A high-temperature reduction roasting method was used to achieve metallic iron and zinc recovery from blast furnace gas ash(BFA).The reduction processes for Zn-containing and Fe-containing oxides were analyzed in deta...A high-temperature reduction roasting method was used to achieve metallic iron and zinc recovery from blast furnace gas ash(BFA).The reduction processes for Zn-containing and Fe-containing oxides were analyzed in detail by using ther-modynamic equilibrium calculation and the principle of minimum free energy.The results showed that the main reaction in the system is the reduction of ZnFe_(2)_(4)and iron oxides.Over the full temperature range,iron oxides were more easily reduced than zinc oxides.Regardless of the amount of CO contained in the system,the reduction of ZnO to Zn was difficult to proceed below the boiling point(906℃)of Zn.When the reduction temperature is below 906℃,the reduction process of zinc ferrate was ZnFe_(2)_(4)→ZnO;when the reduction temperature is above 906℃,its reduction process becomed ZnFe_(2)_(4)→ZnO→Zn(g).The metallization and dezincification rates of the BFA gradually increased with increasing reaction temperature.As the C/O ratio increased,the metallization and dezincification rates first increased and then decreased.The effect of reduction time on BFA reduction was similar to that of reaction temperature.展开更多
By analyzing recent development of reheating furnace in Shougang,the direction of rolling reheating furnace is large type,high efficiency,lower pollution and automation etc.Many advanced technologies are integrated in...By analyzing recent development of reheating furnace in Shougang,the direction of rolling reheating furnace is large type,high efficiency,lower pollution and automation etc.Many advanced technologies are integrated in new rolling reheating furnace such as working beam,regenerative combustion,evaporation cooling and hot loading and hot feeding etc.It shows that reheating furnace technology is upgraded.During the process of product structure adjustment in Shougang,because product heating quality is improved,energy-saving of reheating furnace should pay attention to aspects such as energy-saving of heating variety steel,equality of heating steel,heating system,oxidation loss and so on.This will offer reference for energy-saving of domestic and overseas reheating furnace technology.展开更多
1 Scope This standard specifies the classification, technical requirements, test methods, quality appraisal procedures, packing, marking, transportation, storage and quality certificate of castables for steel rolling...1 Scope This standard specifies the classification, technical requirements, test methods, quality appraisal procedures, packing, marking, transportation, storage and quality certificate of castables for steel rolling reheating furnace.展开更多
High-temperature performance tests of chromium-containing stuffing sand for a steel ladle w ith different ratios w ere performed. A high-temperature simulation test furnace w as used to analyze the influence of the co...High-temperature performance tests of chromium-containing stuffing sand for a steel ladle w ith different ratios w ere performed. A high-temperature simulation test furnace w as used to analyze the influence of the composition ratio of ladle filler sand and sintering time on the high-temperature compression resistance of chromium-containing stuffing sand in the temperature range of 1 500- 1 600 ℃. The results show that the refractoriness of ladle filler sand w as the low est( only 1 610 ℃) w hen the composition ratio of chromite sand and silica sand w as 6∶ 4. M oreover,the high-temperature compression resistance w as high w hen the content of chromite sand w as at 70%; the resistance increased w ith increasing sintering time. When the sintering time w as extended at a temperature of 1 600 ℃,the high-temperature compression resistance of ladle filler sand first increased and then decreased after being overburnt.展开更多
针对棒线材的免加热直接轧制技术将铸坯从连铸机直接运输到轧机进行轧制,可完全取消传统加热炉,实现节能减排的目标。与传统棒线材轧制工艺相比,直轧率偏低是影响免加热直接轧制技术推广的因素之一。提出了一种新送钢控制模型,依据现场...针对棒线材的免加热直接轧制技术将铸坯从连铸机直接运输到轧机进行轧制,可完全取消传统加热炉,实现节能减排的目标。与传统棒线材轧制工艺相比,直轧率偏低是影响免加热直接轧制技术推广的因素之一。提出了一种新送钢控制模型,依据现场实际生产工艺参数,研究对比了先进先出模型(first in first out, FIFO)和所提控制模型的运行效果。结果显示,在四机四流连接一条轧线下,采用FIFO控制模型的直轧率为88.7%,与实测直轧率吻合较好,而采用所提控制模型可将直轧率提高到94.3%。同时还模拟研究了两种模型在五机五流连接一条轧线下的直轧率,结果显示使用FIFO控制模型、所提控制模型的直轧率分别为74.3%和81.7%。通过结果对比发现,送钢控制因素直接影响直轧率。另外,连铸机流数与轧机能力的匹配程度也是影响直轧率的重要因素之一。展开更多
Accurate control of slab temperature and heating rate is an important significance to improve product performance and reduce carbon emissions for steel rolling reheating furnace(SRRF).Firstly,a spatial temporal distri...Accurate control of slab temperature and heating rate is an important significance to improve product performance and reduce carbon emissions for steel rolling reheating furnace(SRRF).Firstly,a spatial temporal distributed-nonlinear autoregressive with exogenous inputs correlation model(STD-NARXCM)to spatial temporal distributed-autoregressive with exogenous inputs correlation model(STD-ARXCM)in working point is established.Secondly,a new coordinated time-sharing control architecture in different time periods is proposed,which is along the length of the SRRF to improve the control performance.Thirdly,a hybrid control algorithm of expert-fuzzy is proposed to improve the dynamic of the temperature and the heating rate during time period 0 to t_(1).A hybrid control algorithm of expert-fuzzy-PID is proposed to enhance the control accuracy and the heating rate during time period t_(1) to t_(2).A hybrid control algorithm of expert-active disturbance rejection control(ADRC)is proposed to boost the anti-interference and the heating rate during time period t_(2) to t_(3).Finally,the experimental results show that the coordinated time-sharing algorithm can meet the process requirements,the maximum deviation of temperature value is 8-13.5℃.展开更多
The flow characteristics of high-temperature flue gas are important in the heat transfer of coal-water slurry(CWS) combustion furnaces.The flow field of a 250 kg/h vertical-type slag tap cyclone furnace was non-intr...The flow characteristics of high-temperature flue gas are important in the heat transfer of coal-water slurry(CWS) combustion furnaces.The flow field of a 250 kg/h vertical-type slag tap cyclone furnace was non-intrusively investigated,using two-dimensional particle-image velocimetry(2D PIV).The method was verified using traceable fly ash particles in high-temperature flue gas.The flow field of the flue gas was analyzed with a time-averaged method,based on which the effects of excess air ratio and loading were investigated.The flue gas separated by a gas separator maintained good rigidity near the furnace wall,rather than eroding the heating surface.Numerical simulations validated the reliability of PIV under the actual circumstances within the furnace.This study provides guidelines for applying 2D PIV in analyzing flue gas in thermal test boilers.展开更多
The oxidation behavior and mechanism of as-received and 30 % cold-rolled alumina-forming austenitic(AFA) steel were investigated in dry air at 700℃.The results show that the mass gain per unit area curves of as-recei...The oxidation behavior and mechanism of as-received and 30 % cold-rolled alumina-forming austenitic(AFA) steel were investigated in dry air at 700℃.The results show that the mass gain per unit area curves of as-received and 30 % cold-rolled steels subject to near-parabolic law before 100 h oxidation time.Two samples both show higher high-temperature oxidation resistance due to the formation of dense Al_(2)O_(3) oxide scale.Gradual spallation of outer scale results in the formation of continuous and dense alumina scale.Dislocations can act as short-circuit diffusion channel for the diffusion of Al from alloy matrix to surface,and also provide nucleation sites for B2-NiAl phase,which ensure the continuous formation of Al_(2)O_(3) scale.展开更多
基金This work was supported by the National Natural Science Foundation of China(Grant No.51704021)Key Research and Development Projects of Sichuan Province(021YFG0114)+1 种基金Key Research and Development Projects of Shandong Province(2021CXGC010209)the Joint Funds of the National Natural Science Foundation of China(U1560203).
文摘A high-temperature reduction roasting method was used to achieve metallic iron and zinc recovery from blast furnace gas ash(BFA).The reduction processes for Zn-containing and Fe-containing oxides were analyzed in detail by using ther-modynamic equilibrium calculation and the principle of minimum free energy.The results showed that the main reaction in the system is the reduction of ZnFe_(2)_(4)and iron oxides.Over the full temperature range,iron oxides were more easily reduced than zinc oxides.Regardless of the amount of CO contained in the system,the reduction of ZnO to Zn was difficult to proceed below the boiling point(906℃)of Zn.When the reduction temperature is below 906℃,the reduction process of zinc ferrate was ZnFe_(2)_(4)→ZnO;when the reduction temperature is above 906℃,its reduction process becomed ZnFe_(2)_(4)→ZnO→Zn(g).The metallization and dezincification rates of the BFA gradually increased with increasing reaction temperature.As the C/O ratio increased,the metallization and dezincification rates first increased and then decreased.The effect of reduction time on BFA reduction was similar to that of reaction temperature.
文摘By analyzing recent development of reheating furnace in Shougang,the direction of rolling reheating furnace is large type,high efficiency,lower pollution and automation etc.Many advanced technologies are integrated in new rolling reheating furnace such as working beam,regenerative combustion,evaporation cooling and hot loading and hot feeding etc.It shows that reheating furnace technology is upgraded.During the process of product structure adjustment in Shougang,because product heating quality is improved,energy-saving of reheating furnace should pay attention to aspects such as energy-saving of heating variety steel,equality of heating steel,heating system,oxidation loss and so on.This will offer reference for energy-saving of domestic and overseas reheating furnace technology.
文摘1 Scope This standard specifies the classification, technical requirements, test methods, quality appraisal procedures, packing, marking, transportation, storage and quality certificate of castables for steel rolling reheating furnace.
文摘High-temperature performance tests of chromium-containing stuffing sand for a steel ladle w ith different ratios w ere performed. A high-temperature simulation test furnace w as used to analyze the influence of the composition ratio of ladle filler sand and sintering time on the high-temperature compression resistance of chromium-containing stuffing sand in the temperature range of 1 500- 1 600 ℃. The results show that the refractoriness of ladle filler sand w as the low est( only 1 610 ℃) w hen the composition ratio of chromite sand and silica sand w as 6∶ 4. M oreover,the high-temperature compression resistance w as high w hen the content of chromite sand w as at 70%; the resistance increased w ith increasing sintering time. When the sintering time w as extended at a temperature of 1 600 ℃,the high-temperature compression resistance of ladle filler sand first increased and then decreased after being overburnt.
文摘针对棒线材的免加热直接轧制技术将铸坯从连铸机直接运输到轧机进行轧制,可完全取消传统加热炉,实现节能减排的目标。与传统棒线材轧制工艺相比,直轧率偏低是影响免加热直接轧制技术推广的因素之一。提出了一种新送钢控制模型,依据现场实际生产工艺参数,研究对比了先进先出模型(first in first out, FIFO)和所提控制模型的运行效果。结果显示,在四机四流连接一条轧线下,采用FIFO控制模型的直轧率为88.7%,与实测直轧率吻合较好,而采用所提控制模型可将直轧率提高到94.3%。同时还模拟研究了两种模型在五机五流连接一条轧线下的直轧率,结果显示使用FIFO控制模型、所提控制模型的直轧率分别为74.3%和81.7%。通过结果对比发现,送钢控制因素直接影响直轧率。另外,连铸机流数与轧机能力的匹配程度也是影响直轧率的重要因素之一。
基金This work was supported by the National Natural Science Foundation of China(Nos.62173032 and 62003038).
文摘Accurate control of slab temperature and heating rate is an important significance to improve product performance and reduce carbon emissions for steel rolling reheating furnace(SRRF).Firstly,a spatial temporal distributed-nonlinear autoregressive with exogenous inputs correlation model(STD-NARXCM)to spatial temporal distributed-autoregressive with exogenous inputs correlation model(STD-ARXCM)in working point is established.Secondly,a new coordinated time-sharing control architecture in different time periods is proposed,which is along the length of the SRRF to improve the control performance.Thirdly,a hybrid control algorithm of expert-fuzzy is proposed to improve the dynamic of the temperature and the heating rate during time period 0 to t_(1).A hybrid control algorithm of expert-fuzzy-PID is proposed to enhance the control accuracy and the heating rate during time period t_(1) to t_(2).A hybrid control algorithm of expert-active disturbance rejection control(ADRC)is proposed to boost the anti-interference and the heating rate during time period t_(2) to t_(3).Finally,the experimental results show that the coordinated time-sharing algorithm can meet the process requirements,the maximum deviation of temperature value is 8-13.5℃.
基金supported by the National Basic Research Program of China(No.2012CB214906)the Natural Science Foundation of China(No.51176162)
文摘The flow characteristics of high-temperature flue gas are important in the heat transfer of coal-water slurry(CWS) combustion furnaces.The flow field of a 250 kg/h vertical-type slag tap cyclone furnace was non-intrusively investigated,using two-dimensional particle-image velocimetry(2D PIV).The method was verified using traceable fly ash particles in high-temperature flue gas.The flow field of the flue gas was analyzed with a time-averaged method,based on which the effects of excess air ratio and loading were investigated.The flue gas separated by a gas separator maintained good rigidity near the furnace wall,rather than eroding the heating surface.Numerical simulations validated the reliability of PIV under the actual circumstances within the furnace.This study provides guidelines for applying 2D PIV in analyzing flue gas in thermal test boilers.
基金financially supported by the National Natural Science Foundation of China and Shanghai Baosteel Group Company(No. U1960204)the National Natural Science Foundation of China(Nos. 51871042 and 51501034)the Fundamental Research Funds for the Central Universities (No. N2023026)。
文摘The oxidation behavior and mechanism of as-received and 30 % cold-rolled alumina-forming austenitic(AFA) steel were investigated in dry air at 700℃.The results show that the mass gain per unit area curves of as-received and 30 % cold-rolled steels subject to near-parabolic law before 100 h oxidation time.Two samples both show higher high-temperature oxidation resistance due to the formation of dense Al_(2)O_(3) oxide scale.Gradual spallation of outer scale results in the formation of continuous and dense alumina scale.Dislocations can act as short-circuit diffusion channel for the diffusion of Al from alloy matrix to surface,and also provide nucleation sites for B2-NiAl phase,which ensure the continuous formation of Al_(2)O_(3) scale.