Productivity Analysis Method of Abnormal High-Pressure Gas Reservoir in Ying-Qiong Basin

Ying-Qiong Basin in the west of South China Sea contains plenty of abnormal high-pressure gas reservoirs, whose stress sensitivity is crucial for well productivity. To explore the influence of stress sensitivity on production, the variable outlet back pressure stress sensitivity experiments were applied to test core sample permeability under different burden pressure and obtain the relational expression of power function of core stress sensitivity. Afterwards, new productivity equation is deduced in consideration of reservoir stress sensitivity, and the affection of stress sensitivity on production is analyzed. The result demonstrates close link between stress sensitivity and productivity, since single well production decreases dramatically when reservoir stress sensitivity has been taken into account. This research is constructive for well-testing data interpretation in stress sensitive gas reservoirs.

Influence of introducing Zr,Ti,Nb and Ce elements on externally solidified crystals and mechanical properties of high-pressure die-casting Al–Si alloy

High pressure die casting(HPDC)AlSi10Mn Mg alloy castings are widely used in the automobile industry.Mg can optimize the mechanical properties of castings through heat treatment,while the release of thermal stress arouses the deformation of large integrated die-castings.Herein,the development of non-heat treatment Al alloys is becoming the hot topic.In addition,HPDC contains externally solidified crystals(ESCs),which are detrimental to the mechanical properties of castings.To achieve high strength and toughness of non-heat treatment die-casting Al-Si alloy,we used AlSi9Mn alloy as matrix with the introduction of Zr,Ti,Nb,and Ce.Their influences on ESCs and mechanical properties were systematically investigated through three-dimensional reconstruction and thermodynamic simulation.Our results reveal that the addition of Ti increased ESCs'size and porosity,while the introduction of Nb refined ESCs and decreased porosity.Meanwhile,large-sized Al_3(Zr,Ti)phases formed and degraded the mechanical properties.Subsequent introduction of Ce resulted in the poisoning effect and reduced mechanical properties.

Solar neutrino background in high-pressure gaseous ^(82)SeF_(6) TPC neutrinoless double beta decay experiments

In this study,the possibility of observing a solar neutrino background in a future neutrinoless double beta decay experiment using a high-pressure gaseous ^(82)SeF_(6) TPC is investigated.Various contributions are simulated,and possible features that could be used for event classification are discussed;two types of backgrounds are identified.The rate of multi-site background events is approximately 0.63 events/(ton·yr)in a 30 keV ROI window.This background could be effectively reduced to less than 0.0001 events/(ton·yr)(95%C.L.)while maintaining a high signal efficiency of 93%by applying a selection based on the number of clusters and energy of the leading cluster.The rate of the single-electron background events is approximately 0.01 events/(ton·yr)in the ROI.Assuming a reduction factor of 10 for the single-electron background events obtained via the algorithms developed for radioactive background rejection,the total background induced by the solar neutrino would be 0.001 events/(ton·yr),which is sufficiently small for conducting ton-level experiments.

Gas Film Disturbance Characteristics Analysis of High-Speed and High-Pressure Dry Gas Seal

The dry gas seal（DGS） has been widely used in high parameters centrifugal compressor, but the intense vibrations of shafting, especially in high-speed condition, usually result in DGS＇s failure. So the DGS＇s ability of resisting outside interference has become a determining factor of the further development of centrifugal compressor. However, the systematic researches of which about gas film disturbance characteristics of high parameters DGS are very little. In order to study gas film disturbance characteristics of high-speed and high-pressure spiral groove dry gas seal（S-DGS） with a flexibly mounted stator, rotor axial runout and misalignment are taken into consideration, and the finite difference method and analytical method are used to analyze the influence of gas film thickness disturbance on sealing performance parameters, what＇s more, the effects of many key factors on gas film thickness disturbance are systematically investigated. The results show that, when sealed pressure is 10.1MPa and seal face average linear velocity is 107.3 m/s, gas film thickness disturbance has a significant effect on leakage rate, but has relatively litter effect on open force; Excessively large excitation amplitude or excessively high excitation frequency can lead to severe gas film thickness disturbance; And it is beneficial to assure a smaller gas film thickness disturbance when the stator material density is between 3.1 g/cm3 to 8.4 g/cm3; Ensuring sealing performance while minimizing support axial stiffness and support axial damping can help to improve dynamic tracking property of dry gas seal. The proposed research provides the instruction to optimize dynamic tracking property of the DGS.

A study of hydrate plug formation in a subsea natural gas pipeline using a novel high-pressure flow loop

The natural gas pipeline from Platform QKI8-1 in the southwest of Bohai Bay to the onshore processing facility is a subsea wet gas pipeline exposed to high pressure and low temperature for a long distance. Blockages in the pipeline occur occasionally. To maintain the natural gas flow in the pipeline, we proposed a method for analyzing blockages and ascribed them to the hydrate formation and agglomeration. A new high-pressure flow loop was developed to investigate hydrate plug formation and hydrate particle size, using a mixture of diesel oil, water, and natural gas as experimental fluids. The influences of pressure and initial flow rate were also studied. Experimental results indicated that when the flow rate was below 850 kg/h, gas hydrates would form and then plug the pipeline, even at a low water content （10%） of a water/oil emulsion. Furthermore, some practical suggestions were made for daily management of the subsea pipeline.

Effects of ultrasound on the desulfurization performance of hot coal gas over Zn-Mn-Cu supported on semi-coke sorbent prepared by high-pressure impregnation method

Zn-Mn-Cu/SC（U） sorbent was hydrothermally synthesized by ultrasound-assisted high-pressure impregnation method with semi-coke（SC）as support and the mixed solution of zinc nitrate,manganese nitrate and copper nitrate as active component precursors.The desulfurization performances of hot coal gas on the prepared sorbent at a mid-temperature of 500°C were tested in fixed-bed reactor.Morphology and pore structure of the prepared sorbent were also characterized by TEM,N2adsorption/desorption isotherms and XRD.For comparison,the sorbent of Zn-Mn-Cu/SC prepared by conventional high-pressure impregnation was also evaluated and characterized in order to study the effects of ultrasound treatment.Zn-Mn-Cu/SC（U） sorbent prepared by high-pressure impregnation under ultrasound-assisted condition showed a better desulfurization performance than Zn-Mn-Cu/SC.It could remove H2 S from 1000×10-6m3/m3 to 0.1×10-6m3/m3 at 500°C and maintained for 12.5 h with the sulfur capacity of 7.74%,in which both the breakthrough time and sulfur capacity were about 32% and 51% higher than those of Zn-Mn-Cu/SC sorbent.The introduction of ultrasound during high-pressure impregnation process greatly improved the morphology and pore structure of the sorbent.The ultrasonic treatment made particle size of active components smaller and made them more evenly disperse on semi-coke support,which provided more opportunities to contact with H2S in coal-based gases.However,there were no any difference in compositions and existing forms of active components on the Zn-Mn-Cu/SC and Zn-Mn-Cu/SC（U） sorbents.

Mold Filling and Prevention of Gas Entrapment in High-pressure Die-casting

This paper presents some results of direct observation of mold filling in a specially designed die-casting by X-ray diffraction, including comparison with numerical simulation. Based on such work the authors discuss how to prevent gas entrapment and propose new methods.

CFD simulation of gas–liquid flow in a high-pressure bubble column with a modified population balance model

In this study,based on the Luo bubble coalescence model,a model correction factor C_e for pressures according to the literature experimental results was introduced in the bubble coalescence efficiency term.Then,a coupled modified population balance model(PBM) with computational fluid dynamics(CFD) was used to simulate a high-pressure bubble column.The simulation results with and without C_e were compared with the experimental data.The modified CFD-PBM coupled model was used to investigate its applicability to broader experimental conditions.These results showed that the modified CFD-PBM coupled model can predict the hydrodynamic behaviors under various operating conditions.

Nano-scale Reinforcements and Properties of Al-Si-Cu Alloy Processed by High-Pressure Torsion

To improve the comprehensive mechanical properties of Al-Si-Cu alloy,it was treated by a high-pressure torsion process,and the effect of the deformation degree on the microstructure and properties of the Al-Si-Cu alloy was studied.The results show that the reinforcements(β-Si andθ-CuAl_(2)phases)of the Al-Si-Cu alloy are dispersed in theα-Al matrix phase with finer phase size after the treatment.The processed samples exhibit grain sizes in the submicron or even nanometer range,which effectively improves the mechanical properties of the material.The hardness and strength of the deformed alloy are both significantly raised to 268 HV and 390.04 MPa by 10 turns HPT process,and the fracture morphology shows that the material gradually transits from brittle to plastic before and after deformation.The elements interdiffusion at the interface between the phases has also been effectively enhanced.In addition,it is found that the severe plastic deformation at room temperature induces a ternary eutectic reaction,resulting in the formation of ternary Al+Si+CuAl_(2)eutectic.

Experimental and Finite Element Analysis of Corroded High-Pressure Pipeline Repaired by Laminated Composite

Repairs of corroded high-pressure pipelines are essential for fluids transportation under high pressure.One of the methods used in their repairs is the use of layered composites.The composite used must have the necessary strength.Therefore,the experiments and analytical solutions presented in this paper are performed according to the relevant standards and codes,including ASME PCC-2,ASME B31.8S,ASME B31.4,ISO 24817 and ASME B31.G.In addition,the experimental tests are replicated numerically using the finite element method.Setting the strain gauges at different distances from the defect location,can reduce the nonlinear effects,deformation,and fluctuations due to the high pressure.The direct relationship between the depth of an axial defect and the stress concentration is observed at the inner side edges of the defect.Composite reparation reduces the non-linearities related to the sharp variation of the geometry and a more reliable numerical simulation could be performed.

CO_(2)high-pressure miscible flooding and storage technology and its application in Shengli Oilfield,China

There are various issues for CO_(2)flooding and storage in Shengli Oilfield,which are characterized by low light hydrocarbon content of oil and high miscible pressure,strong reservoir heterogeneity and low sweep efficiency,gas channeling and difficult whole-process control.Through laboratory experiments,technical research and field practice,the theory and technology of CO_(2)high pressure miscible flooding and storage are established.By increasing the formation pressure to 1.2 times the minimum miscible pressure,the miscibility of the medium-heavy components can be improved,the production percentage of oil in small pores can be increased,the displacing front developed evenly,and the swept volume expanded.Rapid high-pressure miscibility is realized through advanced pressure flooding and energy replenishment,and technologies of cascade water-alternating-gas(WAG),injection and production coupling and multistage chemical plugging are used for dynamic control of flow resistance,so as to obtain the optimum of oil recovery and CO_(2)storage factor.The research results have been applied to the Gao89-Fan142 in carbon capture,utilization and storage(CCUS)demonstration site,where the daily oil production of the block has increased from 254.6 t to 358.2 t,and the recovery degree is expected to increase by 11.6 percentage points in 15 years,providing theoretical and technical support for the large-scale development of CCUS.

Novel Methodologies for Preventing Crack Propagation in Steel Gas Pipelines Considering the Temperature Effect

Using the software ANSYS-19.2/Explicit Dynamics,this study performedfinite-element modeling of the large-diameter steel pipeline cross-section for the Beineu-Bozoy-Shymkent gas pipeline with a non-through straight crack,strengthened by steel wire wrapping.The effects of the thread tensile force of the steel winding in the form of single rings at the crack edges and the wires with different winding diameters and pitches were also studied.The results showed that the strengthening was preferably executed at a minimum value of the thread tensile force,which was 6.4%more effective than that at its maximum value.The analysis of the influence of the winding dia-meters showed that the equivalent stresses increased by 32%from the beginning of the crack growth until the wire broke.The increment in winding diameter decelerated the disclosure of the edge crack and reduced its length by 8.2%.The analysis of the influence of the winding pitch showed that decreasing the distance between the winding turns also led to a 33.6%reduction in the length of the straight crack and a 7.9%reduction in the maximum stres-ses on the strengthened pipeline cross-section.The analysis of the temperature effect on the pipeline material,within a range from-40℃ to+50℃,resulted in a crack length change of up to 5.8%.As the temperature dropped,the crack length decreased.Within such a temperature range,the maximum stresses were observed along the cen-tral area of the crack,which were equal to 413 MPa at+50℃ and 440 MPa at-40℃.The results also showed that the presence of the steel winding in the pipeline significantly reduced the length of crack propagation up to 8.4 times,depending on the temperature effect and design parameters of prestressing.This work integrated the existing methods for crack localization along steel gas pipelines.

Mutual regulation of microglia and astrocytes after Gas6 inhibits spinal cord injury

Invasive inflammation and excessive scar formation are the main reasons for the difficulty in repairing nervous tissue after spinal cord injury.Microglia and astrocytes play key roles in the spinal cord injury micro-environment and share a close interaction.However,the mechanisms involved remain unclear.In this study,we found that after spinal cord injury,resting microglia(M0)were polarized into pro-inflammatory phenotypes(MG1 and MG3),while resting astrocytes were polarized into reactive and scar-forming phenotypes.The expression of growth arrest-specific 6(Gas6)and its receptor Axl were significantly down-regulated in microglia and astrocytes after spinal cord injury.In vitro experiments showed that Gas6 had negative effects on the polarization of reactive astrocytes and pro-inflammatory microglia,and even inhibited the cross-regulation between them.We further demonstrated that Gas6 can inhibit the polarization of reactive astrocytes by suppressing the activation of the Yes-associated protein signaling pathway.This,in turn,inhibited the polarization of pro-inflammatory microglia by suppressing the activation of the nuclear factor-κB/p65 and Janus kinase/signal transducer and activator of transcription signaling pathways.In vivo experiments showed that Gas6 inhibited the polarization of pro-inflammatory microglia and reactive astrocytes in the injured spinal cord,thereby promoting tissue repair and motor function recovery.Overall,Gas6 may play a role in the treatment of spinal cord injury.It can inhibit the inflammatory pathway of microglia and polarization of astrocytes,attenuate the interaction between microglia and astrocytes in the inflammatory microenvironment,and thereby alleviate local inflammation and reduce scar formation in the spinal cord.

Mesenteric ischemia with intrasplenic gas:A case report

BACKGROUND Acute mesenteric ischemia is a life-threatening disease.Intrasplenic gas is an extremely rare finding in such cases.CASE SUMMARY We report a case of a 79-year-old woman with a history of end-stage renal disease on hemodialysis for approximately 20 years,type 2 diabetes mellitus,and atrial fibrillation who presented with two days of epigastric pain.A computed tomography scan of the abdomen revealed intraperitoneal free air and significant intrasplenic gas.Laparoscopy revealed diffuse intestinal gangrene,and acute superior mesenteric ischemia was diagnosed.The patient died within 24 hours owing to profound shock.CONCLUSION Intrasplenic gas is an extremely rare finding on computed tomography imaging in cases of acute mesenteric ischemia.

Effects of Instantaneous High-pressure on Denaturalization of β-Lactoglobulin

[ Objective] The study aimed to explore the denaturalization law of β-Iactoglobulin （β-LG） under instantaneous high-pressure（IHP） con- dition. [Methed] Using fresh milk as testing material, effects of pressure, feed temperature and treatment time on the denaturalization of β-LG were studied via SDS-PAGE electrophoresis and sulfhydryl content detection after IHP treatment. [ Result] IHP could induce the agglomeration and depo- lymerization Of β-LG. The agglomeration of the β-LG increased with the elevated pressure from 20 to 60 MPa, but 80 MPa pressure led to depolyme- rization. The effect of feed temperature （25 -45 ℃） was similar to that of the pressure, while the influence of treatment time （2 -8 min） was not obvious. [ Conclusion] The study provided a theoretical basis for the elimination of allergens in β-LG and the application of IHP technology in milk treatment.

Tectonic Evolution of an Early Precambrian High-Pressure Granulite Belt in the North China Craton

A large-scale high-pressure granulite belt (HPGB), more than 700 km long, is recognized within the metamorphic basement of the North China craton. In the regional tectonic framework, the Hengshan-Chengde HPGB is located in the central collision belt between the western block and eastern block, and represents the deep crustal structural level. The typical high-pressure granulite (HPG) outcrops are distributed in the Hengshan and Chengde areas. HPGs commonly occur as mafic xenoliths within ductile shear zones, and underwent multipile deformations. To the south, the Hengshan-Chengde HPGB is juxtaposed with the Wutai greenstone belt by several strike-slip shear zones. Preliminary isotopic age dating indicates that HPGs from North China were mainly generated at the end of the Neoarchaean, assocaited with tectonic assembly of the western and eastern blocks.

Effect of high-pressure homogenization on stability of emulsions containing zein and pectin

The aim of this study was to investigate the effect of high-pressure homogenization on the droplet size and physical stability of different formulations of pectin–zein stabilized rice bran oil emulsions. The obtained emulsions, both before and after passing through highpressure homogenizer, were subjected to stability test under environmental stress conditions,that is, temperature cycling at 4 °C/40 °C for 6 cycles and centrifugal test at 3000 rpm for 10 min. Applying high-pressure homogenization after mechanical homogenization caused only a small additional decrease in emulsion droplet size. The droplet size of emulsions was influenced by the type of pectin used;emulsions using high methoxy pectin(HMP) were smaller than that using low methoxy pectin(LMP). This is due to a greater emulsifying property of HMP than LMP. The emulsions stabilized by HMP–zein showed good physical stability with lower percent creaming index than those using LMP, both before and after passing through high-pressure homogenizer. The stability of emulsions after passing through high-pressure homogenizer was slightly higher when using higher zein concentration, resulting from stronger pectin–zein complexes that could rearrange and adsorb onto the emulsion droplets.

Protolith ages and timing of peak and retrograde metamorphism of the high-pressure granulites in the Shandong Peninsula,eastern North China Craton

High-pressure （HP） granulites widely occur as enclaves within tonalite-trondhjemite- granodiorite （TTG） gneisses of the Early Precambrian metamorphic basement in the Shandong Peninsula, southeast part of the North China Craton （NCC）. Based on cathodoluminescence （CL）, laser Raman spec- troscopy and in-situ U-Pb dating, we characterize the zircons from the HP granulites and group them into three main types： inherited （magmatic） zircon, HP metamorphic zircon and retrograde zircon. The inher- ited zircons with clear or weakly defined magmatic zoning contain inclusions of apatites, and 207pb/206pb ages of 2915--2890 Ma and 2763--2510 Ma, correlating with two magmatic events in the Archaean base- ment. The homogeneous HP metamorphic zircons contain index minerals of high-pressure metamor- phism including garnet, clinopyroxene, plagioclase, quartz, rutile and apatite, and yield 207pb/2066pb ages between 1900 and 1850 Ma, marking the timing of peak HP granulite facies metamorphism. The retrograde zircons contain inclusions of orthopyroxene, plagioclase, quartz, apatite and amphibole, and yield the youngest 207pb/206pb ages of 1840-1820 Ma among the three groups, which we correlate to the medium to low-pressure granulite facies retrograde metamorphism. The data presented in this study suggest subduction of Meso- and Neoarchean magmatic protoliths to lower crust depths where they were subjected to HP granulite facies metamorphism during Palaeoproterozoic （1900-1850 Ma）. Subse- quently, the HP granulites were exhumated to upper crust levels, and were ovel-printed by medium to low-pressure granulite and amphibolite facies retrograde event at ca. 1840--820 Ma.

Mechanisms and capacity of high-pressure soaking after hydraulic fracturing in tight/shale oil reservoirs

Huff-n-puff by water has been conducted to enhance oil recovery after hydraulic fracturing in tight/shale oil reservoirs.However,the mechanisms and capacity are still unclear,which significantly limits the application of this technique.In order to figure out the mechanisms,the whole process of pressurizing,high-pressure soaking,and depressurizing was firstly discussed,and a mechanistic model was established.Subsequently,the simulation model was verified and employed to investigate the significances of high-pressure soaking,the contributions of different mechanisms,and the sensitivity analysis in different scenarios.The results show that high-pressure soaking plays an essential role in oil production by both imbibition and elasticity after hydraulic fracturing.The contribution of imbibition increases as the increase in bottom hole pressure(BHP),interfacial tension,and specific surface area,but slightly decreases as the oil viscosity increases.In addition,it first decreases and then slightly increases with the increase in matrix permeability.The optimal soaking time is linear with the increases of both oil viscosity and BHP and logarithmically declines with the increase in matrix permeability and specific surface area.Moreover,it shows a rising tendency as the interficial tension(IFT)increases.Overall,a general model was achieved to calculate the optimal soaking time.

In situ experimental study on TBM excavation with high-pressure water-jet-assisted rock breaking

China’s first high-pressure hydraulically coupled rock-breaking tunnel boring machine(TBM) was designed to overcome the rock breaking problems of TBM in super-hard rock geology, where high-pressure water jet system is configured, including high-flow pump sets, high-pressure rotary joint and high-pressure water jet injection device. In order to investigate the rock breaking performance of high-pressure water-jet-assisted TBM, in situ excavation tests were carried out at the Wan’anxi Water Diversion Project in Longyan, Fujian Province, China, under different water jet pressure and rotational speed. The rock-breaking performance of TBM was analyzed including penetration, cutterhead load, advance rate and field penetration index. The test results show that the adoption of high-pressure water-jet-assisted rock breaking technology can improve the boreability of rock mass, where the TBM penetration increases by 64% under the water jet pressure of 270 MPa. In addition, with the increase of the water jet pressure, the TBM penetration increases and the field penetration index decreases. The auxiliary rock-breaking effect of high-pressure water jet decreases with the increase of cutterhead rotational speed. In the case of the in situ tunneling test parameters of this study, the advance rate is the maximum when the pressure of the high-pressure water jet is 270 MPa and the cutterhead rotational speed is 6 r/min. The technical superiority of high-pressure water-jet-assisted rock breaking technology is highlighted and it provides guidance for the excavation parameter selection of high-pressure hydraulically coupled rock-breaking TBM.