Effect of bipolar-plates design on corrosion,mass and heat transfer in proton-exchange membrane fuel cells and water electrolyzers:A review

Attaining a decarbonized and sustainable energy system,which is the core solution to global energy issues,is accessible through the development of hydrogen energy.Proton-exchange membrane water electrolyzers(PEMWEs)are promising devices for hydrogen production,given their high efficiency,rapid responsiveness,and compactness.Bipolar plates account for a relatively high percentage of the total cost and weight compared with other components of PEMWEs.Thus,optimization of their design may accelerate the promotion of PEMWEs.This paper reviews the advances in materials and flow-field design for bipolar plates.First,the working conditions of proton-exchange membrane fuel cells(PEMFCs)and PEMWEs are compared,including reaction direction,operating temperature,pressure,input/output,and potential.Then,the current research status of bipolar-plate substrates and surface coatings is summarized,and some typical channel-rib flow fields and porous flow fields are presented.Furthermore,the effects of materials on mass and heat transfer and the possibility of reducing corrosion by improving the flow field structure are explored.Finally,this review discusses the potential directions of the development of bipolar-plate design,including material fabrication,flow-field geometry optimization using threedimensional printing,and surface-coating composition optimization based on computational materials science.

Research on Solar Water Heating System and Architectural Integration Design—A Case Study of Anqing Children Welfare Home

Taking the planning and major architectural design projects of Anqing Children Welfare Home for example,through the research on categories and each component of solar water heating system,the paper discussed strategies and methods to realize solar energy and architectural integration design in the climate condition and location environment of Anhui Province.

Operation Performance of Central Solar Heating System with Seasonal Storage Water Tank in Harbin

This paper presented a preliminary research on the central solar heating system with seasonal storage(CSHSSS)used in cold climate in China.A mathematical model of the solar energy seasonal storage water tank used in the central solar heating system was firstly developed based on energy conservation.This was followed by the simulation of the CSHSSS used in a two-floor villa in Harbin,and analysis of the impacts on storage water temperature of tank volume,solar collector area,tank burial depth,insulation thickness around the tank,etc.The results show there is a relatively economical tank volume to optimize the system efficiency,which decreases with increasing tank volume at the constant collector area,and increases with increasing collector area at the constant tank volume.Furthermore,the insulation thickness has obvious effect on avoiding heat loss,while the tank burial depth doesn't.In addition,the relationship between the solar collector efficiency and storage water temperature is also obtained,it decreases quickly with increasing storing water temperature,and then increases slowly after starting space heating system.These may be helpful for relevant design and optimization in cold climates in China and all over the world.

Computer simulation of Cu:AlOOH/water in a microchannel heat sink using a porous media technique and solved by numerical analysis AGM and FEM

Extensive improvements in small-scale thermal systems in electronic circuits,automotive industries,and microcomputers conduct the study of microsystems as essential.Flow and thermic field characteristics of the coherent nanofluid-guided microchannel heat sink are described in this perusal.The porous media approximate was used to search the heat distribution in the expanded sheet and Cu:γ-AlOOH/water.A hybrid blend of Boehme copper and aluminum nanoparticles is evaluated to have a cooling effect on the microchannel heat sink.By using Akbari Ganji and finite element methods,linear and non-linear differential equations as well as simple dimensionless equations have been analyzed.The purpose of this study is to investigate the fluid and thermal parameters of copper hybrid solution added to water,such as Nusselt number and Darcy number so that we can reach the best cooling of the fluid.Also,by installing a piece of fin on the wall of the heat sink,the coefficient of conductive heat transfer and displacement heat transfer with the surrounding air fluid increases,and the efficiency of the system increases.The overall results show that expanding values on the NP(series heat transfer fluid system maximizes performance with temperatures)volume division of copper,as well as boehmite alumina particles,lead to a decrease within the stream velocity of the Cu:AlOOH/water.Increasing the volume fraction of nanoparticles in the hybrid mixture decreases the temperature of the solid surface and the hybrid nanofluid.The Brownian movement improves as the volume percentage of nanoparticles in the hybrid mixture grows,spreading the heat across the environment.As a result,heat transmission rates rise.As the Darcy number increases,the thermal field for solid sections and Cu:AlOOH/water improves.

Energy efficiency performance of multi-energy district heating and hot water supply system

A district heating and hot water supply system is presented which synthetically utilizes geothermal energy,solar thermal energy and natural gas thermal energy.The multi-energy utilization system has been set at the new campus of Tianjin Polytechnic University(TPU),A couple of deep geothermal wells which are 2 300 m in depth were dug,Deep geothermal energy cascade utilization is achieved by two stages of plate heat exchangers(PHE) and two stages of water source heat pumps(WSHP).Shallow geothermal energy is used in assistant heating by two ground coupled heat pumps(GCHPs) with 580 vertical ground wells which are 120 m in depth.Solar thermal energy collected by vacuum tube arrays(VTAs) and geothermal energy are complementarily utilized to make domestic hot water.Superfluous solar energy can be stored in shallow soil for the GCHP utilization.The system can use fossil fuel thermal energy by two natural gas boilers(NGB) to assist in heating and making hot water.The heating energy efficiency was measured in the winter of 2010-2011.The coefficients of performance(COP) under different heating conditions are discussed.The performance of hot water production is tested in a local typical winter day and the solar thermal energy utilization factor is presented.The rusults show that the average system COP is 5.75 or 4.96 under different working conditions,and the typical solar energy utilization factor is 0.324.

Water-Tank Experiment on the Thermal Circulation Induced by the Bottom Heating in an Asymmetric Valley

Water tank experiments were carried out to investigate the thermal convection due to the bottom heating in an asymmetrical valley under neutral and stably stratified approach flows with the Particle Image Velometry (PIV) visualization technique. In the neutral stratification approach flow, the ascending draft induced by bottom heating is mainly located in the center of the valley in calm ambient wind. However, with ambient wind flow, the thermal convection is shifted leeward, and the descending draft is located on the leeward side of the valley, while the ascending draft is located on the windward side. The descending draft is minorly turbulent and organized, while the ascending draft is highly turbulent. With the increase of the towing speed, the descending and ascending drafts induced by the mechanical elevation begin to play a more dominant role in the valley flow, while the role of the thermal convection in the valley airflow becomes limited. In the stable stratification approach flow, the thermal convection is limited by the stable stratification and no distinct circulation is formed in calm ambient wind. With ambient wind, agravity wave appears in the upper layer in the valley. With the increase of the ambient wind speed, a gravity wave plays an important role in the valley flow, and the location and intensity of the thermal convection are also modulated by the gravity internal waves. The thermal convection has difficulty penetrating the upper stable layer. Its exchange is limited between the air in the upper layer and that in the lower layer in the valley, and it is adverse to the diffusion of pollutants in the valley.

Significance of Nanoparticles Aggregation with Cattaneo-Christov Heat Flux on the Water and Ethylene Glycol Mixture Based MWCNTs-Nanofluid Flow over a Stretching Cylinder

This work aims to analyze the flow of electrically conducting MWCNTs-nanofluid over a stretching cylinder with the aggregation and non-aggregation effects of nanoparticles. The working fluid comprised a combination of water and ethylene glycol, with volumetric proportions of (50:50) considered. Convective boundary constraints and modified Fourier law are implemented in heat transmission assessment. The mathematical flow model is formulated in the form of PDEs and is transformed into ODEs via similarity transformation. Numerical outcomes will be obtained with the use of the bvp4c technique and will be displayed with the help of graphs and tables. The results show that the surface drag coefficient is enhanced in the case of aggregation of nanoparticles whereas heat transfer rate is enhanced in the non-aggregation effect of nanoparticles. Furthermore, the temperature distribution enhances the increasing values of particle volume fraction in the case of aggregation effects of nanoparticles whereas temperature distribution lowers in the case of non-aggregation effect of nanoparticles. .

Supplementation of vitamin E or a botanical extract as antioxidants to improve growth performance and health of growing pigs housed under thermoneutral or heat-stressed conditions

Background Heat stress has severe negative consequences on performance and health of pigs,leading to significant economic losses.The objective of this study was to investigate the effects of supplemental vitamin E and a botanical extract in feed or drinking water on growth performance,intestinal health,and oxidative and immune status in grow-ing pigs housed under heat stress conditions.Methods Duplicate experiments were conducted,each using 64 crossbred pigs with an initial body weight of 50.7±3.8 and 43.9±3.6 kg and age of 13-week and 12-week,respectively.Pigs(n=128)were housed individually and assigned within weight blocks and sex to a 2×4 factorial arrangement consisting of 2 environments(thermo-neutral(21.2℃)or heat-stressed(30.9℃))and 4 supplementation treatments(control diet;control+100 IU/L of D-α-tocopherol in water;control+200 IU/kg of DL-α-tocopheryl-acetate in feed;or control+400 mg/kg of a botanical extract in feed).Results Heat stress for 28 d reduced(P≤0.001)final body weight,average daily gain,and average daily feed intake(-7.4 kg,-26.7%,and-25.4%,respectively)but no effects of supplementation were detected(P>0.05).Serum vitamin E increased(P<0.001)with vitamin E supplementation in water and in feed(1.64 vs.3.59 and 1.64 vs.3.24),but not for the botanical extract(1.64 vs.1.67 mg/kg)and was greater when supplemented in water vs.feed(P=0.002).Liver vitamin E increased(P<0.001)with vitamin E supplementations in water(3.9 vs.31.8)and feed(3.9 vs.18.0),but not with the botanical extract(3.9 vs.4.9 mg/kg).Serum malondialdehyde was reduced with heat stress on d 2,but increased on d 28(interaction,P<0.001),and was greater(P<0.05)for antioxidant supplementation compared to control.Cellular proliferation was reduced(P=0.037)in the jejunum under heat stress,but increased in the ileum when vitamin E was supplemented in feed and water under heat stress(interaction,P=0.04).Tumor necrosis factor-αin jejunum and ileum mucosa decreased by heat stress(P<0.05)and was reduced by vitamin E sup-plementations under heat stress(interaction,P<0.001).Conclusions The addition of the antioxidants in feed or in drinking water did not alleviate the negative impact of heat stress on feed intake and growth rate of growing pigs.

Hydrographic Characteristics and Oceanic Heat Flux in the Upper Arctic Ocean over the Alpha Ridge Observed by the DTOP Platform in 2018 and 2021

In 2018 and 2021,the Drift-Towing Ocean Profilers(DTOP)provided extensive temperature and salinity data on the upper 120m ocean through their drifts over the Alpha Ridge north of the Canada Basin.The thickness and temperature maximum of Alaska Coastal Water(ACW)ranged from 20m to 40m and-1.5℃to-0.8℃,respectively,and the salinity generally maintained from 30.2 to 32.5.Comparison with World Ocean Atlas 2018’s climatology manifested a 40m-thick and warm ACW roughly ex-ceeding the temperature maximum by 0.4–0.5℃in June–August 2021.This anomalously warm ACW was highly related to the ex-pansion of the Beaufort Gyre in the negative Arctic Oscillation phase.During summer,the under-ice oceanic heat flux F_(w)^(OHF)was elevated,with a maximum value of above 25Wm^(-2).F_(w)^(OHF)was typically low in the freezing season,with an average value of 1.2Wm^(-2).The estimates of upward heat flux contributed by ACW to the sea ice bottom F_(w)^(OHF)were in the range of 3–4Wm^(-2)in June–August 2021,when ACW contained a heat content of more than 80MJm^(-2).The heat loss over this period was driven by a weak stratification upon the ACW layer associated with a surface mixed layer(SML)approaching the ACW core.After autumn,F_(w)^(OHF)was reduced(<2 Wm^(-2))except during rare events when it elevated F_(w)^(OHF)slightly.In addition,the intensive and widespread Ekman suction,which created a violent upwelling north of the Canada Basin,was largely responsible for the substantial cooling and thinning of the ACW layer in the summer of 2021.

Numerical Study of Thermal Performance of Phase Change Material Energy Storage Floor in Solar Water Heating System

The conventional solar heating floor system contains a big water tank to store energy in the day time for heating at night,which takes much building space and is very heavy.In order to reduce the water tank volume even to cancel the tank,a novel structure of integrated water pipe floor heating system using shape-stabilized phase change materials(SSPCM)for thermal energy storage was developed.A numerical model was developed to analyze the performance of SSPCM floor heating system under the intermittent heating condition,which was verified by our experimental data.The thermal performance of the heating system and the effects of various factors on it were analyzed numerically.The factors including phase transition temperature,heat of fusion,thermal conductivity of SSPCM and thermal conductivity of the decoration material were analyzed.The results show that tm and kd are the most import influencing factors on the thermal performance of SSPCM floor heating system,since they determine the heat source temperature and thermal resistance between SSPCM plates and indoor air,respectively.Hm should be large to store enough thermal energy in the day time for nighttimes heating.The effects of kp can be ignored in this system.The SSPCM floor heating system has potential of making use of the daytime solar energy for heating at night efficiently in various climates when its structure is properly designed.

Yields,growth and water use under chemical topping in relations to row configuration and plant density in drip-irrigated cotton

Background Water deficit is an important problem in agricultural production in arid regions.With the advent of wholly mechanized technology for cotton planting in Xinjiang,it is important to determine which planting mode could achieve high yield,fiber quality and water use efficiency(WUE).This study aimed to explore if chemical topping affected cotton yield,quality and water use in relation to row configuration and plant densities.Results Experiments were carried out in Xinjiang China,in 2020 and 2021 with two topping method,manual topping and chemical topping,two plant densities,low and high,and two row configurations,i.e.,76 cm equal rows and 10+66 cm narrow-wide rows,which were commonly applied in matching harvest machine.Chemical topping increased seed cotton yield,but did not affect cotton fiber quality comparing to traditional manual topping.Under equal row spacing,the WUE in higher density was 62.4%higher than in the lower one.However,under narrow-wide row spacing,the WUE in lower density was 53.3%higher than in higher one(farmers’practice).For machine-harvest cotton in Xinjiang,the optimal row configuration and plant density for chemical topping was narrow-wide rows with 15 plants m-2 or equal rows with 18 plants m-2.Conclusion The plant density recommended in narrow-wide rows was less than farmers’practice and the density in equal rows was moderate with local practice.Our results provide new knowledge on optimizing agronomic managements of machine-harvested cotton for both high yield and water efficient.

AHFO-based soil water content sensing technology considering soil-sensor thermal contact resistance

The actively heated fiber-optic(AHFO)technology has become emerged as a research focus due to its advantages of distributed,real-time measurement and good durability.These attributes have led to the gradual application of AHFO technology to the water content measurement of in situ soil.However,all existing in situ applications of AHFO technology fail to consider the effect of soilesensor contact quality on water content measurements,limiting potential for the wider application of AHFO technology.To address this issue,the authors propose a method for determining the soilesensor thermal contact resistance based on the principle of an infinite cylindrical heat source.This is then used to establish an AHFO water content measurement technology that considers the thermal contact resistance.The reliability and validity of the new measurement technology are explored through a laboratory test and a field case study,and the spatial-temporal evolution of the soil water content in the case is revealed.The results demonstrate that method for determining the soilesensor thermal contact resistance is highly effective and applicable to all types of soils.This method requires only the moisture content,dry density,and thermal response of the in situ soil to be obtained.In the field case,the measurement error of soil water content between the AHFO method,which takes into account the thermal contact resistance,and the neutron scattering method is only 0.011.The water content of in situ soil exhibits a seasonal variation,with an increase in spring and autumn and a decrease in summer and winter.Furthermore,the response of shallow soils to precipitation and evaporation is significant.These findings contribute to the enhancement of the accuracy of the AHFO technology in the measurement of the water content of in situ soils,thereby facilitating the dissemination and utilization of this technology.

Space heating and hot water demand analysis of dwellings connected to district heating scheme in UK

To achieve CO2 emissions reductions, the UK Building Regulations require developers of new residential buildings to calculate expected CO2 emissions arising from their energy consumption using a methodology such as Standard Assessment Procedure （SAP 2005） or, more recently SAP 2009. SAP encompasses all domestic heat consumption and a limited proportion of the electricity consumption. However, these calculations are rarely verified with real energy consumption and related CO2 emissions. This work presents the results of an analysis based on weekly heat demand data for more than 200 individual fiats. The data were collected from a recently built residential development connected to a district heating network. A method for separating out the domestic hot water （DHW） use and space heating （SH） demand has been developed and these values are compared to the demand calculated using SAP 2005 and SAP 2009 methodologies. The analysis also shows the variation in DHW and SH consumption with size of flats and with tenure （privately owned or social housing）. Evaluation of the space heating consumption also includes an estimate of the heating degree day （HDD） base temperature for each block of fiats and compares this to the average base temperature calculated using the SAP 2005 methodology.

Heating of Nanosized Liquid Water in High-Intensity Terahertz Pulses

Non-equilibrium molecular dynamics simulations of liquid water in picosecond high-power terahertz pulses are performed by using a non-polarizable potential model. Numerical results show that the energy absorption of water molecules exhibits a pronounced resonance with THz pulses in the frequency range of 14-17 THz. With the THz pulse at resonant frequencies, the maximum temperature is about 562 K by heating the water at room temperature. Further investigation indicates that the results are independent of the size of the nanoscale water box. The efficiency of energy transfer by resonant absorption is more than seven times of microwave heating. These studies show promising applications of ultrashort THz pulses.

Natural convection of an alumina-water nanofluid inside an inclined wavy-walled cavity with a non-uniform heating using Tiwari and Das' nanofluid model

The present study is devoted to numerical analysis of natural convective heat transfer and fluid flow of alumina-water nanofluid in an inclined wavy-walled cavity under the effect of non-uniform heating. A single-phase nanofluid model with experimental correlations for the nanofluid viscosity and thermal conductivity has been included in the mathematical model. The considered governing equations formulated in dimensionless stream function, vorticity, and temperature have been solved by the finite difference method. The cavity inclination angle and irregular walls(wavy and undulation numbers)are very good control parameters for the heat transfer and fluid flow. Nowadays, optimal parameters are necessary for the heat transfer enhancement in different practical applications. The effects of the involved parameters on the streamlines and isotherms as well as on the average Nusselt number and nanofluid flow rate have been analyzed. It has been found that the heat transfer rate and fluid flow rate are non-monotonic functions of the cavity inclination angle and undulation number.

Refrigerator Coupling to a Water-Heater and Heating Floor to Save Energy and to Reduce Carbon Emissions

With an aim of rationing use of energy, energy safety, and to reduce carbon emission, our interest was geared towards the refrigerators and all the refrigerating machines. Indeed the heat yielded by the exchanger condenser can be developed for the water heating, floors heating etc. After an encouraging theoretical study, two prototypes were produced in order to validate the theoretical results. A first refrigerator was coupled with a water-heater and another with a heating floor. The water temperature reached, in one day, is of 60℃;which makes it possible to predict better results with a continuously used refrigerator. In the same way for the heating floor coupled with the second refrigerator, the temperature reached high values because the surface is reduced;however for the heating floors the standard fixes the temperature between 28℃ and 30℃.

The Preliminary Research of Sea Water District Heating and Cooling for Tallinn Coastal Area

This paper describes possibilities to utilize sea water for district heating and cooling purposes in Tallinn costal area. The sea water temperature profiles and suitability of heating and cooling generation are studied for continental climatic conditions. The district network study bases on 21 buildings located near to the Gulf of Finland. Industrial reversible heat pump technology is selected to cover heating and cooling loads for the new buildings. Combination of existing district heating and heat pump technology is considered for existing buildings. The results show possibilities, threats and need for further research of the sea water based heat pump district network implementation.

Water, Air Emissions, and Cost Impacts of Air-Cooled Microturbines for Combined Cooling, Heating, and Power Systems： A Case Study in the Atlanta Region

The increasing pace of urbanization means that cities and global organizations are looking for ways to increase energy efficiency and reduce emissions. Combined cooling, heating, and power （CCHP） systems have the potential to improve the energy generation efficiency of a city or urban region by providing energy for heating, cooling, and electricity simultaneously. The purpose of this study is to estimate the water consumption for energy generation use, carbon dioxide （CO2） and NOx emissions, and economic impact of implementing CCHP systems for five generic building types within the Atlanta metropolitan region, under various operational scenarios following the building thermal （heating and cooling） demands. Operating the CCHP system to follow the hourly thermal demand reduces CO2 emissions for most building types both with and without net metering. The system can be economically beneficial for all building types depending on the price of natural gas, the implementation of net metering, and the cost structure assumed for the CCHP system. The greatest reduction in water consumption for energy production and NOx emissions occurs when there is net metering and when the system is operated to meet the maximum yearly thermal demand, although this scenario also results in an increase in greenhouse gas emissions and, in some cases, cost. CCHP systems are more economical for medium office, large office, and multifamilv residential buildings.

Evaluation of Liquid Water Content in Thermal Efficient Heating Mechanism Using Water Vapor for Industrial Furnace

Thermal efficiency has improved by using high-temperature vapor produced by spraying water vapor along with flame from a burner. This study aims to apply high-temperature steam heating mechanism in a high-efficient industrial furnace and household gas range. Past studies in this laboratory show that the heat transfer is promoted due to the appropriate amount of water content in each convection, radiation heat transfer. Then, water vapor-added industrial metal melting furnace has been researched. However, the existing furnace was intended to evaluate only the effect of water vapor except measuring surrounding environment, for example temperature and humidity. In this study, the effect of surrounding environment to the furnace is examined, and possibility of heat transfer enhancement is estimated. As a result, surrounding experimental condition has little effect on the change of heating ability, while this experimental furnace shows gradual degradation of heating ability in every experimental trial. Then optimum amount of water supply to the apparatus was discussed. Too much water injection leads to more consumption of heat as latent heat of water in phase change, and exceeds the effect of water vapor in heat transfer. There is a possibility of suitable total water supply, despite that there is no significant change in gas usage in water injection case compared with no water injection.

Program for Solar Water Heating Systems Based on the F-Chart Method

This paper aims at presenting an application developed in Java for optimizing the design of centralized solar water heating systems with forced circulation, based on the f-chart method. The program uses data from the Brazilian Solar Atlas, performance data of flat plate collectors and thermal reservoirs from the standardized tests run within the Brazilian Labeling Program, and values of water consumption of appliances defined by the ABNT. The program finds the inclination of the collector that maximizes the annual solar fraction, or for the winter, and enables the use of arrays in series and parallel collectors. From the investment costs and O ＆ M （operations and maintenance） of solar heating systems, the program carries out economical analysis using classical parameters as net present value, discounted payback and internal rate of return. The program was validated through examples from the book of Duffle ＆ Beckman and also by comparison with the results from a project developed at UFRGS, having obtained good agreement.