The ex-situ incorporation of the secondary SiC reinforcement,along with the in-situ incorporation of the tertiary and quaternary Mg_(3)N_(2) and Si_(3)N_(4) phases,in the primary matrix of Mg_(2)Si is employed in orde...The ex-situ incorporation of the secondary SiC reinforcement,along with the in-situ incorporation of the tertiary and quaternary Mg_(3)N_(2) and Si_(3)N_(4) phases,in the primary matrix of Mg_(2)Si is employed in order to provide ultimate wear resistance based on the laser-irradiation-induced inclusion of N_(2) gas during laser powder bed fusion.This is substantialized based on both the thermal diffusion-and chemical reactionbased metallurgy of the Mg_(2)Si–SiC/nitride hybrid composite.This study also proposes a functional platform for systematically modulating a functionally graded structure and modeling build-direction-dependent architectonics during additive manufacturing.This strategy enables the development of a compositional gradient from the center to the edge of each melt pool of the Mg_(2)Si–SiC/nitride hybrid composite.Consequently,the coefficient of friction of the hybrid composite exhibits a 309.3%decrease to–1.67 compared to–0.54 for the conventional nonreinforced Mg_(2)Si structure,while the tensile strength exhibits a 171.3%increase to 831.5 MPa compared to 485.3 MPa for the conventional structure.This outstanding mechanical behavior is due to the(1)the complementary and synergistic reinforcement effects of the SiC and nitride compounds,each of which possesses an intrinsically high hardness,and(2)the strong adhesion of these compounds to the Mg_(2)Si matrix despite their small sizes and low concentrations.展开更多
Hybrid nanofluids are remarkable functioning liquids that are intended to reduce the energy loss while maximizing the heat transmission.In the involvement of suction and nonlinear thermal radiation effects,this study ...Hybrid nanofluids are remarkable functioning liquids that are intended to reduce the energy loss while maximizing the heat transmission.In the involvement of suction and nonlinear thermal radiation effects,this study attempted to explore the energy transmission features of the inclined magnetohydrodynamic(MHD)stagnation flow of CNTs-hybrid nanofluid across the nonlinear permeable stretching or shrinking sheet.This work also included some noteworthy features like chemical reactions,variable molecular diffusivity,quadratic convection,viscous dissipation,velocity slip and heat omission assessment.Employing appropriate similarity components,the model equations were modified to ODEs and computed by using the HAM technique.The impact of various relevant flow characteristics on movement,heat and concentration profiles was investigated and plotted on a graph.Considering various model factors,the significance of drag friction,heat and mass transfer rate were also computed in tabular and graphical form.This leads to the conclusion that such factors have a considerable impact on the dynamics of fluid as well as other engineering measurements of interest.Furthermore,viscous forces are dominated by increasing the values ofλ_(p),δ_(m)andδ_(q),and as a result,F(ξ)accelerates while the opposite trend is observed for M andφ.The drag friction is boosted by the augmentation M,λ_(p)andφ,but the rate of heat transfer declined.According to our findings,hybrid nanoliquid effects dominate that of ordinary nanofluid in terms of F(ξ),Θ(ξ)andφ(ξ)profiles.The HAM and the numerical technique(shooting method)were found to be in good agreement.展开更多
Together with the development of high-performance advanced electronics,flexible supercapacitors(SCs)with tailored nanostructures have great attraction.Electrochemically deposited nanosheet arrays of nickel magnesium s...Together with the development of high-performance advanced electronics,flexible supercapacitors(SCs)with tailored nanostructures have great attraction.Electrochemically deposited nanosheet arrays of nickel magnesium selenide(NixMg3-xSe4,NMgS)with high capacitance provide high potentials as a positive electrode in flexible SCs.To further enhance their electrochemical properties and long-term cycling stability,a promising strategy of surface engineering with conducting polymer poly(3,4-ethylenedioxythiophene)(PEDOT)is proposed.The present work proposes the construction of PEDOT shielded NMgS(P@NMgS-2)on a flexible carbon cloth substrate via a hierarchical electrodeposition technique.Benefitting from the synergistic effect,the P@NMgS-2 exhibits an excellent areal capacitance value of 1440 mF cm^(-2)at 4 mA cm^(-2).A novel shape-adaptable polymer gel electrolyte-assisted flexible quasi-solid-state hybrid SC(FQHSC)device constructed with P@NMgS-2 as a positive electrode and activated carbon as a negative electrode demonstrates the maximum power and energy density values of 14.13 mW cm^(-2)and 0.18 mWh cm^(-2),respectively,followed by outstanding cycling stability(∼100%capacitance retention over 50,000 cycles).Furthermore,the FQHSC device successfully powered electronic devices with no serious degradation upon bending and twisting for wearable electronic applications.展开更多
In this work,a two-dimensional hybrid model,which consists of a bulk fluid module,a sheath module and an ion Monte-Carlo module,is developed to investigate the modulation of ion energy and angular distributions at dif...In this work,a two-dimensional hybrid model,which consists of a bulk fluid module,a sheath module and an ion Monte-Carlo module,is developed to investigate the modulation of ion energy and angular distributions at different radial positions in a biased argon inductively coupled plasma.The results indicate that when the bias voltage amplitude increases or the bias frequency decreases,the ion energy peak separation width becomes wider.Besides,the widths of the ion energy peaks at the edge of the substrate are smaller than those at the center due to the lower plasma density there,indicating the nonuniformity of the ion energy distribution function(IEDF)along the radial direction.As the pressure increases from 1 to 10 Pa,the discrepancy of the IEDFs at different radial positions becomes more obvious,i.e.the IEDF at the radial edge is characterized by multiple low energy peaks.When a dual frequency bias source is applied,the IEDF exhibits three or four peaks,and it could be modulated efficiently by the relative phase between the two bias frequencies.The results obtained in this work could help to improve the radial uniformity of the IEDF and thus the etching process.展开更多
Cloud storage is widely used by large companies to store vast amounts of data and files,offering flexibility,financial savings,and security.However,information shoplifting poses significant threats,potentially leading...Cloud storage is widely used by large companies to store vast amounts of data and files,offering flexibility,financial savings,and security.However,information shoplifting poses significant threats,potentially leading to poor performance and privacy breaches.Blockchain-based cognitive computing can help protect and maintain information security and privacy in cloud platforms,ensuring businesses can focus on business development.To ensure data security in cloud platforms,this research proposed a blockchain-based Hybridized Data Driven Cognitive Computing(HD2C)model.However,the proposed HD2C framework addresses breaches of the privacy information of mixed participants of the Internet of Things(IoT)in the cloud.HD2C is developed by combining Federated Learning(FL)with a Blockchain consensus algorithm to connect smart contracts with Proof of Authority.The“Data Island”problem can be solved by FL’s emphasis on privacy and lightning-fast processing,while Blockchain provides a decentralized incentive structure that is impervious to poisoning.FL with Blockchain allows quick consensus through smart member selection and verification.The HD2C paradigm significantly improves the computational processing efficiency of intelligent manufacturing.Extensive analysis results derived from IIoT datasets confirm HD2C superiority.When compared to other consensus algorithms,the Blockchain PoA’s foundational cost is significant.The accuracy and memory utilization evaluation results predict the total benefits of the system.In comparison to the values 0.004 and 0.04,the value of 0.4 achieves good accuracy.According to the experiment results,the number of transactions per second has minimal impact on memory requirements.The findings of this study resulted in the development of a brand-new IIoT framework based on blockchain technology.展开更多
Protoplasts derived from common wheat (Triticum aestivum L,. cv. Jinan 177) were fused with UV-treated protoplasts of Agropyron elongatum. (Host) Nevski by PEG method, and fertile asymmetric somatic hybrid plants rese...Protoplasts derived from common wheat (Triticum aestivum L,. cv. Jinan 177) were fused with UV-treated protoplasts of Agropyron elongatum. (Host) Nevski by PEG method, and fertile asymmetric somatic hybrid plants resembling wheat morphology were obtained. The F-2 hybrid plants could be divided into 3 types according to their morphology. Type I hybrids had high and loosely standing stalks with big spikes and grains. Type ii hybrids were dwarf and compact in shape with high tillering ability and smaller spikes. Type III hybrids were similar to type I as a whole but had more compact and erect spikes. All the F-2 hybrid lines were superior to wheat in seed protein content, although some difference existed between themselves. Protein analysis of immature embryos and flag leaves from hybrids by two-dimensional electrophoresis showed that they possessed characteristic proteins of both parents and some new proteins. There existed also some different kinds of proteins in different lines.展开更多
A novel polymer/SiO2 hybrid emulsion(PAES)was prepared by directly mixing colloidal silica with polyacrylate emulsion(PAE)modified by a saline coupling agent.The sol-gel-derived thin films were obtained by addition of...A novel polymer/SiO2 hybrid emulsion(PAES)was prepared by directly mixing colloidal silica with polyacrylate emulsion(PAE)modified by a saline coupling agent.The sol-gel-derived thin films were obtained by addition of co-solvents into the PAES.The effects ofγ-methacryloxypropyltrimethoxysilane(KH-570)content and co-solvent on the properties of PAES films were investigated.Dynamic laser scattering(DLS)data indicate that the average diameter of PAES(96 nm)is slightly larger than that of PAE(89 nm).Transmission electron microscopy (TEM)photo discloses that colloidal silica particles are dispersed uniformly around polyacrylate particles and some of the colloidal silica particles are adsorbed on the surface of PAE particles.The crosslinking degree data and Fourier transform infrared(FT-IR)spectra confirm that the chemical structure of the PAES is changed to form Si-O-Si-polymer crosslinking networks during the film formation.Atomic force microscope(AFM)photos show the solvent induced sol-gel process of colloidal silica and the Si-based polymer distribution on the film surface of the dried PAES.Thermogravimetric analysis(TGA)curves demonstrate that the PAES films display much better thermal stability than PAE.展开更多
Photoacoustic technology in combination with molecular imaging is a highly effective method for accurately diagnosing brain glioma. For glioma detection at a deeper site, contrast agents with higher photoacoustic imag...Photoacoustic technology in combination with molecular imaging is a highly effective method for accurately diagnosing brain glioma. For glioma detection at a deeper site, contrast agents with higher photoacoustic imaging sensitivity are needed. Herein, we report a MoS_2–ICG hybrid with indocyanine green(ICG) conjugated to the surface of MoS_2 nanosheets. The hybrid significantly enhanced photoacoustic imaging sensitivity compared to MoS_2 nanosheets. This conjugation results in remarkably high optical absorbance across a broad near-infrared spectrum, redshifting of the ICG absorption peak and photothermal/photoacoustic conversion efficiency enhancement of ICG. A tumor mass of 3.5 mm beneath the mouse scalp was clearly visualized by using MoS_2–ICG as a contrast agent for the in vivo photoacoustic imaging of orthotopic glioma, which is nearly twofold deeper than the tumors imaged in our previous report using MoS_2 nanosheet. Thus, combined with its good stability and high biocompatibility, the MoS_2–ICG hybrid developed in this study has a great potential for high-efficiency tumor molecular imaging in translational medicine.展开更多
In situ melt polycondensation was proposed to prepare biodegradable aliphatic-aromatic copolyesters/nano-SiO2 hybrids based on terephthalic acid (TPA), poly(L-lactic acid) oligomer (OLLA), 1,4-butanediol (BDO)...In situ melt polycondensation was proposed to prepare biodegradable aliphatic-aromatic copolyesters/nano-SiO2 hybrids based on terephthalic acid (TPA), poly(L-lactic acid) oligomer (OLLA), 1,4-butanediol (BDO) and nano-SiO2. TEM and FT-IR characterizations confirmed that TPA, OLLA and BDO copolymerized to obtain biodegradable copolyesters, poly(butylene terepbthalate-co-lactate) (PBTL), and the abundant hydroxyl groups on the surface of nano-SiO2 provided potential sites for in situ grafting with the simultaneous resulted PBTL. The nano-SiO2 particles were chemically wrapped with PBTL to form PBTL/nano- SiO2 hybrids. Due to the good dispersion and interfacial adhesion of nano-SiO2 particles with the copolyester matrix, the tensile strength and the Young's modulus increased from 5.4 and 5.6 MPa for neat PBTL to 16 and 390 MPa for PBTL/nano-SiO2 hybrids with 5 wt.% nano-SiO2, respectively. The mechanical properties of PBTL/nano-SiO2 hybrids were substantially improved.展开更多
We synthesized a mesoporous film based on TiO2-reduced graphene oxide(RGO)hybrids using a one-step vapor-thermal method without the need for an additional annealing process.The vapor-thermally prepared TiO2-graphene h...We synthesized a mesoporous film based on TiO2-reduced graphene oxide(RGO)hybrids using a one-step vapor-thermal method without the need for an additional annealing process.The vapor-thermally prepared TiO2-graphene hybrid(VTH)features unique structures with an ultra-large specific surface area of^260 m^2 g^-1 and low aggregation,giving rise to enhanced light harvesting and increased charge generation and separation efficiency.It was observed that a mesoporous film with uniform pore distribution is simultaneously obtained during the VTH growth process.When a 5.0 wt%RGO VTH film was used as the active layer in photocatalysis,the highest photocatalytic activity for degradation of methyl orange was achieved.For another,when a 0.75 wt%RGO VTH film was used as the photoanode in a dye-sensitized solar cell,the power conversion efficiency reached 7.58%,which represents an increase of 73.1%compared to a solar cell using an a photoanode of pure TiO2 synthesized by a traditional solvothermal method.It is expected that this facile method for the synthesis of TiO2/graphene hybrid mesoporous films will be useful in practical applications for preparing other metal oxide/graphene hybrids with ultra-high photocatalytic activity and photovoltaic performance.展开更多
In continuous wave CO2 laser-TlG hybrid welding process, the laser energy is not fully utilized because of the absorption and defocusing by plasma in the arc space. Therefore, the optimal welding result can only be ac...In continuous wave CO2 laser-TlG hybrid welding process, the laser energy is not fully utilized because of the absorption and defocusing by plasma in the arc space. Therefore, the optimal welding result can only be achieved in a limited energy range. In order to improve the welding performance further, a novel hybrid welding method--pulse CO2 laser-TIG arc hybrid welding by coordinated control is proposed and investigated. The experimental results indicate that, compared with continuous wave CO2 laser-TIG hybrid welding, the absorption and defocusing of laser energy by plasma are decreased further, and at the same time, the availability ratio of laser and arc energy can be increased when a coordinated frequency is controlled. As a result, the weld appearance is also improved as well as the weld depth is deepened. Furthermore, the effect of frequency and phase of pulse laser and TIG arc on the arc images and welding characteristics is also studied. However, the novel hybrid method has great potentials in the application of industrials from views of techniques and economy.展开更多
Entropy Generation Optimization(EGO)attained huge interest of scientists and researchers due to its numerous applications comprised in mechanical engineering,air conditioners,heat engines,thermal machines,heat exchang...Entropy Generation Optimization(EGO)attained huge interest of scientists and researchers due to its numerous applications comprised in mechanical engineering,air conditioners,heat engines,thermal machines,heat exchange,refrigerators,heat pumps and substance mixing etc.Therefore,the study of radiative hybrid nanofluid(GO-MoS_(2)/C_(2)H_(6)O_(2)–H_(2)O)and the conventional nanofluid(MoS_(2)/C_(2)H_(6)O_(2)–H_(2)O)is conducted in the presence of Lorentz forces.The flow configuration is modeled between the parallel rotating plates in which the lower plate is permeable.The models which govern the flow in rotating system are solved numerically over the domain of interest and furnished the results for the temperature,entropy generation and thermophysical characteristics of the hybrid as well as conventional nanofluids,respectively.It is examined that the thermal profile intensifies against stronger thermal radiations and magnetic field.The surface of the plate is heated due to the imposed thermal radiations and magnetic field which cause the increment in the temperature.It is also observed that the temperature declines against more rotating plates.Further,the entropy production increases for more dissipative effects and declines against more magnetized fluid.Thermal conductivities of the hybrid nanofluid enhances promptly in comparison with regular liquid therefore,under consideration hybrid nanofluid is reliable for the heat transfer.Moreover,dominating thermal transport is perceived for the hybrid nanofluid which showed that hybrid suspension GO-MoS_(2)/C_(2)H_(6)O_(2)–H_(2)O is better for industrial,engineering and technological uses.展开更多
Recently, a kind of hybrid solution MEA-methanol shows a better CO_2 capture performance over aqueous MEA solution. However, the vaporization of methanol is the biggest disadvantage that hinders its application, so it...Recently, a kind of hybrid solution MEA-methanol shows a better CO_2 capture performance over aqueous MEA solution. However, the vaporization of methanol is the biggest disadvantage that hinders its application, so it is necessary to minimize the vaporization of methanol during both the absorption and regeneration processes. In this work, two kinds of hybrid solutions were studied and compared with aqueous MEA solution and MEA-methanol solution, including MEA/TEA/methanol solution and MEA/glycerol/methanol solution. The absorption property of MEA/glycerol/methanol solution is better than aqueous MEA solution within a certain period of time and the absorption property of MEA/TEA/methanol solution is too poor to be used in CO_2 capture. By increasing the concentration of TEA and decreasing the concentration of MEA, the absorption rate, CO_2 capture efficiency and absorption capacity all decreased. Upon adding glycerol, the cyclic capacity decreased and the generation temperature increased, and moreover, the density and viscosity also increased considerably. So after adding TEA and glycerol, the CO_2 capture performance of MEAmethanol solvent cannot be improved.展开更多
Commercial grade weakly basic resin D301 was impregnated with iron through a simple method using ferric chloride. Experiments for single, bisolute and trinary competitive adsorption were carried out to investigate the...Commercial grade weakly basic resin D301 was impregnated with iron through a simple method using ferric chloride. Experiments for single, bisolute and trinary competitive adsorption were carried out to investigate the adsorption behavior of 2-naphthalenesulfonic acid(NSA), sulfuric acid and sulfurous acid from their solution at 298 K onto the novel hybrid iron impregnated D301(Fe-D301). Adsorption affinity of NSA on Fe-D301 was found to be much higher than that of sulfuric acid, while adsorption affinity of sulfuric acid was slightly higher than that of sulfurous acid. The data of single-solute adsorption were fitted to the Langmuir model and the Freundlich adsorption model. The non-ideal competitive adsorbed model coupled with the single-solute adsorption models were used to predict the bisolute and trinary-solute competitive adsorption equilibria. The NICM coupled with the Langmuir model yields the favorable representation of the bisolute and trinary-solute competitive adsorption behavior.展开更多
Hybrid nanoSiO_(2) (HNS) modified cement pastes were explored as a kind of surface protection material (SPM).The carbonation resistance and mechanical properties of SPMs coated samples were tested.Thermogravimetric an...Hybrid nanoSiO_(2) (HNS) modified cement pastes were explored as a kind of surface protection material (SPM).The carbonation resistance and mechanical properties of SPMs coated samples were tested.Thermogravimetric analysis (TGA),X-ray diffraction (XRD),scanning electron microscope (SEM),and mercury intrusion porosimetry (MIP) were further employed to evaluate the chemical composition and microstructure characteristics of SPM.Besides,thermodynamic modeling was adopted to simulate the changes in the phase assemblages of SPM under the carbonation process.The results showed that SPM with 1 wt% HNS could effectively enhance the carbonation resistance.The incorporation of HNS could densify the microstructure and refine the pore structure.Moreover,the thaumasite can be stable at ambient temperature with the addition of HNS,which is beneficial to maintain alkalinity under the carbonation process.展开更多
Gibbons and siamangs (Hylobatidae) are well-known for their rapid chromosomal evolution,which has resulted in high speciation rate within the family.On the other hand,distinct karyotypes do not prevent speciation,al...Gibbons and siamangs (Hylobatidae) are well-known for their rapid chromosomal evolution,which has resulted in high speciation rate within the family.On the other hand,distinct karyotypes do not prevent speciation,allowing interbreeding between individuals in captivity,and the unwanted hybrids are ethically problematic as all gibbon species are endangered or critically endangered.Thus,accurate species identification is crucial for captive breeding,particularly in China where studbooks are unavailable.Identification based on external morphology is difficult,especially for hybrids,because species are usually similar in appearance.In this study,we employed G-banding karyotyping and fluorescence in situ hybridization (FISH) as well as a PCR-based approach to examine karyotypic characteristics and identify crested gibbons of the genus Nomascus from zoos and nature reserves in China.We characterized and identified five karyotypes from 21 individuals of Nomascus.Using karyotypes and mitochondrial and nuclear genes,we identified three purebred species and three hybrids,including one F2 hybrid between N.gabriellae and N.siki.Our results also supported that N.leucogenys and N.siki shared the same inversion on chromosome 7,which resolves arguments from previous studies.Our results demonstrated that both karyotyping and DNA-based approaches were suitable for identifying purebred species,though neither was ideal for hybrid identification.The advantages and disadvantages of both approaches are discussed.Our results further highlight the importance of animal ethics and welfare,which are critical for endangered species in captivity.展开更多
基金supported by the Learning & Academic Research Institution for Master’s and Ph.D. Students and Postdocs (LAMP) Program of the National Research Foundation of Korea (NRF) grant funded by the Ministry of Education (No. RS-2023-00285353)supported by the National Research Foundation of Korea (NRF) grant funded by the Korean government (MSIP) (NRF-2021R1A2C3006662, NRF-2022R1A5A1030054, and 2021R1A2C1091301)+3 种基金the support from Natural Sciences and Engineering Research Council of Canada (NSERC)Canada Foundation for Innovation (CFI)Atlantic Canada Opportunities Agency (ACOA)the New Brunswick Innovation Foundation (NBIF)
文摘The ex-situ incorporation of the secondary SiC reinforcement,along with the in-situ incorporation of the tertiary and quaternary Mg_(3)N_(2) and Si_(3)N_(4) phases,in the primary matrix of Mg_(2)Si is employed in order to provide ultimate wear resistance based on the laser-irradiation-induced inclusion of N_(2) gas during laser powder bed fusion.This is substantialized based on both the thermal diffusion-and chemical reactionbased metallurgy of the Mg_(2)Si–SiC/nitride hybrid composite.This study also proposes a functional platform for systematically modulating a functionally graded structure and modeling build-direction-dependent architectonics during additive manufacturing.This strategy enables the development of a compositional gradient from the center to the edge of each melt pool of the Mg_(2)Si–SiC/nitride hybrid composite.Consequently,the coefficient of friction of the hybrid composite exhibits a 309.3%decrease to–1.67 compared to–0.54 for the conventional nonreinforced Mg_(2)Si structure,while the tensile strength exhibits a 171.3%increase to 831.5 MPa compared to 485.3 MPa for the conventional structure.This outstanding mechanical behavior is due to the(1)the complementary and synergistic reinforcement effects of the SiC and nitride compounds,each of which possesses an intrinsically high hardness,and(2)the strong adhesion of these compounds to the Mg_(2)Si matrix despite their small sizes and low concentrations.
基金funded by King Mongkut’s University of Technology North Bangkok with Contract no.KMUTNB-Post-65-07。
文摘Hybrid nanofluids are remarkable functioning liquids that are intended to reduce the energy loss while maximizing the heat transmission.In the involvement of suction and nonlinear thermal radiation effects,this study attempted to explore the energy transmission features of the inclined magnetohydrodynamic(MHD)stagnation flow of CNTs-hybrid nanofluid across the nonlinear permeable stretching or shrinking sheet.This work also included some noteworthy features like chemical reactions,variable molecular diffusivity,quadratic convection,viscous dissipation,velocity slip and heat omission assessment.Employing appropriate similarity components,the model equations were modified to ODEs and computed by using the HAM technique.The impact of various relevant flow characteristics on movement,heat and concentration profiles was investigated and plotted on a graph.Considering various model factors,the significance of drag friction,heat and mass transfer rate were also computed in tabular and graphical form.This leads to the conclusion that such factors have a considerable impact on the dynamics of fluid as well as other engineering measurements of interest.Furthermore,viscous forces are dominated by increasing the values ofλ_(p),δ_(m)andδ_(q),and as a result,F(ξ)accelerates while the opposite trend is observed for M andφ.The drag friction is boosted by the augmentation M,λ_(p)andφ,but the rate of heat transfer declined.According to our findings,hybrid nanoliquid effects dominate that of ordinary nanofluid in terms of F(ξ),Θ(ξ)andφ(ξ)profiles.The HAM and the numerical technique(shooting method)were found to be in good agreement.
基金This work was supported by the National Research Foundation of Korea Grant funded by the Korea government(MSIP)(No.2018R1A6A1A03025708 and No.2020R1A2B5B01002318).
文摘Together with the development of high-performance advanced electronics,flexible supercapacitors(SCs)with tailored nanostructures have great attraction.Electrochemically deposited nanosheet arrays of nickel magnesium selenide(NixMg3-xSe4,NMgS)with high capacitance provide high potentials as a positive electrode in flexible SCs.To further enhance their electrochemical properties and long-term cycling stability,a promising strategy of surface engineering with conducting polymer poly(3,4-ethylenedioxythiophene)(PEDOT)is proposed.The present work proposes the construction of PEDOT shielded NMgS(P@NMgS-2)on a flexible carbon cloth substrate via a hierarchical electrodeposition technique.Benefitting from the synergistic effect,the P@NMgS-2 exhibits an excellent areal capacitance value of 1440 mF cm^(-2)at 4 mA cm^(-2).A novel shape-adaptable polymer gel electrolyte-assisted flexible quasi-solid-state hybrid SC(FQHSC)device constructed with P@NMgS-2 as a positive electrode and activated carbon as a negative electrode demonstrates the maximum power and energy density values of 14.13 mW cm^(-2)and 0.18 mWh cm^(-2),respectively,followed by outstanding cycling stability(∼100%capacitance retention over 50,000 cycles).Furthermore,the FQHSC device successfully powered electronic devices with no serious degradation upon bending and twisting for wearable electronic applications.
基金financially supported by National Natural Science Foundation of China(Nos.11935005 and 11875101)the Fundamental Research Funds for the Central Universities(No.DUT21LAB110)。
文摘In this work,a two-dimensional hybrid model,which consists of a bulk fluid module,a sheath module and an ion Monte-Carlo module,is developed to investigate the modulation of ion energy and angular distributions at different radial positions in a biased argon inductively coupled plasma.The results indicate that when the bias voltage amplitude increases or the bias frequency decreases,the ion energy peak separation width becomes wider.Besides,the widths of the ion energy peaks at the edge of the substrate are smaller than those at the center due to the lower plasma density there,indicating the nonuniformity of the ion energy distribution function(IEDF)along the radial direction.As the pressure increases from 1 to 10 Pa,the discrepancy of the IEDFs at different radial positions becomes more obvious,i.e.the IEDF at the radial edge is characterized by multiple low energy peaks.When a dual frequency bias source is applied,the IEDF exhibits three or four peaks,and it could be modulated efficiently by the relative phase between the two bias frequencies.The results obtained in this work could help to improve the radial uniformity of the IEDF and thus the etching process.
文摘Cloud storage is widely used by large companies to store vast amounts of data and files,offering flexibility,financial savings,and security.However,information shoplifting poses significant threats,potentially leading to poor performance and privacy breaches.Blockchain-based cognitive computing can help protect and maintain information security and privacy in cloud platforms,ensuring businesses can focus on business development.To ensure data security in cloud platforms,this research proposed a blockchain-based Hybridized Data Driven Cognitive Computing(HD2C)model.However,the proposed HD2C framework addresses breaches of the privacy information of mixed participants of the Internet of Things(IoT)in the cloud.HD2C is developed by combining Federated Learning(FL)with a Blockchain consensus algorithm to connect smart contracts with Proof of Authority.The“Data Island”problem can be solved by FL’s emphasis on privacy and lightning-fast processing,while Blockchain provides a decentralized incentive structure that is impervious to poisoning.FL with Blockchain allows quick consensus through smart member selection and verification.The HD2C paradigm significantly improves the computational processing efficiency of intelligent manufacturing.Extensive analysis results derived from IIoT datasets confirm HD2C superiority.When compared to other consensus algorithms,the Blockchain PoA’s foundational cost is significant.The accuracy and memory utilization evaluation results predict the total benefits of the system.In comparison to the values 0.004 and 0.04,the value of 0.4 achieves good accuracy.According to the experiment results,the number of transactions per second has minimal impact on memory requirements.The findings of this study resulted in the development of a brand-new IIoT framework based on blockchain technology.
文摘Protoplasts derived from common wheat (Triticum aestivum L,. cv. Jinan 177) were fused with UV-treated protoplasts of Agropyron elongatum. (Host) Nevski by PEG method, and fertile asymmetric somatic hybrid plants resembling wheat morphology were obtained. The F-2 hybrid plants could be divided into 3 types according to their morphology. Type I hybrids had high and loosely standing stalks with big spikes and grains. Type ii hybrids were dwarf and compact in shape with high tillering ability and smaller spikes. Type III hybrids were similar to type I as a whole but had more compact and erect spikes. All the F-2 hybrid lines were superior to wheat in seed protein content, although some difference existed between themselves. Protein analysis of immature embryos and flag leaves from hybrids by two-dimensional electrophoresis showed that they possessed characteristic proteins of both parents and some new proteins. There existed also some different kinds of proteins in different lines.
基金Supported by the Program for New Century Excellent Talents in University(NCET-08-0204) National Natural Science Foundation of China(20976060) the Scientific Research Foundation for the Returned Overseas Chinese Scholars State Edu-cation Ministry (China)
文摘A novel polymer/SiO2 hybrid emulsion(PAES)was prepared by directly mixing colloidal silica with polyacrylate emulsion(PAE)modified by a saline coupling agent.The sol-gel-derived thin films were obtained by addition of co-solvents into the PAES.The effects ofγ-methacryloxypropyltrimethoxysilane(KH-570)content and co-solvent on the properties of PAES films were investigated.Dynamic laser scattering(DLS)data indicate that the average diameter of PAES(96 nm)is slightly larger than that of PAE(89 nm).Transmission electron microscopy (TEM)photo discloses that colloidal silica particles are dispersed uniformly around polyacrylate particles and some of the colloidal silica particles are adsorbed on the surface of PAE particles.The crosslinking degree data and Fourier transform infrared(FT-IR)spectra confirm that the chemical structure of the PAES is changed to form Si-O-Si-polymer crosslinking networks during the film formation.Atomic force microscope(AFM)photos show the solvent induced sol-gel process of colloidal silica and the Si-based polymer distribution on the film surface of the dried PAES.Thermogravimetric analysis(TGA)curves demonstrate that the PAES films display much better thermal stability than PAE.
基金National Natural Science Foundation of China (NSFC) Grants 91739117, 81522024, 81427804, 61405234, 81430038 and 61475182National Key Basic Research (973) Program of China Grant 2014CB744503 and 2015CB755500+3 种基金Guangdong Natural Science Foundation Grant 2014B050505013 and 2014A030312006Shenzhen Science and Technology Innovation Grant JCYJ20170413153129570, JCYJ20160531175040976, JCYJ 20150521144321005, JCYJ20160608214524052, JCYJ201604221 53149834 JCYJ20150731154850923SIAT Innovation Program for Excellent Young Researchers 201510
文摘Photoacoustic technology in combination with molecular imaging is a highly effective method for accurately diagnosing brain glioma. For glioma detection at a deeper site, contrast agents with higher photoacoustic imaging sensitivity are needed. Herein, we report a MoS_2–ICG hybrid with indocyanine green(ICG) conjugated to the surface of MoS_2 nanosheets. The hybrid significantly enhanced photoacoustic imaging sensitivity compared to MoS_2 nanosheets. This conjugation results in remarkably high optical absorbance across a broad near-infrared spectrum, redshifting of the ICG absorption peak and photothermal/photoacoustic conversion efficiency enhancement of ICG. A tumor mass of 3.5 mm beneath the mouse scalp was clearly visualized by using MoS_2–ICG as a contrast agent for the in vivo photoacoustic imaging of orthotopic glioma, which is nearly twofold deeper than the tumors imaged in our previous report using MoS_2 nanosheet. Thus, combined with its good stability and high biocompatibility, the MoS_2–ICG hybrid developed in this study has a great potential for high-efficiency tumor molecular imaging in translational medicine.
基金support from the Natural Science Foundation of Ningbo(No.2007A610030)Science and Technology Department of Zhejiang Province(No.2008C11092-2)
文摘In situ melt polycondensation was proposed to prepare biodegradable aliphatic-aromatic copolyesters/nano-SiO2 hybrids based on terephthalic acid (TPA), poly(L-lactic acid) oligomer (OLLA), 1,4-butanediol (BDO) and nano-SiO2. TEM and FT-IR characterizations confirmed that TPA, OLLA and BDO copolymerized to obtain biodegradable copolyesters, poly(butylene terepbthalate-co-lactate) (PBTL), and the abundant hydroxyl groups on the surface of nano-SiO2 provided potential sites for in situ grafting with the simultaneous resulted PBTL. The nano-SiO2 particles were chemically wrapped with PBTL to form PBTL/nano- SiO2 hybrids. Due to the good dispersion and interfacial adhesion of nano-SiO2 particles with the copolyester matrix, the tensile strength and the Young's modulus increased from 5.4 and 5.6 MPa for neat PBTL to 16 and 390 MPa for PBTL/nano-SiO2 hybrids with 5 wt.% nano-SiO2, respectively. The mechanical properties of PBTL/nano-SiO2 hybrids were substantially improved.
文摘We synthesized a mesoporous film based on TiO2-reduced graphene oxide(RGO)hybrids using a one-step vapor-thermal method without the need for an additional annealing process.The vapor-thermally prepared TiO2-graphene hybrid(VTH)features unique structures with an ultra-large specific surface area of^260 m^2 g^-1 and low aggregation,giving rise to enhanced light harvesting and increased charge generation and separation efficiency.It was observed that a mesoporous film with uniform pore distribution is simultaneously obtained during the VTH growth process.When a 5.0 wt%RGO VTH film was used as the active layer in photocatalysis,the highest photocatalytic activity for degradation of methyl orange was achieved.For another,when a 0.75 wt%RGO VTH film was used as the photoanode in a dye-sensitized solar cell,the power conversion efficiency reached 7.58%,which represents an increase of 73.1%compared to a solar cell using an a photoanode of pure TiO2 synthesized by a traditional solvothermal method.It is expected that this facile method for the synthesis of TiO2/graphene hybrid mesoporous films will be useful in practical applications for preparing other metal oxide/graphene hybrids with ultra-high photocatalytic activity and photovoltaic performance.
文摘In continuous wave CO2 laser-TlG hybrid welding process, the laser energy is not fully utilized because of the absorption and defocusing by plasma in the arc space. Therefore, the optimal welding result can only be achieved in a limited energy range. In order to improve the welding performance further, a novel hybrid welding method--pulse CO2 laser-TIG arc hybrid welding by coordinated control is proposed and investigated. The experimental results indicate that, compared with continuous wave CO2 laser-TIG hybrid welding, the absorption and defocusing of laser energy by plasma are decreased further, and at the same time, the availability ratio of laser and arc energy can be increased when a coordinated frequency is controlled. As a result, the weld appearance is also improved as well as the weld depth is deepened. Furthermore, the effect of frequency and phase of pulse laser and TIG arc on the arc images and welding characteristics is also studied. However, the novel hybrid method has great potentials in the application of industrials from views of techniques and economy.
文摘Entropy Generation Optimization(EGO)attained huge interest of scientists and researchers due to its numerous applications comprised in mechanical engineering,air conditioners,heat engines,thermal machines,heat exchange,refrigerators,heat pumps and substance mixing etc.Therefore,the study of radiative hybrid nanofluid(GO-MoS_(2)/C_(2)H_(6)O_(2)–H_(2)O)and the conventional nanofluid(MoS_(2)/C_(2)H_(6)O_(2)–H_(2)O)is conducted in the presence of Lorentz forces.The flow configuration is modeled between the parallel rotating plates in which the lower plate is permeable.The models which govern the flow in rotating system are solved numerically over the domain of interest and furnished the results for the temperature,entropy generation and thermophysical characteristics of the hybrid as well as conventional nanofluids,respectively.It is examined that the thermal profile intensifies against stronger thermal radiations and magnetic field.The surface of the plate is heated due to the imposed thermal radiations and magnetic field which cause the increment in the temperature.It is also observed that the temperature declines against more rotating plates.Further,the entropy production increases for more dissipative effects and declines against more magnetized fluid.Thermal conductivities of the hybrid nanofluid enhances promptly in comparison with regular liquid therefore,under consideration hybrid nanofluid is reliable for the heat transfer.Moreover,dominating thermal transport is perceived for the hybrid nanofluid which showed that hybrid suspension GO-MoS_(2)/C_(2)H_(6)O_(2)–H_(2)O is better for industrial,engineering and technological uses.
基金supported by the Sinopec Ningbo Engineering Co., Ltd. (No. 14850000-14-ZC0609-0003, H8XY-0032)
文摘Recently, a kind of hybrid solution MEA-methanol shows a better CO_2 capture performance over aqueous MEA solution. However, the vaporization of methanol is the biggest disadvantage that hinders its application, so it is necessary to minimize the vaporization of methanol during both the absorption and regeneration processes. In this work, two kinds of hybrid solutions were studied and compared with aqueous MEA solution and MEA-methanol solution, including MEA/TEA/methanol solution and MEA/glycerol/methanol solution. The absorption property of MEA/glycerol/methanol solution is better than aqueous MEA solution within a certain period of time and the absorption property of MEA/TEA/methanol solution is too poor to be used in CO_2 capture. By increasing the concentration of TEA and decreasing the concentration of MEA, the absorption rate, CO_2 capture efficiency and absorption capacity all decreased. Upon adding glycerol, the cyclic capacity decreased and the generation temperature increased, and moreover, the density and viscosity also increased considerably. So after adding TEA and glycerol, the CO_2 capture performance of MEAmethanol solvent cannot be improved.
基金Supported by the National Natural Science Foundation of China(No.21276027)the Higher Educational Science and Technology Program of Shandong Province,China(No.J14LC05)
文摘Commercial grade weakly basic resin D301 was impregnated with iron through a simple method using ferric chloride. Experiments for single, bisolute and trinary competitive adsorption were carried out to investigate the adsorption behavior of 2-naphthalenesulfonic acid(NSA), sulfuric acid and sulfurous acid from their solution at 298 K onto the novel hybrid iron impregnated D301(Fe-D301). Adsorption affinity of NSA on Fe-D301 was found to be much higher than that of sulfuric acid, while adsorption affinity of sulfuric acid was slightly higher than that of sulfurous acid. The data of single-solute adsorption were fitted to the Langmuir model and the Freundlich adsorption model. The non-ideal competitive adsorbed model coupled with the single-solute adsorption models were used to predict the bisolute and trinary-solute competitive adsorption equilibria. The NICM coupled with the Langmuir model yields the favorable representation of the bisolute and trinary-solute competitive adsorption behavior.
基金Funded by the National Natural Science Foundation of China (Nos.51808188, 52178202, 52108206)the Fundamental Research Funds for the Central Universities (No.B210201041)。
文摘Hybrid nanoSiO_(2) (HNS) modified cement pastes were explored as a kind of surface protection material (SPM).The carbonation resistance and mechanical properties of SPMs coated samples were tested.Thermogravimetric analysis (TGA),X-ray diffraction (XRD),scanning electron microscope (SEM),and mercury intrusion porosimetry (MIP) were further employed to evaluate the chemical composition and microstructure characteristics of SPM.Besides,thermodynamic modeling was adopted to simulate the changes in the phase assemblages of SPM under the carbonation process.The results showed that SPM with 1 wt% HNS could effectively enhance the carbonation resistance.The incorporation of HNS could densify the microstructure and refine the pore structure.Moreover,the thaumasite can be stable at ambient temperature with the addition of HNS,which is beneficial to maintain alkalinity under the carbonation process.
基金supported by the Wildlife Conservation Program of Yunnan Province,ChinaK.H. was supported by a JSPS Postdoctoral Fellowship for Overseas Researchers(P16092)
文摘Gibbons and siamangs (Hylobatidae) are well-known for their rapid chromosomal evolution,which has resulted in high speciation rate within the family.On the other hand,distinct karyotypes do not prevent speciation,allowing interbreeding between individuals in captivity,and the unwanted hybrids are ethically problematic as all gibbon species are endangered or critically endangered.Thus,accurate species identification is crucial for captive breeding,particularly in China where studbooks are unavailable.Identification based on external morphology is difficult,especially for hybrids,because species are usually similar in appearance.In this study,we employed G-banding karyotyping and fluorescence in situ hybridization (FISH) as well as a PCR-based approach to examine karyotypic characteristics and identify crested gibbons of the genus Nomascus from zoos and nature reserves in China.We characterized and identified five karyotypes from 21 individuals of Nomascus.Using karyotypes and mitochondrial and nuclear genes,we identified three purebred species and three hybrids,including one F2 hybrid between N.gabriellae and N.siki.Our results also supported that N.leucogenys and N.siki shared the same inversion on chromosome 7,which resolves arguments from previous studies.Our results demonstrated that both karyotyping and DNA-based approaches were suitable for identifying purebred species,though neither was ideal for hybrid identification.The advantages and disadvantages of both approaches are discussed.Our results further highlight the importance of animal ethics and welfare,which are critical for endangered species in captivity.