The effect of reverse pressure.on theological behavior has been studied. The apparatus is a capillary rheometer with counter pressure chamber being held at a high reverse pressure by means of a cock. The results show ...The effect of reverse pressure.on theological behavior has been studied. The apparatus is a capillary rheometer with counter pressure chamber being held at a high reverse pressure by means of a cock. The results show that with the increase in temperature, the shear viscosity of hydrophilic PET is reduced. It is different that the effect of temperature on shear viscosity is varied under the condition of all shear rates or all pressures, and the effect is more prominent at 50 MPa or at 216 s^-1. At the same time, the pressure coefficients decrease with increasing the shear rate and the temperature and tend to reach a constant value nearly at the temperature of 290 ℃.展开更多
基金financially supported by the National "Twelfth Five-Year" Plan for Science&Technology(2011BAE05B00)the State Key Laboratory of Hollow Fiber Membrane Materials and Processes
文摘The effect of reverse pressure.on theological behavior has been studied. The apparatus is a capillary rheometer with counter pressure chamber being held at a high reverse pressure by means of a cock. The results show that with the increase in temperature, the shear viscosity of hydrophilic PET is reduced. It is different that the effect of temperature on shear viscosity is varied under the condition of all shear rates or all pressures, and the effect is more prominent at 50 MPa or at 216 s^-1. At the same time, the pressure coefficients decrease with increasing the shear rate and the temperature and tend to reach a constant value nearly at the temperature of 290 ℃.