In recent years,switched inductor(SL)technology,switched capacitor(SC)technology,and switched inductor-capacitor(SL-SC)technology have been widely applied to optimize and improve DC-DC boost converters,which can effec...In recent years,switched inductor(SL)technology,switched capacitor(SC)technology,and switched inductor-capacitor(SL-SC)technology have been widely applied to optimize and improve DC-DC boost converters,which can effectively enhance voltage gain and reduce device stress.To address the issue of low output voltage in current renewable energy power generation systems,this study proposes a novel non-isolated cubic high-gain DC-DC converter based on the traditional quadratic DC-DC boost converter by incorporating a SC and a SL-SC unit.Firstly,the proposed converter’s details are elaborated,including its topology structure,operating mode,voltage gain,device stress,and power loss.Subsequently,a comparative analysis is conducted on the voltage gain and device stress between the proposed converter and other high-gain converters.Then,a closed-loop simulation system is constructed to obtain simulation waveforms of various devices and explore the dynamic performance.Finally,an experimental prototype is built,experimental waveforms are obtained,and the experimental dynamic performance and conversion efficiency are analyzed.The theoretical analysis’s correctness is verified through simulation and experimental results.The proposed converter has advantages such as high voltage gain,low device stress,high conversion efficiency,simple control,and wide input voltage range,achieving a good balance between voltage gain,device stress,and power loss.The proposed converter is well-suited for renewable energy systems and holds theoretical significance and practical value in renewable energy applications.It provides an effective solution to the issue of low output voltage in renewable energy power generation systems.展开更多
Serving as a promising alternative to liquid electrolyte in the application of portable and wearable devices,gel polymer electrolytes(GPEs)are expected to obtain more preferable properties rather than just be satisfie...Serving as a promising alternative to liquid electrolyte in the application of portable and wearable devices,gel polymer electrolytes(GPEs)are expected to obtain more preferable properties rather than just be satisfied with the merits of high safety and deformability.Here,an easy-operated method is employed to fabricate cross-linked composite polymer membranes used for GPEs assisted by UV irradiation,in which N-doped carbon quantum dots(N-CQDs)and TiO2are introduced as photocatalysts and additives to improve the performances of GPEs.Specifically,N-CQDs participate as a cross-linker to construct the inner porous structure,and TiO2nanoparticles serve as a stabilizer to improve the electrochemical stability of GPEs under high voltage(3.5 V).The excellent thermal and mechanical stability of the membrane fabricated in this work guarantee the safety of the supercapacitors(SCs).This GPE based SC not only exhibits prominent rate performance(105%capacitance retention at the current density of 40A g^(-1))and cyclic stability(85%at 1 A g^(-1)under 3.5 V after 20,000 cycles),but also displays remarkable energy density(42.88 Wh kg^(-1))with high power density(19.3 k W kg^(-1)).Moreover,the superior rate and cycling performances of the as-prepared GPE based flexible SCs under flat and bending state confirm the feasibility of its application in flexible energy storage devices.展开更多
The structural transformations,oxygen releasing and side reactions with electrolytes on the surface are considered as the main causes of the performance degradation of Li-rich layered oxides(LROs)cathodes in Li-ion ba...The structural transformations,oxygen releasing and side reactions with electrolytes on the surface are considered as the main causes of the performance degradation of Li-rich layered oxides(LROs)cathodes in Li-ion batteries.Thus,stabilizing the surfaces of LROs is the key to realize their practical application in high energy density Li-ion batteries.Surface coating is regarded as one of the most effective strategies for high voltage cathodes.The ideal coating materials should prevent cathodes from electrolyte corrosion and possess both electronic and Li-ionic conductivities simultaneously.However,commonly reported coating materials are unable to balance these functions well.Herein,a new type of coating material,La_(2)CuO_(4)was introduced to mitigate the surface issues of LROs for the first time,due to its superb electronic conductivity(26-35 mS·cm^(-1))and lithium-ionic diffusion coefficient(10^(-12)-10^(-13)cm^(2)·s^(-1)).After coating with the La_(2)CuO_(4),the capacity retention of Li_(1.2)Ni_(0.54)Co_(0.13)Mn_(0.13)O_(2)cathode was increased to 85.9%(compared to 79.3%of uncoated cathode)after 150 cycles in the voltage range of 2.0-4.8 V.In addition,only negligible degradations on the deliverable capacity and rate capability were observed.展开更多
High voltage fracturing technology was widely used in the field of reservoir reconstruction due to its advantages of being clean, pollution-free, and high-efficiency. However, high-frequency circuit oscillation occurs...High voltage fracturing technology was widely used in the field of reservoir reconstruction due to its advantages of being clean, pollution-free, and high-efficiency. However, high-frequency circuit oscillation occurs during the underwater high voltage pulse discharge process, which brings security risks to the stability of the pulse fracturing system. In order to solve this problem, an underwater pulse power discharge system was established, the circuit oscillation generation conditions were analyzed and the circuit oscillation suppression method was proposed. Firstly, the system structure was introduced and the charging model of the energy storage capacitor was established by the state space average method. Next, the electrode high-voltage breakdown model was established through COMSOL software, the electrode breakdown process was analyzed according to the electron density distribution image, and the plasma channel impedance was estimated based on the conductivity simulation results. Then the underwater pulse power discharge process and the circuit oscillation generation condition were analyzed, and the circuit oscillation suppression strategy of using the thyristor to replace the gas spark switch was proposed. Finally, laboratory experiments were carried out to verify the precision of the theoretical model and the suppression effect of circuit oscillation. The experimental results show that the voltage variation of the energy storage capacitor, the impedance change of the pulse power discharge process, and the equivalent circuit in each discharge stage were consistent with the theoretical model. The proposed oscillation suppression strategy cannot only prevent the damage caused by circuit oscillation but also reduce the damping oscillation time by77.1%, which can greatly improve the stability of the system. This research has potential application value in the field of underwater pulse power discharge for reservoir reconstruction.展开更多
Owing to the high specific capacity and high voltage,Ni-rich(LiNi0.8Co0.1Mn0.1O2,LNCM811)cathode has been considered as one of the most promising candidate cathode materials for next generation lithium ion batteries,w...Owing to the high specific capacity and high voltage,Ni-rich(LiNi0.8Co0.1Mn0.1O2,LNCM811)cathode has been considered as one of the most promising candidate cathode materials for next generation lithium ion batteries,whereas severe capacity fading greatly hinders its practical application.Notably,the compatibility of Ni-rich materials with LiBF4-containing electrolyte has not yet been realized.Herein,1 M LiPF6-based electrolyte with introducing 2 M LiBF4 is proposed to dramatically improve the cyclic stability of high voltage LNCM811/Li half-cell.Addition of high concentrated LiBF4 improves the moisture stability of electrolyte,which hinders the generation of harmful by-product HF,resulting in improved interfacial stability of LNCM811.Lithium plating/stripping reaction of Li/Li symmetric cell confirms that the enhanced cyclic stability is ascribed to the improved interfacial stability of LNCM811 instead of lithium electrode.Morphology and composition characterization results reveal that LiBF4 participates in the CEI film-forming reaction,resulting in suppressed oxidation of electrolyte and interfacial structural destruction of LNCM811.展开更多
Currently ether solvents have been regarded as the most compatible organic solvents with lithium metal in electrolytes of lithium batteries.However,ether solvents are unstable under high voltage (>4.0 V),and prone ...Currently ether solvents have been regarded as the most compatible organic solvents with lithium metal in electrolytes of lithium batteries.However,ether solvents are unstable under high voltage (>4.0 V),and prone to side reactions with nickel-rich high-voltage cathode materials.In this work,a novel dual-solvent electrolyte in ethylene glycol dimethyl ether (DME) and butyronitrile (BN) mixed solvent was designed and fabricated for Li/Li Ni_(0.5)Mn_(0.3)Co_(0.2)O_(2)-based lithium metal batteries.When charged to high voltage4.3 V,the battery cycled in this optimal electrolyte can maintain the capacity at 133.7 m Ah g^(-1) with a retention of 88.84%after 150 cycles at 0.2 C and-10℃.During long-term cycling,the battery also exhibits excellent cycling performance with capacity maintained at about 112.0 m Ah g^(-1) after 500 cycles at 1C and-10℃.BN has strong oxidation resistance and high conductivity,which can inhibit the decomposition of ether solvents under high voltage and improve the low temperature performance of battery effectively.Additionally,the cyano (–C≡N) group in BN molecular has a strong coordination ability with the high-valent metal ions and can mask the active ions on the cathode,correspondingly reducing the corrosion of cathode material by the electrolyte.Moreover,cyano group can participate in the hydrolysis to remove trace amounts of water and acidic by-products such as HF in the electrolyte.Therefore,the boosting effect of butyronitrile for ether solvents can provide a promising strategy for enhancing the performance of high voltage lithium metal batteries for practical industrialization.展开更多
The spinel LiNi_(0.5)Mn_(1.5)O_(4)(LNMO)has been attracted great attention as lithium ion cathode material due to its high voltage and large energy density.However,the practical application of LNMO is still limited by...The spinel LiNi_(0.5)Mn_(1.5)O_(4)(LNMO)has been attracted great attention as lithium ion cathode material due to its high voltage and large energy density.However,the practical application of LNMO is still limited by poor cycling stability.Herein,to improve the cycling stability of spinel LNMO,it was treated with anneal process at 900℃for 2 h after prepared by traditional solid-state method(LNMO-A).LNMO-A sample presented better electrochemical property especially under high rate,with capacity of 91.2 mAhg^(-1) after 1000 cycles under 10 C.Its superior electrochemical property was ascribed to the anneal process,resulting a stable crystal structure,indicated by XRD and Raman results of electrodes after 1000 cycles under 10 C and the longer solid-solution reaction,revealed by in-situ XRD.In addition,the optimized particle size,micro morphology and the larger BET area surface induced by the recrystallization in anneal process also contributes to its superior electrochemical property.What's more,the thin layer,which interacted LNMO-A particles with each other,induced by particles remelting in anneal process is also beneficial for its excellent electrochemical property.This study not only improved the electrochemical properties by anneal process,but also revealed the origins and mechanisms for its improvement.展开更多
Based on vibration signal of high voltage circuit breaker,a new method of intelligent fault diagnosis that wavelet packet extracts energy entropy which are used as characteristic vector of the support vector machine(S...Based on vibration signal of high voltage circuit breaker,a new method of intelligent fault diagnosis that wavelet packet extracts energy entropy which are used as characteristic vector of the support vector machine(SVM)to construct classifier for fault diagnosis is presented.The acceleration sensors are applied to collecting the vibration data of different states of high voltage circuit breakers based on self-made experimental platform in this method.The wavelet packet are fully applied to analyze the vibration signal and decompose vibration signal into three layers,and wavelet packet energy entropy of each frequency band are as the characteristic vector of circuit breaker failure mode.Then the intelligent diagnosis network is established on the basis of the support vector machine theory.It is verified that the method has a better capability of classification and a higher accuracy compared with the traditional neural network diagnosis method through distinguishing the three fault modes which are tripping device stuck,the vacuum arcing chamber fixed bolt looseness and too much friction force of the transmission mechanism of circuit breaker in this paper.展开更多
Research on high voltage(HV)silicon carbide(SiC)power semiconductor devices has attracted much attention in recent years.This paper overviews the development and status of HV SiC devices.Meanwhile,benefits of HV SiC d...Research on high voltage(HV)silicon carbide(SiC)power semiconductor devices has attracted much attention in recent years.This paper overviews the development and status of HV SiC devices.Meanwhile,benefits of HV SiC devices are presented.The technologies and challenges for HV SiC device application in converter design are discussed.The state-of-the-art applications of HV SiC devices are also reviewed.展开更多
In order to improve hydrophobic characteristics which will affect the service performance of fast-growing poplar due to growing bacteria in the humid environment.In this study,a simple method was proposed to treat pop...In order to improve hydrophobic characteristics which will affect the service performance of fast-growing poplar due to growing bacteria in the humid environment.In this study,a simple method was proposed to treat poplar via the high voltage electric field(HVEF)with copper as the electrode plate.Scanning electron microscope(SEM),Fourier transforms infrared spectroscopy(FTIR),X-ray diffraction(XRD)and contact angle tester were adopted to evaluate the surface morphology,surface group of poplar,crystallinity and wettability under HVEF.It was found by SEM that a large number of copper particles were uniformly attached to the surface of poplar.In all three sections,the weight percentage of the Cu element was accounting for more than half.The diffraction peaks of copper-containing compounds appeared in the(XRD).FTIR analysis confirmed that the reaction between copper and poplar took place.The surface contact angle of three sections of poplar increased in the following order:cross section<radial section<tangential section(increased by 34°,45°and 53°,respectively).An environmentfriendly and efficient method of HVEF treating fast-growing wood with copper as the electrode plate can promote its outdoor application.展开更多
In this study,the effects of three different particle sizes of wood wastes(A=–8+12 mesh;B=–12+20 mesh;C=–20+30 mesh)and factory shavings(D)on the properties of particleboard were investigated.According to the test ...In this study,the effects of three different particle sizes of wood wastes(A=–8+12 mesh;B=–12+20 mesh;C=–20+30 mesh)and factory shavings(D)on the properties of particleboard were investigated.According to the test results,three-layer particleboard was designed.Particleboard face layers made with mixture of A,B,and C.The core layer made with D.The ratio of core layer to face layers is 50:50.Three-layer particleboard were fabricated with 12%urea-formaldehyde(UF)resins and three different high voltage electrostatic field intensities(0 kv,30 kv,60 kv).The internal bond(IB)strength,modulus of rupture(MOR),modulus of elasticity(MOE),thickness swelling(TS),and water absorption(WA)of particleboard were evaluated.The density distribution of the three-layer particleboard were examined by vertical density profiles(VDP),and the bonding mechanism and functional groups changes in the particles were analyzed by FTIR analysis.The results showed that HVEF treatment intensity play a remarkable role in properties of particleboard.The particleboard with higher electrostatic field intensities treatment has higher MOE,MOR,IB,and TS.Under HVEF treatment(60 kv),the MOR,modulus of MOE,and IB of three-layer particleboard were 23.61 N/mm^(2),2787.09 N/mm^(2),and 0.86 N/mm^(2),respectively.FTIR indicated that the surface activity of wood particles was increased electric field treatment.展开更多
This article focuses on the aggression of lightning overload on the equipment of the electrical network of sites where storm activity is very dense;and the electrocution of people located in the direct environment of ...This article focuses on the aggression of lightning overload on the equipment of the electrical network of sites where storm activity is very dense;and the electrocution of people located in the direct environment of the high-voltage substation during the flow of lightning current to the ground through the ground socket. The modeling of the flow circuit of the shock wave consisting of guard wire, lightning arrester and ground socket couple to the transformer of the high voltage substations, thanks to the approach of a servo block, led to the synthesis of a PID regulator (corrector) whose action is to reject the effects of the overvoltage on the network equipment and to significantly reduce or even cancel the effects of the step or touch voltage due to the distribution of the potential around the ground socket;and thus improve the quality of service of the high-voltage transmission and distribution electricity network, especially in stormy times.展开更多
MXene-based aqueous symmetric supercapacitors(SSCs)are attractive due to their good rate performances and green nature.However,it remains a challenge to reach voltages much over 1.2 V,which significantly diminishes th...MXene-based aqueous symmetric supercapacitors(SSCs)are attractive due to their good rate performances and green nature.However,it remains a challenge to reach voltages much over 1.2 V,which significantly diminishes their energy density.Herein,we report on Mo_(1.33)CTz MXene-based SSCs possessing high voltages in a 19.5 M LiCl electrolyte.Benefiting from the vacancy-rich structure and high stable potential window of Mo_(1.33)CTz,the obtained SSCs deliver a maximum energy density of>38.2 mWh cm^(-3) at a power density of 196.6 mW cm^(-3) under an operating voltage of 1.4 V,along with excellent rate performance and impressive cycling stability.This highly concentrated LiCl electrolyte is also applicable to Ti_(3)C_(2)Tz,the most widely studied MXene,achieving a maximum energy density of>41.3 mWh cm^(-3) at a power density of 165.2 mW cm^(-3) with an operating voltage of 1.8 V.The drop in energy density with increasing power in the Ti_(3)C_(2)Tz cells was steeper than for the Mo-based cells.This work provides a roadmap to develop superior SSCs with high voltages and high energy densities.展开更多
The large current generated by starting directly of super large capacity and high voltage induction motor would have a huge impact on the grid as well as the motor itself.The variation of the power factor and electrom...The large current generated by starting directly of super large capacity and high voltage induction motor would have a huge impact on the grid as well as the motor itself.The variation of the power factor and electromagnetic torque during direct start of motors with different capacity and voltage levels are obtained.Aiming at the problem that the secondary impact of auto-transformer starter is too large and the cost of magnetic control starter is too high,the auto-transformer and magnetic control soft start method of super large capacity and high voltage motor is proposed and the basic working principle is analyzed.The calculation formula of cost for magnetic control soft starter and auto-transformer and magnetic control soft starter is deduced,and specific examples are analyzed and compared.It is concluded that the choice of auto-transformer with appropriate tapping ratio can greatly reduce the cost of auto-transformer and magnetic control soft starter compared with the other one.Finally,the simulation and experiment results show that the start method can effectively avoid secondary current impact and constrain the motor starting current to less than 2.5 times the rated current.展开更多
The electrolyte directly contacts the essential parts of a lithium-ion battery,and as a result,the electrochemical properties of the electrolyte have a significant impact on the voltage platform,charge discharge capac...The electrolyte directly contacts the essential parts of a lithium-ion battery,and as a result,the electrochemical properties of the electrolyte have a significant impact on the voltage platform,charge discharge capacity,energy density,service life,and rate discharge performance.By raising the voltage at the charge/discharge plateau,the energy density of the battery is increased.However,this causes transition metal dissolution,irreversible phase changes of the cathode active material,and parasitic electrolyte oxidation reactions.This article presents an overview of these concerns to provide a clear explanation of the issues involved in the development of electrolytes for high-voltage lithium-ion batteries.Additionally,solidstate electrolytes enable various applications and will likely have an impact on the development of batteries with high energy densities.It is necessary to improve the high-voltage performance of electrolytes by creating solvents with high thermal stabilities and high voltage resistance and additives with superior film forming performance,multifunctional capabilities,and stable lithium salts.To offer suggestions for the future development of high-energy lithium-ion batteries,we conclude by offering our own opinions and insights on the current development of lithium-ion batteries.展开更多
High-voltage circuit breakers are the core equipment in power networks,and to a certain extent,are related to the safe and reliable operation of power systems.However,their core components are prone to mechanical faul...High-voltage circuit breakers are the core equipment in power networks,and to a certain extent,are related to the safe and reliable operation of power systems.However,their core components are prone to mechanical faults.This study proposes a component separation method to detect multiple mechanical faults in circuit breakers that can achieve online real-time monitoring.First,a model and strategy are presented for obtaining mechanical voiceprint signals from circuit breakers.Subsequently,the component separation method was used to decompose the voiceprint signals of multiple faults into individual component signals.Based on this,the recognition of the features of a single-fault voiceprint signal can be achieved.Finally,multiple faults in high-voltage circuit breakers were identified through an experimental simulation and verification of the circuit breaker voiceprint signals collected from the substation site.The research results indicate that the proposed method exhibits excellent performance for multiple mechanical faults,such as spring structures and loose internal components of circuit breakers.In addition,it provides a reference method for the real-time online monitoring of high-voltage circuit breakers.展开更多
Aqueous rechargeable zinc batteries are very attractive for energy storage applications due to their low cost and high safety.However,low operating voltages limit their further development.For the first time,this work...Aqueous rechargeable zinc batteries are very attractive for energy storage applications due to their low cost and high safety.However,low operating voltages limit their further development.For the first time,this work proposes a unique approach to increase the voltages of aqueous zinc batteries by using tri-functional metallic bipolar electrode with good electrochemical activity and ultrahigh electronic conductivity,which not only participates in redox reactions,but also functions as an electrical highway for charge transport.Furthermore,bipolar electrode can replace expensive ion selective membrane to separate electrolytes with different pH;thus,redox couples with higher potential in acid condition and Zn=Zn(OH)^(2-)_(4) couple with lower potential in alkaline condition can be employed together,leading to high voltages of aqueous zinc batteries.Herein,two types of metallic bipolar electrodes of Cu and Ag are utilized based on three kinds of aqueous zinc batteries:Zn–MnO_(2),Zn–I_(2),and Zn–Br_(2).The voltage of aqueous Zn–MnO_(2) battery is raised to 1.84 V by employing one Cu bipolar electrode,which shows no capacity attenuation after 3500 cycles.Moreover,the other Ag bipolar electrode can be adopted to successfully construct Zn–I_(2) and Zn–Br_(2) batteries exhibiting much higher voltages of 2.44 and 2.67 V,which also show no obvious capacity degradation for 1000 and 800 cycles,representing decent cycle stability.Since bipolar electrode can be applied in a large family of aqueous batteries,this work offers an elaborate high-voltage concept based on tri-functional metallic bipolar electrode as a model system to open a door to explore high-voltage aqueous batteries.展开更多
基金This work was supported by China Railway Corporation Science and Technology Research and Development Project(P2021J038).
文摘In recent years,switched inductor(SL)technology,switched capacitor(SC)technology,and switched inductor-capacitor(SL-SC)technology have been widely applied to optimize and improve DC-DC boost converters,which can effectively enhance voltage gain and reduce device stress.To address the issue of low output voltage in current renewable energy power generation systems,this study proposes a novel non-isolated cubic high-gain DC-DC converter based on the traditional quadratic DC-DC boost converter by incorporating a SC and a SL-SC unit.Firstly,the proposed converter’s details are elaborated,including its topology structure,operating mode,voltage gain,device stress,and power loss.Subsequently,a comparative analysis is conducted on the voltage gain and device stress between the proposed converter and other high-gain converters.Then,a closed-loop simulation system is constructed to obtain simulation waveforms of various devices and explore the dynamic performance.Finally,an experimental prototype is built,experimental waveforms are obtained,and the experimental dynamic performance and conversion efficiency are analyzed.The theoretical analysis’s correctness is verified through simulation and experimental results.The proposed converter has advantages such as high voltage gain,low device stress,high conversion efficiency,simple control,and wide input voltage range,achieving a good balance between voltage gain,device stress,and power loss.The proposed converter is well-suited for renewable energy systems and holds theoretical significance and practical value in renewable energy applications.It provides an effective solution to the issue of low output voltage in renewable energy power generation systems.
基金funding supports from the Natural Science Basis Research Plan in Shaanxi Province of China(2019JLZ-10)the Independent Research Project of National Key Laboratory of Electrical Insulation and Power Equipment(EIPE19111)。
文摘Serving as a promising alternative to liquid electrolyte in the application of portable and wearable devices,gel polymer electrolytes(GPEs)are expected to obtain more preferable properties rather than just be satisfied with the merits of high safety and deformability.Here,an easy-operated method is employed to fabricate cross-linked composite polymer membranes used for GPEs assisted by UV irradiation,in which N-doped carbon quantum dots(N-CQDs)and TiO2are introduced as photocatalysts and additives to improve the performances of GPEs.Specifically,N-CQDs participate as a cross-linker to construct the inner porous structure,and TiO2nanoparticles serve as a stabilizer to improve the electrochemical stability of GPEs under high voltage(3.5 V).The excellent thermal and mechanical stability of the membrane fabricated in this work guarantee the safety of the supercapacitors(SCs).This GPE based SC not only exhibits prominent rate performance(105%capacitance retention at the current density of 40A g^(-1))and cyclic stability(85%at 1 A g^(-1)under 3.5 V after 20,000 cycles),but also displays remarkable energy density(42.88 Wh kg^(-1))with high power density(19.3 k W kg^(-1)).Moreover,the superior rate and cycling performances of the as-prepared GPE based flexible SCs under flat and bending state confirm the feasibility of its application in flexible energy storage devices.
基金Project supported by the National Key Research and Development Program of China(Grant No.2019YFE0100200)the National Natural Science Foundation of China(Grant No.U1964205)the Beijing Municipal Science and Technology Commission(Grant No.Z191100004719001)。
文摘The structural transformations,oxygen releasing and side reactions with electrolytes on the surface are considered as the main causes of the performance degradation of Li-rich layered oxides(LROs)cathodes in Li-ion batteries.Thus,stabilizing the surfaces of LROs is the key to realize their practical application in high energy density Li-ion batteries.Surface coating is regarded as one of the most effective strategies for high voltage cathodes.The ideal coating materials should prevent cathodes from electrolyte corrosion and possess both electronic and Li-ionic conductivities simultaneously.However,commonly reported coating materials are unable to balance these functions well.Herein,a new type of coating material,La_(2)CuO_(4)was introduced to mitigate the surface issues of LROs for the first time,due to its superb electronic conductivity(26-35 mS·cm^(-1))and lithium-ionic diffusion coefficient(10^(-12)-10^(-13)cm^(2)·s^(-1)).After coating with the La_(2)CuO_(4),the capacity retention of Li_(1.2)Ni_(0.54)Co_(0.13)Mn_(0.13)O_(2)cathode was increased to 85.9%(compared to 79.3%of uncoated cathode)after 150 cycles in the voltage range of 2.0-4.8 V.In addition,only negligible degradations on the deliverable capacity and rate capability were observed.
基金financially supported by the National Science and Technology Major Project(No.2016ZX05034004)。
文摘High voltage fracturing technology was widely used in the field of reservoir reconstruction due to its advantages of being clean, pollution-free, and high-efficiency. However, high-frequency circuit oscillation occurs during the underwater high voltage pulse discharge process, which brings security risks to the stability of the pulse fracturing system. In order to solve this problem, an underwater pulse power discharge system was established, the circuit oscillation generation conditions were analyzed and the circuit oscillation suppression method was proposed. Firstly, the system structure was introduced and the charging model of the energy storage capacitor was established by the state space average method. Next, the electrode high-voltage breakdown model was established through COMSOL software, the electrode breakdown process was analyzed according to the electron density distribution image, and the plasma channel impedance was estimated based on the conductivity simulation results. Then the underwater pulse power discharge process and the circuit oscillation generation condition were analyzed, and the circuit oscillation suppression strategy of using the thyristor to replace the gas spark switch was proposed. Finally, laboratory experiments were carried out to verify the precision of the theoretical model and the suppression effect of circuit oscillation. The experimental results show that the voltage variation of the energy storage capacitor, the impedance change of the pulse power discharge process, and the equivalent circuit in each discharge stage were consistent with the theoretical model. The proposed oscillation suppression strategy cannot only prevent the damage caused by circuit oscillation but also reduce the damping oscillation time by77.1%, which can greatly improve the stability of the system. This research has potential application value in the field of underwater pulse power discharge for reservoir reconstruction.
基金supported by the National Natural Science Foundation of China(21573080)the Guangdong Program for Support of Top-notch Young Professionals(2015TQ01N870)+1 种基金Distinguished Young Scholar(2017B030306013)the Science and Technology Planning Project of Guangdong Province(Grant no.2017B090901020)
文摘Owing to the high specific capacity and high voltage,Ni-rich(LiNi0.8Co0.1Mn0.1O2,LNCM811)cathode has been considered as one of the most promising candidate cathode materials for next generation lithium ion batteries,whereas severe capacity fading greatly hinders its practical application.Notably,the compatibility of Ni-rich materials with LiBF4-containing electrolyte has not yet been realized.Herein,1 M LiPF6-based electrolyte with introducing 2 M LiBF4 is proposed to dramatically improve the cyclic stability of high voltage LNCM811/Li half-cell.Addition of high concentrated LiBF4 improves the moisture stability of electrolyte,which hinders the generation of harmful by-product HF,resulting in improved interfacial stability of LNCM811.Lithium plating/stripping reaction of Li/Li symmetric cell confirms that the enhanced cyclic stability is ascribed to the improved interfacial stability of LNCM811 instead of lithium electrode.Morphology and composition characterization results reveal that LiBF4 participates in the CEI film-forming reaction,resulting in suppressed oxidation of electrolyte and interfacial structural destruction of LNCM811.
基金financially supported by the National Natural Science Foundation of China(Nos.21978073 and U1903217)Project funded by the China Postdoctoral Science Foundation(No.2019M662574)。
文摘Currently ether solvents have been regarded as the most compatible organic solvents with lithium metal in electrolytes of lithium batteries.However,ether solvents are unstable under high voltage (>4.0 V),and prone to side reactions with nickel-rich high-voltage cathode materials.In this work,a novel dual-solvent electrolyte in ethylene glycol dimethyl ether (DME) and butyronitrile (BN) mixed solvent was designed and fabricated for Li/Li Ni_(0.5)Mn_(0.3)Co_(0.2)O_(2)-based lithium metal batteries.When charged to high voltage4.3 V,the battery cycled in this optimal electrolyte can maintain the capacity at 133.7 m Ah g^(-1) with a retention of 88.84%after 150 cycles at 0.2 C and-10℃.During long-term cycling,the battery also exhibits excellent cycling performance with capacity maintained at about 112.0 m Ah g^(-1) after 500 cycles at 1C and-10℃.BN has strong oxidation resistance and high conductivity,which can inhibit the decomposition of ether solvents under high voltage and improve the low temperature performance of battery effectively.Additionally,the cyano (–C≡N) group in BN molecular has a strong coordination ability with the high-valent metal ions and can mask the active ions on the cathode,correspondingly reducing the corrosion of cathode material by the electrolyte.Moreover,cyano group can participate in the hydrolysis to remove trace amounts of water and acidic by-products such as HF in the electrolyte.Therefore,the boosting effect of butyronitrile for ether solvents can provide a promising strategy for enhancing the performance of high voltage lithium metal batteries for practical industrialization.
基金Natural Science Foundation of Shandong Province(ZR2018MEM017)。
文摘The spinel LiNi_(0.5)Mn_(1.5)O_(4)(LNMO)has been attracted great attention as lithium ion cathode material due to its high voltage and large energy density.However,the practical application of LNMO is still limited by poor cycling stability.Herein,to improve the cycling stability of spinel LNMO,it was treated with anneal process at 900℃for 2 h after prepared by traditional solid-state method(LNMO-A).LNMO-A sample presented better electrochemical property especially under high rate,with capacity of 91.2 mAhg^(-1) after 1000 cycles under 10 C.Its superior electrochemical property was ascribed to the anneal process,resulting a stable crystal structure,indicated by XRD and Raman results of electrodes after 1000 cycles under 10 C and the longer solid-solution reaction,revealed by in-situ XRD.In addition,the optimized particle size,micro morphology and the larger BET area surface induced by the recrystallization in anneal process also contributes to its superior electrochemical property.What's more,the thin layer,which interacted LNMO-A particles with each other,induced by particles remelting in anneal process is also beneficial for its excellent electrochemical property.This study not only improved the electrochemical properties by anneal process,but also revealed the origins and mechanisms for its improvement.
基金Project Supported by National Natural Science Foundation of China(51177104)Liaoning Province Natural Science Foundation of China(201102169)
文摘Based on vibration signal of high voltage circuit breaker,a new method of intelligent fault diagnosis that wavelet packet extracts energy entropy which are used as characteristic vector of the support vector machine(SVM)to construct classifier for fault diagnosis is presented.The acceleration sensors are applied to collecting the vibration data of different states of high voltage circuit breakers based on self-made experimental platform in this method.The wavelet packet are fully applied to analyze the vibration signal and decompose vibration signal into three layers,and wavelet packet energy entropy of each frequency band are as the characteristic vector of circuit breaker failure mode.Then the intelligent diagnosis network is established on the basis of the support vector machine theory.It is verified that the method has a better capability of classification and a higher accuracy compared with the traditional neural network diagnosis method through distinguishing the three fault modes which are tripping device stuck,the vacuum arcing chamber fixed bolt looseness and too much friction force of the transmission mechanism of circuit breaker in this paper.
基金This work made use of the Engineering Research Center Shared Facilities supported by the Engineering Research Center Program of the National Science Foundation and DOE under ARPA-E and Power America Program and the CURENT Industry Partnership Program.
文摘Research on high voltage(HV)silicon carbide(SiC)power semiconductor devices has attracted much attention in recent years.This paper overviews the development and status of HV SiC devices.Meanwhile,benefits of HV SiC devices are presented.The technologies and challenges for HV SiC device application in converter design are discussed.The state-of-the-art applications of HV SiC devices are also reviewed.
文摘In order to improve hydrophobic characteristics which will affect the service performance of fast-growing poplar due to growing bacteria in the humid environment.In this study,a simple method was proposed to treat poplar via the high voltage electric field(HVEF)with copper as the electrode plate.Scanning electron microscope(SEM),Fourier transforms infrared spectroscopy(FTIR),X-ray diffraction(XRD)and contact angle tester were adopted to evaluate the surface morphology,surface group of poplar,crystallinity and wettability under HVEF.It was found by SEM that a large number of copper particles were uniformly attached to the surface of poplar.In all three sections,the weight percentage of the Cu element was accounting for more than half.The diffraction peaks of copper-containing compounds appeared in the(XRD).FTIR analysis confirmed that the reaction between copper and poplar took place.The surface contact angle of three sections of poplar increased in the following order:cross section<radial section<tangential section(increased by 34°,45°and 53°,respectively).An environmentfriendly and efficient method of HVEF treating fast-growing wood with copper as the electrode plate can promote its outdoor application.
基金The Authors acknowledge funding support by the National Key R&D Program of China(2017YFC0703501)The authors wish to acknowledge the National Natural Science Foundation of China(Grant No.32071700).
文摘In this study,the effects of three different particle sizes of wood wastes(A=–8+12 mesh;B=–12+20 mesh;C=–20+30 mesh)and factory shavings(D)on the properties of particleboard were investigated.According to the test results,three-layer particleboard was designed.Particleboard face layers made with mixture of A,B,and C.The core layer made with D.The ratio of core layer to face layers is 50:50.Three-layer particleboard were fabricated with 12%urea-formaldehyde(UF)resins and three different high voltage electrostatic field intensities(0 kv,30 kv,60 kv).The internal bond(IB)strength,modulus of rupture(MOR),modulus of elasticity(MOE),thickness swelling(TS),and water absorption(WA)of particleboard were evaluated.The density distribution of the three-layer particleboard were examined by vertical density profiles(VDP),and the bonding mechanism and functional groups changes in the particles were analyzed by FTIR analysis.The results showed that HVEF treatment intensity play a remarkable role in properties of particleboard.The particleboard with higher electrostatic field intensities treatment has higher MOE,MOR,IB,and TS.Under HVEF treatment(60 kv),the MOR,modulus of MOE,and IB of three-layer particleboard were 23.61 N/mm^(2),2787.09 N/mm^(2),and 0.86 N/mm^(2),respectively.FTIR indicated that the surface activity of wood particles was increased electric field treatment.
文摘This article focuses on the aggression of lightning overload on the equipment of the electrical network of sites where storm activity is very dense;and the electrocution of people located in the direct environment of the high-voltage substation during the flow of lightning current to the ground through the ground socket. The modeling of the flow circuit of the shock wave consisting of guard wire, lightning arrester and ground socket couple to the transformer of the high voltage substations, thanks to the approach of a servo block, led to the synthesis of a PID regulator (corrector) whose action is to reject the effects of the overvoltage on the network equipment and to significantly reduce or even cancel the effects of the step or touch voltage due to the distribution of the potential around the ground socket;and thus improve the quality of service of the high-voltage transmission and distribution electricity network, especially in stormy times.
基金supported by the Swedish Foundation for Strategic Research(SSF)EM16-0004.
文摘MXene-based aqueous symmetric supercapacitors(SSCs)are attractive due to their good rate performances and green nature.However,it remains a challenge to reach voltages much over 1.2 V,which significantly diminishes their energy density.Herein,we report on Mo_(1.33)CTz MXene-based SSCs possessing high voltages in a 19.5 M LiCl electrolyte.Benefiting from the vacancy-rich structure and high stable potential window of Mo_(1.33)CTz,the obtained SSCs deliver a maximum energy density of>38.2 mWh cm^(-3) at a power density of 196.6 mW cm^(-3) under an operating voltage of 1.4 V,along with excellent rate performance and impressive cycling stability.This highly concentrated LiCl electrolyte is also applicable to Ti_(3)C_(2)Tz,the most widely studied MXene,achieving a maximum energy density of>41.3 mWh cm^(-3) at a power density of 165.2 mW cm^(-3) with an operating voltage of 1.8 V.The drop in energy density with increasing power in the Ti_(3)C_(2)Tz cells was steeper than for the Mo-based cells.This work provides a roadmap to develop superior SSCs with high voltages and high energy densities.
基金This work was supported in part by the National Key Research and Development Program of China under Grant 2017YFB0902904,in part by the Natural Science Foundation of Hubei Province under Grant 2016CFB448,and in part by the Shenzhen City Science and Technology Innovation Plan under Grant JCYJ20170306170937861,and in part by Wuhan City Science and Technology Program under Grant 2016070204020165.
文摘The large current generated by starting directly of super large capacity and high voltage induction motor would have a huge impact on the grid as well as the motor itself.The variation of the power factor and electromagnetic torque during direct start of motors with different capacity and voltage levels are obtained.Aiming at the problem that the secondary impact of auto-transformer starter is too large and the cost of magnetic control starter is too high,the auto-transformer and magnetic control soft start method of super large capacity and high voltage motor is proposed and the basic working principle is analyzed.The calculation formula of cost for magnetic control soft starter and auto-transformer and magnetic control soft starter is deduced,and specific examples are analyzed and compared.It is concluded that the choice of auto-transformer with appropriate tapping ratio can greatly reduce the cost of auto-transformer and magnetic control soft starter compared with the other one.Finally,the simulation and experiment results show that the start method can effectively avoid secondary current impact and constrain the motor starting current to less than 2.5 times the rated current.
基金supported by the Shandong Provincial Natural Science Foundation,China(No.ZR2019MEM014)。
文摘The electrolyte directly contacts the essential parts of a lithium-ion battery,and as a result,the electrochemical properties of the electrolyte have a significant impact on the voltage platform,charge discharge capacity,energy density,service life,and rate discharge performance.By raising the voltage at the charge/discharge plateau,the energy density of the battery is increased.However,this causes transition metal dissolution,irreversible phase changes of the cathode active material,and parasitic electrolyte oxidation reactions.This article presents an overview of these concerns to provide a clear explanation of the issues involved in the development of electrolytes for high-voltage lithium-ion batteries.Additionally,solidstate electrolytes enable various applications and will likely have an impact on the development of batteries with high energy densities.It is necessary to improve the high-voltage performance of electrolytes by creating solvents with high thermal stabilities and high voltage resistance and additives with superior film forming performance,multifunctional capabilities,and stable lithium salts.To offer suggestions for the future development of high-energy lithium-ion batteries,we conclude by offering our own opinions and insights on the current development of lithium-ion batteries.
基金supported by the State Key Laboratory of Technology and Equipment for Defense against Power System Operational Risks(No.SGNR0000KJJS2302137)the National Natural Science Foundation of China(Grant No.62203248)the Natural Science Foundation of Shandong Province(Grant No.ZR2020ME194).
文摘High-voltage circuit breakers are the core equipment in power networks,and to a certain extent,are related to the safe and reliable operation of power systems.However,their core components are prone to mechanical faults.This study proposes a component separation method to detect multiple mechanical faults in circuit breakers that can achieve online real-time monitoring.First,a model and strategy are presented for obtaining mechanical voiceprint signals from circuit breakers.Subsequently,the component separation method was used to decompose the voiceprint signals of multiple faults into individual component signals.Based on this,the recognition of the features of a single-fault voiceprint signal can be achieved.Finally,multiple faults in high-voltage circuit breakers were identified through an experimental simulation and verification of the circuit breaker voiceprint signals collected from the substation site.The research results indicate that the proposed method exhibits excellent performance for multiple mechanical faults,such as spring structures and loose internal components of circuit breakers.In addition,it provides a reference method for the real-time online monitoring of high-voltage circuit breakers.
基金The authors would like to acknowledge the financial support sponsored by Ten-thousand Talents Program,K.C.Wong Pioneer Talent Program,Shanghai Pujiang Program (Grant No.19PJ1410600)the National Natural Science Foundation of China (Grant No.51901240).
文摘Aqueous rechargeable zinc batteries are very attractive for energy storage applications due to their low cost and high safety.However,low operating voltages limit their further development.For the first time,this work proposes a unique approach to increase the voltages of aqueous zinc batteries by using tri-functional metallic bipolar electrode with good electrochemical activity and ultrahigh electronic conductivity,which not only participates in redox reactions,but also functions as an electrical highway for charge transport.Furthermore,bipolar electrode can replace expensive ion selective membrane to separate electrolytes with different pH;thus,redox couples with higher potential in acid condition and Zn=Zn(OH)^(2-)_(4) couple with lower potential in alkaline condition can be employed together,leading to high voltages of aqueous zinc batteries.Herein,two types of metallic bipolar electrodes of Cu and Ag are utilized based on three kinds of aqueous zinc batteries:Zn–MnO_(2),Zn–I_(2),and Zn–Br_(2).The voltage of aqueous Zn–MnO_(2) battery is raised to 1.84 V by employing one Cu bipolar electrode,which shows no capacity attenuation after 3500 cycles.Moreover,the other Ag bipolar electrode can be adopted to successfully construct Zn–I_(2) and Zn–Br_(2) batteries exhibiting much higher voltages of 2.44 and 2.67 V,which also show no obvious capacity degradation for 1000 and 800 cycles,representing decent cycle stability.Since bipolar electrode can be applied in a large family of aqueous batteries,this work offers an elaborate high-voltage concept based on tri-functional metallic bipolar electrode as a model system to open a door to explore high-voltage aqueous batteries.