The fundamental equation of mineral production allows to model and design the dynamics of mineral production, however complex they are or could be. It considers not only the case of a constant production to reserves r...The fundamental equation of mineral production allows to model and design the dynamics of mineral production, however complex they are or could be. It considers not only the case of a constant production to reserves ratio for given intervals of time, but with a piecewise approach, it is also enabled to account the variation on time of this ratio. With a constant production to reserves ratio, the limit expression of the fundamental equation takes the form of an Erlang distribution with a fixed shape parameter. The rate parameter equals the scale factor. The discrete piecewise version, instead of considering the reserves and the production to reserves ratio being constant through certain intervals of time, updates both variables by units of time. This version, using either lineal or non lineal functions for the variables involved, let to model known production profiles or to forecast them by experimental design. The Hubbert’s linearization updated with recent data and the p-box method applied to determine ultimate recovery of U.S. crude oil reserves indicate official accounts underestimate them. The analysis of the ideal model of production based on Hubbert’s linearization and curve, can be made by decomposing it in the distribution with time of the reserves and of the production to reserves ratio. The distribution of reserves with time is synchronized for both the ideal Hubbert’s curve and real profiles, disregarding whether they match or not. The departure of real profiles from the ideal Hubbert’s curve lies on the differences or correspondences of the distribution with time of the production to reserves ratio. The MonteCarlo simulation applied to forecast US crude oil production for the next five years points to a slow decline, with average annual yields presenting a difference lower than 10% between the start and the end of the simulation.展开更多
In this paper, research results from the time interval 2002-2012 are used to give an account of the chemical composition of soils on the territory of the Kovykta gas condensate field. The findings presented provide a ...In this paper, research results from the time interval 2002-2012 are used to give an account of the chemical composition of soils on the territory of the Kovykta gas condensate field. The findings presented provide a better understanding of the ecological state of soil cover, its resilience to anthropogenic impacts, and its possible disturbance caused by the drilling pad construction activity, and by the laying of geophysical profiles. An analysis of soil pollution for the study territory generally showed that the soils are polluted with chemical elements which refer to toxicity classes: Pb, Cu, Ni, Cr, Ba and Mn. High levels ofoil products were detected near boreholes. Strong mineralization was recorded in the soil near borehole. It has a chloride-sodium chemical composition. As a result of the construction of foundation pits, recesses, ditches and earth embankments, the soil is totally destroyed, and rock outcrops show up. Disturbances of the sod cover due to road construction or even by all-terrain vehicles in these extreme conditions entail an accelerated development of linear erosion to form scours and gullies. Elimination of the canopy layer leads to an increase in surface heating, and to an acceleration of permafrost thawing. Swamping is accelerated on negative relief forms due to the increased entry of melt waters.展开更多
建立并比较固相萃取-气相色谱法和全二维气相色谱法测定食品接触用纸制品中饱和烃矿物油(saturated hydrocarbon mineral oil,MOSH)迁移量的技术.结果表明,优化后的两种方法均能实现迁移液中MOSH的有效分离和检测,方法的相对标准偏差均...建立并比较固相萃取-气相色谱法和全二维气相色谱法测定食品接触用纸制品中饱和烃矿物油(saturated hydrocarbon mineral oil,MOSH)迁移量的技术.结果表明,优化后的两种方法均能实现迁移液中MOSH的有效分离和检测,方法的相对标准偏差均较好,为4.3%.相较于固相萃取-气相色谱法,全二维气相色谱法前处理更简单,检出限更低(1.0 mg/L),回收率更高(94.4%~102.4%).对17批实际样品的检测表明,两种方法的定量结果的偏差为8.6%,全二维气相色谱法具有更广泛的适用性,可对个别固相萃取-气相色谱法不能检出的样品进行检测与定量.本研究针对食品接触材料检测的难点问题,研究并验证了新技术,为新标准的制定提供了方法学基础数据支撑.展开更多
文摘The fundamental equation of mineral production allows to model and design the dynamics of mineral production, however complex they are or could be. It considers not only the case of a constant production to reserves ratio for given intervals of time, but with a piecewise approach, it is also enabled to account the variation on time of this ratio. With a constant production to reserves ratio, the limit expression of the fundamental equation takes the form of an Erlang distribution with a fixed shape parameter. The rate parameter equals the scale factor. The discrete piecewise version, instead of considering the reserves and the production to reserves ratio being constant through certain intervals of time, updates both variables by units of time. This version, using either lineal or non lineal functions for the variables involved, let to model known production profiles or to forecast them by experimental design. The Hubbert’s linearization updated with recent data and the p-box method applied to determine ultimate recovery of U.S. crude oil reserves indicate official accounts underestimate them. The analysis of the ideal model of production based on Hubbert’s linearization and curve, can be made by decomposing it in the distribution with time of the reserves and of the production to reserves ratio. The distribution of reserves with time is synchronized for both the ideal Hubbert’s curve and real profiles, disregarding whether they match or not. The departure of real profiles from the ideal Hubbert’s curve lies on the differences or correspondences of the distribution with time of the production to reserves ratio. The MonteCarlo simulation applied to forecast US crude oil production for the next five years points to a slow decline, with average annual yields presenting a difference lower than 10% between the start and the end of the simulation.
文摘In this paper, research results from the time interval 2002-2012 are used to give an account of the chemical composition of soils on the territory of the Kovykta gas condensate field. The findings presented provide a better understanding of the ecological state of soil cover, its resilience to anthropogenic impacts, and its possible disturbance caused by the drilling pad construction activity, and by the laying of geophysical profiles. An analysis of soil pollution for the study territory generally showed that the soils are polluted with chemical elements which refer to toxicity classes: Pb, Cu, Ni, Cr, Ba and Mn. High levels ofoil products were detected near boreholes. Strong mineralization was recorded in the soil near borehole. It has a chloride-sodium chemical composition. As a result of the construction of foundation pits, recesses, ditches and earth embankments, the soil is totally destroyed, and rock outcrops show up. Disturbances of the sod cover due to road construction or even by all-terrain vehicles in these extreme conditions entail an accelerated development of linear erosion to form scours and gullies. Elimination of the canopy layer leads to an increase in surface heating, and to an acceleration of permafrost thawing. Swamping is accelerated on negative relief forms due to the increased entry of melt waters.
文摘建立并比较固相萃取-气相色谱法和全二维气相色谱法测定食品接触用纸制品中饱和烃矿物油(saturated hydrocarbon mineral oil,MOSH)迁移量的技术.结果表明,优化后的两种方法均能实现迁移液中MOSH的有效分离和检测,方法的相对标准偏差均较好,为4.3%.相较于固相萃取-气相色谱法,全二维气相色谱法前处理更简单,检出限更低(1.0 mg/L),回收率更高(94.4%~102.4%).对17批实际样品的检测表明,两种方法的定量结果的偏差为8.6%,全二维气相色谱法具有更广泛的适用性,可对个别固相萃取-气相色谱法不能检出的样品进行检测与定量.本研究针对食品接触材料检测的难点问题,研究并验证了新技术,为新标准的制定提供了方法学基础数据支撑.