The Jinding Zn-Pb deposit,Yunnan Province, southwestern China,represents the youngest,only continental sediment-hosted giant Zn-Pb deposit in the world.Various kinds of organic matters,such as the kerogen,light-and he...The Jinding Zn-Pb deposit,Yunnan Province, southwestern China,represents the youngest,only continental sediment-hosted giant Zn-Pb deposit in the world.Various kinds of organic matters,such as the kerogen,light-and heavy-oil,hydrocarbon gas, bitumen of different occurrences and maturation,have been observed in recent underground and open pit mining.Oil-gas traces and oil-and methane-in-展开更多
The?Annage gold deposit is located at the east part of the eastern Kunlun orogenic belt. The characteristics of ore-forming fluids and metallogenesis were discussed by using fluid petrography, micro-thermometry and hy...The?Annage gold deposit is located at the east part of the eastern Kunlun orogenic belt. The characteristics of ore-forming fluids and metallogenesis were discussed by using fluid petrography, micro-thermometry and hydrogen-oxygen isotope analysis. Three stages, namely quartz-pyrite stage (A), quartz-polymetallic-sulfide stage (B) and quartz-ankerite stage (C) were included in the hydrothermal process as indicated by the results of this study. Inclusions developed in ore-bearing quartz veins from stages A and B are of three types: aqueous inclusions (type I), CO2-bearing inclusions (type II) and pure CO2?inclusions (type III). All three types of inclusions, mainly type I, are presented in stage A, having homogenization temperatures at 180°C - 360°C, and salinities ranging from 0.53% to 21.44%. In addition to development of type I inclusions, type II and III inclusions increase significantly in stage B, with homogenization temperatures ranging from 160°C to 330°C, and salinities are from 1.32% to 22.01%. Based on micro-thermometry, fluids in Annage deposit are of H2O-NaCl-CO2?type with medium-high temperature (140°C - 395°C) and medium-low salinity (0.53% - 22.01%). Results of hydrogen-oxygen isotope analysis show that ore-forming fluid is mainly CO2-rich magmatic fluid, mixed with shallow groundwater or metamorphic hydrothermal in the late mineralization stages. Calculated metallogenic pressures are in the range of 79 - 130MPa corresponding to a maximum depth of 4.8 km. The Annage deposit is a mesothermal quartz vein type gold deposit.展开更多
[ Objective l The study aimed to discuss the optimal conditions of extracting humic acids from brown coal using hydrogen peroxide （H202）. [ Method] Fulvic acid （FA） was prepared through oxidizing the brown coal fr...[ Objective l The study aimed to discuss the optimal conditions of extracting humic acids from brown coal using hydrogen peroxide （H202）. [ Method] Fulvic acid （FA） was prepared through oxidizing the brown coal from Qujing City, Yunnan Province using H202, and humic acids were extracted from the original brown coal and its residues respectively, then the dominate constituents of humic acids were obtained by using pH grading method, finally their chemical composition of humid acids was characterized by Fourier transform infrared spectrometry and func- tional group content analysis. [Result] The mass ratio of the brown coal and oxidant affected the yield of FA most obviously, followed by oxidization temperature and duration, while oxidant concentration had no obvious effect. The optimum conditions were determined as follows： coal-oxidant ratio was 1 ： 0.60, oxidization temperature was 45 ℃, oxidization duration was 210 min, and the concentration of hydrogen peroxide was 20%. Under the conditions, the yield of FA was up to 20.40%. Analysis of component properties indicated that the content of carboxyl and total acidic groups in FA improved obviously under the optimum conditions, and the content of active functional groups in OHA was higher than that of HA, while the domi- nate constituents of OHA needed higher pH during precipitation compared with those of HA. [ Conclusion] The research could provide a new method to prepare good humic acids using brown coal,展开更多
文摘The Jinding Zn-Pb deposit,Yunnan Province, southwestern China,represents the youngest,only continental sediment-hosted giant Zn-Pb deposit in the world.Various kinds of organic matters,such as the kerogen,light-and heavy-oil,hydrocarbon gas, bitumen of different occurrences and maturation,have been observed in recent underground and open pit mining.Oil-gas traces and oil-and methane-in-
文摘The?Annage gold deposit is located at the east part of the eastern Kunlun orogenic belt. The characteristics of ore-forming fluids and metallogenesis were discussed by using fluid petrography, micro-thermometry and hydrogen-oxygen isotope analysis. Three stages, namely quartz-pyrite stage (A), quartz-polymetallic-sulfide stage (B) and quartz-ankerite stage (C) were included in the hydrothermal process as indicated by the results of this study. Inclusions developed in ore-bearing quartz veins from stages A and B are of three types: aqueous inclusions (type I), CO2-bearing inclusions (type II) and pure CO2?inclusions (type III). All three types of inclusions, mainly type I, are presented in stage A, having homogenization temperatures at 180°C - 360°C, and salinities ranging from 0.53% to 21.44%. In addition to development of type I inclusions, type II and III inclusions increase significantly in stage B, with homogenization temperatures ranging from 160°C to 330°C, and salinities are from 1.32% to 22.01%. Based on micro-thermometry, fluids in Annage deposit are of H2O-NaCl-CO2?type with medium-high temperature (140°C - 395°C) and medium-low salinity (0.53% - 22.01%). Results of hydrogen-oxygen isotope analysis show that ore-forming fluid is mainly CO2-rich magmatic fluid, mixed with shallow groundwater or metamorphic hydrothermal in the late mineralization stages. Calculated metallogenic pressures are in the range of 79 - 130MPa corresponding to a maximum depth of 4.8 km. The Annage deposit is a mesothermal quartz vein type gold deposit.
基金Supported by Scientific Research Foundation of Educational Commission of Yunnan Province,China (08C0186)
文摘[ Objective l The study aimed to discuss the optimal conditions of extracting humic acids from brown coal using hydrogen peroxide （H202）. [ Method] Fulvic acid （FA） was prepared through oxidizing the brown coal from Qujing City, Yunnan Province using H202, and humic acids were extracted from the original brown coal and its residues respectively, then the dominate constituents of humic acids were obtained by using pH grading method, finally their chemical composition of humid acids was characterized by Fourier transform infrared spectrometry and func- tional group content analysis. [Result] The mass ratio of the brown coal and oxidant affected the yield of FA most obviously, followed by oxidization temperature and duration, while oxidant concentration had no obvious effect. The optimum conditions were determined as follows： coal-oxidant ratio was 1 ： 0.60, oxidization temperature was 45 ℃, oxidization duration was 210 min, and the concentration of hydrogen peroxide was 20%. Under the conditions, the yield of FA was up to 20.40%. Analysis of component properties indicated that the content of carboxyl and total acidic groups in FA improved obviously under the optimum conditions, and the content of active functional groups in OHA was higher than that of HA, while the domi- nate constituents of OHA needed higher pH during precipitation compared with those of HA. [ Conclusion] The research could provide a new method to prepare good humic acids using brown coal,
