Genetic mechanism and main controlling factors of high-quality clastic rock reservoirs in deep and ultradeep layers:A case study of Oligocene Linhe Formation in Linhe Depression,Hetao Basin,NW China

Based on new data from cores,drilling and logging,combined with extensive rock and mineral testing analysis,a systematic analysis is conducted on the characteristics,diagenesis types,genesis and controlling factors of deep to ultra-deep abnormally high porosity clastic rock reservoirs in the Oligocene Linhe Formation in the Hetao Basin.The reservoir space of the deep to ultra-deep clastic rock reservoirs in the Linhe Formation is mainly primary pores,and the coupling of three favorable diagenetic elements,namely the rock fabric with strong compaction resistance,weak thermal compaction diagenetic dynamic field,and diagenetic environment with weak fluid compaction-weak cementation,is conducive to the preservation of primary pores.The Linhe Formation clastic rocks have a superior preexisting material composition,with an average total content of 90%for quartz,feldspar,and rigid rock fragments,and strong resistance to compaction.The geothermal gradient in Linhe Depression in the range of(2.0–2.6)°C/100 m is low,and together with the burial history of long-term shallow burial and late rapid deep burial,it forms a weak thermal compaction diagenetic dynamic field environment.The diagenetic environment of the saline lake basin is characterized by weak fluid compaction.At the same time,the paleosalinity has zoning characteristics,and weak cementation in low salinity areas is conducive to the preservation of primary pores.The hydrodynamic conditions of sedimentation,salinity differentiation of ancient water in saline lake basins,and sand body thickness jointly control the distribution of high-quality reservoirs in the Linhe Formation.

High Tech和High Touch概念下酒店品牌营销策略分析——以丽思卡尔顿酒店品牌营销为例

近年来,人工智能与共享经济的不断发展,对传统服务型酒店品牌营销造成了一定冲击。同时,High Tech(高新科技)与High Touch(高关怀度服务)概念的产生,给顾客选择酒店品牌带来一定影响。本文以丽思卡尔顿酒店品牌营销为例,分析酒店业市场中存在的产品定价与促销策略不合理、销售渠道扁平、品牌营销缺乏创造力等问题,提出从顾客的消费需求出发,结合我国酒店品牌的市场特色,创新营销方式,提升营销策略,进而帮助酒店品牌营销的全方面优化,实现可持续发展。

论英国建筑技术美学谱系中传统与新统的博弈—以High-Tech建筑技术美学为例

传统与新统的博弈贯穿英国建筑技术美学谱系二百余年的发展历程。本文以High-Tech建筑技术美学为例,以其角色转换为切入点,对英国建筑技术美学谱系发展过程中普遍存在的演进规律加以研究,得出传统与新统的博弈既构成英国建筑技术美学谱系发展的基本语言又是其演进主要动力的结论,并为中国的建筑技术美学研究提供相关借鉴和思考。

Genesis of the high gamma sandstone of the Yanchang Formation in the Ordos Basin,China

Recently, more attention has been paid on the high gamma sandstone reservoirs of the Yanchang Formation in the Ordos Basin, China. These high gamma sandstones have logging characteristics different from conventional sandstones, which influences the identification of sandstone reservoirs. Zhang et al （2010） proposed that the high gamma sandstones of the Yanchang Formation might be the result of re-deposition of homochronous sedimentary tufts or previous tufts as a part of the sandstone. However, we present a different viewpoint： 1） few tufts or tuff debris have been found in the high gamma sandstones of the Yanchang Formation; 2） high gamma （or high Th content） sandstones of Yanchang Formation are not related to either clay minerals or feldspar; 3） the heavy minerals in the sandstone reservoirs of the Yanchang Formation are dominated by zircon, which is characterized by abnormally high Th and U contents, up to 2,163 ppm and 1,362 ppm, respectively. This is sufficient to explain the high gamma anomaly. The conclusion is that the high gamma value of the Yanchang Formation sandstones might be caused by zircon with high Th and U contents in sandstones rather than from the tuff components.

Pressure Prediction for High-Temperature and High-Pressure Formation and Its Application to Drilling in the Northern South China Sea

There are plentiful potential hydrocarbon resources in the Yinggehai and Qiongdongnan basins in the northern South China Sea. However, the special petrol-geological condition with high formation temperature and pressure greatly blocked hydrocarbon exploration. The conventional means of drills, including methods in the prediction and monitoring of underground strata pressure, can no longer meet the requirements in this area. The China National Offshore Oil Corporation has allocated one well with a designed depth of 3200 m and pressure coefficient of 2.3 in the Yinggehai Basin (called test well in the paper) in order to find gas reservoirs in middle-deep section in the Miocene Huangliu and Meishan formations at the depth below 3000 m. Therefore, combined with the '863' national high-tech project, the authors analyzed the distribution of overpressure in the Yinggehai and Qiongdongnan basins, and set up a series of key technologies and methods to predict and monitor formation pressure, and then apply the results to pressure prediction of the test well. Because of the exact pressure prediction before and during drilling, associated procedure design of casing and their allocation in test well has been ensured to be more rational. This well is successfully drilled to the depth of 3485 m (nearly 300 m deeper than the designed depth) under the formation pressure about 2.3 SG (EMW), which indicate that a new step in the technology of drilling in higher temperature and pressure has been reached in the China National Offshore Oil Corporation.

Geochemical characteristics and genetic mechanism of the high-N2 shale gas reservoir in the Longmaxi Formation, Dianqianbei Area, China

As an important pilot target for shale gas exploration and development in China,the Longmaxi Formation shale in the Dianqianbei Area is characterized by high content of nitrogen,which severely increases exploration risk.Accordingly,this study explores the genesis of shale gas reservoir and the mechanism of nitrogen enrichment through investigating shale gas compositions,isotope features,and geochemical characteristics of associated gases.The high-nitrogen shale gas reservoir in the Longmaxi Formation is demonstrated to be a typical dry gas reservoir.Specifically,the alkane carbon isotope reversal is ascribed to the secondary cracking of crude oil and the Rayleigh fractionation induced by the basalt mantle plume.Such a thermogenic oil-type gas reservoir is composed of both oil-cracking gas and kerogen-cracking gas.The normally high nitrogen content(18.05%-40.92%) is attributed to organic matter cracking and thermal ammoniation in the high-maturity stage.Specifically,the high heat flow effect of the Emeishan mantle plume exacerbates the thermal cracking of organic matter in the Longmaxi Formation shale,accompanied by nitrogen generation.In comparison,the abnormally high nitrogen content(86.79%-98.54%) is ascribed to the communication between the atmosphere and deep underground fluids by deep faults,which results in hydrocarbon loss and nitrogen intrusion,acting as the key factor for deconstruction of the primary shale gas reservoir.Results of this study not only enrich research on genetic mechanism of high-maturity N_@ shale gas reservoirs,but also provide theoretical guidance for subsequent gas reservoir resource evaluation and well-drilling deployment in this area.

Subduction Initiation for the Formation of High-Cr Chromitites in the Kop Ophiolite, NE Turkey

The Kop ophiolite in NE Turkey,representing a forearc fragment of Neo-Tethys ocean,mainly consists of a paleoMoho transition zone(MTZ)and a harzburgitic upper mantle unit.The Kop MTZ locally contains cumulate

Kinetics and formation mechanisms of intragranular ferrite in V?N microalloyed 600 MPa high strength rebar steel

To systematically investigate the kinetics and formation mechanisms of intragranular ferrite（IGF）, isothermal heat treatment in the temperature range of 450℃to 600℃ with holding for 30 s to 300 s, analysis of the corresponding microstructures, and observation of the precipitated particles were conducted in V-N microalloyed 600 MPa high strength rebar steel. The potency of V（C,N） for IGF nucleation was also analyzed statistically. The results show that the dominant microstructure transforms from bainite（B） and acicular ferrite（AF） to grain boundary ferrite（GBF）, intragranular polygonal ferrite（IPF）, and pearlite（P） as the isothermal temperature increases from 450℃ to 600℃. When the holding time at 600℃ is extended from 30 s to 60 s, 120 s, and 300 s, the GBF content ranges from 6.0vol% to 6.5vol% and the IPF content increases from 0.5vol% to 2.8vol%, 13.1vol%, and 13.5vol%, respectively, because the ferrite transformation preferentially occurs at the grain boundaries and then occurs at the austenite grains. Notably, V（C,N） particles are the most effective nucleation site for the formation of IPF, accounting for 51% of the said formation.

Geological characteristics and high production control factors of shale gas reservoirs in Silurian Longmaxi Formation, southern Sichuan Basin, SW China

Marine shale gas resources have great potential in the south of the Sichuan Basin in China.At present,the high-quality shale gas resources at depth of 2000–3500 m are under effective development,and strategic breakthroughs have been made in deeper shale gas resources at depth of 3500–4500 m.To promote the effective production of shale gas in this area,this study examines key factors controlling high shale gas production and presents the next exploration direction in the southern Sichuan Basin based on summarizing the geological understandings from the Lower Silurian Longmaxi Formation shale gas exploration combined with the latest results of geological evaluation.The results show that:(1)The relative sea depth in marine shelf sedimentary environment controls the development and distribution of reservoirs.In the relatively deep water area in deep-water shelf,grade-I reservoirs with a larger continuous thickness develop.The relative depth of sea in marine shelf sedimentary environment can be determined by redox conditions.The research shows that the uranium to thorium mass ratio greater than 1.25 indicates relatively deep water in anoxic reduction environment,and the uranium to thorium mass ratio of 0.75–1.25 indicates semi-deep water in weak reduction and weak oxidation environment,and the uranium to thorium mass ratio less than 0.75 indicates relatively shallow water in strong oxidation environment.(2)The propped fractures in shale reservoirs subject to fracturing treatment are generally 10–12 m high,if grade-I reservoirs are more than 10 m in continuous thickness,then all the propped section would be high-quality reserves;in this case,the longer the continuous thickness of penetrated grade-I reservoirs,the higher the production will be.(3)The shale gas reservoirs at 3500–4500 m depth in southern Sichuan are characterized by high formation pressure,high pressure coefficient,well preserved pores,good pore structure and high proportion of free gas,making them the most favorable new field for shale gas exploration;and the pressure coefficient greater than 1.2 is a necessary condition for shale gas wells to obtain high production.(4)High production wells in the deep shale gas reservoirs are those in areas where Long11-Long13 sub-beds are more than 10 m thick,with 1500 m long horizontal section,grade-I reservoirs penetration rate of over 90%,and fractured by dense cutting+high intensity sand injection+large displacement+large liquid volume.(5)The relatively deep-water area in the deep-water shelf and the area at depth of 3500–4500 m well overlap in the southern Sichuan,and the overlapping area is the most favorable shale gas exploration and development zones in the southern Sichuan in the future.With advancement in theory and technology,annual shale gas production in the southern Sichuan is expected to reach 450×108 m3.

美国High Tech High教育模式在卫生职业教育中的应用研究

将美国High Tech High系统的教育模式引入到我国卫生职业化教育中。通过调查对美国High Tech High系统的教育模式和我国卫生职业教育情况进行了详细解析和对比,运用SWOT方法解析了相应教育模式在卫生职业教育中的应用。提出新形势下基于项目制的卫生职业教育模式,其具有较强适应性,必将推动卫生职业教育的发展。

A LOCATIONAL COMPARATIVE STUDY ON HIGH-TECH INDUSTRIAL ZONES IN CHINA

ＡＬＯＣＡＴＩＯＮＡＬＣＯＭＰＡＲＡＴＩＶＥＳＴＵＤＹＯＮＨＩＧＨ－ＴＥＣＨＩＮＤＵＳＴＲＩＡＬＺＯＮＥＳＩＮＣＨＩＮＡＷｅｉＸｉｎｚｈｅｎ魏心镇；ＳｈｉＹｏｎｇｈｕｉ史永辉（ＤｅｐａｒｔｍｅｎｔｏｆＧｅｏｇｒａｐｈｙ．ＰｅｋｉｎｇＵｎｉｖｅｒｓｉｔ...

Spatial Evolution and Locational Determinants of High-tech Industries in Beijing

Using datasets on high-tech industries in Beijing as empirical studies, this paper attempts to interpret spatial shift of high-tech manufacturing firms and to examine the main determinants that have had the greatest effect on this spatial evolution. We aimed at merging these two aspects by using firm level databases in 1996 and 2010. To explain spatial change of the high-tech firms in Beijing, the Kernel density estimation method was used for hotspot analysis and detection by comparing their locations in 1996 and 2010, through which spatial features and their temporal changes could be approximately plotted. Furthermore, to provide quantitative results, Ripley′s K-function was used as an instrument to reveal spatial shift and the dispersion distance of high-tech manufacturing firms in Beijing. By employing a negative binominal regression model, we evaluated the main determinants that have significantly affected the spatial evolution of high-tech manufacturing firms and compared differential influence of these locational factors on overall high-tech firms and each sub-sectors. The empirical analysis shows that high-tech industries in Beijing, in general, have evident agglomeration characteristics, and that the hotspot has shifted from the central city to suburban areas. In combination with the Ripley index, this study concludes that high-tech firms are now more scattered in metropolitan areas of Beijing as compared with 1996. The results of regression model indicate that the firms′ locational decisions are significantly influenced by the spatial planning and regulation policies of the municipal government. In addition, market processes involving transportation accessibility and agglomeration economy have been found to be important in explaining the dynamics of locational variation of high-tech manufacturing firms in Beijing. Research into how markets and the government interact to determine the location of high-tech manufacturing production will be helpful for policymakers to enact effective policies toward a more efficient urban spatial structure.

Heterogeneity and influencing factors of marine gravity flow tight sandstone under abnormally high pressure:A case study from the Miocene Huangliu Formation reservoirs in LD10 area,Yinggehai Basin,South China Sea

The characteristics of reservoir heterogeneity of the marine gravity flow tight sandstone from the Miocene Huangliu Formation under abnormally high pressure setting at LD10 area in Yinggehai Basin are studied,and the influencing factors on reservoir heterogeneity are discussed,based on modular formation dynamics test,thin sections,XRD analysis of clay minerals,scanning electron microscopy,measurement of pore throat image,porosity and permeability,and high pressure Hg injection,as well as the stimulation of burial thermal history.The aim is to elucidate characteristics of the heterogeneity and the evolution process of heterogeneity of the reservoir,and predict the favorable reservoirs distribution.(1)The heterogeneity of the reservoir is mainly controlled by the cement heterogeneity,pore throat heterogeneity,quality of the reservoir heterogeneity,and the diagenesis under an abnormally high pressure setting.(2)The differences in pore-throat structure caused by diagenetic evolution affected the intergranular material heterogeneity and the pore throat heterogeneity,and finally controlled the heterogeneity of reservoir quality.(3)Compared with the reservoir under normal pressure,abnormally high pressure restrains strength of the compaction and cementation and enhances the dissolution of the reservoir to some extent,and abnormally high pressure thus weakening the heterogeneity of the reservoir to a certain degree.The favorable reservoirs are mainly distributed in the gravity flow sand body under the strong overpressure zone in the middle and lower part of Huangliu Formation.

High temperature X-ray diffraction study of the formation of Na_(2)Ti_(3)O_(7) from a mixture of sodium carbonate and titanium oxide

Na2Ti3O7 has attracted much attention in the field of anode materials for Na-ion batteries thanks to its non-toxicity and very low working potential of 0.3 V vs Na0/Na+.Building a clearer picture of its formation from cheap Na_(2)CO_(3) and TiO_(2) starting materials is therefore of obvious interest.Here,we report new insights from an in-situ high temperature X-ray diffraction study conducted from room temperature to 800°C,complemented by ex-situ characterizations.We were thereby able to position the previously reported Na_(4)Ti_(5)O_(12) and Na_(2)Ti_(6)O_(13) intermediate phases in a reaction scheme involving three successive steps and temperature ranges.Shifts and/or broadening of a subset of the Na_(2)Ti_(6)O_(13) reflections suggested a combination of intra-layer disorder with the well-established ordering of successive layers.This in-situ study was carried out on reproducible mixtures of Na_(2)CO_(3) and TiO_(2) in 1:3 molar ratio prepared by spraydrying of mixed aqueous suspensions.Single-phase Na_(2)Ti_(3)O_(7) was obtained after only 8 h at 800°C in air,instead of a minimum of 20 h for a conventional solid-state route using the same precursors.Microstructure analysis revealed~15 mm diameter granules made up from rectangular rods of a fewmm length presenting electrochemical properties in line with expectations.In the absence of grinding or formation of intimate composites with conductive carbon,the specific capacity of 137 m Ah/g at C/5 decreased at higher rates.

Formation Mechanism and Microstructure of High-Strength Gypsum

The microstructure, phase composition, and thermal characteristics of various natural gypsums and the high-strength gypsum──the converted product of natural one are analysed.The formation mecbanism of high-strength gypsum is further discussed. It is found that the high-streugth gypsum is of hollow irregular hexagonal prism structure, which is almost free from tbe (010) and (100) cleavages and can form clustered fibrous crystals with high-strength.

HIGH NUCLEOPHILICITY OF FORMATE TOWARD POLYHALOFLUOROALKENES

High nucleophilicity of formate toward polyhalofluoroalkenes under acidic condition is described. This reaction offers a convenient method for the synthesis of E-α,β-unsaturated polyhalofluorocarboxylic acids.

A Study on Theoretical Model and Applied Evaluation of Land Use Performance of High-tech Zone in Urban Fringe: A Case Study in Haidian District, Beijing

High-tech industrial zone is an important carrier for constructing innovative cities. It also plays an important role in implementing the national independent innovative strategy. How-ever, most of the high-tech industrial zones have many problems in their development process, such as efficiency of land use, weakness of oriented function and lack of land intensive. To solve these problems, the authors of this paper introduced the concept of land use performance and established the theoretical model to assess the land use performance of high-tech industrial zones. The model consists of the following three-dimensional parts: land use benefit, land use efficiency and innovative function. Based on this theory model, an index system which was composed of three secondary indictors, eight tertiary indictors and 37 fourth-grade indictors was set up to evaluate the land use performance of high-tech zone. To avoid the defects of plus model and function model, the authors brought out a three-dimensional evaluation model to examine the index of the land use performance of the high-tech industrial parks, which equals to the evaluation indicator system of land use performance of high-tech zone based on the above research. The authors examined the land use performance of five different high-tech industrial parks in Haidian District, Beijing City. The results indicated that the indicator system per-forms better in the aspect of evaluating land use benefit, land use efficiency and function of the high-tech industrial zone compared with other models.

Porosity, permeability and rock mechanics of Lower Silurian Longmaxi Formation deep shale under temperature-pressure coupling in the Sichuan Basin, SW China

To investigate the porosity, permeability and rock mechanics of deep shale under temperature-pressure coupling, we selected the core samples of deep shale from the Lower Silurian Longmaxi Formation in the Weirong and Yongchuan areas of the Sichuan Basin for porosity and permeability experiments and a triaxial compression and sound wave integration experiment at the maximum temperature and pressure of 120 ℃ and 70 MPa. The results show that the microscopic porosity and permeability change and the macroscopic rock deformation are mutually constrained, both showing the trend of steep and then gentle variation. At the maximum temperature and pressure, the porosity reduces by 34%–71%, and the permeability decreases by 85%–97%. With the rising temperature and pressure, deep shale undergoes plastic deformation in which organic pores and clay mineral pores are compressed and microfractures are closed, and elastic deformation in which brittle mineral pores and rock skeleton particles are compacted. Compared with previous experiments under high confining pressure and normal temperature,the experiment under high temperature and high pressure coupling reveals the effect of high temperature on stress sensitivity of porosity and permeability. High temperature can increase the plasticity of the rock, intensify the compression of pores due to high confining pressure, and induce thermal stress between the rock skeleton particles, allowing the reopening of shale bedding or the creation of new fractures along weak planes such as bedding, which inhibits the decrease of permeability with the increase of temperature and confining pressure. Compared with the triaxial mechanical experiment at normal temperature, the triaxial compression experiment at high temperature and high pressure demonstrates that the compressive strength and peak strain of deep shale increase significantly due to the coupling of temperature and pressure. The compressive strength is up to 435 MPa and the peak strain exceeds 2%, indicating that high temperature is not conducive to fracture initiation and expansion by increasing rock plasticity. Lithofacies and mineral composition have great impacts on the porosity, permeability and rock mechanics of deep shale. Shales with different lithologies are different in the difficulty and extent of brittle failure. The stress-strain characteristics of rocks under actual geological conditions are key support to the optimization of reservoir stimulation program.

Genesis of the high gamma sandstone of the Yanchang Formation in the Ordos Basin,China:A reply

The authors of ＇Genesis of the high gamma sandstone of the Yanchang Formation in the Ordos Basin, China＇ questioned the viewpoint that high-gamma-ray sandstone might be caused by homochronous sedimentary volcano tuff ash or previous tuff. The authors argued that the main reason for the high-gamma-ray sandstone should be from high Th and U contents in zircon. In reply, we discuss the problems with the authors from the category of high-gamma-ray sandstones, rock characteristics, and possible sources of radioactivity. The results still indicate that the high gamma ray characteristics might be caused by homochronous sedimentary volcano tuff ash or reworked previous turfs.

Hydrothermal Formation of Lath-Shaped Trioctahedral Smectite with High Crystallinity

Lath-shaped and highly crystalline trioctahedral smectites were synthesized under hydrothermal conditions. The quenched glasses with stoichiometrically dehydrated Na-smectite compositions were treated at （a） 500℃ and 100 MPa for 1 and 11 days; and （b） 300℃ and 100 MPa for 7 days. The crystallinity and particle size of products were dependent on the chemical composition of the starting glass, synthetic temperature and duration of hydrothermal treatment. The high structural ordering and large dimensions of the products were confirmed from the sharpness of XRD peaks; and hydration behavior under controlled relative humidity. Transmission electron microscopy was also performed for the characterization of the particle size of product. Particle sizes vary from ca. 10 nm to a few pm by changing the chemical compositions of the starting materials. The product with the highest structural ordering and largest dimension was obtained from Nao.33（Mg1.83Al0.67）Si4O11 glass treated at 500℃ and 100 MPa for 1 day. The obtained results also confirmed the metastability and compositional dependency in the formation of highly crystalline trioctahedral smectite at hydrothermal conditions.