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Synergistic effect of Zr and Mo on precipitation and high-temperature properties of Al-Si-Cu-Mg alloys
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作者 Chao Gao Bing-rong Zhang +2 位作者 Yin-ming Li Zhi-ming Wang Xiang-bin Meng 《China Foundry》 SCIE EI CAS CSCD 2024年第1期71-81,共11页
This study focuses on finding a solution to the sharp decline in mechanical properties of Al-Si-Cu-Mg alloys due to rapid coarsening of traditional intermediate phases at high temperature.A new type of modified al oy,... This study focuses on finding a solution to the sharp decline in mechanical properties of Al-Si-Cu-Mg alloys due to rapid coarsening of traditional intermediate phases at high temperature.A new type of modified al oy,to be used in automobile engines at high temperatures,was prepared by adding Zr and Mo into Al-Si-Cu-Mg alloy.The synergistic effects of Zr and Mo on the microstructure evolution and high-temperature mechanical properties were studied.Results show that the addition of Zr and Mo generates a series of intermetallic phases dispersed in the alloy.They can improve the strength of the alloy by hindering dislocation movement and crack propagation.In addition,some nano-strengthened phases show coherent interfaces with the matrix and improve grain refinement.The addition of Mo greatly improves the heat resistance of the alloy.The extremely low diffusivity of Mo enables it to improve the thermal stability of the intermetallic phases,inhibit precipitation during aging,reduce the size of the precipitates,and improve the heat resistance of the alloy. 展开更多
关键词 Al-Si-Cu-Mg alloy high-temperature properties Zr-Mo-rich intermetallics nano-strengthening phases
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High-temperature properties and microstructure of Mo microalloyed ultra-high-strength steel 被引量:3
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作者 Qi-hang Han Yong-lin Kang +2 位作者 Xian-meng Zhao Lu-feng Gao Xue-song Qiu 《International Journal of Minerals,Metallurgy and Materials》 SCIE EI CAS CSCD 2011年第4期407-412,共6页
The high-temperature mechanical properties and microstructure of forging billets of C-Si-Mn-Cr and C-Si-Mn-Cr-Mo ultra-high-strength cold-rolled steels(tensile strength≥1000 MPa,elongation≥10%) were studied.Throug... The high-temperature mechanical properties and microstructure of forging billets of C-Si-Mn-Cr and C-Si-Mn-Cr-Mo ultra-high-strength cold-rolled steels(tensile strength≥1000 MPa,elongation≥10%) were studied.Through the comparison of reduction in area and hot deformation resistance at 600-1300°C,the Mo-containing steel was found to possess a higher strength and a better plasticity than the Mo-free one.The equilibrium phase diagram and atom fraction of Mo in different phases at different temperatures were calculated by Thermo-Calc software(TCW).The results analyzed by using transmission electron microscopy and TCW show that precipitates in the Mo-containing steel are primarily M23C6,which promote pearlite formation.The experimental data also show that a lower ductility point existing in the Mo-free steel at 850°C is eliminated in the Mo-containing one.This is mainly due to the segregation of Mo at grain boundaries investigated by electron probe microanalysis(EPMA),which improves the strength of grain boundaries. 展开更多
关键词 high strength steels high temperature properties MICROSTRUCTURE MOLYBDENUM THERMODYNAMICS
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Proposing a machine learning approach to analyze and predict basic high-temperature properties of iron ore fines and its factors
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作者 Qing-ke Sun Yao-zu Wang +4 位作者 Jian-liang Zhang Zheng-jian Liu Le-le Niu Chang-dong Shan Yun-fei Ma 《Journal of Iron and Steel Research International》 SCIE EI CAS CSCD 2024年第5期1082-1094,共13页
The basic high-temperature properties of iron ore play a crucial role in optimizing sintering and ore blending,but the testing process for these properties is complex and has significant lag time,which cannot meet the... The basic high-temperature properties of iron ore play a crucial role in optimizing sintering and ore blending,but the testing process for these properties is complex and has significant lag time,which cannot meet the actual needs of ore blending.A prediction model for the basic high-temperature properties of iron ore fines was thus proposed based on a combination of machine learning algorithms and genetic algorithms.First,the prediction accuracy of different machine learning models for the basic high-temperature properties of iron ore fines was compared.Then,a random forest model optimized by genetic algorithms was built,further improving the prediction accuracy of the model.The test results show that the random forest model optimized by genetic algorithms has the highest prediction accuracy for the lowest assimilation temperature and liquid phase fluidity of iron ore,with a determination coefficient of 0.903 for the lowest assimilation temperature and 0.927 for the liquid phase fluidity after optimization.The trained model meets the fluctuation requirements of on-site testing and has been successfully applied to actual production on site. 展开更多
关键词 Iron ore Basic high-temperature property Machine learning Random forest Genetic algorithm
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A novel high-Cr CoNi-based superalloy with superior high-temperature microstructural stability, oxidation resistance and mechanical properties
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作者 Xiaorui Zhang Min Zou +3 位作者 Song Lu Longfei Li Xiaoli Zhuang Qiang Feng 《International Journal of Minerals,Metallurgy and Materials》 SCIE EI CAS CSCD 2024年第6期1373-1381,共9页
A novel multicomponent high-Cr CoNi-based superalloy with superior comprehensive performance was prepared,and the evaluation of its high-temperature microstructural stability,oxidation resistance,and mechanical proper... A novel multicomponent high-Cr CoNi-based superalloy with superior comprehensive performance was prepared,and the evaluation of its high-temperature microstructural stability,oxidation resistance,and mechanical properties was conducted mainly using its cast polycrystalline alloy.The results disclosed that the morphology of theγ′phase remained stable,and the coarsening rate was slow during the long-term aging at 900–1000℃.The activation energy forγ′precipitate coarsening of alloy 9CoNi-Cr was(402±51)kJ/mol,which is higher compared with those of CMSX-4 and some other Ni-based and Co-based superalloys.Importantly,there was no indica-tion of the formation of topologically close-packed phases during this process.All these factors demonstrated the superior microstructural stability of the alloy.The mass gain of alloy 9CoNi-Cr was 0.6 mg/cm^(2) after oxidation at 1000℃ for 100 h,and the oxidation resistance was comparable to advanced Ni-based superalloys CMSX-4,which can be attributed to the formation of a continuous Al_(2)O_(3) protective layer.Moreover,the compressive yield strength of this cast polycrystalline alloy at high temperatures is clearly higher than that of the conventional Ni-based cast superalloy and the compressive minimum creep rate at 950℃ is comparable to that of the conventional Ni-based cast superalloy,demonstrating the alloy’s good mechanical properties at high temperature.This is partially because high Cr is bene-ficial in improving theγandγ′phase strengths of alloy 9CoNi-Cr. 展开更多
关键词 CoNi-based superalloys microstructure COARSENING OXIDATION mechanical properties
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Improving mechanical properties and high-temperature oxidation of press hardened steel by adding Cr and Si
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作者 Rong Zhu Yonggang Yang +4 位作者 Baozhong Zhang Borui Zhang Lei Li Yanxin Wu Zhenli Mi 《International Journal of Minerals,Metallurgy and Materials》 SCIE EI CAS CSCD 2024年第8期1865-1875,共11页
This work investigated the effect of Cr and Si on the mechanical properties and oxidation resistance of press hardened steel.Results indicated that the microstructure of the Cr-Si micro-alloyed press hardened steel co... This work investigated the effect of Cr and Si on the mechanical properties and oxidation resistance of press hardened steel.Results indicated that the microstructure of the Cr-Si micro-alloyed press hardened steel consisted of lath martensite,M_(23)C_(6)carbides,and retained austenite.The retained austenite and carbides are responsible for the increase in elongation of the micro-alloyed steel.In addition,after oxidation at 930℃for 5 min,the thickness of the oxide scales on the Cr-Si micro-alloyed press hardened steel is less than 5μm,much thinner than 45.50μm-thick oxide scales on 22MnB5.The oxide scales of the Cr-Si micro-alloyed steel are composed of Fe_(2)O_(3),Fe_(3)O_(4),mixed spinel oxide(FeCr_(2)O_(4)and Fe_(2)SiO_(4)),and amorphous SiO_(2).Adding Cr and Si significantly reduces the thickness of the oxide scales and prevents the generation of the FeO phase.Due to the increase of spinel FeCr_(2)O_(4)and Fe_(2)SiO_(4)phase in the inner oxide scale and the amorphous SiO_(2)close to the substrate,the oxidation resistance of the Cr-Si micro-alloyed press hardened steel is improved. 展开更多
关键词 Cr-Si micro-alloyed press hardened steel mechanical properties oxidation resistance amorphous SiO_(2)
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The Research for Surface Properties of Steel Slag Powder and High-Temperature Rheological Properties of Asphalt Mortar
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作者 WANG Yefei YUAN Yan +2 位作者 YANG Lihong LIU Yong CHEN Yiwen 《Journal of Wuhan University of Technology(Materials Science)》 SCIE EI CAS CSCD 2023年第5期1096-1104,共9页
In order to evaluate the feasibility of steel slag powder as filler,the coating properties of steel slag and limestone aggregate were compared by water boiling test,the micro morphology difierences between steel slag ... In order to evaluate the feasibility of steel slag powder as filler,the coating properties of steel slag and limestone aggregate were compared by water boiling test,the micro morphology difierences between steel slag powder and mineral powder(limestone powder)were compared by scanning electron microscope(SEM),and the high-temperature rheological properties of asphalt mortar with difierent ratio of filler quality to asphalt quality(F/A)and difierent substitution rates of mineral powder(S/F)were studied by dynamic shear rheological test.The results show that the surface microstructure of steel slag powder is more abundant than that of mineral powder,and the adhesion of steel slag to asphalt is better than that of limestone.At the same temperature,the lower the ratio of S/F is,the greater the rutting factor and complex modulus will be.In addition,the complex modulus and rutting factor of the asphalt mortar increase with the increase of F/A,and the filler type and F/A have a negligible efiect on the phase angle. 展开更多
关键词 steel slag powder asphalt mortar microcosmic ADHESION high-temperature rheological properties
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Wire arc additive manufacturing of a heat-resistant Al-Cu-Ag-Sc alloy:microstructures and high-temperature mechanical properties
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作者 董博伦 蔡笑宇 +4 位作者 夏云浩 刘放 赵宏伟 林三宝 戴鸿滨 《China Welding》 CAS 2023年第4期1-10,共10页
With a high energy efficiency,low geometric limitation,and low cracking susceptivity to cracks,wire arc additive manufacturing(WAAM)has become an ideal substitute for casting in the manufacturing of load-bearing high ... With a high energy efficiency,low geometric limitation,and low cracking susceptivity to cracks,wire arc additive manufacturing(WAAM)has become an ideal substitute for casting in the manufacturing of load-bearing high strength aluminum components in aerospace industry.Recently,in scientific researches,the room temperature mechanical performance of additive manufactured high strength aluminum alloys has been continuously broken through,and proves these alloys can achieve comparable or even higher properties than the forged counterpart.Since the aluminum components for aerospace usage experience high-low temperature cycling due to the absence of atmosphere protection,the high temperature performances of additive manufactured high strength aluminum alloys are also important.However,few research focuses on that.A special 2319Ag Sc with 0.4 wt.%Ag and 0.2 wt.%Sc addition designed for high temperature application is deposited successfully via cold metal transfer(CMT)based on WAAM.The microstructures and high temperature tensile properties are investigated.The results show that the as-deposited 2319Ag Sc alloy presents an alternate distribution of columnar grains and equiaxed grains with no significant textures.Main second phases are Al_(2)Cu and Al3Sc,while co-growth of Al_(2)Cu and bulk Al_(3)Sc is found on the grain boundary.During manufacturing,nanoscale Al_(2)Cu can precipitate out from the matrix.Ag and Mg form nano-scaleΩphase on the Al_(2)Cu precipitates.At 260℃,average yield strengths in the horizontal direction and vertical direction are 87 MPa±2 MPa,87 MPa±4 MPa,while average ultimate tensile strengths are 140 MPa±7 MPa,141 MPa±11 MPa,and average elongations are 11.0%±2.5%,13.5%±3.0%.Anisotropy in different directions is weak. 展开更多
关键词 Wire arc additive manufacturing Al-Cu-Ag-Sc heat resistance microstructure high temperature property
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High-temperature mechanical properties of aluminium alloys reinforced with titanium diboride (TiB_2) particles 被引量:6
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作者 J.Ooro 《Rare Metals》 SCIE EI CAS CSCD 2011年第2期200-205,共6页
The physical and mechanical properties of metal matrix composites were improved by the addition of reinforcements. The mechanical properties of particulate-reinforced metal-matrix composites based on aluminium alloys ... The physical and mechanical properties of metal matrix composites were improved by the addition of reinforcements. The mechanical properties of particulate-reinforced metal-matrix composites based on aluminium alloys (6061 and 7015) at high temperatures were studied. Titanium diboride (TiB2) particles were used as the reinforcement. All the composites were produced by hot extrusion. The tensile properties and fracture characteristics of these materials were investigated at room temperature and at high temperatures to determine their ultimate strength and strain to failure. The fracture surface was analysed by scanning electron microscopy. TiB2 particles provide high stability of the alumin- ium alloys (6061 and 7015) in the fabrication process. An improvement in the mechanical behaviour was achieved by adding TiB2 particles as reinforcement in both the aluminium alloys. Adding TiB2 particles reduces the ductility of the aluminium alloys but does not change the microscopic mode of failure, and the fracture surface exhibits a ductile appearance with dimples formed by coalescence. 展开更多
关键词 metal-matrix composites aluminium high-temperature properties titanium diboride
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Effect of extrusion process on microstructure and mechanical properties of Ni_3Al-B-Cr alloy during self-propagation high-temperature synthesis 被引量:3
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作者 盛立远 奚廷斐 +2 位作者 赖琛 郭建亭 郑玉峰 《Transactions of Nonferrous Metals Society of China》 SCIE EI CAS CSCD 2012年第3期489-495,共7页
The well-densified Ni3Al-0.5B-5Cr alloy was fabricated by self-propagation high-temperature synthesis and extrusion technique. Microstructure examination shows that the synthesized alloy has fine microstructure and co... The well-densified Ni3Al-0.5B-5Cr alloy was fabricated by self-propagation high-temperature synthesis and extrusion technique. Microstructure examination shows that the synthesized alloy has fine microstructure and contains Ni3Al, Al2O3, Ni3B and Cr3Ni2 phases. Moreover, the self-propagation high-temperature synthesis and extrusion lead to great deformation and recrystallization in the alloy, which helps to refine the microstructure and weaken the misorientation. In addition, the subsequent extrusion procedure redistributes the Al2O3 particles and eliminates the γ-Ni phase. Compared with the alloy synthesized without extrusion, the Ni3Al-0.5B-5Cr alloy fabricated by self-propagation high-temperature synthesis and extrusion has better room temperature mechanical properties, which should be ascribed to the microstructure evolution. 展开更多
关键词 Ni3Al intermetallic compound self-propagation high-temperature synthesis EXTRUSION MICROSTRUCTURE mechanical properties
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Effects of Sn element on microstructure and properties of Zn-Cu-Bi-Sn high-temperature solder 被引量:2
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作者 邢飞 邱小明 李阳东 《Transactions of Nonferrous Metals Society of China》 SCIE EI CAS CSCD 2015年第3期879-884,共6页
The microstructures and properties of the Zn-Cu-Bi-Sn(ZCBS) high-temperature solders with various Sn contents were studied using differential scanning calorimetry(DSC),scanning electron microscopy(SEM) and X-ray diffr... The microstructures and properties of the Zn-Cu-Bi-Sn(ZCBS) high-temperature solders with various Sn contents were studied using differential scanning calorimetry(DSC),scanning electron microscopy(SEM) and X-ray diffraction(XRD).The results indicate that the increase of Sn content can both decrease the melting temperature and melting range of ZCBS solders and it can also effectively improve the wettability on Cu substrate.The shear strength of solder joints reaches a maximum value with the Sn addition of 5%(mass fraction),which is attributed to the formation of refined β-Sn and primary ε-CuZn_5 phases in η-Zn matrix.However,when the content of Sn exceeds 5%,the shear strength decreases due to the formation of coarse β-Sn phase,which is net-shaped presented at the grain boundary. 展开更多
关键词 SOLDER Zn-based solder SN high-temperature solder thermal property WETTABILITY
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Harness High-Temperature Thermal Energy via Elastic Thermoelectric Aerogels 被引量:1
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作者 Hongxiong Li Zhaofu Ding +5 位作者 Quan Zhou Jun Chen Zhuoxin Liu Chunyu Du Lirong Liang Guangming Chen 《Nano-Micro Letters》 SCIE EI CAS CSCD 2024年第8期196-210,共15页
Despite notable progress in thermoelectric(TE)materials and devices,developing TE aerogels with high-temperature resistance,superior TE performance and excellent elasticity to enable self-powered high-temperature moni... Despite notable progress in thermoelectric(TE)materials and devices,developing TE aerogels with high-temperature resistance,superior TE performance and excellent elasticity to enable self-powered high-temperature monitoring/warning in industrial and wearable applications remains a great challenge.Herein,a highly elastic,flame-retardant and high-temperature-resistant TE aerogel,made of poly(3,4-ethylene dioxythiophene):poly(styrenesulfonate)/single-walled carbon nanotube(PEDOT:PSS/SWCNT)composites,has been fabricated,displaying attractive compression-induced power factor enhancement.The as-fabricated sensors with the aerogel can achieve accurately pressure stimuli detection and wide temperature range monitoring.Subsequently,a flexible TE generator is assembled,consisting of 25 aerogels connected in series,capable of delivering a maximum output power of 400μW when subjected to a temperature difference of 300 K.This demonstrates its outstanding high-temperature heat harvesting capability and promising application prospects for real-time temperature monitoring on industrial high-temperature pipelines.Moreover,the designed self-powered wearable sensing glove can realize precise wide-range temperature detection,high-temperature warning and accurate recognition of human hand gestures.The aerogel-based intelligent wearable sensing system developed for firefighters demonstrates the desired self-powered and highly sensitive high-temperature fire warning capability.Benefitting from these desirable properties,the elastic and high-temperature-resistant aerogels present various promising applications including self-powered high-temperature monitoring,industrial overheat warning,waste heat energy recycling and even wearable healthcare. 展开更多
关键词 THERMOELECTRICS AEROGEL SELF-POWERED high-temperature monitoring high-temperature warning
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Enhanced High-Temperature Energy Storage Performance of All-Organic Composite Dielectric via Constructing Fiber-Re in forced Structure 被引量:1
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作者 Mengjia Feng Yu Feng +5 位作者 Changhai Zhang Tiandong Zhang Xu Tong Qiang Gao Qingguo Chen Qingguo Chi 《Energy & Environmental Materials》 SCIE EI CAS CSCD 2024年第2期299-307,共9页
Optimizing the high-temperature energy storage characteristics of energy storage dielectrics is of great significance for the development of pulsed power devices and power control systems.Selecting a polymer with a hi... Optimizing the high-temperature energy storage characteristics of energy storage dielectrics is of great significance for the development of pulsed power devices and power control systems.Selecting a polymer with a higher glass transition temperature(T_(g))as the matrix is one of the effective ways to increase the upper limit of the polymer operating temperature.However,current high-T_(g)polymers have limitations,and it is difficult to meet the demand for high-temperature energy storage dielectrics with only one polymer.For example,polyetherimide has high-energy storage efficiency,but low breakdown strength at high temperatures.Polyimide has high corona resistance,but low high-temperature energy storage efficiency.In this work,combining the advantages of two polymer,a novel high-T_(g)polymer fiber-reinforced microstructure is designed.Polyimide is designed as extremely fine fibers distributed in the composite dielectric,which will facilitate the reduction of high-temperature conductivity loss for polyimide.At the same time,due to the high-temperature resistance and corona resistance of polyimide,the high-temperature breakdown strength of the composite dielectric is enhanced.After the polyimide content with the best high-temperature energy storage characteristics is determined,molecular semiconductors(ITIC)are blended into the polyimide fibers to further improve the high-temperature efficiency.Ultimately,excellent high-temperature energy storage properties are obtained.The 0.25 vol%ITIC-polyimide/polyetherimide composite exhibits high-energy density and high discharge efficiency at 150℃(2.9 J cm^(-3),90%)and 180℃(2.16 J cm^(-3),90%).This work provides a scalable design idea for high-performance all-organic high-temperature energy storage dielectrics. 展开更多
关键词 all-organic energy storage density high-temperature high-temperature breakdown strength
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Effect of Ti-Al content on microstructure and mechanical properties of C_f/Al and TiAl joint by laser ignited self-propagating high-temperature synthesis 被引量:5
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作者 冯广杰 李卓然 +1 位作者 冯士诚 申忠科 《Transactions of Nonferrous Metals Society of China》 SCIE EI CAS CSCD 2015年第5期1468-1477,共10页
Cf/Al composites and TiAl alloys were joined by laser ignited self-propagating high-temperature synthesis(SHS) with Ni-Al-Ti interlayer. The effect of Ti-Al content on interfacial microstructure and mechanical prope... Cf/Al composites and TiAl alloys were joined by laser ignited self-propagating high-temperature synthesis(SHS) with Ni-Al-Ti interlayer. The effect of Ti-Al content on interfacial microstructure and mechanical properties of the joints was investigated. Localized melt of the substrates occurred in the joints. γ-Ni0.35Al0.30Ti0.35, NiA l3 and Ni2Al3 reaction layers formed adjacent to the substrates. Joint flaws, such as pores and cracks, made the joint density decrease and worked as the fracture source, which led to the sharp decline of joint strength. Additive Ti-Al increased joint density and strengthened the interlayer adhesion to Cf/Al. The joint flaws could be controlled by changing the Ti-Al content. When the Ti-Al content was 0.1, the joint was free of cracks with high density and reached the maximum shear strength of 24.12 MPa. 展开更多
关键词 Cf/Al composite TiAl alloys JOINT self-propagating high-temperature synthesis INTERLAYER Ti-Al content
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Research on thermal insulation materials properties under HTHP conditions for deep oil and gas reservoir rock ITP-Coring 被引量:1
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作者 Zhi-Qiang He He-Ping Xie +4 位作者 Ling Chen Jian-Ping Yang Bo Yu Zi-Jie Wei Ming-Zhong Gao 《Petroleum Science》 SCIE EI CAS CSCD 2024年第4期2625-2637,共13页
Deep oil and gas reservoirs are under high-temperature conditions,but traditional coring methods do not consider temperature-preserved measures and ignore the influence of temperature on rock porosity and permeability... Deep oil and gas reservoirs are under high-temperature conditions,but traditional coring methods do not consider temperature-preserved measures and ignore the influence of temperature on rock porosity and permeability,resulting in distorted resource assessments.The development of in situ temperaturepreserved coring(ITP-Coring)technology for deep reservoir rock is urgent,and thermal insulation materials are key.Therefore,hollow glass microsphere/epoxy resin thermal insulation materials(HGM/EP materials)were proposed as thermal insulation materials.The materials properties under coupled hightemperature and high-pressure(HTHP)conditions were tested.The results indicated that high pressures led to HGM destruction and that the materials water absorption significantly increased;additionally,increasing temperature accelerated the process.High temperatures directly caused the thermal conductivity of the materials to increase;additionally,the thermal conduction and convection of water caused by high pressures led to an exponential increase in the thermal conductivity.High temperatures weakened the matrix,and high pressures destroyed the HGM,which resulted in a decrease in the tensile mechanical properties of the materials.The materials entered the high elastic state at 150℃,and the mechanical properties were weakened more obviously,while the pressure led to a significant effect when the water absorption was above 10%.Meanwhile,the tensile strength/strain were 13.62 MPa/1.3%and 6.09 MPa/0.86%at 100℃ and 100 MPa,respectively,which meet the application requirements of the self-designed coring device.Finally,K46-f40 and K46-f50 HGM/EP materials were proven to be suitable for ITP-Coring under coupled conditions below 100℃ and 100 MPa.To further improve the materials properties,the interface layer and EP matrix should be optimized.The results can provide references for the optimization and engineering application of materials and thus technical support for deep oil and gas resource development. 展开更多
关键词 Deep oil and gas reservoir rock In situ temperature-preserved coring(ITPCoring) Hollow glass microsphere/epoxy resin thermal insulation materials(HGM/EP materials) high-temperature and high-pressure(HTHP) Physical and mechanical properties
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High-throughput calculations combining machine learning to investigate the corrosion properties of binary Mg alloys 被引量:3
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作者 Yaowei Wang Tian Xie +4 位作者 Qingli Tang Mingxu Wang Tao Ying Hong Zhu Xiaoqin Zeng 《Journal of Magnesium and Alloys》 SCIE EI CAS CSCD 2024年第4期1406-1418,共13页
Magnesium(Mg)alloys have shown great prospects as both structural and biomedical materials,while poor corrosion resistance limits their further application.In this work,to avoid the time-consuming and laborious experi... Magnesium(Mg)alloys have shown great prospects as both structural and biomedical materials,while poor corrosion resistance limits their further application.In this work,to avoid the time-consuming and laborious experiment trial,a high-throughput computational strategy based on first-principles calculations is designed for screening corrosion-resistant binary Mg alloy with intermetallics,from both the thermodynamic and kinetic perspectives.The stable binary Mg intermetallics with low equilibrium potential difference with respect to the Mg matrix are firstly identified.Then,the hydrogen adsorption energies on the surfaces of these Mg intermetallics are calculated,and the corrosion exchange current density is further calculated by a hydrogen evolution reaction(HER)kinetic model.Several intermetallics,e.g.Y_(3)Mg,Y_(2)Mg and La_(5)Mg,are identified to be promising intermetallics which might effectively hinder the cathodic HER.Furthermore,machine learning(ML)models are developed to predict Mg intermetallics with proper hydrogen adsorption energy employing work function(W_(f))and weighted first ionization energy(WFIE).The generalization of the ML models is tested on five new binary Mg intermetallics with the average root mean square error(RMSE)of 0.11 eV.This study not only predicts some promising binary Mg intermetallics which may suppress the galvanic corrosion,but also provides a high-throughput screening strategy and ML models for the design of corrosion-resistant alloy,which can be extended to ternary Mg alloys or other alloy systems. 展开更多
关键词 Mg intermetallics Corrosion property HIGH-THROUGHPUT Density functional theory Machine learning
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Microstructures,corrosion behavior and mechanical properties of as-cast Mg-6Zn-2X(Fe/Cu/Ni)alloys for plugging tool applications 被引量:1
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作者 Baosheng Liu Jiali Wei +4 位作者 Shaohua Zhang Yuezhong Zhang Pengpeng Wu Daqing Fang Guorui Ma 《International Journal of Minerals,Metallurgy and Materials》 SCIE EI CAS CSCD 2024年第4期697-711,共15页
Mg-6Zn-2X(Fe/Cu/Ni)alloys were prepared through semi-continuous casting,with the aim of identifying a degradable magnesium(Mg)alloy suitable for use in fracturing balls.A comparative analysis was conducted to assess t... Mg-6Zn-2X(Fe/Cu/Ni)alloys were prepared through semi-continuous casting,with the aim of identifying a degradable magnesium(Mg)alloy suitable for use in fracturing balls.A comparative analysis was conducted to assess the impacts of adding Cu and Ni,which result in finer grains and the formation of galvanic corrosion sites.Scanner electronic microscopy examination revealed that precipitated phases concentrated at grain boundaries,forming a semi-continuous network structure that facilitated corrosion penetration in Mg-6Zn-2Cu and Mg-6Zn-2Ni alloys.Pitting corrosion was observed in Mg-6Zn-2Fe,while galvanic corrosion was identified as the primary mechanism in Mg-6Zn-2Cu and Mg-6Zn-2Ni alloys.Among the tests,the Mg-6Zn-2Ni alloy exhibited the highest corrosion rate(approximately 932.9 mm/a)due to its significant potential difference.Mechanical testing showed that Mg-6Zn-2Ni alloy possessed suitable ultimate compressive strength,making it a potential candidate material for degradable fracturing balls,effectively addressing the challenges of balancing strength and degradation rate in fracturing applications. 展开更多
关键词 magnesium alloys microstructure micro-galvanic corrosion mechanical properties
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Effects of deformation temperatures on microstructures,aging behaviors and mechanical properties of Mg-Gd-Er-Zr alloys fabricated by hard-plate rolling 被引量:1
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作者 Ke Liu Dalong Hu +4 位作者 Feng Lou Zijian Yu Shubo Li Xian Du Wenbo Du 《Journal of Magnesium and Alloys》 SCIE EI CAS CSCD 2024年第6期2345-2359,共15页
In this investigation,a high-strength Mg-12Gd-1.0Er-0.5Zr(wt.%)alloy sheet was produced by hot extrusion(HE)and subsequent hard-plate rolling(HPR)at different temperatures.The results indicate that the microstructures... In this investigation,a high-strength Mg-12Gd-1.0Er-0.5Zr(wt.%)alloy sheet was produced by hot extrusion(HE)and subsequent hard-plate rolling(HPR)at different temperatures.The results indicate that the microstructures of these final-rolled sheets are inhomogeneous,mainly including coarse deformed grains and dynamic recrystallized(DRXed)grains,and the volume fraction of these coarse deformed grains increases as the rolling temperature increases.Thus,more DRXed grains can be found in R-385℃sheet,resulting in a smaller average grain size and weaker basal texture,while the biggest grains and the highest strong basal texture are present in R-450℃sheet.Amounts of dynamic precipitation ofβphases which are mainly determined by the rolling temperature are present in these sheets,and its precipitation can consume the content of Gd solutes in the matrix.As a result,the lowest number density ofβphase in R-450℃sheet is beneficial to modify the age hardening response.Thus,the R-450℃sheet displays the best age hardening response because of a severe traditional precipitation ofβ’(more)andβH/βM(less)precipitates,resulting in a sharp improvement in strength,i.e.ultimate tensile strength(UTS)of∼518±17 MPa and yield strength(YS)of∼438±18 MPa.However,the elongation(EL)of this sheet reduces greatly,and its value is∼2.7±0.3%.By contrasting,the EL of the peak-aging R-385℃sheet keeps better,changing from∼4.9±1.2%to∼4.8±1.4%due to a novel dislocation-induced chain-like precipitate which is helpful to keep good balance between strength and ductility. 展开更多
关键词 Mg-Gd-Er-Zr sheets Age hardening response PRECIPITATES Mechanical properties
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Pulsed current-assisted twelve-roll precision rolling deformation of SUS304 ultra-thin strips with exceptional mechanical properties 被引量:1
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作者 Wanwan Fan Tao Wang +3 位作者 Jinxiong Hou Zhongkai Ren Qingxue Huang Guanghui Wu 《International Journal of Extreme Manufacturing》 SCIE EI CAS CSCD 2024年第4期291-305,共15页
Innovative pulsed current-assisted multi-pass rolling tests were conducted on a 12-roll mill during the rolling deformation processing of SUS304 ultra-thin strips.The results show that in the first rolling pass,the ro... Innovative pulsed current-assisted multi-pass rolling tests were conducted on a 12-roll mill during the rolling deformation processing of SUS304 ultra-thin strips.The results show that in the first rolling pass,the rolling reduction rate of a conventionally rolled sample(at room temperature)is 33.8%,which can be increased to 41.5%by pulsed current-assisted rolling,enabling the formation of an ultra-thin strip with a size of 67.3μm in only one rolling pass.After three passes of pulsed current-assisted rolling,the thickness of the ultra-thin strip can be further reduced to 51.7μm.To clearly compare the effects of a pulsed current on the microstructure and mechanical response of the ultra-thin strip,ultra-thin strips with nearly the same thickness reduction were analyzed.It was found that pulsed current can reduce the degree of work-hardening of the rolled samples by promoting dislocation detachment,reducing the density of stacking faults,inhibiting martensitic phase transformation,and shortening the total length of grain boundaries.As a result,the ductility of ultra-thin strips can be effectively restored to approximately 16.3%while maintaining a high tensile strength of 1118 MPa.Therefore,pulsed current-assisted rolling deformation shows great potential for the formation of ultra-thin strips with a combination of high strength and ductility. 展开更多
关键词 pulsedcurrent-assisted SUS304 ultra-thinstrip rolling reductionrate WORK-HARDENING mechanical properties
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Hydrothermal treatment of pearl millet grains:Effects on nutritional composition,antinutrients and flour properties 被引量:1
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作者 P.Prashanth T.Jayasree Joshi +1 位作者 Shagolshem Mukta Singh P.Srinivasa Rao 《Grain & Oil Science and Technology》 CAS 2024年第2期87-95,共9页
Pearl millet(Pennisetum glaucum)is one of the major millets with high nutritional properties.This crop exhibits exceptional resilience to drought and high temperatures.However,the processing of pearl millet poses a si... Pearl millet(Pennisetum glaucum)is one of the major millets with high nutritional properties.This crop exhibits exceptional resilience to drought and high temperatures.However,the processing of pearl millet poses a significant challenge due to its high lipid content,enzyme activity,and presence of antinutrients.Consequently,it becomes imperative to enhance the quality and prolong the shelf life of pearl millet flour by employing suitable technologies.Hydrothermal treatment in the food industry has long been seen as promising due to its potential to reduce microbial load,inactivate enzymes,and improve nutrient retention.This study aims to investigate the effects of hydrothermal treatment on the quality characteristics of pearl millet.The independent variables of the study were soaking temperature(35,45,55℃),soaking time(2,3,4 h),and steaming time(5,10,15 min).Treatment conditions had a statistically significant effect on nutrient retention.Major antinutrients like tannins and phytates were reduced by 0.99% to 5.94% and 0.36% to 6.00%,respectively,after the treatment.Lipase activity decreased significantly up to 10% with the treatment conditions.The findings of this study could potentially encourage the use of pearl millet flour in the production of various food items and promote the application of hydrothermal treatment in the field of food processing. 展开更多
关键词 Pearl millet Hydrothermal treatment Nutritional properties ANTINUTRIENTS
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Transformation of long-period stacking ordered structures in Mg-Gd-Y-Zn alloys upon synergistic characterization of first-principles calculation and experiment and its effects on mechanical properties 被引量:1
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作者 Mingyu Li Guangzong Zhang +4 位作者 Siqi Yin Changfeng Wang Ying Fu Chenyang Gu Renguo Guan 《Journal of Magnesium and Alloys》 SCIE EI CAS CSCD 2024年第5期1867-1879,共13页
Based on experiments and first-principles calculations,the microstructures and mechanical properties of as-cast and solution treated Mg-10Gd-4Y-xZn-0.6Zr(x=0,1,2,wt.%)alloys are investigated.The transformation process... Based on experiments and first-principles calculations,the microstructures and mechanical properties of as-cast and solution treated Mg-10Gd-4Y-xZn-0.6Zr(x=0,1,2,wt.%)alloys are investigated.The transformation process of long-period stacking ordered(LPSO)structure during solidification and heat treatment and its effect on the mechanical properties of experimental alloys are discussed.Results reveal that the stacking faults and 18R LPSO phases appear in the as-cast Mg-10Gd-4Y-1Zn-0.6Zr and Mg-10Gd-4Y-2Zn-0.6Zr alloys,respectively.After solution treatment,the stacking faults and 18R LPSO phase transform into 14H LPSO phase.The Enthalpies of formation and reaction energy of 14H and 18R LPSO are calculated based on first-principles.Results show that the alloying ability of 18R is stronger than that of 14H.The reaction energies show that the 14H LPSO phase is more stable than the 18R LPSO.The elastic properties of the 14H and 18R LPSO phases are also evaluated by first-principles calculations,and the results are in good agreement with the experimental results.The precipitation of LPSO phase improves the tensile strength,yield strength and elongation of the alloy.After solution treatment,the Mg-10Gd-4Y-2Zn-0.6Zr alloy has the best mechanical properties,and its ultimate tensile strength and yield strength are 278.7 MPa and 196.4 MPa,respectively.The elongation of Mg-10Gd-4Y-2Zn-0.6Zr reaches 15.1,which is higher than that of Mg-10Gd-4Y0.6Zr alloy.The improving mechanism of elastic modulus by the LPSO phases and the influence on the alloy mechanical properties are also analyzed. 展开更多
关键词 Mg-Gd-Y-Zn alloys Long-period stacking ordered First-principles calculations ENTHALPIES Mechanical properties
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