A new o-phthalato-bridged oxamide copper（Ⅱ） complex 1, {[Cu2（oxap）]（pht）. 4H2O}n （oxap=N, N＇-bis（2-aminopropyl）oxamide, pht= phthalate dianion）, has been prepared and structurally characterized. It crystal...A new o-phthalato-bridged oxamide copper（Ⅱ） complex 1, {[Cu2（oxap）]（pht）. 4H2O}n （oxap=N, N＇-bis（2-aminopropyl）oxamide, pht= phthalate dianion）, has been prepared and structurally characterized. It crystallizes in monoclinic, space group C2/c with a=23.424（4）, h=7.9696（14）, c=15.727（3）A°,β=129.617（2）°, C16H28Cu2N4O10, Mr=563.50, V=2261.6（7） A°, Z=4, Dc=1.655 g/cm^3, μ（MoKα）=1.939 mm^-1, F（000） = 1160, the final R=0.0393 and wR=0.0928 for 1707 observed reflections with I〉2σ（1）. Single-crystal X-ray analysis reveals that 1 displays a one-dimensional zigzag chain structure, in which each Cu（oxap） moiety adopting trans-conformation is connected by ,μ1,6-phthalate anion bridges, and these zigzag chains are further linked by another ,μ1,6-phthalate anion bridge to form a 2D sheet structure. The polar guest water molecules reside in the inter-and intrasheets to stabilize the whole crystal structure.展开更多
基金This project was supported by the National Natural Science Foundation of China (No 20331010) and Natural Science Foundation of Tianjing (No. 033602011)
文摘A new o-phthalato-bridged oxamide copper（Ⅱ） complex 1, {[Cu2（oxap）]（pht）. 4H2O}n （oxap=N, N＇-bis（2-aminopropyl）oxamide, pht= phthalate dianion）, has been prepared and structurally characterized. It crystallizes in monoclinic, space group C2/c with a=23.424（4）, h=7.9696（14）, c=15.727（3）A°,β=129.617（2）°, C16H28Cu2N4O10, Mr=563.50, V=2261.6（7） A°, Z=4, Dc=1.655 g/cm^3, μ（MoKα）=1.939 mm^-1, F（000） = 1160, the final R=0.0393 and wR=0.0928 for 1707 observed reflections with I〉2σ（1）. Single-crystal X-ray analysis reveals that 1 displays a one-dimensional zigzag chain structure, in which each Cu（oxap） moiety adopting trans-conformation is connected by ,μ1,6-phthalate anion bridges, and these zigzag chains are further linked by another ,μ1,6-phthalate anion bridge to form a 2D sheet structure. The polar guest water molecules reside in the inter-and intrasheets to stabilize the whole crystal structure.
