Reaction of dimers of (R) thionophosphine sulfide (R = P - C6H4OMe,SMe ) with Co, (CO), yields the novel hexacobalt cluster [Co'(μ3, -S)2, (CO) 14 (μ4 -μ4- and the trinuclear clusterPSCH,)J 2' In 1, tw0 Co3...Reaction of dimers of (R) thionophosphine sulfide (R = P - C6H4OMe,SMe ) with Co, (CO), yields the novel hexacobalt cluster [Co'(μ3, -S)2, (CO) 14 (μ4 -μ4- and the trinuclear clusterPSCH,)J 2' In 1, tw0 Co3S(C0)7 units linked by a novel phosphido-thio1ato bifunc-tiona1 bridging p'-SPR ligand as backbone.展开更多
Ⅰ. INTRODUCTION Polynuclear metal cluster compounds have attracted much interest owing to their novel structural features and potential uses as heterogeneous catalysts. The structural characterization of these cluste...Ⅰ. INTRODUCTION Polynuclear metal cluster compounds have attracted much interest owing to their novel structural features and potential uses as heterogeneous catalysts. The structural characterization of these cluster compounds is of fundamental importance in establishing the relationship between the geometric and electronic structures. Recently, we have展开更多
文摘Reaction of dimers of (R) thionophosphine sulfide (R = P - C6H4OMe,SMe ) with Co, (CO), yields the novel hexacobalt cluster [Co'(μ3, -S)2, (CO) 14 (μ4 -μ4- and the trinuclear clusterPSCH,)J 2' In 1, tw0 Co3S(C0)7 units linked by a novel phosphido-thio1ato bifunc-tiona1 bridging p'-SPR ligand as backbone.
基金Project supported by the National Natural Science Foundation of China
文摘Ⅰ. INTRODUCTION Polynuclear metal cluster compounds have attracted much interest owing to their novel structural features and potential uses as heterogeneous catalysts. The structural characterization of these cluster compounds is of fundamental importance in establishing the relationship between the geometric and electronic structures. Recently, we have
