To achieve the utilization of the abandoned ultrafine ilmenite(-20 μm) produced in the titanium magnetite processing plant in Panzhihua,the superconducting high-gradient magnetic separation(SMS) technology was propos...To achieve the utilization of the abandoned ultrafine ilmenite(-20 μm) produced in the titanium magnetite processing plant in Panzhihua,the superconducting high-gradient magnetic separation(SMS) technology was proposed in this study.After optimizing the conditions of magnetic intensity,feeding and pulsation,an SMS concentrate with TiO_(2) grade of 16.03% and TiO_(2) recovery of 66.39% was obtained through one roughing-one cleaning pre-concentration flowsheet.The specific magnetic force and magnetic force were calculated and analysed to illustrate the pre-concentration mechanism,and the results revealed that the combination of high magnetic field and strong pulsating resulted in the effective preconcentration of the ultrafine ilmenite in the SMS process.In addition,the magnetic force analysis indicated that the high magnetic intensity and high magnetic gradient are the key factors of the SMS technology.Furthermore,the EDS-Mapping detection certified that the ultrafine ilmenite was concentrated from the gangue minerals using SMS technology.展开更多
The removal of phosphate from municipal sewage by high gradient magnetic separation using aluminium sulphate as precipitating agent and Fe3O4 as seeding material was studied. The effects of aluminium sulphate, Fe3O4, ...The removal of phosphate from municipal sewage by high gradient magnetic separation using aluminium sulphate as precipitating agent and Fe3O4 as seeding material was studied. The effects of aluminium sulphate, Fe3O4, magnetic field intensity, pH value and flow-rate of sewage on phosphorus removal rate were investigated. The results show that addition of 200 mg/L Al2(SO4)3·18H2O and 300 mg/L Fe3O4, magnetic field intensity of 200 kA/m, pH value of 4.57.0 and flow-rate of 6.15 cm/s are both efficient and economic technical parameters for removal of phosphate. The pH value has a tremendous effect on the removal of phosphate. In the pH range of (4.5)7.0, more than 95% phosphate can be removed. Theoretical analysis indicates that the solubility of AlPO4 is minimum at pH 4.07.0 and the electrostatic attractive force between AlPO4 and Fe3O4 is maximum at pH 4.5(6.5.)展开更多
A new method-dry High Gradient Magnetic Separation (HGMS)-to remove iron from ultrafine kaolin powder is described. A new kind of disperser, which breaks down the particle clusters in the powder by high speed gas fl...A new method-dry High Gradient Magnetic Separation (HGMS)-to remove iron from ultrafine kaolin powder is described. A new kind of disperser, which breaks down the particle clusters in the powder by high speed gas flow from an air compressor, is used to completely disperse the powders. The dispersed particles are passed through vibrating HGMS by a vacuum pump to remove the iron. The magnetic and nonmagnetic fractions are separately collected by cloth collectors. Dry HGMS laboratory experiments are carried out. A product containing 0.90% Fe<sub>2</sub>O<sub>3</sub> was obtained, and the recovery was 70%.展开更多
We present a review of the principal developments in the evolution and synergism of solute and particle migration in a liquid melt in high-gradient magnetic fields and we also describe their effects on the solidificat...We present a review of the principal developments in the evolution and synergism of solute and particle migration in a liquid melt in high-gradient magnetic fields and we also describe their effects on the solidification microstructure of alloys.Diverse areas relevant to various aspects of theory and applications of high-gradient magnetic field-controlled migration of solutes and particles are surveyed. They include introduction, high-gradient magnetic field effects, migration behavior of solute and particles in high-gradient magnetic fields, microstructure evolution induced by high-gradient magnetic fieldcontrolled migrations of solute and particles, and properties of materials modified by high-gradient magnetic field-tailored microstructure. Selected examples of binary and multiphase alloy systems are presented and examined, with the main focus on the correlation between the high-gradient magnetic field-modified migration and the related solidification microstructure evolution. Particular attention is given to the mechanisms responsible for the microstructure evolution induced by highgradient magnetic fields.展开更多
Scandium (Sc) concentration from the rare earth ore by high gradient magnetic separation (HGMS) was determined on the basis of Sc content, geophysical parameter determination and the magnetic analyses of the ore. Base...Scandium (Sc) concentration from the rare earth ore by high gradient magnetic separation (HGMS) was determined on the basis of Sc content, geophysical parameter determination and the magnetic analyses of the ore. Based on the condition experiments, expanding experiments were carried out. The results showed that the ore had a Sc grade of 48.90 g/t, and after removing iron by low-intensity magnetic separation, a Sc concentrate of 314.89 g/t grade and with 77.53% recovery was obtained by one-stage roughing-one...展开更多
An S-band high-gradient accelerating structure is designed for a proton therapy linear accelerator(linac)to accommodate the new development of compact,singleroom facilities and ultra-high dose rate(FLASH)radiotherapy....An S-band high-gradient accelerating structure is designed for a proton therapy linear accelerator(linac)to accommodate the new development of compact,singleroom facilities and ultra-high dose rate(FLASH)radiotherapy.To optimize the design,an efficient optimization scheme is applied to improve the simulation efficiency.An S-band accelerating structure with 2856 MHz is designed with a low beta of 0.38,which is a difficult structure to achieve for a linac accelerating proton particles from 70 to 250 MeV,as a high gradient up to 50 MV/m is required.A special design involving a dual-feed coupler eliminates the dipole field effect.This paper presents all the details pertaining to the design,fabrication,and cold test results of the S-band high-gradient accelerating structure.展开更多
This paper describes the design and preliminary test of the low-level radio frequency(LLRF)part of the C band high-gradient test facility for the Shanghai Soft X-ray Free-Electron Laser(SXFEL)-Linear Accelerator(LINAC...This paper describes the design and preliminary test of the low-level radio frequency(LLRF)part of the C band high-gradient test facility for the Shanghai Soft X-ray Free-Electron Laser(SXFEL)-Linear Accelerator(LINAC).Before installation,the accelerating structures should be tested and conditioned.During the conditioning process,breakdown detection is needed to protect the accelerating structures and klystron from damage.The PCI extensions for instrumentation-based LLRF system and auto-conditioning algorithm are designed and applied in the LLRF part of the C band high-gradient test facility.Three C band accelerating structures and 1 pulse compressor have completed conditioning and were installed in the SXFEL-LINAC.展开更多
This paper reports on the design,fabrication,RF measurement,and high-power test of a prototype accelerator—such as 11.424 GHz with 12 cells—and a traveling wave of two halves.It was found that the unloaded gradient ...This paper reports on the design,fabrication,RF measurement,and high-power test of a prototype accelerator—such as 11.424 GHz with 12 cells—and a traveling wave of two halves.It was found that the unloaded gradient reached 103 MV/m during the high-power test and the measured breakdown rate,after 3.17×10^(7) pulses,was 1.62×10^(-4)/pulse/m at 94 MV/m and a 90 ns pulse length.We thus concluded that the high-gradient two-half linear accelerator is cost-effective,especially in high-frequency RF linear acceleration.Finally,we suggest that silverbased alloy brazing can further reduce costs.展开更多
X-band high-gradient linear accelerators are a challenging and attractive technology for compact electron linear-accelerator facilities.The Very Compact Inverse Compton Scattering Gamma-ray Source(VIGAS)program at Tsi...X-band high-gradient linear accelerators are a challenging and attractive technology for compact electron linear-accelerator facilities.The Very Compact Inverse Compton Scattering Gamma-ray Source(VIGAS)program at Tsinghua University will utilize X-band high-gradient accelerating structures to boost the electron beam from 50 to 350 MeV over a short distance.A constant-impedance traveling-wave structure consisting of 72 cells working in the 2π/3 mode was designed and fabricated for this project.Precise tuning and detailed measurements were successfully applied to the structure.After 180 h of conditioning in the Tsinghua high-power test stand,the structure reached a target gradient of 80 MV/m.The breakdown rate versus gradient of this structure was measured and analyzed.展开更多
Thin film composite(TFC) membranes represent a highly promising platform for efficient nanofiltration(NF)processes. However, the improvement in permeance is impeded by the substrates with low permeances. Herein,highly...Thin film composite(TFC) membranes represent a highly promising platform for efficient nanofiltration(NF)processes. However, the improvement in permeance is impeded by the substrates with low permeances. Herein,highly permeable gradient phenolic membranes with tight selectivity are used as substrates to prepare TFC membranes with high permeances by the layer-by-layer assembly method. The negatively charged phenolic substrates are alternately assembled with polycation polyethylenimine(PEI) and polyanion poly(acrylic acid)(PAA)as a result of electrostatic interactions, forming thin and compact PEI/PAA layers tightly attached to the substrate surface. Benefiting from the high permeances and tight surface pores of the gradient nanoporous structures of the substrates, the produced PEI/PAA membranes exhibit a permeance up to 506 L? m-2?h-1?MPa-1, which is ~2–10 times higher than that of other membranes with similar rejections. The PEI/PAA membranes are capable of retaining N 96.1% of negatively charged dyes following the mechanism of electrostatic repulsion. We demonstrate that the membranes can also separate positively and neutrally charged dyes from water via other mechanisms.This work opens a new avenue for the design and preparation of high-flux NF membranes, which is also applicable to enhance the permeance of other TFC membranes.展开更多
Short copper standing wave (SW) structures operating at an X-band frequency have been recently designed and manufactured at the Laboratori Nazionali di Frascati of the Istituto Nazionale di Fisica Nucleare (INFN) ...Short copper standing wave (SW) structures operating at an X-band frequency have been recently designed and manufactured at the Laboratori Nazionali di Frascati of the Istituto Nazionale di Fisica Nucleare (INFN) using the vacuum brazing technique. High power tests of the structures have been performed at the SLAC National Accelerator Laboratory. In this manuscript we report the results of these tests and the activity in progress to enhance the high gradient performance of the next generation of structures, particularly the technological characterization of high performance coatings obtained via molybdenum sputtering.展开更多
A polymeric nanopore membrane with selective ionic transport has been proposed as a potential device to convert the chemical potential energy in salinity gradients to electrical power. However, its energy conversion e...A polymeric nanopore membrane with selective ionic transport has been proposed as a potential device to convert the chemical potential energy in salinity gradients to electrical power. However, its energy conversion efficiency and power density are often limited due to the challenge in reliably controlling the size of the nanopores with the conventional chemical etching method. Here we report that without chemical etching, polyimide (PI) membranes irradiated with GeV heavy ions have negatively charged nanopores, showing nearly perfect selectivity for cations over anions, and they can generate electrical power from salinity gradients. We further demonstrate that the power generation efficiency of the PI membrane approaches the theoretical limit, and the maximum power density reaches 130m W/m2 with a modified etching method, outperforming the previous energy conversion device that was made of polymeric nanopore membranes.展开更多
The detailed laser surface remelting experiments of Cu-31.4 wt pct Mn and Cu-26.6 wt pct Mn alloys on a 5 kW CO2 laser were carried out to study the effects of processing parameters (scanning velocity, output power of...The detailed laser surface remelting experiments of Cu-31.4 wt pct Mn and Cu-26.6 wt pct Mn alloys on a 5 kW CO2 laser were carried out to study the effects of processing parameters (scanning velocity, output power of laser) on the growth direction of microstructure in the molten pool and cellular spacing selection under the condition of ultra-high temperature gradient and rapid directional solidification. The experimental results show that the growth direction of microstructure is strongly affected by laser processing parameters. The ultra-high temperature gradient directional solidification can be realized on the surface of samples during laser surface remelting by controlling laser processing parameters, the temperature gradient and growth velocity can reach 106 K/m and 24.1 mm/s, respectively, and the solidification microstructure in the center of the molten pool grows along the laser beam scanning direction. There exists a distribution range of cellular spacings under the laser rapid solidification conditions, and the average spacing decreases with increasing of growth rate. The maximum, λmax, minimum, λmin, and average primary spacing, A, as functions of growth rate, Vb, can be given by,λmax=12.54Vb-0.61, λmin=4.47 Vb-0.52, λ=9.09Vb-0.62, respectively. The experimental results are compared with the current Hunt-Lu model for rapid cellular/dendritic growth, and a good agreement is found.展开更多
The introduction of functionalized magnetizable particles and high-gradient magnetic separation represents a time and money saving alternative to conventional purification and separation unit operations in the biotech...The introduction of functionalized magnetizable particles and high-gradient magnetic separation represents a time and money saving alternative to conventional purification and separation unit operations in the biotechnical sector. This technique has some advantages especially for the recycling of immobilized enzymes. A new magnetic filter with sight glasses was constructed and produced to study the performance of high-gradient magnetic separation at varied parameters. By optical analysis the buildup of a clogging was identified as the major parameter which affected the separation performance. For the cleaning procedure, a two-phase flow of water with highly dispersed air bubbles was tested which led to a nearly complete cleaning of the filter chamber.展开更多
The introduction of functionalized magnetizable particles for the purification of enzymes or for the multi-use of pre-immobilized biocatalysts offers a great potential for time and cost savings in biotechnological pro...The introduction of functionalized magnetizable particles for the purification of enzymes or for the multi-use of pre-immobilized biocatalysts offers a great potential for time and cost savings in biotechnological process design. The selective separation of the magnetizable particles is performed for example by a high-gradient magnetic separator. In this study FEM and CFD simulations of the magnetic field and the fluid flow field within a filter chamber of a magnetic separator were carried out, to find an optimal separator design. The motion of virtual magnetizable particles was calculated with a one-way coupled Lagrangian approach in order to test many geometric and parametric variations in reduced time. It was found that a flow homogenisator smoothed the fluid flow, so that the linear velocity became nearly equal over the cross section in the direction of flow. Furthermore the retention of magnetizable particles increases with a high total edge length within the filter matrix.展开更多
The components and structures of lithosphere, inhomogeneous, are changing incessantly in different periods. Therefore, the state of load, called the pressure, in lithosphere is also incessantly changing. When the lith...The components and structures of lithosphere, inhomogeneous, are changing incessantly in different periods. Therefore, the state of load, called the pressure, in lithosphere is also incessantly changing. When the lithosphere volume remains the same, namely on the premise of isovolumes, the geobarmal gradient is: (d p /d h) v =( p / h) v +( p / T) v (d T /d h) v . If β =(d p /d h) v /( p / h) v is supposed, then β =1+ rg -1 C v (d T /d h) v . When the geothermal degree in (d T /d h) v is zero, then the pressure grade of lithosphere is equal to the lithostatic grade, which is the minimum value in the pressure grade of lithosphere. Suppose that the lithosphere is made only up of quartz, C v ≌ C p =0.782+5.718×10 -4 T -1.883×10 4 T -2 (J· g -1 · K -1 ) is obtained, which is the minimum one in lithospheric rock, and then the geothermal grade value of 20 ℃/km is calculated according to the geophysical transection data of Qinling Mountain orogeny. The results show that the high pressure and ultrahigh pressure eclogites in Jiangsu Province and Huangzhen, Dabie may, on the condition of incompletely isovolumes, occur in the depths of 17-40 km with the increase in geothermal temperature, whose values of β do not correspond to the theoretic value of 3.08.展开更多
After successfully locating one abandoned brine well by an electromagnetic method during testing in 2001 and five abandoned brine wells by a high resolution magnetic method during 2002, a high resolution magnetic meth...After successfully locating one abandoned brine well by an electromagnetic method during testing in 2001 and five abandoned brine wells by a high resolution magnetic method during 2002, a high resolution magnetic method was again proposed to search for wells in 2003 when a second sensor was employed to acquire data for calculating the pseudo vertical gradient of magnetic fields. Total area surveyed in 2003 was 1,024,000 ft 2, which was divided into grids with an average size of 10,000 ft 2 and distributed across eight different sites. Magnetic anomalies and their vertical gradients from known brine wells were first recorded as signatures to identify anomalies caused by possible buried brine wells. Of fifty one verified anomalies, thirty one anomalies were due to wells buried at depths from 0 to 8.5 ft: twenty one 6 to 9 inch abandoned brine wells, seven 1.5 to 3 inch probable water wells, one 16 inch dewatering well for a construction site at a depth of 3 ft, and two 4 inch wells on the ground surface. Approximate monopole shaped anomalies were observed from all these wells after data corrections. However, the range of amplitudes of magnetic anomalies from 7,000 to 28,000 nT from these abandoned brine wells was measured. This range of anomalies is mainly due to the thickness and depth of buried wells. Anomaly amplitudes from 1.5 to 3 inch wells are 4,000 to 8,000 nT and linearly correlate with the buried depth. One 3 inch well that caused an anomaly of 13,000 nT could be the inner pipe of a brine well. Gradient anomalies are roughly in a range of 100 to 200 nT/inch for 1.5 to 3 inch wells and 200 to 300 nT/inch for brine wells.As indicated by the potential field theory, gradient data possess higher horizontal resolution than the magnetic field itself. Gradient data provide valuable assistance in determining horizontal locations of anomaly sources for excavation. In practice, however, improvement in the horizontal resolution is limited by survey line spacing. If only one sensor is used in a survey, there is rapid decrease in the horizontal resolution when sensor height increases from 14 to 44 inches. This indicates that it is critical to keep the sensor as close to the ground as possible when hunting buried wells that are close to each other. It also suggests that the downward continuation is useful to increase the horizontal resolution in well hunting.展开更多
基金financial support from the Joint Fund (Key program U2067201) for Nuclear Technology Innovation Sponsored by the National Natural Science Foundation of China and the China National Nuclear CorporationNational key research and development program (2019YFC1907702) Sponsored by MOSTthe Fundamental Research Funds for the Central Universities (N2001013) for supporting this research。
文摘To achieve the utilization of the abandoned ultrafine ilmenite(-20 μm) produced in the titanium magnetite processing plant in Panzhihua,the superconducting high-gradient magnetic separation(SMS) technology was proposed in this study.After optimizing the conditions of magnetic intensity,feeding and pulsation,an SMS concentrate with TiO_(2) grade of 16.03% and TiO_(2) recovery of 66.39% was obtained through one roughing-one cleaning pre-concentration flowsheet.The specific magnetic force and magnetic force were calculated and analysed to illustrate the pre-concentration mechanism,and the results revealed that the combination of high magnetic field and strong pulsating resulted in the effective preconcentration of the ultrafine ilmenite in the SMS process.In addition,the magnetic force analysis indicated that the high magnetic intensity and high magnetic gradient are the key factors of the SMS technology.Furthermore,the EDS-Mapping detection certified that the ultrafine ilmenite was concentrated from the gangue minerals using SMS technology.
文摘The removal of phosphate from municipal sewage by high gradient magnetic separation using aluminium sulphate as precipitating agent and Fe3O4 as seeding material was studied. The effects of aluminium sulphate, Fe3O4, magnetic field intensity, pH value and flow-rate of sewage on phosphorus removal rate were investigated. The results show that addition of 200 mg/L Al2(SO4)3·18H2O and 300 mg/L Fe3O4, magnetic field intensity of 200 kA/m, pH value of 4.57.0 and flow-rate of 6.15 cm/s are both efficient and economic technical parameters for removal of phosphate. The pH value has a tremendous effect on the removal of phosphate. In the pH range of (4.5)7.0, more than 95% phosphate can be removed. Theoretical analysis indicates that the solubility of AlPO4 is minimum at pH 4.07.0 and the electrostatic attractive force between AlPO4 and Fe3O4 is maximum at pH 4.5(6.5.)
基金The project was financially supported by China National Science and Technology Committee
文摘A new method-dry High Gradient Magnetic Separation (HGMS)-to remove iron from ultrafine kaolin powder is described. A new kind of disperser, which breaks down the particle clusters in the powder by high speed gas flow from an air compressor, is used to completely disperse the powders. The dispersed particles are passed through vibrating HGMS by a vacuum pump to remove the iron. The magnetic and nonmagnetic fractions are separately collected by cloth collectors. Dry HGMS laboratory experiments are carried out. A product containing 0.90% Fe<sub>2</sub>O<sub>3</sub> was obtained, and the recovery was 70%.
基金Project supported by the National Natural Science Foundation of China(Grant Nos.51425401,51690161,51574073,and 51774086)Fundamental Research Funds for the Central Universities,China(Grant Nos.N170902002 and N170908001)Liaoning Innovative Research Team in University,China(Grant No.LT2017011)
文摘We present a review of the principal developments in the evolution and synergism of solute and particle migration in a liquid melt in high-gradient magnetic fields and we also describe their effects on the solidification microstructure of alloys.Diverse areas relevant to various aspects of theory and applications of high-gradient magnetic field-controlled migration of solutes and particles are surveyed. They include introduction, high-gradient magnetic field effects, migration behavior of solute and particles in high-gradient magnetic fields, microstructure evolution induced by high-gradient magnetic fieldcontrolled migrations of solute and particles, and properties of materials modified by high-gradient magnetic field-tailored microstructure. Selected examples of binary and multiphase alloy systems are presented and examined, with the main focus on the correlation between the high-gradient magnetic field-modified migration and the related solidification microstructure evolution. Particular attention is given to the mechanisms responsible for the microstructure evolution induced by highgradient magnetic fields.
文摘Scandium (Sc) concentration from the rare earth ore by high gradient magnetic separation (HGMS) was determined on the basis of Sc content, geophysical parameter determination and the magnetic analyses of the ore. Based on the condition experiments, expanding experiments were carried out. The results showed that the ore had a Sc grade of 48.90 g/t, and after removing iron by low-intensity magnetic separation, a Sc concentrate of 314.89 g/t grade and with 77.53% recovery was obtained by one-stage roughing-one...
基金This work was supported by the Alliance of International Science Organizations(No.ANSO-CR-KP-2020-16).
文摘An S-band high-gradient accelerating structure is designed for a proton therapy linear accelerator(linac)to accommodate the new development of compact,singleroom facilities and ultra-high dose rate(FLASH)radiotherapy.To optimize the design,an efficient optimization scheme is applied to improve the simulation efficiency.An S-band accelerating structure with 2856 MHz is designed with a low beta of 0.38,which is a difficult structure to achieve for a linac accelerating proton particles from 70 to 250 MeV,as a high gradient up to 50 MV/m is required.A special design involving a dual-feed coupler eliminates the dipole field effect.This paper presents all the details pertaining to the design,fabrication,and cold test results of the S-band high-gradient accelerating structure.
基金This work was supported by the National Key R&D Program of China(No.2018YFF0109203).
文摘This paper describes the design and preliminary test of the low-level radio frequency(LLRF)part of the C band high-gradient test facility for the Shanghai Soft X-ray Free-Electron Laser(SXFEL)-Linear Accelerator(LINAC).Before installation,the accelerating structures should be tested and conditioned.During the conditioning process,breakdown detection is needed to protect the accelerating structures and klystron from damage.The PCI extensions for instrumentation-based LLRF system and auto-conditioning algorithm are designed and applied in the LLRF part of the C band high-gradient test facility.Three C band accelerating structures and 1 pulse compressor have completed conditioning and were installed in the SXFEL-LINAC.
基金supported by the National Natural Science Foundation of China(No.11922504)。
文摘This paper reports on the design,fabrication,RF measurement,and high-power test of a prototype accelerator—such as 11.424 GHz with 12 cells—and a traveling wave of two halves.It was found that the unloaded gradient reached 103 MV/m during the high-power test and the measured breakdown rate,after 3.17×10^(7) pulses,was 1.62×10^(-4)/pulse/m at 94 MV/m and a 90 ns pulse length.We thus concluded that the high-gradient two-half linear accelerator is cost-effective,especially in high-frequency RF linear acceleration.Finally,we suggest that silverbased alloy brazing can further reduce costs.
基金supported by the National Natural Science Foundation of China (Nos. 11922504 and 12027902)
文摘X-band high-gradient linear accelerators are a challenging and attractive technology for compact electron linear-accelerator facilities.The Very Compact Inverse Compton Scattering Gamma-ray Source(VIGAS)program at Tsinghua University will utilize X-band high-gradient accelerating structures to boost the electron beam from 50 to 350 MeV over a short distance.A constant-impedance traveling-wave structure consisting of 72 cells working in the 2π/3 mode was designed and fabricated for this project.Precise tuning and detailed measurements were successfully applied to the structure.After 180 h of conditioning in the Tsinghua high-power test stand,the structure reached a target gradient of 80 MV/m.The breakdown rate versus gradient of this structure was measured and analyzed.
基金financially supported by National Natural Science Foundation of China(No.50827102)the Scientific Research Foundation for Ph.D.,Northwest A&F University(No.Z109021103)+1 种基金the Special Fund for Basic Scientific Research of Central Colleges,Northwest A&F University(No.Z109021114)the Fund of the State Key Laboratory of Solidification Processing in NWPU(No.SKLSP201220)
基金Supported by the National Basic Research Program of China(2015CB655301)the Natural Science Foundation of China(21825803)+2 种基金and the Natural Science Foundation of Jiangsu Province(BK20150063)the Program of Excellent Innovation Teams of Jiangsu Higher Education Institutionsthe Project of Priority Academic Program Development of Jiangsu Higher Education Institutions(PAPD).
文摘Thin film composite(TFC) membranes represent a highly promising platform for efficient nanofiltration(NF)processes. However, the improvement in permeance is impeded by the substrates with low permeances. Herein,highly permeable gradient phenolic membranes with tight selectivity are used as substrates to prepare TFC membranes with high permeances by the layer-by-layer assembly method. The negatively charged phenolic substrates are alternately assembled with polycation polyethylenimine(PEI) and polyanion poly(acrylic acid)(PAA)as a result of electrostatic interactions, forming thin and compact PEI/PAA layers tightly attached to the substrate surface. Benefiting from the high permeances and tight surface pores of the gradient nanoporous structures of the substrates, the produced PEI/PAA membranes exhibit a permeance up to 506 L? m-2?h-1?MPa-1, which is ~2–10 times higher than that of other membranes with similar rejections. The PEI/PAA membranes are capable of retaining N 96.1% of negatively charged dyes following the mechanism of electrostatic repulsion. We demonstrate that the membranes can also separate positively and neutrally charged dyes from water via other mechanisms.This work opens a new avenue for the design and preparation of high-flux NF membranes, which is also applicable to enhance the permeance of other TFC membranes.
基金Supported by Technological Innovation Project of Institute of High Energy Physics
文摘Short copper standing wave (SW) structures operating at an X-band frequency have been recently designed and manufactured at the Laboratori Nazionali di Frascati of the Istituto Nazionale di Fisica Nucleare (INFN) using the vacuum brazing technique. High power tests of the structures have been performed at the SLAC National Accelerator Laboratory. In this manuscript we report the results of these tests and the activity in progress to enhance the high gradient performance of the next generation of structures, particularly the technological characterization of high performance coatings obtained via molybdenum sputtering.
基金Supported by the National Natural Science Foundation of China under Grant No 11335003
文摘A polymeric nanopore membrane with selective ionic transport has been proposed as a potential device to convert the chemical potential energy in salinity gradients to electrical power. However, its energy conversion efficiency and power density are often limited due to the challenge in reliably controlling the size of the nanopores with the conventional chemical etching method. Here we report that without chemical etching, polyimide (PI) membranes irradiated with GeV heavy ions have negatively charged nanopores, showing nearly perfect selectivity for cations over anions, and they can generate electrical power from salinity gradients. We further demonstrate that the power generation efficiency of the PI membrane approaches the theoretical limit, and the maximum power density reaches 130m W/m2 with a modified etching method, outperforming the previous energy conversion device that was made of polymeric nanopore membranes.
基金The financial aid of the National Natural Science Foundation of China under grant No.59771054Postdoctoral Science Foundation of China+1 种基金Postdoctoral Science Foundation of Tsinghua-Zhongda985 Science Foundation of Tsinghua University are gratefully acknowledged.
文摘The detailed laser surface remelting experiments of Cu-31.4 wt pct Mn and Cu-26.6 wt pct Mn alloys on a 5 kW CO2 laser were carried out to study the effects of processing parameters (scanning velocity, output power of laser) on the growth direction of microstructure in the molten pool and cellular spacing selection under the condition of ultra-high temperature gradient and rapid directional solidification. The experimental results show that the growth direction of microstructure is strongly affected by laser processing parameters. The ultra-high temperature gradient directional solidification can be realized on the surface of samples during laser surface remelting by controlling laser processing parameters, the temperature gradient and growth velocity can reach 106 K/m and 24.1 mm/s, respectively, and the solidification microstructure in the center of the molten pool grows along the laser beam scanning direction. There exists a distribution range of cellular spacings under the laser rapid solidification conditions, and the average spacing decreases with increasing of growth rate. The maximum, λmax, minimum, λmin, and average primary spacing, A, as functions of growth rate, Vb, can be given by,λmax=12.54Vb-0.61, λmin=4.47 Vb-0.52, λ=9.09Vb-0.62, respectively. The experimental results are compared with the current Hunt-Lu model for rapid cellular/dendritic growth, and a good agreement is found.
文摘The introduction of functionalized magnetizable particles and high-gradient magnetic separation represents a time and money saving alternative to conventional purification and separation unit operations in the biotechnical sector. This technique has some advantages especially for the recycling of immobilized enzymes. A new magnetic filter with sight glasses was constructed and produced to study the performance of high-gradient magnetic separation at varied parameters. By optical analysis the buildup of a clogging was identified as the major parameter which affected the separation performance. For the cleaning procedure, a two-phase flow of water with highly dispersed air bubbles was tested which led to a nearly complete cleaning of the filter chamber.
文摘The introduction of functionalized magnetizable particles for the purification of enzymes or for the multi-use of pre-immobilized biocatalysts offers a great potential for time and cost savings in biotechnological process design. The selective separation of the magnetizable particles is performed for example by a high-gradient magnetic separator. In this study FEM and CFD simulations of the magnetic field and the fluid flow field within a filter chamber of a magnetic separator were carried out, to find an optimal separator design. The motion of virtual magnetizable particles was calculated with a one-way coupled Lagrangian approach in order to test many geometric and parametric variations in reduced time. It was found that a flow homogenisator smoothed the fluid flow, so that the linear velocity became nearly equal over the cross section in the direction of flow. Furthermore the retention of magnetizable particles increases with a high total edge length within the filter matrix.
文摘The components and structures of lithosphere, inhomogeneous, are changing incessantly in different periods. Therefore, the state of load, called the pressure, in lithosphere is also incessantly changing. When the lithosphere volume remains the same, namely on the premise of isovolumes, the geobarmal gradient is: (d p /d h) v =( p / h) v +( p / T) v (d T /d h) v . If β =(d p /d h) v /( p / h) v is supposed, then β =1+ rg -1 C v (d T /d h) v . When the geothermal degree in (d T /d h) v is zero, then the pressure grade of lithosphere is equal to the lithostatic grade, which is the minimum value in the pressure grade of lithosphere. Suppose that the lithosphere is made only up of quartz, C v ≌ C p =0.782+5.718×10 -4 T -1.883×10 4 T -2 (J· g -1 · K -1 ) is obtained, which is the minimum one in lithospheric rock, and then the geothermal grade value of 20 ℃/km is calculated according to the geophysical transection data of Qinling Mountain orogeny. The results show that the high pressure and ultrahigh pressure eclogites in Jiangsu Province and Huangzhen, Dabie may, on the condition of incompletely isovolumes, occur in the depths of 17-40 km with the increase in geothermal temperature, whose values of β do not correspond to the theoretic value of 3.08.
文摘After successfully locating one abandoned brine well by an electromagnetic method during testing in 2001 and five abandoned brine wells by a high resolution magnetic method during 2002, a high resolution magnetic method was again proposed to search for wells in 2003 when a second sensor was employed to acquire data for calculating the pseudo vertical gradient of magnetic fields. Total area surveyed in 2003 was 1,024,000 ft 2, which was divided into grids with an average size of 10,000 ft 2 and distributed across eight different sites. Magnetic anomalies and their vertical gradients from known brine wells were first recorded as signatures to identify anomalies caused by possible buried brine wells. Of fifty one verified anomalies, thirty one anomalies were due to wells buried at depths from 0 to 8.5 ft: twenty one 6 to 9 inch abandoned brine wells, seven 1.5 to 3 inch probable water wells, one 16 inch dewatering well for a construction site at a depth of 3 ft, and two 4 inch wells on the ground surface. Approximate monopole shaped anomalies were observed from all these wells after data corrections. However, the range of amplitudes of magnetic anomalies from 7,000 to 28,000 nT from these abandoned brine wells was measured. This range of anomalies is mainly due to the thickness and depth of buried wells. Anomaly amplitudes from 1.5 to 3 inch wells are 4,000 to 8,000 nT and linearly correlate with the buried depth. One 3 inch well that caused an anomaly of 13,000 nT could be the inner pipe of a brine well. Gradient anomalies are roughly in a range of 100 to 200 nT/inch for 1.5 to 3 inch wells and 200 to 300 nT/inch for brine wells.As indicated by the potential field theory, gradient data possess higher horizontal resolution than the magnetic field itself. Gradient data provide valuable assistance in determining horizontal locations of anomaly sources for excavation. In practice, however, improvement in the horizontal resolution is limited by survey line spacing. If only one sensor is used in a survey, there is rapid decrease in the horizontal resolution when sensor height increases from 14 to 44 inches. This indicates that it is critical to keep the sensor as close to the ground as possible when hunting buried wells that are close to each other. It also suggests that the downward continuation is useful to increase the horizontal resolution in well hunting.