The Qinghai-Tibet Plateau is now experiencing ecological degradation risks as a result of climate change and human activities.The alpine grassland ecology in permafrost zones is fragile and susceptible to deterioratio...The Qinghai-Tibet Plateau is now experiencing ecological degradation risks as a result of climate change and human activities.The alpine grassland ecology in permafrost zones is fragile and susceptible to deterioration due to its high altitude,low temperature,and limited oxygen,which complicates the repair of damaged land.Biological soil crusts(BSCs)are crucial for land restoration in plateau regions because they can thrive in harsh conditions and have environmentally beneficial traits.Inoculated biological soil crust(IBSC)has shown success in low-altitude desert regions,but may not be easily duplicated to the plateau environment.Therefore,it is essential to do a comprehensive and multifaceted analysis of the basic theoretical comprehension and practical application of BSCs on the Tibetan Plateau.This review article aims to provide a brief summary of the ecological significance and the mechanisms related to the creation,growth,and progression of BSCs.It discusses the techniques used for cultivating BSCs in laboratories and using them in the field,focusing on the Qinghai-Tibet Plateau circumstance.We thoroughly discussed the potential and the required paths for further studies.This study may be used as a basis for selecting suitable microbial strains and accompanying supplemental actions for implementing IBSCs in the Qinghai-Tibet Plateau.展开更多
High-silica granitoids record the formation and evolution of the continental crust.A new intrusive complex has been recognized among silicic volcanic rocks of the Weixi arc,Southwest China.The intrusions consist of gr...High-silica granitoids record the formation and evolution of the continental crust.A new intrusive complex has been recognized among silicic volcanic rocks of the Weixi arc,Southwest China.The intrusions consist of granites,granitic porphyries,and granodiorites.Zircon U-Pb age data indicate that the Weixi granitoids formed at 248-240 Ma and were coeval with silicic volcanic rocks of the Weixi arc.The Weixi granitoids are enriched in Rb,Th,and U,depleted in Ba,Sr,Nb,Ta,and Ti,and have high light/heavy rare earth element ratios and slightly negative Eu anomalies.The Weixi granitoids have negative ε_(Nd)(t)values(-9.8 to-7.8)and negative zircon ε_(Hf)(t)values(-12.02 to-5.11).The geochemical and isotopic features suggest the Weixi granitoids were derived by partial melting of ancient crustal material.The Weixi granitoids and silicic volcanic rocks were derived from the same magma by crystal accumulation and melt extraction,respectively,and they record the formation of a continental arc in the central Sanjiang orogenic belt.展开更多
To explore the occurrence phases and enrichment mechanism of rare earth elements(REEs)in cobalt-rich crusts,this study analyzes the mineral composition and REE contents of the samples from Marcus-Wake Seamounts by XRD...To explore the occurrence phases and enrichment mechanism of rare earth elements(REEs)in cobalt-rich crusts,this study analyzes the mineral composition and REE contents of the samples from Marcus-Wake Seamounts by XRD,ICP-OES and ICP-MS.The results show that,(1)the cobalt-rich crusts contain the major crystalline mineral(vernadite),the secondary minerals(quartz,plagioclase and carbonate fluorapatite),and a large amount of amorphous ferric oxyhydroxides(FeOOH).(2)The cobalt-rich crusts contains higher Mn(10.83%to 28.76%)and Fe(6.14%to 18.86%)relative to other elements,and are enriched in REEs,with total REE contents of 1563−3238μg/g and Ce contents of 790−1722μg/g.Rare earth element contents of the old crusts are higher than those of the new crusts.Moreover,the non-phosphatized crusts have positive Ce and negative Y anomalies,and yet the phosphatized crusts have positive Ce and positive Y anomalies,indicating that cobalt-rich crusts is hydrogenetic and REEs mainly come from seawater.(3)Analytical data also show that the occurrence phases of elements in cobalt-rich crusts are closely related to their mineral phases.In the non-phosphatized crusts,REEs are adsorbed by colloidal particles into the crusts(about 67%of REEs in the Fe oxide phase,and about 17%of REEs in the Mn oxide phase).In contrast,in the phosphatized crusts(affected by the phosphatization),REEs may combine with phosphate to form rare earth phosphate minerals,and about 64%of REEs are enriched in the residual phase containing carbonate fluorapatite,but correspondingly the influence of Fe and Mn oxide phases on REEs enrichment is greatly reduced.In addition,the oxidizing environment of seawater,high marine productivity,phosphatization,and slow growth rate can promote the REE enrichment.This study provides a reference for the metallogenesis of cobalt-rich crusts in the Pacific.展开更多
Collapsing erosion is a unique phenomenon commonly observed on the granite residue hillslopes in the tropical and subtropical regions of southern China,characterized by its abrupt occurrence and significant erosion vo...Collapsing erosion is a unique phenomenon commonly observed on the granite residue hillslopes in the tropical and subtropical regions of southern China,characterized by its abrupt occurrence and significant erosion volumes.However,the impacts of soil crust conditions on the erosion of colluvial deposits with granite residual soils have only been studied to a limited extent.To address this issue,this study investigates the impacts of three soil crust conditions(i.e.,without crust,10-minute crust,and 20-minute crust)on gully morphology,rainfall infiltration,and runoff and sediment yield during slope erosion of colluvial deposits with granite residues(classified as Acrisols)in Yudu County,Ganzhou City,Jiangxi Province,China,using simulated rainfall tests and photographic methods.The results showed that as the strength of the soil crust increased,the capacity of moisture infiltration and the width and depth of the gully as well as the sediment concentration and yield ratio decreased;at the same time,the runoff ratio increased.The sediment yield in the without-crust test was found to be 1.24 and 1.43 times higher than that observed in the 10-minute crust and 20-minute crust tests,respectively.These results indicate that soil crusts can effectively prevent slope erosion and moisture infiltration,while providing valuable insights for the management of soil erosion in natural environments.展开更多
Biological soil crusts(BSCs)play an important role in soil development and ecological function,and it is more important for quantitatively analyzing the processes and trends of BSCs to identify the advantages and disa...Biological soil crusts(BSCs)play an important role in soil development and ecological function,and it is more important for quantitatively analyzing the processes and trends of BSCs to identify the advantages and disadvantages of BSCs research for the development and application of BSCs theory.Bibliometric analysis of 2,186 BSCs literatures from Web of Science showed an exponential growth trend,as China and the United States as the top 2 in terms of publication volume.High quality publications are mainly from European and American countries,such as the United States,Germany and Spain.The top 3 publishers are Journal of Arid Environments,Soil Biology&Biochemistry and Plant and Soil,and disciplines include ecology,environmental science,and soil science,etc..Research institutions mainly affiliate to the Chinese Academy of Sciences,United States Department of the Interior,United States Geological Survey,Hebrew University of Jerusalem,Consejo Superior de Investigaciones Cientificas,and Universidad Rey Juan Carlos.Authors mainly come from United States,Israel,Spain and China.Funds are mainly from the National Natural Science Foundation of China,Spanish Government,Chinese Academy of Sciences,and National Science Foundation of the United States.Biological soil crusts(biocrusts,cyanobacteria,lichens,moss crusts,bryophytes),drylands,climate change,photosynthesis and desert are high-frequency keywords.Future research will focus on the driving mechanisms of BSCs on global biogeochemical cycles,maintaining global biodiversity on important ecological processes,global C,N,and P cycles.The impact on biological invasion,sandstorms,and water balance,multifunctional and reciprocal mechanisms for maintaining the stability of desert and sandy ecosystems,and impact on the formulation of management policies for arid ecosystems,corresponding to global climate change,and the estimation of regional,local,and microscale distribution of BSCs based on machine deep learning modeling gradually focus on.The ecosystem service functions of BSCs,the soil and water conservation and soil stability mediated by BSCs in arid and semi-arid regions,and the excavation of stress resistant genes for BSCs will be emphasized.展开更多
In recent years,the Fuxian area in the southeastern Ordos Basin has undergone significant exploration,with industrial gas flow tested in wells drilled into the Ordovician marine carbonates.Despite this,the gas accumul...In recent years,the Fuxian area in the southeastern Ordos Basin has undergone significant exploration,with industrial gas flow tested in wells drilled into the Ordovician marine carbonates.Despite this,the gas accumulation patterns of this area are not fully understood,posing challenges for further exploration.Our analysis of geological conditions indicates that the Ordovician Majiagou Formation in this area hosts two gas plays:one found in weathering crusts and the other found in interior of the formation.We investigated various typical gas reservoirs in the area,focusing on differentiating the geological conditions and factors controlling gas accumulation in the weathering-crust and interior gas reservoirs.The results suggest three primary gas accumulation patterns in the Majiagou Formation in the Fuxian area:(1)upper gas accumulation in weathering crusts,present in the high parts of landforms such as residual paleo-hills or buried paleo-platform(Pattern I);(2)the stereoscopic pattern with gas accumulation in both weathering crusts and strata interior,arising in high parts of landforms such as residual paleo-hills or buried paleo-platforms(Pattern II);(3)lower gas accumulation in strata interior,occurring in the upper reaches and on both sides of paleo-trenches(Pattern III).This study will serve as a geological basis for future exploration deployment in the Fuxian area.展开更多
Surfactants were proposed to be added into magnesium sulfate solution to improve the leaching process of weathered crust elution-deposited rare earth ores(WREOs).Effects of surfactants and their concentration on the s...Surfactants were proposed to be added into magnesium sulfate solution to improve the leaching process of weathered crust elution-deposited rare earth ores(WREOs).Effects of surfactants and their concentration on the seepage of leaching solutions and the leaching efficiency of rare earth(RE)and aluminum(Al)were investigated,and the leaching kinetics,the mass transfer process,the adhesion work and the adhesion work reduction factor were analyzed to reveal its strengthening leaching mechanism.The results show that cetyltrimethylammonium bromide(CTAB)has a better strengthening effect on the leaching process than dodecyl trimethyl ammonium bromide(DTAB),sodium dodecyl sulfate(SDS),sodium oleate and oleic acid.In the presence of 0.04%CTAB in 0.2 mol/L solution,the permeability coefficient of WREOs increases from 0.945×10^(-5)to 1.640×10^(-5)cm·s^(-1),and the leaching efficiency of RE increases from 80%to 90%,confirming the promotion of surfactants on the leaching process of WREOs.Kinetic analysis shows that the leaching process conforms to the inner diffusion control model,and the leaching kinetics equations of RE and Al related to CTAB content are obtained.Mass transfer discussion shows a smaller height equivalent to theoretical plate(HETP)of RE and Al at CTAB content of 0.04%,suggesting the higher mass transfer efficiency here.According to the interfacial properties of leaching solutions,the calculated adhesion work and the adhesion work reduction factor further demonstrate the strengthening leaching effect of CTAB on the leaching process of WREOs.展开更多
In this work,we perform a Bayesian inference of the crust-core transition density ρ_(t) of neutron stars based on the neutron-star radius and neutron-skin thickness data using a thermodynamical method.Uniform and Gau...In this work,we perform a Bayesian inference of the crust-core transition density ρ_(t) of neutron stars based on the neutron-star radius and neutron-skin thickness data using a thermodynamical method.Uniform and Gaussian distributions for the ρ_(t) prior were adopted in the Bayesian approach.It has a larger probability of having values higher than 0.1 fm^(−3) for ρ_(t) as the uniform prior and neutron-star radius data were used.This was found to be controlled by the curvature K_(sym) of the nuclear symmetry energy.This phenomenon did not occur if K_(sym) was not extremely negative,namely,K_(sym)>−200 MeV.The value ofρ_(t) obtained was 0.075_(−0.01)^(+0.005) fm^(−3) at a confidence level of 68%when both the neutron-star radius and neutron-skin thickness data were considered.Strong anti-correlations were observed between ρ_(t),slope L,and curvature of the nuclear symmetry energy.The dependence of the three L-K_(sym) correlations predicted in the literature on crust-core density and pressure was quantitatively investigated.The most probable value of 0.08 fm^(−3) for ρ_(t) was obtained from the L-K_(sym) relationship proposed by Holt et al.while larger values were preferred for the other two relationships.展开更多
The Jurassic oceanic crust is the oldest existing oceanic crust on earth,and although distributed sparsely,carries essential information about the earth's evolution.The area around the Pigafetta Basin in the west ...The Jurassic oceanic crust is the oldest existing oceanic crust on earth,and although distributed sparsely,carries essential information about the earth's evolution.The area around the Pigafetta Basin in the west Pacific Ocean(also known as the Jurassic Quiet Zone,JQZ)is one of a few areas where the Jurassic oceanic crust is present.This study takes full advantage of high-resolution multichannel seismic reflection profiles in combination with bathymetry,magnetic,and gravity data from the JQZ to examine the structure,deformation,and morphology of the Jurassic oceanic crust.Our results show the following insights:1)The Moho lies at 2–3 s in two-way travel time beneath the seafloor with the segmented feature.The gaps between the Moho segments well correspond to the seamounts on the seafloor,suggesting the upward migration of magma from the mantle has interrupted the pre-existing Moho.2)The oceanic crust is predominantly deformed by crustal-scale thrust faults,normal faults cutting through the top of basement,and vertical seismic disturbance zones in association with migration of thermal fluids.The thrust faults are locally found and interpreted as the results of tectonic inversion.3)Seafloor morphology in the JQZ is characterized by fault scarps,fold scarps,seamounts,and small hills,indicating the occurrence of active faults.4)The oceanic crust in the JQZ and East Pacific Rise has many structural and geometrical variations,such as the thickness of sediments,seafloor topography,basement morphology,fault size and type.展开更多
Weathering has always been a concerned around the world,as the first and most important step in the global cycle of elements,which leads to the fractionation of isotopes on the scale of geological age.The Middle Ordov...Weathering has always been a concerned around the world,as the first and most important step in the global cycle of elements,which leads to the fractionation of isotopes on the scale of geological age.The Middle Ordovician Majiagou Formation in Daniudi area of the Ordos Basin had experienced weathering for>130 Myr.Through thin section observation,major and trace element analysis,carbon,oxygen,and magnesium isotopes composition analysis,the dolomitization modes and weathering of ancient dolo-mite in Daniudi area were analyzed in detail.The results showed that the Sabkha and brine-reflux dolomitization modes had developed,and the Mg isotopes in different layers of the karst crust were fractionated by various factors.The vertical vadose zone was affected by weathering,the Mg isotope of dolomite(δ^(26)Mgdol)showed a downward decreasing trend;the horizontal underflow zone was controlled by diagenesis and formation fluid,δ^(26)Mgdol showed a vertical invariance and negative;the main reason for Mg isotope fractionation in the deep slow-flow zone was the brine-reflux dolomitization mode during early burial period,which showed a vertical downward increase.Finally,the Mg isotope characteristic data of the ancient weathering crust were provided and the process of Mg isotope frac-tionationinthekarstcrust was explained.展开更多
The bedrock weathered crust in front of the Altun Mountains in the Qaidam Basin,western China,is different from others because this is a salt-lake basin,where saline water fluid infiltrates and is deposited in the ove...The bedrock weathered crust in front of the Altun Mountains in the Qaidam Basin,western China,is different from others because this is a salt-lake basin,where saline water fluid infiltrates and is deposited in the overlying strata.A large amount of gypsum infills the bedrock weathered crust,and this has changed the pore structure.Using core observation,polarized light microscopy,electron probe,physical property analysis and field emission scanning electron microscopy experiments,the characteristics of the weathered bedrock have been studied.There are cracks and a small number of dissolved pores in the interior of the weathered crust.Matrix micropores are widely developed,especially the various matrix cracks formed by tectonics and weathering,as well as the stress characteristics of small dissolved pores,and physical properties such as porosity and permeability.This‘dual structure’developed in the bedrock is important for guiding the exploration of the lake basin bedrock for natural gas.展开更多
Both CT and Avizo software were used to explore the effect of particle gradation on the evolution characteristics of pore structure and seepage paths in weathered crust elution-deposited rare earth ores during leachin...Both CT and Avizo software were used to explore the effect of particle gradation on the evolution characteristics of pore structure and seepage paths in weathered crust elution-deposited rare earth ores during leaching.The results showed that the pore areas in four kinds of ore samples before leaching were mainly concentrated in 10^(4)–10^(7)μm^(2),whose pore quantities accounted for 96.89%,94.94%,90.48%,and 89.45%,respectively,while the corresponding pore volume only accounted for 30.74%,14.55%,7.58%,and 2.84%of the total pore volume.With the decrease of fractal dimension,the average pore throat length increased,but pore throat quantities,the average pore throat radius and coordination number decreased.Compared with that before leaching,the change degree of pore structure during leaching increased with the fractal dimension decreasing.For example,the reduction rate of the average coordination number of ore samples was 14.36%,21.30%,28.00%,and 32.90%,respectively.Seepage simulation results indicated that seepage paths were uniformly distributed before leaching while the streamline density and seepage velocity increased with the fractal dimension decreasing.Besides,the phenomenon of the streamline interruption gradually reduced during leaching while preferential seepage got more obvious with the decrease of the fractal dimension.展开更多
In this research,two shake table experiments were conducted to study the effects of non-liquefiable crust layer and superstructure mass on the responses of two sets of 22 pile groups to liquefactioninduced lateral spr...In this research,two shake table experiments were conducted to study the effects of non-liquefiable crust layer and superstructure mass on the responses of two sets of 22 pile groups to liquefactioninduced lateral spreading.In this regard,an inclined base layer overlain by a very loose liquefiable layer was constructed in both models;while only in one model,a non-liquefiable crust layer was built.A lumped mass,being representative of a superstructure,was attached to the cap of one pile group in both models.The models were fully instrumented with various sensors,including acceleration,displacement,and pore water pressure transducers.Also,the piles were instrumented with pair strain gauges to measure pure bending moments induced by cyclic and monotonic loadings associated with ground shaking and lateral spreading,respectively.The results showed that the existence of the non-liquefiable crust layer increases both the maximum and residual soil displacements at the free field and also the maximum bending moments in the piles.The results of the experiments indicated that the crust layer induces a high kinematic lateral soil pressure and force on the piles which are not present in the crustless case.The crust layer increases the pile cap displacement before liquefaction,albeit decreases it after liquefaction,due to the elastic rebound of the piles in the liquefiable layer.The crust layer postpones both liquefaction triggering and dissipation of excess pore water pressure.The existence of the superstructure mass on the pile caps decreases the acceleration amplitude of the pile caps,while increases their maximum displacement.展开更多
Livestock grazing is the most extensive land use in global drylands and one of the most extensive stressors of biological soil crusts(biocrusts).Despite widespread concern about the importance of biocrusts for global ...Livestock grazing is the most extensive land use in global drylands and one of the most extensive stressors of biological soil crusts(biocrusts).Despite widespread concern about the importance of biocrusts for global carbon(C)cycling,little is known about whether and how long-term grazing alters soil organic carbon(SOC)stability and stock in the biocrust layer.To assess the responses of SOC stability and stock in the biocrust layer to grazing,from June to September 2020,we carried out a large scale field survey in the restored grasslands under long-term grazing with different grazing intensities(represented by the number of goat dung per square meter)and in the grasslands strictly excluded from grazing in four regions(Dingbian County,Shenmu City,Guyuan City and Ansai District)along precipitation gradient in the hilly Loess Plateau,China.In total,51 representative grassland sites were identified as the study sampling sites in this study,including 11 sites in Guyuan City,16 sites in Dingbian County,15 sites in Shenmu City and 9 sites in Ansai District.Combined with extensive laboratory analysis and statistical analysis,at each sampling site,we obtained data on biocrust attributes(cover,community structure,biomass and thickness),soil physical-chemical properties(soil porosity and soil carbon-to-nitrogen ratio(C/N ratio)),and environmental factors(mean annual precipitation,mean annual temperature,altitude,plant cover,litter cover,soil particle-size distribution(the ratio of soil clay and silt content to sand content)),SOC stability index(SI)and SOC stock(SOCS)in the biocrust layer,to conduct this study.Our results revealed that grazing did not change total biocrust cover but markedly altered biocrust community structure by reducing plant cover,with a considerable increase in the relative cover of cyanobacteria(23.1%)while a decrease in the relative cover of mosses(42.2%).Soil porosity and soil C/N ratio in the biocrust layer under grazing decreased significantly by 4.1%–7.2%and 7.2%–13.3%,respectively,compared with those under grazing exclusion.The shifted biocrust community structure ultimately resulted in an average reduction of 15.5%in SOCS in the biocrust layer under grazing.However,compared with higher grazing(intensity of more than 10.00 goat dung/m2),light grazing(intensity of 0.00–10.00 goat dung/m2 or approximately 1.20–2.60 goat/(hm2•a))had no adverse effect on SOCS.SOC stability in the biocrust layer remained unchanged under long-term grazing due to the offset between the positive effect of the decreased soil porosity and the negative effect of the decreased soil C/N ratio on the SOC resistance to decomposition.Mean annual precipitation and soil particle-size distribution also regulated SOC stability indirectly by influencing soil porosity through plant cover and biocrust community structure.These findings suggest that proper grazing might not increase the CO_(2) release potential or adversely affect SOCS in the biocrust layer.This research provides some guidance for proper grazing management in the sustainable utilization of grassland resources and C sequestration in biocrusts in the hilly regions of drylands.展开更多
Based on drill core and thin section observation,major geochemical element analysis and con-ventional well log analysis,this study summarizes the characteristics and thickness of weathering crust of Pennsylvanian volc...Based on drill core and thin section observation,major geochemical element analysis and con-ventional well log analysis,this study summarizes the characteristics and thickness of weathering crust of Pennsylvanian volcanic rocks(Carboniferous)in Shixi area,Junggar Basin.The weathering crust is identified and divided into three types according to the petrological characteristics and well log interpretations in Shixi area,and the isopach of weathering crust is mapped.The results show that:(1)With the increase of depth,the weathering weakens,and the rocks become less fractured with decreased porosity;(2)the weathering crust of the Upper Carboniferous volcanic rocks can be divided into strongly weathered and mildly weathered layers in Shixi area;(3)the weathering crust is relatively thicker in Dinan uplift and Shixi uplift.This study provides research basis for further evaluation of Upper Carboniferous volcanic reservoir,and will benefit for well location deployment and potential oilfield development in the Shixi area.展开更多
Cements are widely developed in clastic rock-originated weathering crust(CWC)reservoirs in the Kexia region along the northwestern margin of the Junggar Basin and significantly affect reservoir physical properties and...Cements are widely developed in clastic rock-originated weathering crust(CWC)reservoirs in the Kexia region along the northwestern margin of the Junggar Basin and significantly affect reservoir physical properties and oil and gas distribution in this area.Focusing on the CWC reservoirs at the top of both the Permian Jiamuhe Formation and the Triassic Karamay Formation,this study analyzed the types and characteristics of cements in the reservoirs and explored their effects on reservoir physical properties based on thin sections,SEM images,XRD results,and tests of physical properties.The main results are as follows.The cements in the CWC reservoirs in Kexia region mainly consist of carbonate minerals(41.5%),clay minerals(27.8%)and zeolite minerals(30%),as well as small amount of siliceous minerals.Among them,the carbonate minerals are dominated by siderite and calcite,the clay minerals mainly include kaolinite,interstratified illite/smectite(I/S)and chlorite,and the zeolite minerals primarily comprise heulandite and laumontite.These different types of multiphase cements are generally paragenetic or associated and affect reservoir physical properties to different degrees.Specifically,the carbonate and clay cements of the early diagenetic stage reduced the reservoirs’average porosity from 21%to 15%.The dissolution of some carbonate and zeolite cements in the early A substage of the middle diagenetic stage restored the average porosity to 18%,and the cementation in the late A substage decreased the average porosity to 13%again,of which about 4%was reduced by carbonate cements.The average porosity of the CWC reservoirs gradually decreased to the current value of approximately 10%in the B substage of the middle diagenetic stage.The impact of cementation on the CWC reservoirs can reach as far as 70 m below the unconformity.Moreover,the types and contents of cements vary with their depth below the unconformity surface,leading to the development of multiple zones with high cement content and the differentiated oil and gas distribution.展开更多
In order to better understand the leaching process of rare earth (RE) and aluminum (Al) from the weathered crust elutiondepositedRE ore, the mass transfer of RE and Al in column leaching was investigated using the...In order to better understand the leaching process of rare earth (RE) and aluminum (Al) from the weathered crust elutiondepositedRE ore, the mass transfer of RE and Al in column leaching was investigated using the chromatographic plate theory. Theresults show that a higher initial ammonium concentration in a certain range can enhance the mass transfer process. pH of leachingagent in the range of 2 to 8 almost has no effect on the mass transfer efficiency of RE, but plays a positive role in the mass transferefficiency of Al under strong acidic condition (pH〈4). There is an optimum flow rate that makes the highest mass transfer efficiency.The optimum leaching condition of RE is the leaching agent pH of 4?8, ammonium concentration of 0.4 mol/L and flow rate of0.5 mL/min. The mass transfer efficiencies of RE and Al both follow the order: (NH4)2SO4〈NH4Cl〈NH4NO3, implying thecomplexing ability of anion.展开更多
The world,the continent and the large country at all times have similar distribution of intervals between recurrences of the great earthquakes,depending on the earthquake sequence. lt indicates that how the force sour...The world,the continent and the large country at all times have similar distribution of intervals between recurrences of the great earthquakes,depending on the earthquake sequence. lt indicates that how the force source of world scale changes with time and space.展开更多
基金funded by the National Key R&D Program of China (2022YFB4202102)the Key R&D Program of Ningxia Hui Autonomous Region (2022BEG02003)the Excellent Member of Youth Innovation Promotion Association CAS (No.Y202085)。
文摘The Qinghai-Tibet Plateau is now experiencing ecological degradation risks as a result of climate change and human activities.The alpine grassland ecology in permafrost zones is fragile and susceptible to deterioration due to its high altitude,low temperature,and limited oxygen,which complicates the repair of damaged land.Biological soil crusts(BSCs)are crucial for land restoration in plateau regions because they can thrive in harsh conditions and have environmentally beneficial traits.Inoculated biological soil crust(IBSC)has shown success in low-altitude desert regions,but may not be easily duplicated to the plateau environment.Therefore,it is essential to do a comprehensive and multifaceted analysis of the basic theoretical comprehension and practical application of BSCs on the Tibetan Plateau.This review article aims to provide a brief summary of the ecological significance and the mechanisms related to the creation,growth,and progression of BSCs.It discusses the techniques used for cultivating BSCs in laboratories and using them in the field,focusing on the Qinghai-Tibet Plateau circumstance.We thoroughly discussed the potential and the required paths for further studies.This study may be used as a basis for selecting suitable microbial strains and accompanying supplemental actions for implementing IBSCs in the Qinghai-Tibet Plateau.
基金financially supported by the State Key Research Development Program of China(Grant No.2022YFF0800903)the National Natural Science Foundation of China(NSFC)(Grant Nos.42261144669 and 42273073)。
文摘High-silica granitoids record the formation and evolution of the continental crust.A new intrusive complex has been recognized among silicic volcanic rocks of the Weixi arc,Southwest China.The intrusions consist of granites,granitic porphyries,and granodiorites.Zircon U-Pb age data indicate that the Weixi granitoids formed at 248-240 Ma and were coeval with silicic volcanic rocks of the Weixi arc.The Weixi granitoids are enriched in Rb,Th,and U,depleted in Ba,Sr,Nb,Ta,and Ti,and have high light/heavy rare earth element ratios and slightly negative Eu anomalies.The Weixi granitoids have negative ε_(Nd)(t)values(-9.8 to-7.8)and negative zircon ε_(Hf)(t)values(-12.02 to-5.11).The geochemical and isotopic features suggest the Weixi granitoids were derived by partial melting of ancient crustal material.The Weixi granitoids and silicic volcanic rocks were derived from the same magma by crystal accumulation and melt extraction,respectively,and they record the formation of a continental arc in the central Sanjiang orogenic belt.
基金The fund of Laoshan Laboratory under contract Nos LSKJ202203602 and LSKJ202204103the China Ocean Mineral Resource Research and Development Association Research Program under contract No.DY135-C1-1-04the Taishan Scholarship from Shandong Province.
文摘To explore the occurrence phases and enrichment mechanism of rare earth elements(REEs)in cobalt-rich crusts,this study analyzes the mineral composition and REE contents of the samples from Marcus-Wake Seamounts by XRD,ICP-OES and ICP-MS.The results show that,(1)the cobalt-rich crusts contain the major crystalline mineral(vernadite),the secondary minerals(quartz,plagioclase and carbonate fluorapatite),and a large amount of amorphous ferric oxyhydroxides(FeOOH).(2)The cobalt-rich crusts contains higher Mn(10.83%to 28.76%)and Fe(6.14%to 18.86%)relative to other elements,and are enriched in REEs,with total REE contents of 1563−3238μg/g and Ce contents of 790−1722μg/g.Rare earth element contents of the old crusts are higher than those of the new crusts.Moreover,the non-phosphatized crusts have positive Ce and negative Y anomalies,and yet the phosphatized crusts have positive Ce and positive Y anomalies,indicating that cobalt-rich crusts is hydrogenetic and REEs mainly come from seawater.(3)Analytical data also show that the occurrence phases of elements in cobalt-rich crusts are closely related to their mineral phases.In the non-phosphatized crusts,REEs are adsorbed by colloidal particles into the crusts(about 67%of REEs in the Fe oxide phase,and about 17%of REEs in the Mn oxide phase).In contrast,in the phosphatized crusts(affected by the phosphatization),REEs may combine with phosphate to form rare earth phosphate minerals,and about 64%of REEs are enriched in the residual phase containing carbonate fluorapatite,but correspondingly the influence of Fe and Mn oxide phases on REEs enrichment is greatly reduced.In addition,the oxidizing environment of seawater,high marine productivity,phosphatization,and slow growth rate can promote the REE enrichment.This study provides a reference for the metallogenesis of cobalt-rich crusts in the Pacific.
基金This work was supported by the National Natural Science Foundation of China[Grant Nos.41962015,52208348]the Jiangxi Provincial Natural Science Foundation[Grant No.20224BAB214064,20232BAB204083].
文摘Collapsing erosion is a unique phenomenon commonly observed on the granite residue hillslopes in the tropical and subtropical regions of southern China,characterized by its abrupt occurrence and significant erosion volumes.However,the impacts of soil crust conditions on the erosion of colluvial deposits with granite residual soils have only been studied to a limited extent.To address this issue,this study investigates the impacts of three soil crust conditions(i.e.,without crust,10-minute crust,and 20-minute crust)on gully morphology,rainfall infiltration,and runoff and sediment yield during slope erosion of colluvial deposits with granite residues(classified as Acrisols)in Yudu County,Ganzhou City,Jiangxi Province,China,using simulated rainfall tests and photographic methods.The results showed that as the strength of the soil crust increased,the capacity of moisture infiltration and the width and depth of the gully as well as the sediment concentration and yield ratio decreased;at the same time,the runoff ratio increased.The sediment yield in the without-crust test was found to be 1.24 and 1.43 times higher than that observed in the 10-minute crust and 20-minute crust tests,respectively.These results indicate that soil crusts can effectively prevent slope erosion and moisture infiltration,while providing valuable insights for the management of soil erosion in natural environments.
基金supported by the National Natural Science Foundation of China(No.32260292,32060277)National Key Research and Development Program of China(No.2020YFC1522200)+2 种基金Shanxi Provincial Basic Research Program of China(No.202303021212060)Shanxi Provincial Cultural Relics Technology Program of China(No.2023KT15)The Local Project Guided by the Central Government of Gansu Province(No.YDZX20216200001728).
文摘Biological soil crusts(BSCs)play an important role in soil development and ecological function,and it is more important for quantitatively analyzing the processes and trends of BSCs to identify the advantages and disadvantages of BSCs research for the development and application of BSCs theory.Bibliometric analysis of 2,186 BSCs literatures from Web of Science showed an exponential growth trend,as China and the United States as the top 2 in terms of publication volume.High quality publications are mainly from European and American countries,such as the United States,Germany and Spain.The top 3 publishers are Journal of Arid Environments,Soil Biology&Biochemistry and Plant and Soil,and disciplines include ecology,environmental science,and soil science,etc..Research institutions mainly affiliate to the Chinese Academy of Sciences,United States Department of the Interior,United States Geological Survey,Hebrew University of Jerusalem,Consejo Superior de Investigaciones Cientificas,and Universidad Rey Juan Carlos.Authors mainly come from United States,Israel,Spain and China.Funds are mainly from the National Natural Science Foundation of China,Spanish Government,Chinese Academy of Sciences,and National Science Foundation of the United States.Biological soil crusts(biocrusts,cyanobacteria,lichens,moss crusts,bryophytes),drylands,climate change,photosynthesis and desert are high-frequency keywords.Future research will focus on the driving mechanisms of BSCs on global biogeochemical cycles,maintaining global biodiversity on important ecological processes,global C,N,and P cycles.The impact on biological invasion,sandstorms,and water balance,multifunctional and reciprocal mechanisms for maintaining the stability of desert and sandy ecosystems,and impact on the formulation of management policies for arid ecosystems,corresponding to global climate change,and the estimation of regional,local,and microscale distribution of BSCs based on machine deep learning modeling gradually focus on.The ecosystem service functions of BSCs,the soil and water conservation and soil stability mediated by BSCs in arid and semi-arid regions,and the excavation of stress resistant genes for BSCs will be emphasized.
基金supported the National Natural Science Foundation of China(Nos.:U19B6003,U20B6001)the Class A Strategic Pilot Science and Technology Program of the Chinese Academy of Sciences(No.:XDA14000000)a project entitled Oil and Gas Enrichment Rules and Favorable Target Selection in the Iran-Iraq region initiated by the Sinopec Science and Technology Department.
文摘In recent years,the Fuxian area in the southeastern Ordos Basin has undergone significant exploration,with industrial gas flow tested in wells drilled into the Ordovician marine carbonates.Despite this,the gas accumulation patterns of this area are not fully understood,posing challenges for further exploration.Our analysis of geological conditions indicates that the Ordovician Majiagou Formation in this area hosts two gas plays:one found in weathering crusts and the other found in interior of the formation.We investigated various typical gas reservoirs in the area,focusing on differentiating the geological conditions and factors controlling gas accumulation in the weathering-crust and interior gas reservoirs.The results suggest three primary gas accumulation patterns in the Majiagou Formation in the Fuxian area:(1)upper gas accumulation in weathering crusts,present in the high parts of landforms such as residual paleo-hills or buried paleo-platform(Pattern I);(2)the stereoscopic pattern with gas accumulation in both weathering crusts and strata interior,arising in high parts of landforms such as residual paleo-hills or buried paleo-platforms(Pattern II);(3)lower gas accumulation in strata interior,occurring in the upper reaches and on both sides of paleo-trenches(Pattern III).This study will serve as a geological basis for future exploration deployment in the Fuxian area.
基金Financial supports for this work from National Natural Science Foundation of China(Nos.22078252 and 52274266)the Graduate Education Innovation Foundation of Wuhan Institute of Technology(No.CX2021463)the Young Top-notch Talent Cultivation Program of Hubei Province are greatly appreciated.
文摘Surfactants were proposed to be added into magnesium sulfate solution to improve the leaching process of weathered crust elution-deposited rare earth ores(WREOs).Effects of surfactants and their concentration on the seepage of leaching solutions and the leaching efficiency of rare earth(RE)and aluminum(Al)were investigated,and the leaching kinetics,the mass transfer process,the adhesion work and the adhesion work reduction factor were analyzed to reveal its strengthening leaching mechanism.The results show that cetyltrimethylammonium bromide(CTAB)has a better strengthening effect on the leaching process than dodecyl trimethyl ammonium bromide(DTAB),sodium dodecyl sulfate(SDS),sodium oleate and oleic acid.In the presence of 0.04%CTAB in 0.2 mol/L solution,the permeability coefficient of WREOs increases from 0.945×10^(-5)to 1.640×10^(-5)cm·s^(-1),and the leaching efficiency of RE increases from 80%to 90%,confirming the promotion of surfactants on the leaching process of WREOs.Kinetic analysis shows that the leaching process conforms to the inner diffusion control model,and the leaching kinetics equations of RE and Al related to CTAB content are obtained.Mass transfer discussion shows a smaller height equivalent to theoretical plate(HETP)of RE and Al at CTAB content of 0.04%,suggesting the higher mass transfer efficiency here.According to the interfacial properties of leaching solutions,the calculated adhesion work and the adhesion work reduction factor further demonstrate the strengthening leaching effect of CTAB on the leaching process of WREOs.
基金supported by the Shanxi Provincial Foundation for Returned Overseas Scholars (No. 20220037)Natural Science Foundation of Shanxi Province (No. 20210302123085)Discipline Construction Project of Yuncheng University
文摘In this work,we perform a Bayesian inference of the crust-core transition density ρ_(t) of neutron stars based on the neutron-star radius and neutron-skin thickness data using a thermodynamical method.Uniform and Gaussian distributions for the ρ_(t) prior were adopted in the Bayesian approach.It has a larger probability of having values higher than 0.1 fm^(−3) for ρ_(t) as the uniform prior and neutron-star radius data were used.This was found to be controlled by the curvature K_(sym) of the nuclear symmetry energy.This phenomenon did not occur if K_(sym) was not extremely negative,namely,K_(sym)>−200 MeV.The value ofρ_(t) obtained was 0.075_(−0.01)^(+0.005) fm^(−3) at a confidence level of 68%when both the neutron-star radius and neutron-skin thickness data were considered.Strong anti-correlations were observed between ρ_(t),slope L,and curvature of the nuclear symmetry energy.The dependence of the three L-K_(sym) correlations predicted in the literature on crust-core density and pressure was quantitatively investigated.The most probable value of 0.08 fm^(−3) for ρ_(t) was obtained from the L-K_(sym) relationship proposed by Holt et al.while larger values were preferred for the other two relationships.
基金the Guangdong Basic and Applied Basic Research Foundation(No.2021B1515020098)the Southern Marine Science and Engineering Guangdong Laboratory(Guangzhou)(No.GML2019ZD 0205)+6 种基金the National Natural Science Foundation of China(Nos.41776058,41890813,42006056,42276222)the Chinese Academy of Sciences Project(Nos.133244KYSB20180029,131551KYSB20200021,Y4SL021001,QYZDYSSW-DQC005,ISEE2021PY03,E1SL3C02)the Development Fund of South China Sea Institute of Oceanology of the Chinese Academy of Sciences(No.SCSIO202207)Guangdong Provincial Research and Development Program in Key Areas(No.2020B1111520001)the Hainan Provincial Natural Science Foundation of China(No.421QN381)the Science and Technology Program of Guangzhou(No.202201010221)the China Postdoctoral Science Foundation(No.2022M711480)。
文摘The Jurassic oceanic crust is the oldest existing oceanic crust on earth,and although distributed sparsely,carries essential information about the earth's evolution.The area around the Pigafetta Basin in the west Pacific Ocean(also known as the Jurassic Quiet Zone,JQZ)is one of a few areas where the Jurassic oceanic crust is present.This study takes full advantage of high-resolution multichannel seismic reflection profiles in combination with bathymetry,magnetic,and gravity data from the JQZ to examine the structure,deformation,and morphology of the Jurassic oceanic crust.Our results show the following insights:1)The Moho lies at 2–3 s in two-way travel time beneath the seafloor with the segmented feature.The gaps between the Moho segments well correspond to the seamounts on the seafloor,suggesting the upward migration of magma from the mantle has interrupted the pre-existing Moho.2)The oceanic crust is predominantly deformed by crustal-scale thrust faults,normal faults cutting through the top of basement,and vertical seismic disturbance zones in association with migration of thermal fluids.The thrust faults are locally found and interpreted as the results of tectonic inversion.3)Seafloor morphology in the JQZ is characterized by fault scarps,fold scarps,seamounts,and small hills,indicating the occurrence of active faults.4)The oceanic crust in the JQZ and East Pacific Rise has many structural and geometrical variations,such as the thickness of sediments,seafloor topography,basement morphology,fault size and type.
基金supported by the National Natural Science Foundation of China(42072177)National Natural Science Foundation of China(U19B6003)Frontier Project of Chinese Academy of Sciences(XDA14010201).
文摘Weathering has always been a concerned around the world,as the first and most important step in the global cycle of elements,which leads to the fractionation of isotopes on the scale of geological age.The Middle Ordovician Majiagou Formation in Daniudi area of the Ordos Basin had experienced weathering for>130 Myr.Through thin section observation,major and trace element analysis,carbon,oxygen,and magnesium isotopes composition analysis,the dolomitization modes and weathering of ancient dolo-mite in Daniudi area were analyzed in detail.The results showed that the Sabkha and brine-reflux dolomitization modes had developed,and the Mg isotopes in different layers of the karst crust were fractionated by various factors.The vertical vadose zone was affected by weathering,the Mg isotope of dolomite(δ^(26)Mgdol)showed a downward decreasing trend;the horizontal underflow zone was controlled by diagenesis and formation fluid,δ^(26)Mgdol showed a vertical invariance and negative;the main reason for Mg isotope fractionation in the deep slow-flow zone was the brine-reflux dolomitization mode during early burial period,which showed a vertical downward increase.Finally,the Mg isotope characteristic data of the ancient weathering crust were provided and the process of Mg isotope frac-tionationinthekarstcrust was explained.
基金the National Major Project of Science and Technology in developing great oil&gas field and coal bed gas(Grant No.2016ZX05007-006)the Study on water-cut control and production stabilization in the old gasfields and efficient development in new gasfields in Qaidam Basin(Grant No.2016E-0106GF)。
文摘The bedrock weathered crust in front of the Altun Mountains in the Qaidam Basin,western China,is different from others because this is a salt-lake basin,where saline water fluid infiltrates and is deposited in the overlying strata.A large amount of gypsum infills the bedrock weathered crust,and this has changed the pore structure.Using core observation,polarized light microscopy,electron probe,physical property analysis and field emission scanning electron microscopy experiments,the characteristics of the weathered bedrock have been studied.There are cracks and a small number of dissolved pores in the interior of the weathered crust.Matrix micropores are widely developed,especially the various matrix cracks formed by tectonics and weathering,as well as the stress characteristics of small dissolved pores,and physical properties such as porosity and permeability.This‘dual structure’developed in the bedrock is important for guiding the exploration of the lake basin bedrock for natural gas.
基金the National Natural Science Foundation of China(Nos.52174258,92162109,52222405 and 52004184).
文摘Both CT and Avizo software were used to explore the effect of particle gradation on the evolution characteristics of pore structure and seepage paths in weathered crust elution-deposited rare earth ores during leaching.The results showed that the pore areas in four kinds of ore samples before leaching were mainly concentrated in 10^(4)–10^(7)μm^(2),whose pore quantities accounted for 96.89%,94.94%,90.48%,and 89.45%,respectively,while the corresponding pore volume only accounted for 30.74%,14.55%,7.58%,and 2.84%of the total pore volume.With the decrease of fractal dimension,the average pore throat length increased,but pore throat quantities,the average pore throat radius and coordination number decreased.Compared with that before leaching,the change degree of pore structure during leaching increased with the fractal dimension decreasing.For example,the reduction rate of the average coordination number of ore samples was 14.36%,21.30%,28.00%,and 32.90%,respectively.Seepage simulation results indicated that seepage paths were uniformly distributed before leaching while the streamline density and seepage velocity increased with the fractal dimension decreasing.Besides,the phenomenon of the streamline interruption gradually reduced during leaching while preferential seepage got more obvious with the decrease of the fractal dimension.
基金support by the Construction and Development of Transportation Infrastructures Company affiliated with the Ministry of Roads and Urban Development of Iran and partial financial support granted by the Research Deputy of the Sharif University of Technology are acknowledged.
文摘In this research,two shake table experiments were conducted to study the effects of non-liquefiable crust layer and superstructure mass on the responses of two sets of 22 pile groups to liquefactioninduced lateral spreading.In this regard,an inclined base layer overlain by a very loose liquefiable layer was constructed in both models;while only in one model,a non-liquefiable crust layer was built.A lumped mass,being representative of a superstructure,was attached to the cap of one pile group in both models.The models were fully instrumented with various sensors,including acceleration,displacement,and pore water pressure transducers.Also,the piles were instrumented with pair strain gauges to measure pure bending moments induced by cyclic and monotonic loadings associated with ground shaking and lateral spreading,respectively.The results showed that the existence of the non-liquefiable crust layer increases both the maximum and residual soil displacements at the free field and also the maximum bending moments in the piles.The results of the experiments indicated that the crust layer induces a high kinematic lateral soil pressure and force on the piles which are not present in the crustless case.The crust layer increases the pile cap displacement before liquefaction,albeit decreases it after liquefaction,due to the elastic rebound of the piles in the liquefiable layer.The crust layer postpones both liquefaction triggering and dissipation of excess pore water pressure.The existence of the superstructure mass on the pile caps decreases the acceleration amplitude of the pile caps,while increases their maximum displacement.
基金supported by the National Natural Science Foundation of China (41830758)the "Light of the West" Cross Team-Key Laboratory Cooperative Research Project of the Chinese Academy of Sciences
文摘Livestock grazing is the most extensive land use in global drylands and one of the most extensive stressors of biological soil crusts(biocrusts).Despite widespread concern about the importance of biocrusts for global carbon(C)cycling,little is known about whether and how long-term grazing alters soil organic carbon(SOC)stability and stock in the biocrust layer.To assess the responses of SOC stability and stock in the biocrust layer to grazing,from June to September 2020,we carried out a large scale field survey in the restored grasslands under long-term grazing with different grazing intensities(represented by the number of goat dung per square meter)and in the grasslands strictly excluded from grazing in four regions(Dingbian County,Shenmu City,Guyuan City and Ansai District)along precipitation gradient in the hilly Loess Plateau,China.In total,51 representative grassland sites were identified as the study sampling sites in this study,including 11 sites in Guyuan City,16 sites in Dingbian County,15 sites in Shenmu City and 9 sites in Ansai District.Combined with extensive laboratory analysis and statistical analysis,at each sampling site,we obtained data on biocrust attributes(cover,community structure,biomass and thickness),soil physical-chemical properties(soil porosity and soil carbon-to-nitrogen ratio(C/N ratio)),and environmental factors(mean annual precipitation,mean annual temperature,altitude,plant cover,litter cover,soil particle-size distribution(the ratio of soil clay and silt content to sand content)),SOC stability index(SI)and SOC stock(SOCS)in the biocrust layer,to conduct this study.Our results revealed that grazing did not change total biocrust cover but markedly altered biocrust community structure by reducing plant cover,with a considerable increase in the relative cover of cyanobacteria(23.1%)while a decrease in the relative cover of mosses(42.2%).Soil porosity and soil C/N ratio in the biocrust layer under grazing decreased significantly by 4.1%–7.2%and 7.2%–13.3%,respectively,compared with those under grazing exclusion.The shifted biocrust community structure ultimately resulted in an average reduction of 15.5%in SOCS in the biocrust layer under grazing.However,compared with higher grazing(intensity of more than 10.00 goat dung/m2),light grazing(intensity of 0.00–10.00 goat dung/m2 or approximately 1.20–2.60 goat/(hm2•a))had no adverse effect on SOCS.SOC stability in the biocrust layer remained unchanged under long-term grazing due to the offset between the positive effect of the decreased soil porosity and the negative effect of the decreased soil C/N ratio on the SOC resistance to decomposition.Mean annual precipitation and soil particle-size distribution also regulated SOC stability indirectly by influencing soil porosity through plant cover and biocrust community structure.These findings suggest that proper grazing might not increase the CO_(2) release potential or adversely affect SOCS in the biocrust layer.This research provides some guidance for proper grazing management in the sustainable utilization of grassland resources and C sequestration in biocrusts in the hilly regions of drylands.
基金Supported by 14th Five-year Major Project of CNPC(No.2021DJ0206).
文摘Based on drill core and thin section observation,major geochemical element analysis and con-ventional well log analysis,this study summarizes the characteristics and thickness of weathering crust of Pennsylvanian volcanic rocks(Carboniferous)in Shixi area,Junggar Basin.The weathering crust is identified and divided into three types according to the petrological characteristics and well log interpretations in Shixi area,and the isopach of weathering crust is mapped.The results show that:(1)With the increase of depth,the weathering weakens,and the rocks become less fractured with decreased porosity;(2)the weathering crust of the Upper Carboniferous volcanic rocks can be divided into strongly weathered and mildly weathered layers in Shixi area;(3)the weathering crust is relatively thicker in Dinan uplift and Shixi uplift.This study provides research basis for further evaluation of Upper Carboniferous volcanic reservoir,and will benefit for well location deployment and potential oilfield development in the Shixi area.
基金supported by the Shandong Province Natural Science Foundation of China(Grant no.ZR2021MD077)the National Major Science and Technology Project of China(Grant no.2017ZX05001-001-006).
文摘Cements are widely developed in clastic rock-originated weathering crust(CWC)reservoirs in the Kexia region along the northwestern margin of the Junggar Basin and significantly affect reservoir physical properties and oil and gas distribution in this area.Focusing on the CWC reservoirs at the top of both the Permian Jiamuhe Formation and the Triassic Karamay Formation,this study analyzed the types and characteristics of cements in the reservoirs and explored their effects on reservoir physical properties based on thin sections,SEM images,XRD results,and tests of physical properties.The main results are as follows.The cements in the CWC reservoirs in Kexia region mainly consist of carbonate minerals(41.5%),clay minerals(27.8%)and zeolite minerals(30%),as well as small amount of siliceous minerals.Among them,the carbonate minerals are dominated by siderite and calcite,the clay minerals mainly include kaolinite,interstratified illite/smectite(I/S)and chlorite,and the zeolite minerals primarily comprise heulandite and laumontite.These different types of multiphase cements are generally paragenetic or associated and affect reservoir physical properties to different degrees.Specifically,the carbonate and clay cements of the early diagenetic stage reduced the reservoirs’average porosity from 21%to 15%.The dissolution of some carbonate and zeolite cements in the early A substage of the middle diagenetic stage restored the average porosity to 18%,and the cementation in the late A substage decreased the average porosity to 13%again,of which about 4%was reduced by carbonate cements.The average porosity of the CWC reservoirs gradually decreased to the current value of approximately 10%in the B substage of the middle diagenetic stage.The impact of cementation on the CWC reservoirs can reach as far as 70 m below the unconformity.Moreover,the types and contents of cements vary with their depth below the unconformity surface,leading to the development of multiple zones with high cement content and the differentiated oil and gas distribution.
基金Projects(51274152,41472071)supported by the National Natural Science Foundation of ChinaProject(T201506)supported by the Program for Excellent Young Scientific and Technological Innovation Team of Hubei Provincial Department of Education,China
文摘In order to better understand the leaching process of rare earth (RE) and aluminum (Al) from the weathered crust elutiondepositedRE ore, the mass transfer of RE and Al in column leaching was investigated using the chromatographic plate theory. Theresults show that a higher initial ammonium concentration in a certain range can enhance the mass transfer process. pH of leachingagent in the range of 2 to 8 almost has no effect on the mass transfer efficiency of RE, but plays a positive role in the mass transferefficiency of Al under strong acidic condition (pH〈4). There is an optimum flow rate that makes the highest mass transfer efficiency.The optimum leaching condition of RE is the leaching agent pH of 4?8, ammonium concentration of 0.4 mol/L and flow rate of0.5 mL/min. The mass transfer efficiencies of RE and Al both follow the order: (NH4)2SO4〈NH4Cl〈NH4NO3, implying thecomplexing ability of anion.
文摘The world,the continent and the large country at all times have similar distribution of intervals between recurrences of the great earthquakes,depending on the earthquake sequence. lt indicates that how the force source of world scale changes with time and space.