional ionic conductivity and interface compatibility between the electrolyte and electrode presents a significant challenge in the development of high-performance CSEs for SSLMBs.To overcome these challenges,we present a method involving the in-situ polymerization of a monomer within a self-supported porous Li_(6.4)La_(3)Zr_(1.4)Ta_(0.6)O_(12)(LLZT)to produce the CSE.The synergy of the continuous conductive LLZT network,well-organized polymer,and their interface can enhance the ionic conductivity of the CSE at room temperature.Furthermore,the in-situ polymerization process can also con-struct the integration and compatibility of the solid electrolyte–solid electrode interface.The synthesized CSE exhibited a high ionic conductivity of 1.117 mS cm^(-1),a significant lithium transference number of 0.627,and exhibited electrochemical stability up to 5.06 V vs.Li/Li+at 30℃.Moreover,the Li|CSE|LiNi_(0.8)Co_(0.1)Mn_(0.1)O_(2) cell delivered a discharge capacity of 105.1 mAh g^(-1) after 400 cycles at 0.5 C and 30℃,corresponding to a capacity retention of 61%.This methodology could be extended to a variety of ceramic,polymer electrolytes,or battery systems,thereby offering a viable strategy to improve the electrochemical properties of CSEs for high-energy–density SSLMBs. 展开更多
关键词 Scalable tape-casting method Self-supported porous Li_(6.4)La_(3)Zr_(1.4)Ta_(0.6)O_(12) Composite solid electrolyte LiF-and B-rich interphase layers
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Advancements and Challenges in Organic–Inorganic Composite Solid Electrolytes for All‑Solid‑State Lithium Batteries
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作者 Xueyan Zhang Shichao Cheng +4 位作者 Chuankai Fu Geping Yin Liguang Wang Yongmin Wu Hua Huo 《Nano-Micro Letters》 SCIE EI CAS 2025年第1期46-97,共52页
To address the limitations of contemporary lithium-ion batteries,particularly their low energy density and safety concerns,all-solid-state lithium batteries equipped with solid-state electrolytes have been identified ... To address the limitations of contemporary lithium-ion batteries,particularly their low energy density and safety concerns,all-solid-state lithium batteries equipped with solid-state electrolytes have been identified as an up-and-coming alternative.Among the various SEs,organic–inorganic composite solid electrolytes(OICSEs)that combine the advantages of both polymer and inorganic materials demonstrate promising potential for large-scale applications.However,OICSEs still face many challenges in practical applications,such as low ionic conductivity and poor interfacial stability,which severely limit their applications.This review provides a comprehensive overview of recent research advancements in OICSEs.Specifically,the influence of inorganic fillers on the main functional parameters of OICSEs,including ionic conductivity,Li+transfer number,mechanical strength,electrochemical stability,electronic conductivity,and thermal stability are systematically discussed.The lithium-ion conduction mechanism of OICSE is thoroughly analyzed and concluded from the microscopic perspective.Besides,the classic inorganic filler types,including both inert and active fillers,are categorized with special emphasis on the relationship between inorganic filler structure design and the electrochemical performance of OICSEs.Finally,the advanced characterization techniques relevant to OICSEs are summarized,and the challenges and perspectives on the future development of OICSEs are also highlighted for constructing superior ASSLBs. 展开更多
关键词 Composite solid electrolytes Inorganic filler Interfacial stability Li-ion conduction mechanism Characterization techniques
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Hemangioblastoma Incidentally Discovered at CT Scan in Bamako: About a Case
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作者 Traore Ousmane N’Diaye Mamadou +5 位作者 Dembélé Mamadou Dembélé Adama Diakité Siaka Sidibé Mansa Drissa Camara Nagnoumague Keita Adama Diaman 《Open Journal of Medical Imaging》 2024年第3期123-127,共5页
Hemangioblastomas are benign vascular tumors of the brain. These are rare tumors, usually located in the cerebellum and most often affecting young adults. The aim was to study the value of CT in the management of hema... Hemangioblastomas are benign vascular tumors of the brain. These are rare tumors, usually located in the cerebellum and most often affecting young adults. The aim was to study the value of CT in the management of hemangioblastoma through observation. We report the case of a 38-year-old patient referred to the radiology and Medical Imaging Department of the Marie Curie Medical Clinic in Bamako, Mali, for an orbito-cerebral CT scan in a context of bilateral eyelid edema. The examination was performed using multi-slice computed tomography (16 slices) with reconstruction in the 3 planes of space without and with the injection of an iodinated contrast agent. The CT scan was crucial in making the diagnosis of hemangioblastoma incidentally, which allowed for adequate management. The patient was operated on, and the radiological outcome was favorable, without significant cystic formation, after postoperative control and clinical signs were resolved. CT can be an interesting alternative in countries like ours despite MRI being the examination of choice in hemangioblastomas. 展开更多
关键词 hemangioblastoma CT Scan Incidental Discovery and Bamako
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Rapid Fabrication of Electrodes for Symmetrical Solid Oxide Cells by Extreme Heat Treatment
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作者 Weiwei Fan Zhu Sun +2 位作者 Manxi Wang Manxian Li Yuming Chen 《Energy & Environmental Materials》 SCIE EI CAS CSCD 2024年第5期349-356,共8页
Symmetrical solid oxide cells(SSOCs)are very useful for energy generation and conversion.To fabricate the electrode of SSOC,it is very time-consuming to use the conventional approach.In this work,we design and develop... Symmetrical solid oxide cells(SSOCs)are very useful for energy generation and conversion.To fabricate the electrode of SSOC,it is very time-consuming to use the conventional approach.In this work,we design and develop a novel method,extreme heat treatment(EHT),to rapidly fabricate electrodes for SSOC.We show that by using the EHT method,the electrode can be fabricated in seconds(the fastest method to date),benefiting from enhanced reaction kinetics.The EHT-fabricated electrode presents a porous structure and good adhesion with the electrolyte.In contrast,tens of hours are needed to prepare the electrode by the conventional approach,and the prepared electrode exhibits a dense structure with a larger particle size due to the lengthy treatment.The EHT-fabricated electrode shows desirable electrochemical performance.Moreover,we show that the electrocatalytic activity of the perovskite electrode can be tuned by the vigorous approach of fast exsolution,deriving from the increased active sites for enhancing the electrochemical reactions.At 900℃,a promising peak power density of 966 mW cm^(-2)is reached.Our work exploits a new territory to fabricate and develop advanced electrodes for SSOCs in a rapid and high-throughput manner. 展开更多
关键词 electrochemical performance extreme heat treatment perovskite electrode symmetrical solid oxide cells
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Eosinophilic solid and cystic renal cell carcinoma with aggressive behavior:Two case reports
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作者 Hui-Hui Cao Hong Li +2 位作者 Xiao-Hong Guo Zhi-Xing Cao Bo-Hui Zhang 《World Journal of Clinical Cases》 SCIE 2024年第22期5124-5130,共7页
BACKGROUND Eosinophilic solid and cystic(ESC)renal cell carcinoma(RCC),a unique and emerging subtype of RCC,has an indolent nature;in some rare instances,it may exhibit metastatic potential.Current cases are inadequat... BACKGROUND Eosinophilic solid and cystic(ESC)renal cell carcinoma(RCC),a unique and emerging subtype of RCC,has an indolent nature;in some rare instances,it may exhibit metastatic potential.Current cases are inadequate to precisely predict the clinical outcome of ESC RCC and determine treatment choices.CASE SUMMARY Herein,we report two patients with ESC RCC.Patient 1 was a young woman with classical pathological characteristics.Patient 2 was a 52-year-old man with multifocal metastases,involving the pulmonary hilar and mediastinal lymph nodes,liver,brain,mesosternum,vertebra,rib,femur,and symphysis pubis.Awareness of ESC RCC,along with its characteristic architecture and immunophenotype,would contribute to making a definitive diagnosis,even on core biopsy samples.CONCLUSION The discovery of ESC RCC molecular signatures may provide new therapeutic strategies in the future. 展开更多
关键词 Eosinophilic solid and cystic renal cell carcinoma solid and cystic growth pattern CK20 TSC1 mutations TSC2 mutations Case report
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Incorporation of Ionic Conductive Polymers into Sulfide Electrolyte-Based Solid-State Batteries to Enhance Electrochemical Stability and Cycle Life
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作者 Juhyoung Kim Woonghee Choi +1 位作者 Seong-Ju Hwang Dong Wook Kim 《Energy & Environmental Materials》 SCIE EI CAS CSCD 2024年第6期4-12,共9页
Sulfide-based inorganic solid electrolytes are promising materials for high-performance safe solid-state batteries.The high ion conductivity,mechanical characteristics,and good processability of sulfide-based inorgani... Sulfide-based inorganic solid electrolytes are promising materials for high-performance safe solid-state batteries.The high ion conductivity,mechanical characteristics,and good processability of sulfide-based inorganic solid electrolytes are desirable properties for realizing high-performance safe solid-state batteries by replacing conventional liquid electrolytes.However,the low chemical and electrochemical stability of sulfide-based inorganic solid electrolytes hinder the commercialization of sulfide-based safe solid-state batteries.Particularly,the instability of sulfide-based inorganic solid electrolytes is intensified in the cathode,comprising various materials.In this study,carbonate-based ionic conductive polymers are introduced to the cathode to protect cathode materials and suppress the reactivity of sulfide electrolytes.Several instruments,including electrochemical spectroscopy,X-ray photoelectron spectroscopy,and scanning electron microscopy,confirm the chemical and electrochemical stability of the polymer electrolytes in contact with sulfide-based inorganic solid electrolytes.Sulfide-based solid-state cells show stable electrochemical performance over 100 cycles when the ionic conductive polymers were applied to the cathode. 展开更多
关键词 composite cathode electrochemical stability ionic conductive polymer solid-state battery sulfide solid electrolyte
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Progress in the application of polymer fibers in solid electrolytes for lithium metal batteries
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作者 Junbao Kang Nanping Deng +1 位作者 Bowen Cheng Weimin Kang 《Journal of Energy Chemistry》 SCIE EI CAS CSCD 2024年第5期26-42,共17页
Solid state lithium metal batteries(SSLMBs)are considered to be one of the most promising battery systems for achieving high energy density and excellent safety for energy storage in the future.However,current existed... Solid state lithium metal batteries(SSLMBs)are considered to be one of the most promising battery systems for achieving high energy density and excellent safety for energy storage in the future.However,current existed solid-state electrolytes(SSEs)are still difficult to meet the practical application requirements of SSLMBs.In this review,based on the analysis of main problems and challenges faced by the development of SSEs,the ingenious application and latest progresses including specific suggestions of various polymer fibers and their membrane products in solving these issues are emphatically reviewed.Firstly,the inherent defects of inorganic and organic electrolytes are pointed out.Then,the application strategies of polymer fibers/fiber membranes in strengthening strength,reducing thickness,enhancing thermal stability,increasing the film formability,improving ion conductivity and optimizing interface stability are discussed in detail from two aspects of improving physical structure properties and electrochemical performances.Finally,the researches and development trends of the intelligent applications of high-performance polymer fibers in SSEs is prospected.This review intends to provide timely and important guidance for the design and development of polymer fiber composite SSEs for SSLMBs. 展开更多
关键词 Composite solide lectrolytes Polymer fibers solid-state lithium metal batteries solid-stateel ectrolytes Nanofiber membranes
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Investigation and optimization of high-valent Ta-doped SrFeO_(3-δ)as air electrode for intermediate-temperature solid oxide fuel cells
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作者 Shanshan Jiang Hao Qiu +7 位作者 Shaohua Xu Xiaomin Xu Jingjing Jiang Beibei Xiao Paulo Sérgio Barros Juliao) Chao Su Daifen Chen Wei Zhou 《International Journal of Minerals,Metallurgy and Materials》 SCIE EI CAS CSCD 2024年第9期2102-2109,共8页
To explore highly active and thermomechanical stable air electrodes for intermediate-temperature solid oxide fuel cells(ITSOFCs),10mol%Ta5+doped in the B site of strontium ferrite perovskite oxide(SrTa_(0.1)Fe_(0.9)O_... To explore highly active and thermomechanical stable air electrodes for intermediate-temperature solid oxide fuel cells(ITSOFCs),10mol%Ta5+doped in the B site of strontium ferrite perovskite oxide(SrTa_(0.1)Fe_(0.9)O_(3-δ),STF)is investigated and optimized.The effects of Ta^(5+)doping on structure,transition metal reduction,oxygen nonstoichiometry,thermal expansion,and electrical performance are evaluated systematically.Via 10mol%Ta^(5+)doping,the thermal expansion coefficient(TEC)decreased from 34.1×10^(-6)(SrFeO_(3-δ))to 14.6×10^(-6) K^(-1)(STF),which is near the TEC of electrolyte(13.3×10^(-6) K^(-1) for Sm_(0.2)Ce_(0.8)O_(1.9),SDC),indicates excellent thermomechanical compatibility.At 550-750℃,STF shows superior oxygen vacancy concentrations(0.262 to 0.331),which is critical in the oxygen-reduction reaction(ORR).Oxygen temperature-programmed desorption(O_(2)-TPD)indicated the thermal reduction onset temperature of iron ion is around 420℃,which matched well with the inflection points on the thermos-gravimetric analysis and electrical conductivity curves.At 600℃,the STF electrode shows area-specific resistance(ASR)of 0.152Ω·cm^(2) and peak power density(PPD)of 749 mW·cm^(-2).ORR activity of STF was further improved by introducing 30wt%Sm_(0.2)Ce_(0.8)O_(1.9)(SDC)powder,STF+SDC composite cathode achieving outstanding ASR value of 0.115Ω·cm2 at 600℃,even comparable with benchmark cobalt-containing cathode,Ba_(0.5)Sr_(0.5)Co_(0.8)Fe_(0.2)O_(3-δ)(BSCF).Distribution of relaxation time(DRT)analysis revealed that the oxygen surface exchange and bulk diffusion were improved by forming a composite cathode.At 650℃,STF+SDC composite cathode achieving an outstanding PPD of 1117 mW·cm^(-2).The excellent results suggest that STF and STF+SDC are promising air electrodes for IT-SOFCs. 展开更多
关键词 strontium ferrite-based perovskite Ta doping composite cathode intermediate-temperature solid oxide fuel cells
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Extending the solid solution range of sodium ferric pyrophosphate:Off‐stoichiometric Na_(3)Fe(2.5)(P_(2)O_(7))_(2)as a novel cathode for sodium‐ion batteries 被引量:1
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作者 Xiang jun Pu Kunran Yang +6 位作者 Zibing Pan Chunhua Song Yangyang Lai Renjie Li Zheng‐Long Xu Zhongxue Chen Yuliang Cao 《Carbon Energy》 SCIE EI CAS CSCD 2024年第4期128-139,共12页
Iron‐based pyrophosphates are attractive cathodes for sodium‐ion batteries due to their large framework,cost‐effectiveness,and high energy density.However,the understanding of the crystal structure is scarce and on... Iron‐based pyrophosphates are attractive cathodes for sodium‐ion batteries due to their large framework,cost‐effectiveness,and high energy density.However,the understanding of the crystal structure is scarce and only a limited candidates have been reported so far.In this work,we found for the first time that a continuous solid solution,Na_(4−α)Fe_(2+α)_(2)(P_(2)O_(7))_(2)(0≤α≤1,could be obtained by mutual substitution of cations at center‐symmetric Na3 and Na4 sites while keeping the crystal building blocks of anionic P_(2)O_(7) unchanged.In particular,a novel off‐stoichiometric Na_(3)Fe(2.5)(P_(2)O_(7))_(2)is thus proposed,and its structure,energy storage mechanism,and electrochemical performance are extensively investigated to unveil the structure–function relationship.The as‐prepared off‐stoichiometric electrode delivers appealing performance with a reversible discharge capacity of 83 mAh g^(−1),a working voltage of 2.9 V(vs.Na^(+)/Na),the retention of 89.2%of the initial capacity after 500 cycles,and enhanced rate capability of 51 mAh g^(−1)at a current density of 1600 mA g^(−1).This research shows that sodium ferric pyrophosphate could form extended solid solution composition and promising phase is concealed in the range of Na_(4−α)Fe_(2+α)_(2)(P_(2)O_(7))_(2),offering more chances for exploration of new cathode materials for the construction of high‐performance SIBs. 展开更多
关键词 extending solid‐solution range off‐stoichiometric Na_(3)Fe_(2.5)(P_(2)O_(7))_(2) sodium‐ion batteries structure-function relationship
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Mass transfer enhancement and hydrodynamic performance with wire mesh coupling solid particles in bubble column reactor
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作者 Chuanjun Di Jipeng Dong +3 位作者 Fei Gao Guanghui Chen Pan Zhang Jianlong Li 《Chinese Journal of Chemical Engineering》 SCIE EI CAS CSCD 2024年第3期195-205,共11页
It is of vital significance to investigate mass transfer enhancements for chemical engineering processes.This work focuses on investigating the coupling influence of embedding wire mesh and adding solid particles on b... It is of vital significance to investigate mass transfer enhancements for chemical engineering processes.This work focuses on investigating the coupling influence of embedding wire mesh and adding solid particles on bubble motion and gas-liquid mass transfer process in a bubble column.Particle image velocimetry(PIV)technology was employed to analyze the flow field and bubble motion behavior,and dynamic oxygen absorption technology was used to measure the gas-liquid volumetric mass transfer coefficient(kLa).The effect of embedding wire mesh,adding solid particles,and wire mesh coupling solid particles on the flow characteristic and kLa were analyzed and compared.The results show that the gas-liquid interface area increases by 33%-72%when using the wire mesh coupling solid particles strategy compared to the gas-liquid two-phase flow,which is superior to the other two strengthening methods.Compared with the system without reinforcement,kLa in the bubble column increased by 0.5-1.8 times with wire mesh coupling solid particles method,which is higher than the sum of kLa increases with inserting wire mesh and adding particles,and the coupling reinforcement mechanism for affecting gas-liquid mass transfer process was discussed to provide a new idea for enhancing gas-liquid mass transfer. 展开更多
关键词 Fluid mechanics BUBBLE Mass transfer Wire mesh coupling solid particles Particle image velocimetry Hydrodynamics
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Household Solid Waste Awareness and Practices among Residents of Windhoek, Namibia
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作者 Jolosi Mukena Youcai Zhao Songa Mutonga 《Journal of Environmental Protection》 2024年第6期641-655,共15页
This study explores household solid waste management (HSWM) practices and awareness among residents of Windhoek West, a rapidly urbanizing constituency in the Khomas Region of Namibia. Employing a descriptive methodol... This study explores household solid waste management (HSWM) practices and awareness among residents of Windhoek West, a rapidly urbanizing constituency in the Khomas Region of Namibia. Employing a descriptive methodology, the research investigates the interplay between public awareness, regulatory frameworks, and the availability of waste management facilities to assess their impact on waste management behaviors. Our findings indicate significant gaps in both knowledge and infrastructure that hinder effective waste management. The study reveals that while there is a high willingness among residents to engage in recycling and waste reduction, actual practices are limited due to inadequate facilities and lack of stringent enforcement of waste policies. This research identifies key factors that influence waste management practices, including demographic characteristics and access to waste management facilities. It also proposes actionable strategies such as expanding recycling and sorting facilities, enhancing educational campaigns tailored to local needs, and implementing regular enforcement mechanisms. These strategies are aimed at improving compliance with waste management protocols and fostering a culture of environmental responsibility. The results of this investigation show the critical role of ongoing education and infrastructural improvement in bridging existing knowledge gaps and facilitating effective waste management practices. This research lays a foundational step toward enhancing sustainable urban development and effective waste management in Windhoek, providing valuable insights for policymakers, community leaders, and stakeholders engaged in urban environmental management. 展开更多
关键词 Household solid Waste Management (HSWM) Public Awareness Waste Segregation Windhoek West Recycling Facilities
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