A process capable of simultaneously oxidizing NO, SO2, and Hg^0 was proposed, using a nigh-voltage and short-duration positive pulsed corona discharge. By focusing on NO, SO2, and Hg^0 oxidation efficiencies, the infl...A process capable of simultaneously oxidizing NO, SO2, and Hg^0 was proposed, using a nigh-voltage and short-duration positive pulsed corona discharge. By focusing on NO, SO2, and Hg^0 oxidation efficiencies, the influences of pulse peak voltage, pulse frequency, initial concentration, electrode number, residence time and water vapor addition were investigated. The results indicate that NO, SO2 and Hg^0 oxidation efficiencies depend primarily on the radicals （OH, HO2, O） and the active species （O3, H2O2, etc.） produced by the pulsed corona discharge. The NO, SO2 and Hg^0 oxidation efficiencies could be improved as pulse peak voltage, pulse frequency, electrode number and residence time increased, but they were reduced with increasing initial concentrations. By adding water vapor, the SO2 oxidation efficiency was improved remarkably, while the NO oxidation efficiency decreased slightly. In our experiments, the simultaneous NO, SO2, and Hg^0 oxidation efficiencies reached to 40%, 98%, and 55% with the initial concentrations 479 mg/m^3, 1040 mg/m^3, and 15.0 μg/m^3, respectively.展开更多
This article discussed the benzoic acid activated carbons which have changed the types and content of acid oxygen-function groups on the surface of activated carbons and their effect on the adsorption for Hg^0 in simu...This article discussed the benzoic acid activated carbons which have changed the types and content of acid oxygen-function groups on the surface of activated carbons and their effect on the adsorption for Hg^0 in simulated flue gas at 140 ℃. These surface acid oxygen function groups were identified by Boehm titration, Fourier transformation infrared spectrum, temperature programmed desorption and X-ray photoelectron spectroscopy. It indicates that the carboxyl, lactone and phenolic were formed when the benzoic acid is loaded on the surface of activated carbons. Among the surface acid oxygen function groups, the carboxyl groups enhance the adsorption capacities of Hg^0 for activated carbons to a greater extent.展开更多
基金supported by the National Natural Science Foundation of China(51676064,51306046,and U1404520)the Young Core Instructor Project in the Higher Education Institutions of Henan Province(2016GGJS-038)+1 种基金the Fundamental Research Funds for the Universities of Henan Province(NSFRF140204)the Outstanding Youth Science Foundation of Henan Polytechnic University(J2016-1)
基金supported by the Science and Technology Research of Department of Education of China (No. 0305,03087)
文摘A process capable of simultaneously oxidizing NO, SO2, and Hg^0 was proposed, using a nigh-voltage and short-duration positive pulsed corona discharge. By focusing on NO, SO2, and Hg^0 oxidation efficiencies, the influences of pulse peak voltage, pulse frequency, initial concentration, electrode number, residence time and water vapor addition were investigated. The results indicate that NO, SO2 and Hg^0 oxidation efficiencies depend primarily on the radicals （OH, HO2, O） and the active species （O3, H2O2, etc.） produced by the pulsed corona discharge. The NO, SO2 and Hg^0 oxidation efficiencies could be improved as pulse peak voltage, pulse frequency, electrode number and residence time increased, but they were reduced with increasing initial concentrations. By adding water vapor, the SO2 oxidation efficiency was improved remarkably, while the NO oxidation efficiency decreased slightly. In our experiments, the simultaneous NO, SO2, and Hg^0 oxidation efficiencies reached to 40%, 98%, and 55% with the initial concentrations 479 mg/m^3, 1040 mg/m^3, and 15.0 μg/m^3, respectively.
文摘This article discussed the benzoic acid activated carbons which have changed the types and content of acid oxygen-function groups on the surface of activated carbons and their effect on the adsorption for Hg^0 in simulated flue gas at 140 ℃. These surface acid oxygen function groups were identified by Boehm titration, Fourier transformation infrared spectrum, temperature programmed desorption and X-ray photoelectron spectroscopy. It indicates that the carboxyl, lactone and phenolic were formed when the benzoic acid is loaded on the surface of activated carbons. Among the surface acid oxygen function groups, the carboxyl groups enhance the adsorption capacities of Hg^0 for activated carbons to a greater extent.
