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低损耗SrY_(0.15)Ce_(0.85)O_(2.925)陶瓷的烧结特性、相结构及微波介电性能研究
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作者 刘彦君 何国强 +4 位作者 何颖晗 李青 戴正立 张海林 周焕福 《功能材料》 CAS CSCD 北大核心 2023年第1期1020-1025,共6页
采用固相反应法制备了SrY_(0.15)Ce_(0.85)O_(2.925)陶瓷材料,利用XRD、SEM和微波矢量网络分析仪研究了材料的相组成、结构、烧结特性和微波介电性能。结果表明,当烧结温度为1450℃时,SrY_(0.15)Ce_(0.85)O_(2.925)陶瓷的综合性能最佳:... 采用固相反应法制备了SrY_(0.15)Ce_(0.85)O_(2.925)陶瓷材料,利用XRD、SEM和微波矢量网络分析仪研究了材料的相组成、结构、烧结特性和微波介电性能。结果表明,当烧结温度为1450℃时,SrY_(0.15)Ce_(0.85)O_(2.925)陶瓷的综合性能最佳:体积密度为5.2 g/cm^(3),相对密度达到92.7%,Q×f=21503 GHz,εr=23.83,τf=-46.43×10^(-6)/℃。以上结果表明,SrY_(0.15)Ce_(0.85)O_(2.925)陶瓷可以作为现代移动通讯器件的备选材料。 展开更多
关键词 低介电常数 SrY_(0.15)ce_(0.85)o_(2.925) 毫米波 微波介质陶瓷
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All-inorganic transparent Hf_(0.85)Ce_(0.15)O_(2)ferroelectric thin films with high flexibility and stability 被引量:1
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作者 Sheng-Tao Mo Kai-Ming Feng +5 位作者 Jing-Lin Pang Kuo Ouyang Li-Mei Jiang Qiong Yang Biao Zhang Jie Jiang 《Nano Research》 SCIE EI CSCD 2023年第4期5065-5072,共8页
Electronic devices that are transparent and flexible have a wide range of applications in the domains of vital sign parameter monitoring,health management,and so on.Ferroelectric memory is a revolutionary nonvolatile ... Electronic devices that are transparent and flexible have a wide range of applications in the domains of vital sign parameter monitoring,health management,and so on.Ferroelectric memory is a revolutionary nonvolatile memory that is ideal for data storage and processing in transparent flexible electronic systems.In this study,Ce-doped hafnium oxide ferroelectric thin film is manufactured on mica substrate by the chemical solution deposition with transparent indium tin oxide(ITO)thin films as the bottom electrodes.The transmittance of mica/ITO/Hf_(0.85)Ce_(0.15)O_(2)thin film is over 80%.The 2Pr of the transparent flexible Hf_(0.85)Ce_(0.15)O_(2)ferroelectric thin film is increased by about 22.4%and the Ec is reduced by 26.7%compared with those of Hf_(0.85)Ce_(0.15)O_(2)ferroelectric thin film grown on p+-Si substrate.The transparent flexible Hf_(0.85)Ce_(0.15)O_(2)ferroelectric thin film can remain keeping good quality when being bent under±2.5 mm bending radius.Additionally,degradation of polarization,retention,and endurance performance was not obvious even at a bending radius of 5.0 mm after 104 bending cycles.This research provides a new strategy and an important experimental basis for the development and implementation of transparent flexible ferroelectric memories. 展开更多
关键词 flexible hf_(0.85)ce_(0.15)o_(2)thin films transparent thin films ferroelectric properties
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PbTi_(0.85)Ni_(0.15)O_(3)/TiO_(2)纳米棒阵列复合材料的压电光催化性能 被引量:1
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作者 周小桔 钱俊 +1 位作者 胡正龙 任一鸣 《复合材料学报》 EI CAS CSCD 北大核心 2024年第3期1367-1377,共11页
压电材料诱导的内建电场是调节电荷转移途径和抑制载流子复合的最有效策略之一。采用水热和溶胶凝胶两步法制备了PbTi0.85Ni0.15O3/TiO_(2)纳米棒阵列复合材料。通过降解有机染料,复合材料展现了优异的压电光催化性能。经30 min,PbTi_(0... 压电材料诱导的内建电场是调节电荷转移途径和抑制载流子复合的最有效策略之一。采用水热和溶胶凝胶两步法制备了PbTi0.85Ni0.15O3/TiO_(2)纳米棒阵列复合材料。通过降解有机染料,复合材料展现了优异的压电光催化性能。经30 min,PbTi_(0.85)Ni_(0.15)O_(3)/TiO_(2)对亚甲基蓝(MB)的压电光催化降解率达到97.3%,降解反应速率为0.1215 min^(-1),是光催化降解速率(0.0372 min^(-1))的3.3倍,是压电催化降解速率(0.0211 min^(-1))的5.7倍。掺杂Ni后,带隙降低,载流子浓度增大,晶格畸变增大,压电光催化性能增强。添加牺牲剂实验和电子自旋共振波谱(ESR)实验结果表明,压电光催化降解中,·O_(2)^(-)和·OH是最主要的活性物质。此外,PbTi_(0.85)Ni_(0.15)O_(3)/TiO_(2)对不同染料的降解和循环5次后的降解率表明复合材料对多种染料具有良好的压电光催化降解性能和良好的稳定性。根据能带排列,提出压电极化导致的能带倾斜和弯曲可以促进光生载流子分离,从而使PbTi_(0.85)Ni_(0.15)O_(3)/TiO_(2)具有优异的压电光催化染料降解性能。 展开更多
关键词 PbTi_(0.85)Ni_(0.15)o_(3)/Tio_(2) 复合材料 压电光催化 降解 能带倾斜
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