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Microwave assisted synthesis & properties of nano HA-TCP biphasic calcium phosphate 被引量:3
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作者 E.Ghomash Pasand A.Nemati +2 位作者 M.Solati-Hashjin K.Arzani A.Farzadi 《International Journal of Minerals,Metallurgy and Materials》 SCIE EI CAS CSCD 2012年第5期441-445,共5页
Biphasic calcium phosphate (BCP) nanopowders were synthesized by using microwave and non-microwave irradiation assisted processes. The synthesized powders were pressed under a pressure of 90 MPa, and then were sinte... Biphasic calcium phosphate (BCP) nanopowders were synthesized by using microwave and non-microwave irradiation assisted processes. The synthesized powders were pressed under a pressure of 90 MPa, and then were sintered at 1000-1200℃ for 1 h. The mechanical properties of the samples were investigated. The formed phases and microstructures were characterized by X-ray diffraction (XRD) and scanning electron microscopy (SEM). The results showed that the synthesis time was shorter, along with a more homogeneous microstructure, when the microwave irradiation assisted method was applied. The compression strength and the Young's modulus of the samples synthesized with microwave irradiation were about 60 MPa and 3 GPa, but those of the samples synthesized without microwave irradiation were about 30 MPa and 2 GPa, respectively. XRD patterns of the microwave irradiation assisted and non-microwave irradiation assisted nanopowders showed the coexistence of hydroxyapatite (HA) and lricalcium phosphate (TCP) phases in the system. 展开更多
关键词 BIOCERAMICS calcium phosphate hydroxyapatite ha Wicalcium phosphate nanoparticles (TCP) mechanical properties microwave irradiation
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Calcium Phosphate Biomaterials: An Update
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作者 Racquel Z LeGeros John P LeGeros 《Journal of Wuhan University of Technology(Materials Science)》 SCIE EI CAS 2005年第B12期1-6,共6页
Current calcium phosphate ( CaP ) biomaterials for bone repair, substitution, augmentation and regeneration include hydroxyapatite ( HA ) from synthetic or biologic origin, beta-tricaicium phosphate ( β- TCP ),... Current calcium phosphate ( CaP ) biomaterials for bone repair, substitution, augmentation and regeneration include hydroxyapatite ( HA ) from synthetic or biologic origin, beta-tricaicium phosphate ( β- TCP ), biphasic calcium phosphate (BCP), and are available as granules, porous blocks, components of compashes (CaP/pollymer) cements, and as coatings on orthopedic and dental implants. Experimental calcium phosphate biomaterials include CO3^- and F-substituted apatites, Mg-and Zn-substituted β-TCP, calcium phosphate glasses, This paper is a brief review of the different types of CaP biomaterials and their properties such as bioactivity , osteoconductivity , osteoinductivity. 展开更多
关键词 calcium phosphates ha β- TCP BCP calcium phosphate cement implant coatings bonegrafts
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桑蚕丝素蛋白初始结构对其矿化作用的影响 被引量:19
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作者 姚菊明 魏克民 +3 位作者 励丽 孔祥东 祝永强 林凤 《化学学报》 SCIE CAS CSCD 北大核心 2007年第7期635-639,共5页
以碱金属离子诱导桑蚕丝素蛋白溶液发生构象转变,研究了蛋白质初始结构对其矿化作用的影响.FT-IR,XRD和SEM等测试结果显示,未经任何处理的桑蚕丝素蛋白溶液矿化后形成片状复合物,其无机相以二水磷酸氢钙(DCPD)为主;而经过K+和Na+金属离... 以碱金属离子诱导桑蚕丝素蛋白溶液发生构象转变,研究了蛋白质初始结构对其矿化作用的影响.FT-IR,XRD和SEM等测试结果显示,未经任何处理的桑蚕丝素蛋白溶液矿化后形成片状复合物,其无机相以二水磷酸氢钙(DCPD)为主;而经过K+和Na+金属离子处理后,桑蚕丝素溶液的结构由无规线团/螺旋构象向β-折叠发生转变,矿化后成纤维状,并相互结合呈现纳米级的三维多孔结构,其无机相以热力学稳定的羟基磷灰石(HA)为主.可以认为,丝素蛋白结构转化为较伸展的β-折叠后,使得更多的亲水基团暴露在外面,在丝素蛋白分子不断凝聚成纤过程中,HA结晶快速生长并附着在这些微纤上,最终形成纤维状的丝素蛋白/HA复合物.该结果为阐明蛋白质的生物矿化过程及其调控机理提供了理论依据,同时可以从矿化复合物的形成来反映这些微量元素可能对骨组织形成的影响,为临床骨组织的修复提供一定的参考. 展开更多
关键词 桑蚕丝素 碱金属离子 磷酸钙 羟基磷灰石 生物矿化 蛋白质结构
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羟基磷灰石人工骨在鞍鼻畸形整复中的应用 被引量:1
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作者 魏海刚 李蜀光 王富森 《中国美容医学》 CAS 2003年第5期529-530,共2页
目的:探讨利用羟基磷灰石人工骨修复鞍鼻畸形的实用性和可行性。方法:自1995年1月至2002年3月,应用羟基磷灰石人工骨自鼻小柱基底部“U”形切口填充修复鞍鼻畸形160例。结果:共治疗160例,158例术后鼻外观良好,曲线流畅、自然,无感染,获... 目的:探讨利用羟基磷灰石人工骨修复鞍鼻畸形的实用性和可行性。方法:自1995年1月至2002年3月,应用羟基磷灰石人工骨自鼻小柱基底部“U”形切口填充修复鞍鼻畸形160例。结果:共治疗160例,158例术后鼻外观良好,曲线流畅、自然,无感染,获得了满意的修复效果。2例术后鼻外形欠佳,经Ⅱ期整复后亦取得了满意效果。结论:羟基磷灰石人工骨是目前整复鞍鼻畸形理想的生物材料之一。 展开更多
关键词 羟基磷灰石人工骨 鞍鼻 畸形 整复 临床应用
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