Expansion Performance and Microstructure of High-performance Concrete using Differently Scaled MgO Agents and Mineral Powder

To investigate the assumptions proposed in this paper,the evolution law governing the strength and expansion performance of MgO and nano-MgO micro-expansive concrete in the environment of mineral powder was firstly observed in this study.Secondly,SEM,XRD,and TG-DSC microscopic tests were conducted to reveal the effects of the active mineral-powder admixture on the hydration degree and expansion performance of MgO and nano-MgO in HPC.Our experimental results successfully verified our hypothesis,which indicated that the expansion performance of macro-MgO and nano-MgO was indeed depressed by the addition of active mineral power admixtures,even though the mechanical property of concrete composites was effectively improved.Furthermore,the hydration test also demonstrated the negative interference on the mineral powders,which was induced by the expansion agents.It is found the amounts of hydrates tend to decrease because the mineral powder ratio reaches and exceeds 40%.Moreover,it is also concluded the effect of expansion agents is governed by the alkalinity cement paste,especially for the nano-MgO.In other words,the expansion performance of nano-MgO will vary more obviously with the hydration process,than MgO.The results of this study provide that effective experimental and theoretical data support the hydration-inhibition mechanism of magnesium expansive agents.

Influence of shrinkage-reducing admixture on drying shrinkage and mechanical properties of high-performance concrete

High-performance concrete （HPC） has specific performance advantages over conventional concrete in strength and durability. HPC mixtures are usually produced with water/binder mass ratios （mW/mB） in the range of 0.2-0.4, so volume changes of concrete as a result of drying, chemical reactions, and temperature change cannot be avoided. For these reasons, shrinkage and cracking are frequent phenomena. It is necessary to add some types of admixture for reduction of shrinkage and cracking of HPC. This study used a shrinkage-reducing admixture （SRA） for that purpose. Concrete was prepared with two different mW/mB （0.22 and 0.40） and four different mass fractions of SRA to binder （w（SRA） = 0%, 1%, 2%, and 4%）. The mineral admixtures used for concrete mixes were： 25% fly ash （FA） and 25% slag by mass of binder for the mixture with mW/mB = 0.40, and 15% silica fume （SF） and 25% FA for the mixture with mW/mB = 0.22. Tests were conducted on 24 prismatic specimens, and shrinkage strains were measured through 120 days of drying. Compressive strength, splitting strength, and static modulus of elasticity were also determined. The results show that the SRA effectively reduces some mechanical properties of HPC. The reductions in compressive strength, splitting tensile strength, and elastic modulus of the concrete were 7%-24%, 9%-19%, and 5%-12%, respectively, after 90 days, compared to concrete mixtures without SRA. SRA can also help reduce drying shrinkage of concrete. The shrinkage strains of HPC with SRA were only as high as 41% of the average free shrinkage of concrete without SRA after 120 days of drying.

INFLUENCE OF MINERAL ADMIXTURES ON MECHANICAL PROPERTIES OF HIGH-PERFORMANCE CONCRETE

The improvements of the mechanical properties, including bulk density of fresh mixtures, elastic modulus, and compressive strengths of four high-performance concrete mixtures, made with the addition of fly ash, refined ground blast - furnace microslag (microslag) and silica fume are studied. The concrete mixtures were determined based on the dispersion testing results. The study indicates that the elastic modulus at 28 and 91 days, and compressive strengths of the concretes are improved a lot when fly ash and microslag by 25 percent by weight of cement are added into the mixtures individually. The improvement is especially evident when silica fume by 5 percent and fly ash by 25 percent by weight of cement are added together into the mixture, while the fresh concrete mixture keeps a good workability. Through the analysis of chemically combined water ratios of the four mixtures at various hydration ages, it is found that the addition of all these mineral mixtures are beneficial to the hydration process, especially, at later stages, which might be one of the reasons for the improvement of mechanical properties. (Author abstract) 4 Refs.

Creep experimental test and analysis of high-performance concrete in bridge

Factors that have effect on concrete creep include mixture composition,curing conditions,ambient exposure conditions,and element geometry.Considering concrete mixtures influence and in order to improve the prediction of prestress loss in important structures,an experimental test under laboratory conditions was carried out to investigate compression creep of two high performance concrete mixtures used for prestressed members in one bridge.Based on the experimental results,a power exponent function of creep degree for structural numerical analysis was used to model the creep degree of two HPCs,and two series of parameters of this function for two HPCs were calculated with evolution program optimum method.The experimental data was compared with CEB-FIP 90 and ACI 209(92) models,and the two code models both overestimated creep degrees of the two HPCs.So it is recommended that the power exponent function should be used in this bridge structure analysis.

Spalling and Mechanical Properties of Fiber Reinforced High-performance Concrete Subjected to Fire

Spalling and mechanical properties of FRHPC subjected to fire were tested on notched beams. The results confirm that the internal vapor pressure is the leading reason for spalling of high-performance concrete （HPC）. At the same time, the temperature-increasing velocity and constrained conditions of concrete element also play significant roles in spalling. Steel fibers cannot reduce the risk of spalling, although they have obvious beneficial effects on the mechanical properties of concrete before and after exposure to fire. Polypropylene （PP） fibers are very useful in preventing HPC from spalling, however, they have negative effects on the strengths. By using hybrid fibers （steel fibers＋PP fibers）, both good anti-spalling performance and improved mechanical properties come true, which may provide necessary safe guarantee for the rescue work and structure repair after fire disaster.

Assessment of early-age cracking of high-performance concrete in restrained ring specimens

High-performance concrete （HPC） is stronger and more durable than conventional concrete. However, shrinkage and shrinkage cracking are common phenomena in HPC, especially early-age cracking. This study assessed early-age cracking of HPC for two mixtures using restrained ring tests. The two mixtures were produced with water/binder mass ratio （mw/mB） of 0.22 and 0.40, respectively. The results show that, with greater steel thickness, the higher degree of restraint resulted in a higher interface pressure and earlier cracking. With steel thickness of 6 mm, 19 mm, and 30 mm, the age of cracking were, respectively, 12 days, 8 days, and 5.4 days with the mw/mB = 0.22 mixture; and 22.5 days, 12.6 days, and 7.1 days with the mw/mB= 0.40 mixture. Cases of the same steel thickness show that the ring specimens with a thicker concrete wall crack later. With the mw/mB = 0.22 mixture, concrete walls with thicknesses of 37.5 mm, 75 mm, and 112.5 mm cracked at 3.4 days, 8.0 days, and 9.8 days, respectively; with the mw/mB = 0.40 mixture, the ages of cracking were 7.1 days, 12.6 days, and 16.0 days, respectively.

FAILURE MODE AND CONSTITUTIVE MODEL OF PLAIN HIGH-STRENGTH HIGH-PERFORMANCE CONCRETE UNDER BIAXIAL COMPRESSION AFTER EXPOSURE TO HIGH TEMPERATURES

An orthotropic constitutive relationship with temperature parameters for plain highstrength high-performance concrete （HSHPC） under biaxial compression is developed. It is based on the experiments performed for characterizing the strength and deformation behavior at two strength levels of HSHPC at 7 different stress ratios including a=σs ： σ3=0.00：-1,-0.20：-1,-0.30 ： -1,-0.40：-1,-0.50：-1,-0.75：-1,-1.00：-1, after the exposure to normal and high temperatures of 20, 200, 300, 400, 500 and 600℃, and using a large static-dynamic true triaxial machine. The biaxial tests were performed on 100 mm×100 mm×100 mm cubic specimens, and friction-reducing pads were used consisting of three layers of plastic membrane with glycerine in-between for the compressive loading plane. Based on the experimental results, failure modes of HSHPC specimens were described. The principal static compressive strengths, strains at the peak stress and stress-strain curves were measured; and the influence of the temperature and stress ratios on them was also analyzed. The experimental results showed that the uniaxial compressive strength of plain HSHPC after exposure to high temperatures does not decrease dramatically with the increase of temperature. The ratio of the biaxial to its uniaxial compressive strength depends on the stress ratios and brittleness-stiffness of HSHPC after exposure to different temperature levels. Comparison of the stress-strain results obtained from the theoretical model and the experimental data indicates good agreement.

Strength Regularity and Failure Criterion of High-Strength High-Performance Concrete under Multiaxial Compression

Multiaxial compression tests were performed on 100 mm×100 mm×100 mm high-strength high-performance concrete （HSI-IPC） cubes and normal strength concrete （NSC） cubes. The failure modes of specimens were presented, the static compressive strengths in principal directions were measured, the influence of the stress ratios was analyzed. The experimental results show that the ultimate strengths for HSHPC and NSC under multiaxial compression are greater than the uniaxial compressive strengths at all stress ratios, and the multiaxial strength is dependent on the brittleness and stiffness of concrete, the stress state and the stress ratios. In addition, the Kupfer-Gersfle and Ottosen＇s failure criteria for plain HSHPC and NSC under multiaxial compressive loading were modified.

Experimental Research on Early-Age Property of High-Performance Concrete Column by Embedded Sensors

This paper aims at monitoring the autogenous shrinkage （AS） of a high-performance concrete （HPC） column specimen using an embedded strain gauge just after concrete pouring. A real size specimen （40 cm×40 cm×100cm） was made to simulate the structural members in construction site. The results show that the amount of HPC AS is comparable to that of drying shrinkage and even larger than it, so AS can not be omitted for HPC. By comparing the plain HPC and reinforced HPC specimens, the influences of reinforced bars on autogenous shrinkage and temperature distribution were obtained.

Experimental study on creep of high-performance concretes

In order to investigate the compression creep of two kinds of high-performance concrete mixtures used for prestressed members in a bridge,an experimental test under laboratory conditions was carried out.Based on the experimental results,a power exponent function was used to model the creep degree of these high-performance concretes(HPCs) for structural numerical analysis,and two series parameters of this function for the HPCs were given with the optimum method of evolution program.The experimental data were compared with CEB-FIP 90 and ACI 92 models.Results show that the two code models both overestimate the creep degree of two HPCs,so it is recommended that the power exponent function should be used for the creep analysis of bridge structure.

INITIAL BINDING CAPACTIES OF CHLORIDE ION OF COMPONENTS IN HIGH-PERFORMANCE CONCRETE

An investigation is reported on the influence of different components of high performance concrete (HPC) on the initial binding capacities (IBC) of chloride ion. The testing results demonstrate that cement has the largest IBC, and the relative binding ratio is as high as 30% of total ion amount. Among the mineral admixtures, fly ash has the largest IBC of chloride ion. The IBC of silica fume is about 14.4%, which is smaller than that of fly ash. The IBC of refined ground blast-furnace slag (microslag) is abnormal due to the influence of sulfate ion contained. The addition of superplasticizer and corrosion inhibitor containing calcium nitrite weakens the IBC of mixtures. The fluidity and pore-filling effect of mineral admixtures are studied with paste samples with WIC ratio of 0.3. The influence mechanism of various components in high-performance concrete in IBC is studied further through SEM and Mercury Instrusion Porosimetry tests with paste samples at the age of 3 days.

HPC端部加强双钢板组合剪力墙的抗震性能

为研究高性能混凝土端部加强双钢板组合剪力墙受力机理及破坏形态,以轴压比、腹部普通混凝土强度等级为关键参数,设计了4片普通试件,7片HPC端部加强试件,运用ABAQUS构建其有限元模型,研究其抗震性能。结果表明:同轴压比下,HPC端部加强试件相比普通试件屈服荷载提高16.30%,峰值荷载提升13.40%;随着轴压比提高,HPC端部加强试件峰值荷载和屈服荷载分别提高7.22%和2.72%,随着轴压比减小,HPC端部加强试件延性提升22.26%;提高腹部腔体混凝土强度等级,HPC端部加强试件的屈服荷载和峰值荷载分别提高13.01%和11.14%,延性提升16.91%。

High-Performance and Multifunctional Cement-Based Composite Material

Concrete is a continuously evolving material, and even the definition of high-performance concrete has changed over time. In this paper, high-performance characteristics of concrete material are considered to be those that support the desirable durability, resilience, and sustainability of civil infrastructure that directly impact our quality of life. It is proposed that high-performance material characteristics include tensile ductility, autogenous crack-width control, and material “greenness.” Furthermore, smart functionalities should be aimed at enhancing infrastructure durability, resilience, and sustainability by responding to changes in the surrounding environment of the structure in order to perform desirable functions, thus causing the material to behave in a manner more akin to certain biological materials. Based on recent advances in engineered cementitious composites (ECCs), this paper suggests that concrete embodying such high-performance characteristics and smart multifunctionalities can be designed, and holds the potential to fulfill the expected civil infrastructure needs of the 21st century. Highlights of relevant properties of ECCs are provided, and directions for necessary future research are indicated.

Carbonation Resistance of Sulphoaluminate Cement-based High Performance Concrete

The influences of water/cement ratio and admixtures on carbonation resistance of sulphoaluminate cement-based high performance concrete （HPC） were investigated. The experimental results show that with the decreasing water/cement ratio, the carbonation depth of sulphoaluminate cement-based HPC is decreased remarkably, and the carbonation resistance capability is also improved with the adding admixtures. The morphologies and structure characteristics of sulphoaluminate cement hydration products before and after carbonation were analyzed using SEM and XRD. The analysis results reveal that the main hydration product of sulphoaluminate cement, that is ettringite （AFt）, decomposes after carbonation.

Properties and Microstructure of Marine Concrete with Composite Mineral Admixture

The influences of compositing mineral admixtures on the regularity of mechanical property, workability, durability and microstructure of C50 marine concrete were investigated. The results show that the incorporation of mineral admixtures can improve the mechanical properties and workability of C50 marine concrete, 3 min-doped mineral admixture had excellent resistance to chloride ion permeability. The microscopic structure mixing mineral admixtures system was well-distributed and compact, little macroporeare can be found.

SULFATE RESISTANCE MECHANISM OF HIGH- PERFORMANCE CONCRETE CONTAINING NCI

It is found that the incorporation of Nitrite Corrosion Inhibitor (NCI) greatly weakens the resistance of mixtures to sulfate attack. To study the mechanism of this phenomenon, in this paper, the influence of NCI addition on the cement paste and microstructure change of high performance concrete specimens is studied by means of quantitative XRD, SEM tests. The results demonstrate that the incorporation of NCI accelerates the formation of calcium hydroxide and ettringite crystals, and weakens the pore refinement effect caused by the secondary hydration reaction of fly ash and microsilica. At the age up to one year, the relative crystal quantity in mixture containing NCI is always higher than that in control mixture. The reasons for the degradation in sulfate resistance of mixtures may be attributed to the increase and stability of the calcium hydroxide and ettringite crystals formed and the weakening of secondary hydration reaction. Based on the results, conclusion can be drawn that NCI should be used cautiously in practical engineering where high resistance to sulfate attack is required. (Author abstract) 7 Refs.

玄武岩石粉对HPC工作性及抗氯离子渗透性能的影响

研究了玄武岩石粉的粒径和替代率0、10%、20%、30%(等质量替代水泥)对高性能混凝土(HPC)工作性和抗氯离子渗透性能的影响,并结合压汞分析技术从微观角度探讨了玄武岩石粉的作用机理。结果表明:随着玄武岩石粉粒径和替代率的增加,HPC的流动度和初凝时间均呈增大趋势;随着玄武岩石粉替代率的增加,HPC的电通量先减小后增大;随着玄武岩石粉粒径的增加,HPC的电通量呈增大趋势;玄武岩石粉的粒径对HPC抗氯离子渗透性能的影响与其替代率紧密相关,当替代率较低时,粒径越小,HPC的抗氯离子渗透性能越好,而当替代率较高时,减小粒径对HPC抗氯离子渗透性能的改善效果不大;玄武岩石粉的填充效应和潜在活性可以提高基体的密实度,从而提高HPC的抗氯离子渗透性能。

Use of Stone Dust in the Design of High Performance Concrete

This research evaluated the suitability of stone dust in the design and production of High Perfor-mance Concrete (HPC). HPC mix was designed, tested, costed and a comparison of concrete classes used in the market (Class 25, 30 and 35) done using Cost Benefit Analysis (CBA). The cost benefit was analyzed using Internal Rate of Return (IRR) and Net Present Value (NPV). Laboratory tests established the properties concrete obtained from the design mix. Compressive strength, slump, and modulus of elasticity were tested and analyzed. Structural analysis using BS 8110 was done for a 10 storey office building to establish the structural member sizes. Members obtained from concrete Classes 25, 30, 35 and the new compressive strengths from HPC (Class 80) were obtained and compared. Analysis was done for structural members’ sizes and area freed as a result of de-signing with HPC as well as the steel reinforcement used. To justify the initial cost of HPC if ado- pted, the Cost Benefit Analysis (CBA) was used to estimate increased costs versus income resulting from increased let table space created. The minimum class of concrete used in design was limited to Class 25 N/mm2. The research shows that it is possible to manufacture high strength concrete using locally available stone dust. The stone dust sampled from Mlolongo quarries achieved a characteristic strength of 86.7 N/mm2 at a water cement ratio of 0.32. With the results structural analysis of a 10 storey office structures with columns spaced at 8 meters center to center was de-signed using the four classes and results compared. There was a reduction of columns from 1.2 m wide to 0.65 m wide (over 45%) when concrete class changes from Class 25 to Class 80 creating over 3% of the total space area per floor. Cost benefit analysis using Net Present Value (NPV) and Internal Rate of Return (IRR) presented business case for the use of HPC. With Class 80, the IRR was at 3% and NPV being 8% of the total initial investment. The steel reinforcement increased by 8.64% using Class 30, 11.68% using Class 35 and reduced by 8.37% at Class 80. Further analysis needs to be done to understand the trend of steel reinforcement keeping all the member sizes the same. In this study the member sizes were optimized based on the steel reinforcement and serviceability. This paper provides useful information to design Engineers and Architects and inform future design of multi storey structures.

Study on durability of concrete in coal mine

There are sulfate and chloride ions corrosion and carbonation to concrete in coal mine. Based on taking test of accelerated carbonation, corrosion of 3.5% weight of NaCl solution and 5% weight of Na2SO4 solution of coal mine concretes, durability of con- cretes which include spray concrete of C20,high performance concretes of C30 and C50 and effect of fly ash on durability have been studied. Results suggest that the coal mineral high performance concretes show good resistance capacities of carbonation, sulfate and chloride corrosion to meet the coal mine construction. And the higher the strength grade is, the better the resistance capacity of corrosion of carbonation is, chloride and sulfate. Moreover, fly ash improves resistance capacity of high performance concrete(HPC) to chloride and sulfate but decreases the resistance capacity of C30’s to carbonation and average dynamic modulus.

钢／聚丙烯混杂纤维对HPC深梁受弯性能的影响

为研究钢纤维和聚丙烯纤维对高性能混凝土(HPC)深梁受弯性能的影响,对17根含有不同钢纤维(体积掺量≤1%)和聚丙烯纤维(体积掺量≤0.2%)以及不同纵筋配筋率的HPC简支深梁进行4点受弯性能试验.结果显示:单一纤维或混杂纤维增强HPC深梁的初裂荷载提高了10%～40%;混杂纤维增强HPC适筋深梁的纵筋屈服荷载提高50%～150%,极限受弯承载力提高1～2倍,但无筋的混杂纤维HPC深梁承载力很小,破坏为剪切脆性破坏.试验结果表明:混杂纤维可以极大提高HPC深梁的受弯承载力,但混杂纤维的作用不能代替纵向钢筋的作用;可采用复合材料强度叠加原理及剩余弯曲强度理论来探讨混杂纤维增强HPC深梁的极限受弯承载力计算公式.