The present paper reports the rapid surface alloying induced by the bombardment of high-current pulsed electron beam. Two kinds of substrate materials were examined to show this effect. The first sample was a pure Al ...The present paper reports the rapid surface alloying induced by the bombardment of high-current pulsed electron beam. Two kinds of substrate materials were examined to show this effect. The first sample was a pure Al metal pre-coated with fine carbon powders prior to the bombardment, and the second alloy is the D2-Crl2MolVl mould steel pre-coated with Cr, Ti, and TiN powders. The surface elements diffuse about several micrometers into the substrate materials only after several bombardments. Tribological behaviors of these samples were characterized and significant improvement in wear resistance was found. Finally, a TEM analysis reveals the presence of stress waves generated by coupled thermal and stress fields, which was considered as the main cause of the enhanced properties.展开更多
In this work,surface modification of a Mg-4Sm-2Al-0.5Mn alloy with high current pulse electron beam(HCPEB)under different number of pulses were investigated.The evolution in microstructure,composition and phase compon...In this work,surface modification of a Mg-4Sm-2Al-0.5Mn alloy with high current pulse electron beam(HCPEB)under different number of pulses were investigated.The evolution in microstructure,composition and phase components and properties in the surface layer before and after HCPEB treatment were characterized.It was found that the Al 11 Sm 3 and Al 2 Sm phases in the surface layer were gradually dissolved during HCPEB treatment,leading to the formation of a chemical homogeneous melted layers.Besides,deformation bands were formed in the treated layer due to the thermal stress generated during treatment.After 15 pulses treatment,the surface hardness increases to the maximum value of about 62.2 HV,about 61.2%higher than that of the untreated state.Electrochemical results show that the 15 pulses treated sample presents the best corrosion resistance in the 3.5wt%NaCl water solution by showing the highest corrosion potential(E_(corr))of-1.339V SEC and the lowest corrosion current density(I_(corr))of 1.48×10^(-6)A·cm^(-2).The results prove that the surface properties of the Mg-4Sm-2Al-0.5Mn alloy can be significantly improved by the HCPEB treatments under proper conditions.展开更多
Surface modification of magnesium alloy AZ91HP (9wt%Al, 0.5wt%Zn, 0.5wt%Mn, Mg remaining percentage) by high current pulsed electron beam (HCPEB) treatment was studied in this paper. The secondary phase MgnAln is near...Surface modification of magnesium alloy AZ91HP (9wt%Al, 0.5wt%Zn, 0.5wt%Mn, Mg remaining percentage) by high current pulsed electron beam (HCPEB) treatment was studied in this paper. The secondary phase MgnAln is nearly completely dissolved and as a result, a super-saturated solid solution forms on the re-melted surface. The microhardness is increased both in and far beyond the heat-affected zone (HAZ), reaching about 250um. Measurements on sliding wear have shown that the wear resistance of the treated samples was improved by a factor of about 2.4 as compared to the as-received sample. It is also found that the sliding wear resistance can be further improved by surface alloying with TiN.展开更多
The surface modification of magnesium alloys (AZ31 and AZ91HP) was studied by a high current pulsed electron beam(HCPEB). The results show that the cross-sectional microhardness of treated samples increases not only i...The surface modification of magnesium alloys (AZ31 and AZ91HP) was studied by a high current pulsed electron beam(HCPEB). The results show that the cross-sectional microhardness of treated samples increases not only in the heat affected zone(HAZ), but also beyond HAZ, reaching over 250μm. This is due to the action of quasi-static thermal stress and the shock thermal stress wave with materials, which result in its fast deformation on the surface layer and so increases microhardness. For the AZ91HP alloy, a nearly complete dissolution of the intermetallic phase Mg_ 17Al_ 12 is observed, and a super-saturated solid solution forms on the re-melted surface, which is due to the solute trapping effect during the fast solidification process. Measurements on sliding wear show that wear resistance is improved by approximately 5.6 and 2.4 times for the AZ31 and AZ91HP respectively, as compared with as-received samples.展开更多
The high-current pulsed electron beam(HCPEB) treatment with current density 6 J/cm^2 was applied on AZ91 Mg alloy to improve its corrosion resistance. Results showed that the net-like Mg_(17)Al_(12) disappeared on the...The high-current pulsed electron beam(HCPEB) treatment with current density 6 J/cm^2 was applied on AZ91 Mg alloy to improve its corrosion resistance. Results showed that the net-like Mg_(17)Al_(12) disappeared on the surface of AZ91 Mg alloy after irradiation by HCPEB, which was instead of supersaturated Al element on the surface. Nevertheless, the application of HCPEB also led to the formation of crater-like and groove-like structures as well as micro-cracks on the surface of AZ91 Mg alloy. After HCPEB treatment by 3, 5 and 10 pulses, the AZ91 Mg alloy exhibited better corrosion resistance.However, the increasing amount of micro-cracks reduced the anti-corrosive properties of AZ91 Mg alloy as the pulse increased to 20 and 30.展开更多
Ti–Al surface alloy was fabricated using a cyclic pulsed liquid-phase mixing of predeposited 100 nm Al film with a-Ti substrate by low-energy high-current electron beam. Electron probe micro-analysis（EPMA）,grazing ...Ti–Al surface alloy was fabricated using a cyclic pulsed liquid-phase mixing of predeposited 100 nm Al film with a-Ti substrate by low-energy high-current electron beam. Electron probe micro-analysis（EPMA）,grazing incidence X-ray diffraction analysis（GIXRD）,transmission electron microscopy（TEM）, and nanoindentation were used to investigate the characterization of Ti–Al surface alloy. The experimental results show that the thickness of alloy layer is ＊3 lm, and the content of Al in the ＊1 lm thickness surface layer is ＊60 at%. The tetragonal TiAl and TiAl2intermetallics were synthesized at the top surface, which have nanocrystalline structure.The main phase formed in the ＊2.5 lm thick surface is TiAl, and there are few TiAl2and Ti3Al phase for the alloy.Dislocation is enhanced in the alloyed layer. The nanohardness of Ti–Al surface alloy increased significantly compared with a-Ti substrate due to the nanostructure and enhanced dislocation. Since the e-beam remelted repeatedly, the Ti–Al surface alloy mixed sufficiently with Ti substrate. Moreover, there is no obvious boundary between the alloyed layer and substrate.展开更多
利用强流脉冲电子束（High current pulsed electron beam,HCPEB）技术对镍基高温合金GH4169进行表面处理,利用X射线衍射仪（X-ray diffraction,XRD）、扫描电子显微镜（Scanning electron microscope,SEM）和透射电子显微镜（Transmiss...利用强流脉冲电子束（High current pulsed electron beam,HCPEB）技术对镍基高温合金GH4169进行表面处理,利用X射线衍射仪（X-ray diffraction,XRD）、扫描电子显微镜（Scanning electron microscope,SEM）和透射电子显微镜（Transmission electron microscopy,TEM）对HCPEB诱发的微观结构进行详细的表征,并考察HCPEB辐照处理后样品表面的腐蚀性能。试验结果表明,HCPEB辐照后GH4169合金表面发生熔化并形成熔坑,熔坑密度随辐照次数的增加而降低,尺寸较大的第二相颗粒等可随着熔坑的喷发而清除,进而实现表面净化。HCPEB辐照后GH4169合金表面形成3~5μm厚的重熔层,重熔层内部以尺寸在100 nm左右的纳米晶为主,HCPEB辐照还可在表层诱发强烈的塑性变形,形成高密度的位错及变形孪晶等变形结构。HCPEB辐照显著地改善了GH4169合金的耐蚀性能,腐蚀性能的改善主要归因于表面净化效应以及表层纳米重熔层和高密度的晶体缺陷的形成,这些微观结构促进了表层钝化膜的形成,起到保护基体的作用。展开更多
文摘The present paper reports the rapid surface alloying induced by the bombardment of high-current pulsed electron beam. Two kinds of substrate materials were examined to show this effect. The first sample was a pure Al metal pre-coated with fine carbon powders prior to the bombardment, and the second alloy is the D2-Crl2MolVl mould steel pre-coated with Cr, Ti, and TiN powders. The surface elements diffuse about several micrometers into the substrate materials only after several bombardments. Tribological behaviors of these samples were characterized and significant improvement in wear resistance was found. Finally, a TEM analysis reveals the presence of stress waves generated by coupled thermal and stress fields, which was considered as the main cause of the enhanced properties.
基金This work was supported by the National Natural Science Foundations of China(No.51271121,51471109).
文摘In this work,surface modification of a Mg-4Sm-2Al-0.5Mn alloy with high current pulse electron beam(HCPEB)under different number of pulses were investigated.The evolution in microstructure,composition and phase components and properties in the surface layer before and after HCPEB treatment were characterized.It was found that the Al 11 Sm 3 and Al 2 Sm phases in the surface layer were gradually dissolved during HCPEB treatment,leading to the formation of a chemical homogeneous melted layers.Besides,deformation bands were formed in the treated layer due to the thermal stress generated during treatment.After 15 pulses treatment,the surface hardness increases to the maximum value of about 62.2 HV,about 61.2%higher than that of the untreated state.Electrochemical results show that the 15 pulses treated sample presents the best corrosion resistance in the 3.5wt%NaCl water solution by showing the highest corrosion potential(E_(corr))of-1.339V SEC and the lowest corrosion current density(I_(corr))of 1.48×10^(-6)A·cm^(-2).The results prove that the surface properties of the Mg-4Sm-2Al-0.5Mn alloy can be significantly improved by the HCPEB treatments under proper conditions.
文摘Surface modification of magnesium alloy AZ91HP (9wt%Al, 0.5wt%Zn, 0.5wt%Mn, Mg remaining percentage) by high current pulsed electron beam (HCPEB) treatment was studied in this paper. The secondary phase MgnAln is nearly completely dissolved and as a result, a super-saturated solid solution forms on the re-melted surface. The microhardness is increased both in and far beyond the heat-affected zone (HAZ), reaching about 250um. Measurements on sliding wear have shown that the wear resistance of the treated samples was improved by a factor of about 2.4 as compared to the as-received sample. It is also found that the sliding wear resistance can be further improved by surface alloying with TiN.
文摘The surface modification of magnesium alloys (AZ31 and AZ91HP) was studied by a high current pulsed electron beam(HCPEB). The results show that the cross-sectional microhardness of treated samples increases not only in the heat affected zone(HAZ), but also beyond HAZ, reaching over 250μm. This is due to the action of quasi-static thermal stress and the shock thermal stress wave with materials, which result in its fast deformation on the surface layer and so increases microhardness. For the AZ91HP alloy, a nearly complete dissolution of the intermetallic phase Mg_ 17Al_ 12 is observed, and a super-saturated solid solution forms on the re-melted surface, which is due to the solute trapping effect during the fast solidification process. Measurements on sliding wear show that wear resistance is improved by approximately 5.6 and 2.4 times for the AZ31 and AZ91HP respectively, as compared with as-received samples.
基金the finacial support from the National Natural Science Foundation of China(Nos.51771128 and 51771129)the Projects of International Cooperation in Shanxi(No.201703D421039)the Natural Science Foundation of Shanxi(No.201601D011034)
文摘The high-current pulsed electron beam(HCPEB) treatment with current density 6 J/cm^2 was applied on AZ91 Mg alloy to improve its corrosion resistance. Results showed that the net-like Mg_(17)Al_(12) disappeared on the surface of AZ91 Mg alloy after irradiation by HCPEB, which was instead of supersaturated Al element on the surface. Nevertheless, the application of HCPEB also led to the formation of crater-like and groove-like structures as well as micro-cracks on the surface of AZ91 Mg alloy. After HCPEB treatment by 3, 5 and 10 pulses, the AZ91 Mg alloy exhibited better corrosion resistance.However, the increasing amount of micro-cracks reduced the anti-corrosive properties of AZ91 Mg alloy as the pulse increased to 20 and 30.
基金financially supported by the National Natural Science Foundation of China and the Russian Foundation for Basic Research (No. 11011120081)Large Scientific Facilities of the National Natural Science Foundation of China and of the Chinese Academy of Sciences (No. 11079012)the National Natural Science Foundation of China (No. 10875021)
文摘Ti–Al surface alloy was fabricated using a cyclic pulsed liquid-phase mixing of predeposited 100 nm Al film with a-Ti substrate by low-energy high-current electron beam. Electron probe micro-analysis（EPMA）,grazing incidence X-ray diffraction analysis（GIXRD）,transmission electron microscopy（TEM）, and nanoindentation were used to investigate the characterization of Ti–Al surface alloy. The experimental results show that the thickness of alloy layer is ＊3 lm, and the content of Al in the ＊1 lm thickness surface layer is ＊60 at%. The tetragonal TiAl and TiAl2intermetallics were synthesized at the top surface, which have nanocrystalline structure.The main phase formed in the ＊2.5 lm thick surface is TiAl, and there are few TiAl2and Ti3Al phase for the alloy.Dislocation is enhanced in the alloyed layer. The nanohardness of Ti–Al surface alloy increased significantly compared with a-Ti substrate due to the nanostructure and enhanced dislocation. Since the e-beam remelted repeatedly, the Ti–Al surface alloy mixed sufficiently with Ti substrate. Moreover, there is no obvious boundary between the alloyed layer and substrate.
文摘利用强流脉冲电子束（High current pulsed electron beam,HCPEB）技术对镍基高温合金GH4169进行表面处理,利用X射线衍射仪（X-ray diffraction,XRD）、扫描电子显微镜（Scanning electron microscope,SEM）和透射电子显微镜（Transmission electron microscopy,TEM）对HCPEB诱发的微观结构进行详细的表征,并考察HCPEB辐照处理后样品表面的腐蚀性能。试验结果表明,HCPEB辐照后GH4169合金表面发生熔化并形成熔坑,熔坑密度随辐照次数的增加而降低,尺寸较大的第二相颗粒等可随着熔坑的喷发而清除,进而实现表面净化。HCPEB辐照后GH4169合金表面形成3~5μm厚的重熔层,重熔层内部以尺寸在100 nm左右的纳米晶为主,HCPEB辐照还可在表层诱发强烈的塑性变形,形成高密度的位错及变形孪晶等变形结构。HCPEB辐照显著地改善了GH4169合金的耐蚀性能,腐蚀性能的改善主要归因于表面净化效应以及表层纳米重熔层和高密度的晶体缺陷的形成,这些微观结构促进了表层钝化膜的形成,起到保护基体的作用。
