The Hongtoushan Volcanogenic Massive Sulphide Deposit（VMSD）occurs in the Hunbei granite-greenstone terrane,Liaoning Province,NE China.Rocks in the mining area have been metamorphosed around 3.0-2.8 Ga to upper amphi...The Hongtoushan Volcanogenic Massive Sulphide Deposit（VMSD）occurs in the Hunbei granite-greenstone terrane,Liaoning Province,NE China.Rocks in the mining area have been metamorphosed around 3.0-2.8 Ga to upper amphibolite facies at temperatures between 600℃and 650℃.Cordierite-anthophyllite gneiss（CAG）in the Hongtoushan mining area,which occurs hundreds of meters below the ore horizon,corresponds to the metamorphosed semi-conformable alteration zone of the VMSD hydrothermal system,whereas the one immediately below the main ore layer represents the metamorphosed pipe-like alteration zone.Whole-rock oxygen isotope signatures were well preserved in both types of CAGs,although the mineral components have been entirely changed during regional metamorphism.Therefore,whole-rock oxygen isotopes can be used to estimate the formation temperature of both types of alteration zone.Calculations show that the semi-conformable and pipelike alteration zones for the Hongtoushan submarine hydrothermal system were formed at 290-360℃and 285-320°C,respectively,whereas estimates for the former were slightly higher than that of the latter,indicating that the semi-conformable alteration zone represents the deep part of the Hongtoushan seafloor hydrothermal system,while the pipe-like alteration zone represents the discharge conduits for metal-rich fluids,which is closer to the seafloor.展开更多
The Archaean massive sulphide Cu\|Zn deposit at Hongtoushan has been metamorphosed to upper amphibolite facies. An investigation on ore textures shows that pyrrhotite in the deposit was originally produced by submarin...The Archaean massive sulphide Cu\|Zn deposit at Hongtoushan has been metamorphosed to upper amphibolite facies. An investigation on ore textures shows that pyrrhotite in the deposit was originally produced by submarine exhalation, and subsequently metamorphosed, annealed and recrystallised. Deformation textures formed by progressive metamorphism of pyrrhotite were erased almost completely under peak conditions, and the presently\|existing deformation textures and ore mylonites are largely resultant from diaphthoresis. Deformation and annealing of pyrrhotite could have been enhanced by fluids. Retrogressive fluids are characterized by high oxygen fugacity.展开更多
Copper-zinc alloy element for boiler energy saving was put in the intake of simulated boiler system to investigate the interaction and transfer of ions in water system both theoretically and experimentally.The fouling...Copper-zinc alloy element for boiler energy saving was put in the intake of simulated boiler system to investigate the interaction and transfer of ions in water system both theoretically and experimentally.The fouling was analyzed by scanning electron microscopy(SEM)and energy dispersive X-ray detector(EDX).The results show that the transfer of calcium and magnesium ions in heat-transfer-surface-water system is affected by zinc ions dissolved from the alloy because of primary battery reaction.Some calcium ions of calcium carbonate crystal are replaced by zinc ions,the growth of aragonite crystal nucleus is retarded,and the transition of calcium carbonate from aragonite to calcite is hampered.展开更多
A copper-zinc alloy doped with rare earth elements was prepared and the mechanism was demonstrated in a simulating boiler and circulating cooling water with rigidity 1 mmol·L-1. The polar curve and scale inhibiti...A copper-zinc alloy doped with rare earth elements was prepared and the mechanism was demonstrated in a simulating boiler and circulating cooling water with rigidity 1 mmol·L-1. The polar curve and scale inhibiting ability of the alloy was tested by a corrosion measurement system and a scale inhibition evaluation system, respectively. Scale samples were characterized with SEM and XRD. It is found that the transfer of cations could be promoted by doping with proper rare earth elements, and the corrosion potentials descend by 25～126 mV. The results indicated that the copper-zinc alloy doped with rare earth elements has higher scale inhibiting ability of CaCO3. The growth of calcite was affected by zinc ions dissolved because of primary battery reaction, and the transition of calcium carbonate from aragonite to calcite was hampered resulting in the proportion of aragonite to calcite is changed from 1.7∶1 to 2.7∶1.展开更多
基金supported financially by the National Basic Research Program of the People's Republic of China (2006CB403501)the National Natural Science Foundation of China(Nos 40872050,40872064)
文摘The Hongtoushan Volcanogenic Massive Sulphide Deposit（VMSD）occurs in the Hunbei granite-greenstone terrane,Liaoning Province,NE China.Rocks in the mining area have been metamorphosed around 3.0-2.8 Ga to upper amphibolite facies at temperatures between 600℃and 650℃.Cordierite-anthophyllite gneiss（CAG）in the Hongtoushan mining area,which occurs hundreds of meters below the ore horizon,corresponds to the metamorphosed semi-conformable alteration zone of the VMSD hydrothermal system,whereas the one immediately below the main ore layer represents the metamorphosed pipe-like alteration zone.Whole-rock oxygen isotope signatures were well preserved in both types of CAGs,although the mineral components have been entirely changed during regional metamorphism.Therefore,whole-rock oxygen isotopes can be used to estimate the formation temperature of both types of alteration zone.Calculations show that the semi-conformable and pipelike alteration zones for the Hongtoushan submarine hydrothermal system were formed at 290-360℃and 285-320°C,respectively,whereas estimates for the former were slightly higher than that of the latter,indicating that the semi-conformable alteration zone represents the deep part of the Hongtoushan seafloor hydrothermal system,while the pipe-like alteration zone represents the discharge conduits for metal-rich fluids,which is closer to the seafloor.
文摘The Archaean massive sulphide Cu\|Zn deposit at Hongtoushan has been metamorphosed to upper amphibolite facies. An investigation on ore textures shows that pyrrhotite in the deposit was originally produced by submarine exhalation, and subsequently metamorphosed, annealed and recrystallised. Deformation textures formed by progressive metamorphism of pyrrhotite were erased almost completely under peak conditions, and the presently\|existing deformation textures and ore mylonites are largely resultant from diaphthoresis. Deformation and annealing of pyrrhotite could have been enhanced by fluids. Retrogressive fluids are characterized by high oxygen fugacity.
基金This work was financially supported by the Key Technologies R&D Program of Tianjin(No.06YFGZGX02400).
文摘Copper-zinc alloy element for boiler energy saving was put in the intake of simulated boiler system to investigate the interaction and transfer of ions in water system both theoretically and experimentally.The fouling was analyzed by scanning electron microscopy(SEM)and energy dispersive X-ray detector(EDX).The results show that the transfer of calcium and magnesium ions in heat-transfer-surface-water system is affected by zinc ions dissolved from the alloy because of primary battery reaction.Some calcium ions of calcium carbonate crystal are replaced by zinc ions,the growth of aragonite crystal nucleus is retarded,and the transition of calcium carbonate from aragonite to calcite is hampered.
基金Key Technologies R&D Program of Tianjin (06YFGZGX02400)
文摘A copper-zinc alloy doped with rare earth elements was prepared and the mechanism was demonstrated in a simulating boiler and circulating cooling water with rigidity 1 mmol·L-1. The polar curve and scale inhibiting ability of the alloy was tested by a corrosion measurement system and a scale inhibition evaluation system, respectively. Scale samples were characterized with SEM and XRD. It is found that the transfer of cations could be promoted by doping with proper rare earth elements, and the corrosion potentials descend by 25～126 mV. The results indicated that the copper-zinc alloy doped with rare earth elements has higher scale inhibiting ability of CaCO3. The growth of calcite was affected by zinc ions dissolved because of primary battery reaction, and the transition of calcium carbonate from aragonite to calcite was hampered resulting in the proportion of aragonite to calcite is changed from 1.7∶1 to 2.7∶1.
