Over the recent three decades, exploration of a large-size Sn-Fe polymetallic ore deposit at the Huanggangliang, the Da Hinggan Mountains, Inner Mongolia, China, has been largely focused on the premise that the minera...Over the recent three decades, exploration of a large-size Sn-Fe polymetallic ore deposit at the Huanggangliang, the Da Hinggan Mountains, Inner Mongolia, China, has been largely focused on the premise that the mineralization represents epigenetic magmatic hydrothermal ore deposit in genetic connection with the Mesozoic magmatism. The Huanggangliang Sn-Fe polymetallic ore deposits occurred in Permian strata, with silt- stone/marble of the Zhesi Formation and spilite/andesite/tuff of the Dashizhai Formation. The characteristics of geological and geochemical data demonstrated that sedimentary hydrothermal mineralization occurred during the basin evolution at the Permian, rather than representing epigenetie magmatic hydrothermal genesis with the following evidences. The ore-bearing skarus are stratiform with underlying metasedimentary rocks and overlying volcanic sedimentary rocks. Sedimentary hydrothermal textures and structures are observed in the stratabound ore-bearing skarn such as bedded-laminated skarn and magnetite ores with small-size folding or soft deforma- tion, synsedimentary breccia of skarn and magnetite ores and concentric shell structure of magnetite ores. So the stratabound ore-bearing skarns associated with magnetite ore and micro-disseminated tin, are peculiar examples of exhalite. The REE contents of the stratabound ore-bearing skarns display ∑LREE-rich （36.91×10^-6） but EHREE-depletion （6. 42 ×10^-6） , with positive Eu anomaly （Eu/Eu ＊ 1.28） and negative Ce anomaly （Ce/ Ce ＊ 0.88 ） , which is totally different from REE pattern of the Huanggang magmatic rocks（ with ∑REE 277.73 ×10^-6, ELREE 220.24 ×10^-6, ∑HREE 57.49 ×10^-6, Eu/Eu＊ 0.06, Ce/Ce＊ 1.52） , which is comparable with modern sea-floor hydrothermal fluid,sedimentary hydrothermal ore deposit and associated hydrothermal sedimentary rocks. Calcite samples with δ13CPDB from -5. 400 ‰ to -4. 397 ‰ and δ18SOSMOW from 9. 095 ‰ to 9. 364 ‰ in the stratabound ore-bearing skarns show sedimentary hydrothermal genesis of the Huanggangliang deposit. This proposition is useful not only for interpretation of the genesis of the Huanggangliang large Sn-Fe polymetallic ore deposit but also significant for mineral exploration in the area especially for finding large deposits caused by sedimentary exhalative mineralization processes.展开更多
基金Project supported by the National Basic Research Program(2009CB421008)Program for Changjiang Scholars and Innovative Research Teamin University (IRT0755)+1 种基金the 111 Project (B07011)China Postdoctoral Science Foundation funded project (20090460400)
文摘Over the recent three decades, exploration of a large-size Sn-Fe polymetallic ore deposit at the Huanggangliang, the Da Hinggan Mountains, Inner Mongolia, China, has been largely focused on the premise that the mineralization represents epigenetic magmatic hydrothermal ore deposit in genetic connection with the Mesozoic magmatism. The Huanggangliang Sn-Fe polymetallic ore deposits occurred in Permian strata, with silt- stone/marble of the Zhesi Formation and spilite/andesite/tuff of the Dashizhai Formation. The characteristics of geological and geochemical data demonstrated that sedimentary hydrothermal mineralization occurred during the basin evolution at the Permian, rather than representing epigenetie magmatic hydrothermal genesis with the following evidences. The ore-bearing skarus are stratiform with underlying metasedimentary rocks and overlying volcanic sedimentary rocks. Sedimentary hydrothermal textures and structures are observed in the stratabound ore-bearing skarn such as bedded-laminated skarn and magnetite ores with small-size folding or soft deforma- tion, synsedimentary breccia of skarn and magnetite ores and concentric shell structure of magnetite ores. So the stratabound ore-bearing skarns associated with magnetite ore and micro-disseminated tin, are peculiar examples of exhalite. The REE contents of the stratabound ore-bearing skarns display ∑LREE-rich （36.91×10^-6） but EHREE-depletion （6. 42 ×10^-6） , with positive Eu anomaly （Eu/Eu ＊ 1.28） and negative Ce anomaly （Ce/ Ce ＊ 0.88 ） , which is totally different from REE pattern of the Huanggang magmatic rocks（ with ∑REE 277.73 ×10^-6, ELREE 220.24 ×10^-6, ∑HREE 57.49 ×10^-6, Eu/Eu＊ 0.06, Ce/Ce＊ 1.52） , which is comparable with modern sea-floor hydrothermal fluid,sedimentary hydrothermal ore deposit and associated hydrothermal sedimentary rocks. Calcite samples with δ13CPDB from -5. 400 ‰ to -4. 397 ‰ and δ18SOSMOW from 9. 095 ‰ to 9. 364 ‰ in the stratabound ore-bearing skarns show sedimentary hydrothermal genesis of the Huanggangliang deposit. This proposition is useful not only for interpretation of the genesis of the Huanggangliang large Sn-Fe polymetallic ore deposit but also significant for mineral exploration in the area especially for finding large deposits caused by sedimentary exhalative mineralization processes.
