A novel 3D hetero-nuclear framework,namely {[K_5Na_6Cu_5^（Ⅱ）（CH3COO）_（20）（CH_3CN）]Cl}_n（1）,was obtained by hydrothermal reaction.Triple metal centers（including sodium/potassium or/and copper） were coordin...A novel 3D hetero-nuclear framework,namely {[K_5Na_6Cu_5^（Ⅱ）（CH3COO）_（20）（CH_3CN）]Cl}_n（1）,was obtained by hydrothermal reaction.Triple metal centers（including sodium/potassium or/and copper） were coordinated to acetate anions in such two heteronuclear clusters,respectively.Moreover,nine kinds of binding modes for acetate anions were illustrated in polymer 1,with the first reported pentadentate coordination mode for acetate ligand.展开更多
基金financially supported by the Youth Teachers'Training Foundation of Minnan Science and Technology Institute,Young and Middle-age academic leader plan of Quanzhou university,and the undergraduate education teaching reform in Fujian province(2017)
文摘A novel 3D hetero-nuclear framework,namely {[K_5Na_6Cu_5^（Ⅱ）（CH3COO）_（20）（CH_3CN）]Cl}_n（1）,was obtained by hydrothermal reaction.Triple metal centers（including sodium/potassium or/and copper） were coordinated to acetate anions in such two heteronuclear clusters,respectively.Moreover,nine kinds of binding modes for acetate anions were illustrated in polymer 1,with the first reported pentadentate coordination mode for acetate ligand.
