An insight on the mechanism of efficient leaching of vanadium from vanadium shale induced by microwave-generated hot spots

Microwave heating can rapidly and uniformly raise the temperature and accelerate the reaction rate.In this paper,microwave heating was used to improve the acid leaching,and the mechanism was investigated via microscopic morphology analysis and numerical simulation by COMSOL Multiphysics software.The effects of the microwave power,leaching temperature,CaF_(2) dosage,H_(2)SO_(4) concentration,and leaching time on the vanadium recovery were investigated.A vanadium recovery of 80.66%is obtained at a microwave power of 550 W,leaching temperature of 95℃,CaF_(2) dosage of 5wt%,H_(2)SO_(4) concentration of 20vol%,and leaching time of 2.5 h.Compared with conventional leaching technology,the vanadium recovery increases by 6.18%,and the leaching time shortens by 79.17%.More obvious pulverization of shale particles and delamination of mica minerals happen in the microwave-assisted leaching process.Numerical simulation results show that the temperature of vanadium shales increases with an increase in electric field(E-field).The distributions of E-field and temperature among vanadium shale particles are relatively uniform,except for the higher content at the contact position of the particles.The analysis results of scaleup experiments and leaching experiments indicate high-temperature hot spots in the process of microwave-assisted leaching,and the local high temperature destroys the mineral structure and accelerates the reaction rate.

Molecular Dynamics Simulation of Shock Response of CL-20 Co-crystals Containing Void Defects

To investigate the effect of void defects on the shock response of hexanitrohexaazaisowurtzitane(CL-20)co-crystals,shock responses of CL-20 co-crystals with energetic materials ligands trinitrotoluene(TNT),1,3-dinitrobenzene(DNB),solvents ligands dimethyl carbonate(DMC) and gamma-butyrolactone(GBL)with void were simulated,using molecular dynamics method and reactive force field.It is found that the CL-20 co-crystals with void defects will form hot spots when impacted,significantly affecting the decomposition of molecules around the void.The degree of molecular fragmentation is relatively low under the reflection velocity of 2 km/s,and the main reactions are the formation of dimer and the shedding of nitro groups.The existence of voids reduces the safety of CL-20 co-crystals,which induced the sensitivity of energetic co-crystals CL-20/TNT and CL-20/DNB to increase more significantly.Detonation has occurred under the reflection velocity of 4 km/s,energetic co-crystals are easier to polymerize than solvent co-crystals,and are not obviously affected by voids.The results show that the energy of the wave decreases after sweeping over the void,which reduces the chemical reaction frequency downstream of the void and affects the detonation performance,especially the solvent co-crystals.

Inter-Row Spacing of PV Power Plant

When designing a solar power plant, it is much more important to avoid the shadow on the PV Panels. As the shadow falls on the PV Panels;it significantly reduces the generation of required power as planned and designed. This research paper and case study will help a lot to avoid shadow, especially when selecting inter-row spacing between the strings of solar power plants.

SYSTEMATIC AND DYNAMIC PROPERTIES OF CASTING HOT SPOT

The variation of casting hot spot with proceeding of solidification andcomponents of casting-mold system is studied by the technique of numerical simulation ofsolidification. The result shows that the thickest part of casting is not exactly the last part ofsolidification in the casting, while the last part of solidification is not exactly casting hot spotat the early stage of solidification. The location, size, shape and number of casting hot spotchange with geomitric, physical and technological factors of the casting-mold system such asthickness of the casting secondary wall and with the passage of time in the course of thesolidification. The former is known as the systematic property of hot spot and the latter, dynamicproperty. Only when the properties of hot spot are grasped completely and accurately, can it be fedmore effectively. By doing so, not only sound castings can be obtained, but also riser efficiencycan be improved.

The Hot Spots in Cereal Rusts and Powdery Mildew Research

Cereal crops, including wheat, barley, oats, rye, etc., are the major sources of calories and proteins for most of the people in the world as well as in China. Cereal rusts and powdery mildews are very important diseases occurred on the cereal crops, which caused yield losses at 5-10% in general and even more than 30% while severe epidemics occurred. In recent years, with the global climate change, change of cultivation system and evolution of the pathogens, the world is facing great challenges caused by cereal diseases.

Hot Spot in Materials with Structural Defects under High Shear Loading Rates

The response of three-dimensional sample of Al, containing vacancy complex, under shear loading was simulated. The molecular dynamics method was used and interaction between atoms was described on the base of pseudopotential theory Solitary waves were generated in the sample under mechanical loading. Their interaction with the vacancy complexes was shown to be able to initiate hot spot in that local region of the complexes. Some parameters of the hot spot as well as solitary waves were calculated. The initiation of the hot spot is accompanied with sufficient local structural relaxation.

STUDY ON LOCATION OF HOT SPOT AT TUBE WALL FOR FIRED CYLINDRICAL FURNACE COMBUSTION

Based on the analysis of heat radiation intensity from flame, a new mathematical model ofthe tube-wall temperatmp of heated tubes is developed by taking down-fired, upright-tube cylindricalfurnace for example. The proposed mathematical model can be employed to indicate both the positionand size of the hot spot at fire-facing wall of heated tube of combustion chamber, and is characteristicof simplicity and efficiency If coupled with thermoelectric couple or infrared viewer, the presentedlocation method of combustion hot spot can offer engineers very valuable proposal to keep furnacerunning more safely The same is true for any other type of tubular furnaces.

THE GEOTHERMAL PULSE OF HOT-SPOT AND ITS DISPERSION PROCESS OVER CHINA-INDIA-BURMA AND CHANGE OF SHORT-TERM CLIMATE

The great gorge of Yarlung Zangbo river is a hot\|spot over earth has been proved by the gravity, geomagnetic, geological, geothermal heat and atmospheric data. Some substances often surge from mantle to the earth surface, which process is not constant and has obvious pulse, characterized by ground temperature over hot\|spot region where is a apparent positive relation in correlation map of the variations of Zedang’s temperature (at 3 2m) in stations over China from 1965 to 1992. It can bring more precipitation here. Out of from the hot spot, there are positive and negative axes around the hot\|spot and to arrange in circular waves with same distance. The average distant of the axes is about 820km, which prove the pulse propagation would infect the distribution of summer precipitation in China. In the hot\|spot region, the geothermal heat pulse propagation has preference direction. So, it has obvious contribution for summer precipitation in South Ch ina.

Identifying hot spots of long-duration extreme climate events in the northwest arid region of China and implications for glaciers and runoff

China’s Northwest Arid Region(NAR),with dry and cold climate conditions and glaciers widely developed in the high mountains,provides vital water resources for Asia.The consecutive cold,warm,dry and wet days have much higher impacts on the water cycle process in this region than extreme temperature and precipitation events with short durations but high intensities.Parametric and nonparametric trend analysis methods widely used in climatology and hydrology are employed to identify the temporal and spatial features of the changes in the consecutive cold,warm,dry and wet days in the NAR based on China’s 0.5°×0.5°meteorological grid datasets of daily temperature and precipitation from 1961 to 2018.This study found that(1)the consecutive cold days(Cold Spell Duration Indicator,CSDI),and the consecutive dry days(CDD)decreased,while the consecutive warm days(Warm Spell Duration Indicator,WSDI),and the consecutive wet days(CWD)increased from 1961 to 2018,(2)and the eastern Kunlun Mountains were the hot spots where all of these consecutive climate indices changed significantly,(3)and the changes in these consecutive climate indices were highly correlated with the rise in the Global Mean Land/Ocean Temperature Index.The results indicated that winters tended to warmer and dryer and summer became hotter and wetter during 1961–2018 in the NAR under the global warming,which can lead to the sustained glacier retreat and the increase in summer runoff in this region,and the eastern Kunlun Mountains are the area where could face high risks of water scarcity and floods if the changes in these climate indices continue in the future.Given the vulnerability of the socio-economic systems in the NAR to a water shortage and floods,it is most crucial to improve the strategies of water resources management,disaster prevention and risk management for this region under climate change.

The ”Hot Spots” Conjecture on Homogeneous Hierarchical Gaskets

In this paper, using spectral decimation, we prove that the "hot spots" conjecture holds on a class of homogeneous hierarchical gaskets introduced by Hambly,i.e., every eigenfunction of the second-smallest eigenvalue of the Neumann Laplacian(introduced by Kigami) attains its maximum and minimum on the boundary.

The hot spots in bovine mastitis research

The 2017 International Bovine Mastitis Conference ＆ The National Mastitis Council Regional in China was successfully held in Beijing on August 25-27, 2017. Nearly 650 participants from more than eight countries （regions） and international organizations attended this conference. The conference provided an communication platform for international counterparts, and the content was closely related to all aspects of dairy cow health, including dairy mastitis pathogens, diagnose, therapeutics, management, residue, bacterial resistance and milk safety. Here we are pleased to have the opportunity to organize a special focus and provide the most updated knowledge of the given topics.

Scalable and Accessible Crash Hot Spot Detection for Traffic Law Enforcement

Law enforcement agencies have begun utilizing traffic and crash data to improve traffic law enforcement delivery. However, many agencies often do not have the resources or expertise to harness fully the benefits this data offers. A free to use, scalable traffic crash hot spot detection tool was developed to aid law enforcement agency decision makers, statewide to the local municipality level. The tool was developed to identify crash hot spots algorithmically with a range of customizable parameters based on location, date and time, and crash factors, enabling quick, dynamic queries. These capabilities provide the ability for law enforcement agencies to conduct “what if” analyses and make data-driven allocation decisions, placing officer resources where they are most needed. The two-step algorithm first identifies potential hot spots based on crash density and then ranks each hot spot using a standardized z-score measure of relative significance. To test the viability of the tool, a pilot was conducted identifying 27 hot spots across Wisconsin where targeted enforcement was then deployed. Despite officer skepticism, results from the pilot found officers at sites targeted for speeding and seatbelt violations were nearly twice as likely to initiate traffic stops compared to non-targeted hot spots. Empirical Bayes before-and-after crash analyses found fatal and injury crashes reduced significantly by nearly 11% during the months with targeted enforcement, while property damage crashes and total crashes were unchanged. Overall, the results show the algorithm can identify hotspots where, coupled with targeted enforcement, traffic safety improvements can be made.

“Hot Nano Spots” as an Interpretation of So-Called Non-Thermal Biological Mobile Phone Effects

Indications exist that mobile phones may cause non-specific biological effects. They are classified as being of implausible non-thermal nature due to low quantum energy and low specific absorption rate levels, even if considering worst cases of "hot spots" of only millimeter size. The considerations of this paper demonstrate that classical theory of polarization offers a conventional interpretation for all three the existence of so far unclarified effects, their low reproducibility and their low intensity. The basis of this explanation is given by the assumption that hot spots contain even hotter “nano spots” on a molecular level according to well known mechanisms of γ-relaxation. In this paper, the concept is put for discussion assuming a heterogeneous system that consists of water molecules as well as larger-sized functional molecules. A consistent interpretation through temperature increase on the level of nanometer sized molecular compounds promises to favor interdisciplinary discussions with respect to safety regulations.

Determination and Analysis of Hot Spot Areas of Deforestation Using Remote Sensing and Geographic Information System Techniques. Case Study: State Sinaloa, México

The main objective of this research is to analyze deforestation in State Sinaloa during the period 1990-2014. For this, “deforestationhot-spot areas” were identified, by crossing maps of 1993 and 2011 at a 1:250,000 scale with knowledge from environmental and forest experts from each region. Landsat images from 1990 and 2014 and Terra Amazon System were used to monitor the most critical hot spot area, applying Linear Spectral Mixture Analysis and Image Segmentation Ground Product. In order to generate the map deforestation year zero (1990), every segmented object of ground product was visually assigned to “Forest” and “No-Forest” categories. Therefore, gains and losses were interpreted for the map deforestation year one (2014). Those products were validated with the help of experts on the subject and applying a confusion matrix. Results obtained indicated that the highest forest loss was located in North-Central Sinaloa (hot spot area number two) by establishing the average annual rate of deforestation of 4741.90 ha/year with an average rate of 0.60%, being higher than the national average rate (0.37%). This result affects directlyon calculation of carbonfluxes at nationallevel.

Some Hot Spots in the Study of Chinese Drugs in the 21st Century

Mankind has entered the 21st century of high speed development in science and e-conomics. Owing to the alteration of disease modes in the new century, the greatly elevated quality of human life and the arrival of aged society, the modes of medicine have obviously changed from the treatment mode

A Summary of Research Hotspots in Educational Economics in China during the"Thirteenth Five-Year Plan"Period

Since the"Thirteenth Five-Year Plan"period,Chinese scholars'research on academic economics has mainly focused on"winning the battle against poverty in education,""developing modern vocational education,""promoting educational structural reform,"and"achieving the equalization of basic public education services."Analysis on themes such as"Humanization."

Spatial and temporal analysis of urban heat island effect over Tiruchirappalli city using geospatial techniques

Alterations made to the natural ground surface and the anthropogenic activity elevate the surface and air temperature in the urban areas compared with the surrounding rural areas,known as urban heat island effect.Thermal remote sensors measure the radiation emitted by ground objects,which can be used to estimate the land surface temperature and are beneficial for studying urban heat island effects.The present study investigates the spatial and temporal variations in the effects of urban heat island over Tiruchirappalli city in India during the summer and winter seasons.The study also identifies hot spots and cold spots within the study area.In this study,a significant land surface temperature difference was observed between the urban and rural areas,predominantly at night,indicating the presence of urban heat island at night.These diurnal land surface temperature fluctuations are also detected seasonally,with a relatively higher temperature intensity during the summer.The trend line analysis shows that the mean land surface temperature of the study area is increasing at a rate of 0.166 K/decade with p less than 0.01.By using the spatial autocorrelation method with the urban heat island index as the key parameter,hot spots with a 99 percent confidence level and a 95 percent confidence level were found within the urban area.A hot spot with 95 and 90 percent confidence level was identified outside the urban area.This spike in temperature for a particular region in the rural area is due to industry and the associated built-up area.The study also identified cold spots with a 90 percent confidence level within the rural area.However,cold spots with a 95 and 99 percent confidence level were not identified within the study area.

Geospatial characteristics of fire occurrences in southern hemispheric Africa and Madagascar during 2001-2020

For this study of long-term spatial patterns and trends of active fires in southern hemispheric Africa and on Madagascar from 2001 to 2020,active fire data from the MODIS FIRMS global fire data products were analyzed.The annual center of fire concentration tended to migrate toward the preserved rainforests and nature conservation areas in the Congo Basin and the mountain forests on the northeastern coast of Madagascar.Fire frequency varied seasonally at both study areas.We used geo statistical analysis techniques,such as measures of dispersion and emerging hot spot analysis,to reveal long-term trends in spatial patterns of fire events.In southern hemispheric Africa,the observed active fires tended to drift northward toward the Zambia-DRC border in the Congo basin.This northward migration progressed toward humid rainforests,which were better suited to sustaining repeated fire events.On Madagascar,the observed active fires tended to migrate toward the east coast in protected mountain forests.The spatial patterns of long-term trends showed a concentration of fires in the tropical regions of southern hemispheric Africa.Moreover,smaller clusters of new hot spots were located over eastern South Africa,overlapping with undifferentiated woodlands.On Madagascar,both hot and cold spots were identified and were separated by the highland region in the center of the island.Most of the eastern island was characterized by cold spots that received less precipitation than did the rest of the island.The presence of increasing hots spots in the densely vegetated areas highlights the urgent need for fire prevention and management in this region.

Highly sensitive and stable probe refractometer based on configurable plasmonic resonance with nano-modified fiber core

A dispersion model is developed to provide a generic tool for configuring plasmonic resonance spectral characteristics.The customized design of the resonance curve aiming at specific detection requirements can be achieved.According to the model,a probe-type nano-modified fiber optic configurable plasmonic resonance(NMF-CPR)sensor with tip hot spot enhancement is demonstrated for the measurement of the refractive index in the range of 1.3332-1.3432 corresponding to the low-concentration biomarker solution.The new-type sensing structure avoids excessive broadening and redshift of the resonance dip,which provides more possibilities for the surface modification of other functional nanomaterials.The tip hot spots in nanogaps between the Au layer and Au nanostars(AuNSs),the tip electric field enhancement of AuNSs,and the high carrier mobility of the WSe_(2)layer synergistically and significantly enhance the sensitivity of the sensor.Ex-perimental results show that the sensitivity and the figure of merit of the tip hot spot enhanced fiber NMF-CPR sensor can achieve up to 2995.70 nm/RIU and 25.04 RIU^(−1),respectively,which are 1.68 times and 1.29 times higher than those of the conventional fiber plasmonic resonance sensor.The results achieve good agreements with numerical simulations,demonstrate a better level compared to similar reported studies,and verify the correctness of the dispersion model.The detection resolution of the sensor reaches up to 2.00×10^(−5)RIU,which is obviously higher than that of the conventional side-polished fiber plasmonic resonance sensor.This indicates a high detection accuracy of the sensor.The dense Au layer effectively prevents the intermediate nanomaterials from shedding and chemical degradation,which enables the sensor with high stability.Furthermore,the terminal reflective sensing structure can be used as a practical probe and can allow a more convenient operation.