High-alkali species in coal are notorious for causing ash slagging and fouling incidents.In this paper,four high-alkali coals were individually subject to hydrothermal pretreatment(HTP),within a batch-type autoclave a...High-alkali species in coal are notorious for causing ash slagging and fouling incidents.In this paper,four high-alkali coals were individually subject to hydrothermal pretreatment(HTP),within a batch-type autoclave at 300 -C for 1 h,and the treated coals were analyzed,along with the oxygen-containing functional groups determined by Fourier transform infrared spectrometer(FT-IR).Then the alkali species and other components in the coal ash were quantified by X-ray fluorescence(XRF)for evaluating the ash slagging and fouling tendency.Apart from this,FactSage was adopted to simulate the occurrence and transformation of alkali species during coal thermal conversion ending at various temperatures.The findings indicate that the treated coals are superior to the parent ones in terms of certain remarkable changes via HTP.The moisture,oxygen and sulfur of the hydrothermally treated coals decline obviously,while the calorific value rises sharply.HTP could reduce the alkali species to less than 2%(%,by weight,equivalent to Na2O in dry ash),with a maximum removal ratio of 88.9%,lowering the ash slagging and fouling tendency.The proposed mechanism of HTP was that the alkali species in coal matrix became released due to the breakage of the coal functional groups and micropores during HTP.展开更多
Based on the daily maximum air temperature(T_(max))data from the China Meteorological Data Network and the NCEP/DOE reanalysis data,the intra-seasonal circulation and evolution of an extreme high temperature event(EHT...Based on the daily maximum air temperature(T_(max))data from the China Meteorological Data Network and the NCEP/DOE reanalysis data,the intra-seasonal circulation and evolution of an extreme high temperature event(EHTE)in the middle reaches of the Yangtze River(MYR)from August 9-21,2011 were explored,as well as the influence of diabatic heating on the position variation of the Western Pacific subtropical high(WPSH).Results show that the daily T_(max) in the MYR exhibits a vigorous intraseasonal oscillation(ISO)of 10-25 days in the extended summer of 1980-2018.The main factors affecting the EHTE in the summer of 2011 are the low-frequency wave train propagating southeastward in the mid-latitude of the upper troposphere and the low-frequency anticyclone moving northwestward in the lowlatitude of the mid-lower troposphere.The diagnosis of 925hPa thermodynamic equation indicates that the ISO features of the T_(max) in the core region is determined by the intra-seasonal variation of the adiabatic variation.In addition,the variations of the WPSH correspond well to the distribution of apparent heat source.In the early stage of the high temperature process,the apparent heat source in the north of the Bay of Bengal is a certain indicator for the westward extension of the WPSH.展开更多
基金the National Key Basic Research Program of China (No. 2014CB238905)
文摘High-alkali species in coal are notorious for causing ash slagging and fouling incidents.In this paper,four high-alkali coals were individually subject to hydrothermal pretreatment(HTP),within a batch-type autoclave at 300 -C for 1 h,and the treated coals were analyzed,along with the oxygen-containing functional groups determined by Fourier transform infrared spectrometer(FT-IR).Then the alkali species and other components in the coal ash were quantified by X-ray fluorescence(XRF)for evaluating the ash slagging and fouling tendency.Apart from this,FactSage was adopted to simulate the occurrence and transformation of alkali species during coal thermal conversion ending at various temperatures.The findings indicate that the treated coals are superior to the parent ones in terms of certain remarkable changes via HTP.The moisture,oxygen and sulfur of the hydrothermally treated coals decline obviously,while the calorific value rises sharply.HTP could reduce the alkali species to less than 2%(%,by weight,equivalent to Na2O in dry ash),with a maximum removal ratio of 88.9%,lowering the ash slagging and fouling tendency.The proposed mechanism of HTP was that the alkali species in coal matrix became released due to the breakage of the coal functional groups and micropores during HTP.
基金National Key Research and Development Program of China(2018YFC1505804)National Natural Science Foundation of China(42075032)。
文摘Based on the daily maximum air temperature(T_(max))data from the China Meteorological Data Network and the NCEP/DOE reanalysis data,the intra-seasonal circulation and evolution of an extreme high temperature event(EHTE)in the middle reaches of the Yangtze River(MYR)from August 9-21,2011 were explored,as well as the influence of diabatic heating on the position variation of the Western Pacific subtropical high(WPSH).Results show that the daily T_(max) in the MYR exhibits a vigorous intraseasonal oscillation(ISO)of 10-25 days in the extended summer of 1980-2018.The main factors affecting the EHTE in the summer of 2011 are the low-frequency wave train propagating southeastward in the mid-latitude of the upper troposphere and the low-frequency anticyclone moving northwestward in the lowlatitude of the mid-lower troposphere.The diagnosis of 925hPa thermodynamic equation indicates that the ISO features of the T_(max) in the core region is determined by the intra-seasonal variation of the adiabatic variation.In addition,the variations of the WPSH correspond well to the distribution of apparent heat source.In the early stage of the high temperature process,the apparent heat source in the north of the Bay of Bengal is a certain indicator for the westward extension of the WPSH.
