Design of high-temperature superconductors at moderate pressures by alloying AlH3 or GaH3

Since the discovery of hydride superconductors,a significant challenge has been to reduce the pressure required for their stabilization.In this context,we propose that alloying could be an effective strategy to achieve this.We focus on a series of alloyed hydrides with the AMH_(6)composition,which can be made via alloying A15 AH_(3)(A=Al or Ga)with M(M=a group IIIB or IVB metal),and study their behavior under pressure.Seven of them are predicted to maintain the A15-type structure,similar to AH_(3)under pressure,providing a platform for studying the effects of alloying on the stability and superconductivity of AH_(3).Among these,the A15-type phases of AlZrH_(6)and AlHfH_(6)are found to be thermodynamically stable in the pressure ranges of 40–150 and 30–181 GPa,respectively.Furthermore,they remain dynamically stable at even lower pressures,as low as 13 GPa for AlZrH_(6)and 6 GPa for AlHfH_(6).These pressures are significantly lower than that required for stabilizing A15 AlH3.Additionally,the introduction of Zr or Hf increases the electronic density of states at the Fermi level compared with AlH3.This enhancement leads to higher critical temperatures(Tc)of 75 and 76 K for AlZrH_(6)and AlHfH_(6)at 20 and 10 GPa,respectively.In the case of GaMH_(6)alloys,where M represents Sc,Ti,Zr,or Hf,these metals reinforce the stability of the A15-type structure and reduce the lowest thermodynamically stable pressure for GaH_(3) from 160 GPa to 116,95,80,and 85 GPa,respectively.Particularly noteworthy are the A15-type GaMH_(6)alloys,which remain dynamically stable at low pressures of 97,28,5,and 6 GPa,simultaneously exhibiting high Tc of 88,39,70,and 49 K at 100,35,10,and 10 GPa,respectively.Overall,these findings enrich the family of A15-type superconductors and provide insights for the future exploration of high-temperature hydride superconductors that can be stabilized at lower pressures.

Study of High-Temperature Superconductor Diplexers for Satellite Communications

The high-temperature superconductor （HTSC） resonator and diplexer are simulated by full-wave tools. A newly developed miniature HTSC diplexer is designed and fabricated on double sided YBa2Cu3O7 （YBCO） film （YBCO/LaAlO3/YBCO）, the thickness of which is 400 nm for YBCO and 0.5 mm for the LaAlO3. The measured results show a good agreement with the simulation. The volume and mass of the diplexers are greatly reduced by miniaturized configuration.

Angular dependence of vertical force and torque when magnetic dipole moves vertically above flat high-temperature superconductor

The interaction between a permanent magnet(PM)assumed as a magnetic dipole and a flat high-temperature superconductor(HTS)is calculated by the advanced frozen-image model.When the dipole vertically moves above the semiinfinite HTS,the general analytical expression of vertical force and that of torque are obtained for an arbitrary angle between the magnetization direction of the PM and the c axis of the HTS.The variations of the force and torque are analyzed for angle and vertical movements in both zero-field cooling(ZFC)condition and field cooling(FC)condition.It is found that the maximum vertical repulsive or attractive force has the positive or negative cosine relation with the angle.However,the maximum torque has the positive or negative sine relation.From the viewpoint of the rotational equilibrium,the orientation of the magnetic dipole with zero angle is deemed to be an unstable equilibrium point in ZFC,but the same orientation is considered as a stable equilibrium point in FC.In addition,both of the variation cycles of the maximum force and torque with the angle areπ.

Lateral magnetic stiffness under different parameters in a high-temperature superconductor levitation system

Magnetic stiffness determines the stability of a high-temperature superconductor(HTS)magnetic levitation system.The quantitative properties of the physical and geometrical parameters that affect the stiffness of HTS levitation systems should be identified for improving the stiffness by some effective methods.The magnetic stiffness is directly related to the first-order derivative of the magnetic force with respect to the corresponding displacement,which indicates that the effects of the parameters on the stiffness should be different from the relationships between the forces and the same parameters.In this paper,we study the influences of some physical and geometrical parameters,including the strength of the external magnetic field(B0)produced by a rectangular permanent magnet(PM),critical current density(Jc),the PM-to-HTS area ratio(α),and thickness ratio(β),on the lateral stiffness by using a numerical approach under zero-field cooling(ZFC)and field cooling(FC)conditions.In the first and second passes of the PM,the lateral stiffness at most of lateral positions essentially increases with B0 increasing and decreases withβincreasing in ZFC and FC.The largest lateral stiffness at every lateral position is almost produced by the minimum value of Jc,which is obviously different from the lateral force–Jc relation.Theα-dependent lateral stiffness changes with some parameters,which include the cooling conditions of the bulk HTS,lateral displacement,and movement history of the PM.These findings can provide some suggestions for improving the lateral stiffness of the HTS levitation system.

Comparative Study of 10-MW High-Temperature Superconductor Wind Generator with Overlapped Field Coil Arrangement

The electromagnetic characteristics and iron loss of a high-temperature superconductor wind generator(HWG)equipped with an overlapped field coil arrangement(OFCA)are studied by comparing with the one equipped with the conventional field coil arrangement(CFCA).Through a quantitative analysis,it was found that HWG with OFCA exhibits better electromagnetic characteristics than HWG with CFCA and can reduce the iron loss by eliminating the magnetic flux sag caused by the adjacent field coil sides with the same current flow direction.In addition,the OFCA topology can further reduce the volume of the wind generator.

Magnetic levitation performance of high-temperature superconductor over three magnetic hills of permanent magnet guideway with iron shims of different thicknesses

Superconducting magnetic levitation performance, including levitation force and guidance force, is important for the application of high-temperature super- conducting maglev. Both of them are not only affected by different arrays of superconductors and magnets, but also by the thickness of the iron shim between permanent magnets. In order to obtain the best levitation performance, the magnetic field distribution, levitation force, and guidance force of a new type of three magnetic hills of permanent magnet guideway with iron shim of different thicknesses （4, 6, and 8 mm） are discussed in this paper. Simulation analysis and experiment results show that the guideway with iron shim of 8 mm thickness possesses the strongest magnetic field and levitation performance when the suspension gap is larger than 10 mm. However, with the decreasing of suspension gap, the guideway with iron shim of 4 mm thickness possesses the best levitation performance. The phenomena can be attributed to the density distribution of flux and magnetization of iron shim.

Theory-orientated discovery of high-temperature superconductors in superhydrides stabilized under high pressure

A dream long held by physicists has been to raise the critical temperature(Tc)—the temperature below which the material exhibits no electrical resistance—of a superconductor to room temperature.The most recent excitement in that regard has centered on rare-earth superhydrides,of which LaH10 at 190 GPa has a remarkably high Tc of 260 K.

COMPOSITIONAL ANALYSIS OF HIGH-TEMPERATURE SUPERCONDUCTOR THIN FILMS BY HIGH ENERGY ELASTIC BACKSCATTERING OF HELIUM IONS

High energy ion backscattering can be used to enhance the sensitivity of oxygen analysis. At He++ ion energy of 8.8 MeV, the yield due to oxygen is about 25 times larger than that predicted by Rutherford formula. The elemental stoichiometry of some bulk and thin film superconductor samples was determined. The details of the measuring method are discribed.

Optimization of intergrain connection in high-temperature superconductor Bi_2Sr_2CaCu_2O_x

A modified spark plasma sintering（SPS） technique was developed for the fabrication of Bi2Sr2CaCu2Ox（Bi-2212）superconducting bulks with better intergrain connections. The influences of the modified SPS process on the microstructures, intergrain connections, and related superconducting properties were systematically analyzed. The modified SPS process can not only increase the final density of the bulk samples but also enhance the texture structures. Clean grain boundaries were obtained instead of the intergrain amorphous layers. Therefore the intergranular properties were obviously improved. Due to the better intergrain connections and the stronger flux pinning properties, the critical current densities of the Bi-2212 bulks obtained via the modified SPS process were greatly increased. The obtained improvements imply the possibility for the modified SPS technique to be used for enhancing the superconducting properties of the Bi-2212 tapes.

Effects of Flux Creep on the Magnetization Curves of High-Temperature Superconductors

The effects of flux creep on the magnetization curves of high-temperature superconductors are investigated numerically for Anderson-Kim model.The pinning energy at zero current density,U_(c),greatly influences the flux penetration process,a larger U_(c),value reults in a larger penetration field.The characteristic of the magnetization curve is also a function of U_(c).The magnetization M and ΔM increase with the increasing U_(c) and depend on the magnetic induction B,so the critical current formula based on Bean model is pot accurate,especially for high-T_(c) superconductor,for which flux creep is a large effect.

Critical Temperature Characteristics of Layered High-Temperature Superconductor Under Pressure

We consider a Ginzburg-Landau modified model of layered high-temperature superconductor under pressure. We have theoretically studied the relation between the pressure and the temperature of layered high-temperature superconductor. If the pressure is not a constant, we have a relation of quadratic equation between the pressure and the temperature of layered high-temperature superconductor. In a special case, we find the critical temperature decreases with further increasing pressure. In another special ease, the critical temperature increases with further increasing pressure.

High-Temperature Superconductors

1987: First BreakthroughsIn 1911, Dutch physicist Heike Kamerlingh Onnes found that some certain materials could become a "perfect conductor" in the presence of extremely low temperatures: the electrical resistance disappeared, and meanwhile the magnetic flux fields got totally expelled from the interior of the material. Such a phenomenon was later named superconductivity, and such materials termed superconductors.

Development of metal-organic deposition-derived second-generation high-temperature superconductor tapes and artificial flux pinning

The second-generation high-temperature superconductor tape(2G-HTS,also known as a coated conductor)based on REBaCuO(REBa_(2)Cu_(3)O_(7-δ))exhibits high current density and potential cost-effective price/performance,compared with conventional superconducting materials.Using commercial 2G-HTS tapes,more than a dozen cable vendors had been manufacturing REBCO cables,such as the latest kilometer-class REBCO cable,which was incorporated into a civil grid on December 2021,as part of the recordbreaking 35-kV-voltage superconductor cable demonstration project in downtown Shanghai.This paper describes the development of HTS-coated conductors,then outlines the various technological routes for their preparation,reviews the artificial flux pinning of coated conductors,and finally summarizes the technological breakthroughs,the latest research advances,and provides an outlook on their application prospects.

Harness High-Temperature Thermal Energy via Elastic Thermoelectric Aerogels

Despite notable progress in thermoelectric(TE)materials and devices,developing TE aerogels with high-temperature resistance,superior TE performance and excellent elasticity to enable self-powered high-temperature monitoring/warning in industrial and wearable applications remains a great challenge.Herein,a highly elastic,flame-retardant and high-temperature-resistant TE aerogel,made of poly(3,4-ethylene dioxythiophene):poly(styrenesulfonate)/single-walled carbon nanotube(PEDOT:PSS/SWCNT)composites,has been fabricated,displaying attractive compression-induced power factor enhancement.The as-fabricated sensors with the aerogel can achieve accurately pressure stimuli detection and wide temperature range monitoring.Subsequently,a flexible TE generator is assembled,consisting of 25 aerogels connected in series,capable of delivering a maximum output power of 400μW when subjected to a temperature difference of 300 K.This demonstrates its outstanding high-temperature heat harvesting capability and promising application prospects for real-time temperature monitoring on industrial high-temperature pipelines.Moreover,the designed self-powered wearable sensing glove can realize precise wide-range temperature detection,high-temperature warning and accurate recognition of human hand gestures.The aerogel-based intelligent wearable sensing system developed for firefighters demonstrates the desired self-powered and highly sensitive high-temperature fire warning capability.Benefitting from these desirable properties,the elastic and high-temperature-resistant aerogels present various promising applications including self-powered high-temperature monitoring,industrial overheat warning,waste heat energy recycling and even wearable healthcare.

Enhanced High-Temperature Energy Storage Performance of All-Organic Composite Dielectric via Constructing Fiber-Re in forced Structure

Optimizing the high-temperature energy storage characteristics of energy storage dielectrics is of great significance for the development of pulsed power devices and power control systems.Selecting a polymer with a higher glass transition temperature(T_(g))as the matrix is one of the effective ways to increase the upper limit of the polymer operating temperature.However,current high-T_(g)polymers have limitations,and it is difficult to meet the demand for high-temperature energy storage dielectrics with only one polymer.For example,polyetherimide has high-energy storage efficiency,but low breakdown strength at high temperatures.Polyimide has high corona resistance,but low high-temperature energy storage efficiency.In this work,combining the advantages of two polymer,a novel high-T_(g)polymer fiber-reinforced microstructure is designed.Polyimide is designed as extremely fine fibers distributed in the composite dielectric,which will facilitate the reduction of high-temperature conductivity loss for polyimide.At the same time,due to the high-temperature resistance and corona resistance of polyimide,the high-temperature breakdown strength of the composite dielectric is enhanced.After the polyimide content with the best high-temperature energy storage characteristics is determined,molecular semiconductors(ITIC)are blended into the polyimide fibers to further improve the high-temperature efficiency.Ultimately,excellent high-temperature energy storage properties are obtained.The 0.25 vol%ITIC-polyimide/polyetherimide composite exhibits high-energy density and high discharge efficiency at 150℃(2.9 J cm^(-3),90%)and 180℃(2.16 J cm^(-3),90%).This work provides a scalable design idea for high-performance all-organic high-temperature energy storage dielectrics.

TiN/Fe_(2)N/C composite with stable and broadband high-temperature microwave absorption

Facing the complex variable high-temperature environment,electromagnetic wave(EMW)absorbing materials maintaining high stability and satisfying absorbing properties is essential.This study focused on the synthesis and EMW absorbing performance evaluation of TiN/Fe_(2)N/C composite materials,which were prepared using electrostatic spinning followed by a high-temperature nitridation process.The TiN/Fe_(2)N/C fibers constructed a well-developed conductive network that generates considerable conduction loss.The heterogeneous interfaces between different components generated a significant level of interfacial polarization.Thanks to the synergistic effect of stable dielectric loss and optimized impedance matching,the TiN/Fe_(2)N/C composite materials demonstrated excellent and stable absorption performance across a wide temperature range(293-453 K).Moreover,TiN/Fe_(2)N/C-15 achieved a minimum reflection loss(RL)of−48.01 dB and an effective absorption bandwidth(EAB)of 3.64 GHz at 2.1 mm and 373 K.This work provides new insights into the development of high-efficiency and stabile EMW absorbing materials under complex variable high-temperature conditions.

High-Temperature Phonon-Mediated Superconductivity with T_(c) above 100K in Monolayer Na(BC)_(2) and K(BC)_(2)

Two-dimensional(2D)materials have demonstrated promising prospects owing to their distinctive electronic properties and exceptional mechanical properties.Among them,2D superconductors with T_(c) above the boiling point of liquid nitrogen(77 K)will exhibit tremendous applicable value in the future.Here,we design two 2D superconductors Na(BC)_(2) and K(BC)_(2) with MgB2-like structures,which are theoretically predicted to host T_(c) as high as 99 and 102 K,respectively.The origin of such high T_(c) is ascribed to the presence of both𝜎-bonding bands and van Hove singularity at the Fermi level.Furthermore,T_(c) of Na(BC)_(2) is boosted up to 153K with a biaxial strain of 5%,which sets a new record among 2D superconductors.The predictions of Na(BC)_(2) and K(BC)_(2) open the door to explore 2D high-temperature superconductors and provide a potential future for developing new applications in 2D materials.

HZSM-5 zeolites undergoing the high-temperature process for boosting the bimolecular reaction in n-heptane catalytic cracking

High-temperature treatment is key to the preparation of zeolite catalysts.Herein,the effects of hightemperature treatment on the property and performance of HZSM-5 zeolites were studied in this work.X-Ray diffraction,N2physisorption,27Al magic angle spinning nuclear magnetic resonance(MAS NMR),and temperature-programmed desorption of ammonia results indicated that the hightemperature treatment at 650℃ hardly affected the inherent crystal and texture of HZSM-5zeolites but facilitated the conversion of framework Al to extra-framework Al,reducing the acid site and enhancing the acid strength.Moreover,the high-temperature treatment improved the performance of HZSM-5 zeolites in n-heptane catalytic cracking,promoting the conversion and light olefins yield while inhibiting coke formation.Based on the kinetic and mechanism analysis,the improvement of HZSM-5 performance caused by high-temperature treatment has been attributed to the formation of extra-framework Al,which enhanced the acid strength,facilitated the bimolecular reaction,and promoted the entropy change to overcome a higher energy barrier in n-heptane catalytic cracking.

Synergistic effect of Zr and Mo on precipitation and high-temperature properties of Al-Si-Cu-Mg alloys

This study focuses on finding a solution to the sharp decline in mechanical properties of Al-Si-Cu-Mg alloys due to rapid coarsening of traditional intermediate phases at high temperature.A new type of modified al oy,to be used in automobile engines at high temperatures,was prepared by adding Zr and Mo into Al-Si-Cu-Mg alloy.The synergistic effects of Zr and Mo on the microstructure evolution and high-temperature mechanical properties were studied.Results show that the addition of Zr and Mo generates a series of intermetallic phases dispersed in the alloy.They can improve the strength of the alloy by hindering dislocation movement and crack propagation.In addition,some nano-strengthened phases show coherent interfaces with the matrix and improve grain refinement.The addition of Mo greatly improves the heat resistance of the alloy.The extremely low diffusivity of Mo enables it to improve the thermal stability of the intermetallic phases,inhibit precipitation during aging,reduce the size of the precipitates,and improve the heat resistance of the alloy.

Electromagnetic modelling using T-A formulation for high-temperature superconductor (RE)Ba2Cu3Ox high field magnets

Second generation(2G)high-temperature superconductor(HTS)(RE)Ba2Cu3Ox(REBCO)shows a great potential in building high field magnets beyond 23.5 T.The electromagnetic modelling is vital for the design of HTS magnet,however,this always suffers the challenge of huge computation for high field magnets with large number of turns.This study presents a novel electromagnetic modelling based on T-A formulation for REBCO magnets with thousands of turns.An equivalent turn method is proposed to reduce the number of turns in calculation,so that the computation cost can be reduced significantly,and meanwhile the key electromagnetic behaviour of HTS magnet can be simulated with enough accuracy.The ramping operation of a fully HTS magnet with 12,000 turns are analysed using both the original T-A model with actual turns and improved T-A model with equivalent turns.The two models show a good agreement on the key electromagnetic behaviours of the magnet:distribution of current density,magnetic fields,screen current induced field and magnetisation loss,so that this improved T-A model using equivalent turns is validated.The T-A modelling of REBCO magnet is a powerful tool for the electromagnetic analysis of industry-scale high field magnets.