SiBCN ceramic aerogel is an ideal potential candidate for ultra-high temperature thermal insulation due to its unique microscopic pore structure combined with the excellent thermal stability of SiBCN ce-ramic.Here,red...SiBCN ceramic aerogel is an ideal potential candidate for ultra-high temperature thermal insulation due to its unique microscopic pore structure combined with the excellent thermal stability of SiBCN ce-ramic.Here,reduced graphene oxide(rGO)modified SiBCN aerogels(rGO/SiBCN)were prepared through solvothermal,freeze-casting and pyrolysis,and the dimension of the aerogel is up toΦ130 mm×28 mm.The density of the rGO/SiBCN aerogel is as low as 0.024 g/cm^(3) and the microstructural regulation is achieved by controlling the rGO content in the aerogel.The hierarchical cellular structure endows the aerogel with a high specific surface area(148.6 m^(2)/g)and low thermal conductivity(0.057 W m^(-1) K^(-1)).The 10 mm-thick sample exhibits excellent thermal insulation and ablation resistance,as evidenced by its ability to reduce the temperature from~1100℃to~180℃under the intense heat of a butane flame.Moreover,benefiting from the ultrahigh-temperature stability of SiBCN,the rGO/SiBCN aerogel exhibits good thermal stability up to 1200℃in argon and short-oxidation resistance at 800℃in air.There-fore,the rGO/SiBCN aerogel with superior overall performance could expand its practical application in high-temperature thermal insulation under extreme environments.展开更多
3D-printed Porous Titanium Alloy Implants(pTi),owing to their biologically inertness and relatively smooth surface morphology,adversely affect the biological functions of surrounding cells.To address the challenges,co...3D-printed Porous Titanium Alloy Implants(pTi),owing to their biologically inertness and relatively smooth surface morphology,adversely affect the biological functions of surrounding cells.To address the challenges,constructing a bioinspired interface that mimics the hierarchical structure of bone tissue can enhance the cellular functions of cells.In this context,Hollow Mesoporous Silica Nanoparticles(HMSNs),renowned for their unique physicochemical properties and superior biocompatibility,offer a promising direction for this research.In this research,the initially synthesized HMSNs were used to construct a“hollow-mesoporous-macroporous”hierarchical bioinspired coating on the pTi surface through the Layer-by-Layer technique.Simultaneously,diverse morphologies of coatings were established by adjusting the deposition strategy of PDDA/HMSNs on the pTi surface(pTi-HMSN-2,pTi-HMSN-4,pTi-HMSN-6).A range of techniques were employed to investigate the physicochemical properties and regulation of cellular biological functions of the diverse HMSN coating strategies.Notably,the pTi-HMSN-4 and pTi-HMSN-6 groups exhibited the uniform coatings,leading to a substantial enhancement in surface roughness and hydrophilicity.Meantime,the coating constructed strategy of pTi-HMSN-4 possessed commendable stability.Based on the aforementioned findings,both pTi-HMSN-4 and pTi-HMSN-6 facilitated the adhesion,spreading,and pseudopodia extension of BMSCs,which led to a notable upsurge in the expression levels of vinculin protein in BMSCs.Comprehensive analysis indicates that the coating,when PDDA/HMSNs are deposited four times,possesses favorable overall performance.The research will provide a solid theoretical basis for the translation of HMSN bioinspired coatings for orthopedic implants.展开更多
Functional graded cellular structure(FGCS)usually shows superiormechanical behaviorwith lowdensity and high stiffness.With the development of additivemanufacturing,functional graded cellular structure gains its popula...Functional graded cellular structure(FGCS)usually shows superiormechanical behaviorwith lowdensity and high stiffness.With the development of additivemanufacturing,functional graded cellular structure gains its popularity in industries.In this paper,a novel approach for designing functionally graded cellular structure is proposed based on a subdomain parameterized level set method(PLSM)under local volume constraints(LVC).In this method,a subdomain level set function is defined,parameterized and updated on each subdomain independently making the proposed approach much faster and more cost-effective.Additionally,the microstructures on arbitrary two adjacent subdomains can be connected perfectly without any additional constraint.Furthermore,the local volume constraint for each subdomain is applied by virtue of the augmented Lagrange multiplier method.Finally,several numerical examples are given to verify the correctness and effectiveness of the proposed approach in designing the functionally graded cellular structure.From the optimized results,it is also found that the number of local volume constraints has little influence on the convergence speed of the developed approach.展开更多
基金National Natural Science Foundation of China(No.52173261).
文摘SiBCN ceramic aerogel is an ideal potential candidate for ultra-high temperature thermal insulation due to its unique microscopic pore structure combined with the excellent thermal stability of SiBCN ce-ramic.Here,reduced graphene oxide(rGO)modified SiBCN aerogels(rGO/SiBCN)were prepared through solvothermal,freeze-casting and pyrolysis,and the dimension of the aerogel is up toΦ130 mm×28 mm.The density of the rGO/SiBCN aerogel is as low as 0.024 g/cm^(3) and the microstructural regulation is achieved by controlling the rGO content in the aerogel.The hierarchical cellular structure endows the aerogel with a high specific surface area(148.6 m^(2)/g)and low thermal conductivity(0.057 W m^(-1) K^(-1)).The 10 mm-thick sample exhibits excellent thermal insulation and ablation resistance,as evidenced by its ability to reduce the temperature from~1100℃to~180℃under the intense heat of a butane flame.Moreover,benefiting from the ultrahigh-temperature stability of SiBCN,the rGO/SiBCN aerogel exhibits good thermal stability up to 1200℃in argon and short-oxidation resistance at 800℃in air.There-fore,the rGO/SiBCN aerogel with superior overall performance could expand its practical application in high-temperature thermal insulation under extreme environments.
基金supported by the National Natural Science Foundation of China(Grant No.82372391,82001971,82102358,82202698,52105343,U21A2099 and U23A20523)Project of“Medical+X”interdisciplinary innovation team of Norman Bethune Health Science Center of Jilin University(Grant No.2022JBGS06)+5 种基金Project of youth interdisciplinary innovation team of Jilin University(Grant No.419070623054)China Postdoctoral Science Foundation(Grant No.2021M701384)Bethune Plan of Jilin University(Grant No.2022B27,2022B03)Wu Jieping Medical Foundation(Grant No.320.6750.18522)Scientific Development Program of Jilin Province(Grant No.20220402067GH)Jilin Province Development and Reform Commission(Grant No.2022C044-2).
文摘3D-printed Porous Titanium Alloy Implants(pTi),owing to their biologically inertness and relatively smooth surface morphology,adversely affect the biological functions of surrounding cells.To address the challenges,constructing a bioinspired interface that mimics the hierarchical structure of bone tissue can enhance the cellular functions of cells.In this context,Hollow Mesoporous Silica Nanoparticles(HMSNs),renowned for their unique physicochemical properties and superior biocompatibility,offer a promising direction for this research.In this research,the initially synthesized HMSNs were used to construct a“hollow-mesoporous-macroporous”hierarchical bioinspired coating on the pTi surface through the Layer-by-Layer technique.Simultaneously,diverse morphologies of coatings were established by adjusting the deposition strategy of PDDA/HMSNs on the pTi surface(pTi-HMSN-2,pTi-HMSN-4,pTi-HMSN-6).A range of techniques were employed to investigate the physicochemical properties and regulation of cellular biological functions of the diverse HMSN coating strategies.Notably,the pTi-HMSN-4 and pTi-HMSN-6 groups exhibited the uniform coatings,leading to a substantial enhancement in surface roughness and hydrophilicity.Meantime,the coating constructed strategy of pTi-HMSN-4 possessed commendable stability.Based on the aforementioned findings,both pTi-HMSN-4 and pTi-HMSN-6 facilitated the adhesion,spreading,and pseudopodia extension of BMSCs,which led to a notable upsurge in the expression levels of vinculin protein in BMSCs.Comprehensive analysis indicates that the coating,when PDDA/HMSNs are deposited four times,possesses favorable overall performance.The research will provide a solid theoretical basis for the translation of HMSN bioinspired coatings for orthopedic implants.
基金This work is supported by the National Natural Science Foundation of China(Grant Nos.12072242,11772237)the Natural Science Foundation of Hubei Province(Grant No.2020CFB816)the open funds of the State Key Laboratory of Structural Analysis for Industrial Equipment(Dalian University of Technology)through contract/Grant No.GZ19110.
文摘Functional graded cellular structure(FGCS)usually shows superiormechanical behaviorwith lowdensity and high stiffness.With the development of additivemanufacturing,functional graded cellular structure gains its popularity in industries.In this paper,a novel approach for designing functionally graded cellular structure is proposed based on a subdomain parameterized level set method(PLSM)under local volume constraints(LVC).In this method,a subdomain level set function is defined,parameterized and updated on each subdomain independently making the proposed approach much faster and more cost-effective.Additionally,the microstructures on arbitrary two adjacent subdomains can be connected perfectly without any additional constraint.Furthermore,the local volume constraint for each subdomain is applied by virtue of the augmented Lagrange multiplier method.Finally,several numerical examples are given to verify the correctness and effectiveness of the proposed approach in designing the functionally graded cellular structure.From the optimized results,it is also found that the number of local volume constraints has little influence on the convergence speed of the developed approach.
