Fine and hyperfine structures of pionic helium atoms

The fine and hyperfine structures of pionic helium metastable states is calculated within the formalism of the Breit-Pauli Hamiltonian by using the variationally generated wave functions in Hylleraas coordinates.Our results not only verify the existing values of Hori et al.[Phys.Rev.A 89,042515(2014)]for the fine structure of π^(4)He^(+),but also determine the hyperfine structure of π^(3)He^(+).

Collisional Line Assignments and Hyperfine Structure Interpretation in Cs22^3△1g State

Accurately known energy level structure of the A＇∑u＋b3 IIu complex of states from a recent global de-perturbation of these states has enabled additional assignments of 140 perturbation facilitated infrared-infrared double resonance （PFIIDR） transitions to the 2^3△1g state from collisionally populated intermediate 1 ＋ A Eu levels. Together with the 221 previously observed 2^3△1g←A1∑u＋←X1∑g＋ Eu X Eg double resonance lines [J. Chem. Phys. 128, 204313 （2008）], molecular constants and the Rydberg-Klein-Rees potential energy curve of the 23△1g state have been recalculated （excluding 54 perturbed levels）. The centrifugal distortion constant has been determined and agrees well with the value calculated based on standard empirical formulas. The hyperfine structure of the 23△1g state, which has not resolved in our sub-Doppler excitation spectra of the 23△1g state, has been interpreted with a preliminary simulation.

Hyperfine structures and the field effects of IBr molecule in its rovibronic ground state

Hyperfine structures and the field effects of IBr molecule in its rovibronic ground state are theoretically studied by diagonalizing the effective Hamiltonian matrix.Perturbations of high-J levels up to 4 are taken into account when studying the hyperfine sub-levels of the J=0 level,and thus,an 80×80 matrix is constructed and solved.Some of the experimentally absent molecular constants are computed using Dalton program.Our results will be helpful in the experimental investigation of manipulation and further cooling of cold IBr molecules.

Stark effect of the hyperfine structure of ICl in its rovibronic ground state:Towards further molecular cooling

Hyperfine structures of IC1 in its vibronic ground state due to the nuclear spin and electric quadruple interactions are determined by diagonalizing the effective Hamiltonian matrix. Furthermore, the Stark sub-levels are precisely determined as well. The results are helpful for electro-static manipulation （trapping or further cooling） of cold IC1 molecules. For example, an electric field of 1000 V/cm can trap IC1 molecules less than 637μK in the lowest hyperfine level.

Determination of hyperfine structure constants of 5D_(5/2) and 7S_(1/2) states of rubidium in cascade atomic system

We present a method to precisely determine the hyperfine structure constants of the rubidium 5D（5/2） and 7S（1/2） states in a cascade atomic system. The probe laser is coupled to the 5S（1/2）→ 5P（3/2） hyperfine transition, while the coupling laser is scanned over the 5P（3/2）→ 5D（5/2）（7S（1/2）） transition. The high-resolution double-resonance optical pumping spectra are obtained with two counter-propagating laser beams acting on rubidium vapor. The hyperfine splitting structures are accurately measured by an optical frequency ruler based on the acousto-optic modulator, thus, the magnetic dipole hyperfine coupling constant A and quadrupole coupling constant B are determined. It is of great significance for the atomic hyperfine structure and fundamental physics research.

Hyperfine Structure of Several Soils from Western Hubei and Inner Mongolia Studied by Mossbauer Spectroscopy

Soil samples taken from Xilamuren Grassland,Resonant Sand Bay,Inner Mongolia,and Yichang,western Hubei Province were investigated by Mssbauer spectroscopy at room temperature and 20 K.This was supplemented with phase identification and elemental analysis to obtain information about the composition and structure types of Fe-containing compounds.The samples collected from both Xilamuren Grassland and Resonant Sand Bay,Inner Mongolia were found to have small amount of iron 1%-2%.The main phases were determined as silica,albite,and microcline.Two or three dominant doublets were observed in the Mssbauer spectra of these samples,respectively and identified as corresponding to the valence states of Fe2＋and Fe3＋.A sextet observed in all the spectra is attributed to the hematite phase.Low temperature Mssbauer measurements have revealed Morin transition.

Mixed-field effect at the hyperfine level of^(127)I^(79)Br in its rovibronic ground state:Toward field manipulation of cold molecules

The mixed-field effect at the hyperfine level of the rovibronic ground state of the^(127)I^(79)Br(X^(1)Σ,v=0,J=0)molecule is computed on the J-I uncoupled basis of|JM_(J)I_(1)M_(1)I_(2)M_(2)>,where J is the molecular total angular momentum excluding nuclear spin,M_J is the projection number of J,I_(1) and I_(2) are the nuclear spins of the iodine and bromine atoms,and M_(1) and M_(2) are the projection numbers of I_(1) and I_(2),respectively.When the two applied electric and magnetic fields are parallel,the perturbations are rare and only one perturbation is observed in a relatively large field regime in our computation range.However,when the two fields are off-parallel,the perturbations increase significantly and some sublevels show the Feshbach-like resonance phenomenon.Therefore,such sublevels transit between weak-field seeking and strong-field seeking repeatedly,which can be utilized to enhance or suppress cold molecular collision and chemical reaction rates.Such behavior of the molecular hyperfine structure in the mixed off-parallel fields may also be utilized to construct an electric-field-assisted anti-Helmholtz magnetic trap for cold molecules and to realize evaporative cooling of cold molecules(sub-mK)into the ultracold regime(μK).

The hyperfine structure of electron spin resonance spectrum of tricobalt cluster radical anion CH_3CCo_3(CO)_9^-

CH_3CCo_3(CO)_9 was synthesized from the reaction between chloralose and Co_2(CO)_. The radical anion was generated by electrochemical reduction,and electron spin resonance spectra in THF were recorded by in situ electrolysis in the sample tube in the ESR cavity at 298 and 110K with the spectral data

Hyperfine Constants for Low-Lying States in ^137Ba^＋

Relativistic many-body perturbation calculation is applied to calculate the hyperfine constants for the lowlying states 6S1/2, 6P1/2, 6P3/2, 5D3/2, and 5D5/2 in the alkaline earth ion ^137Ba^＋. The zeroth-order hyperfine constants are calculated with Dirac-Fock wave functions, and the finite basis sets of the Dirac-Fock equation are constructed by B splines. With the finite basis sets, the core polarization and the correlation effect are calculated. The final results for magnetic dipole hyperfine a constants are obtained.

Control and data acquisition system for collinear laser spectroscopy experiments

A control and data acquisition system was implemented for the recently developed collinear laser spectroscopy setup.This system is dedicated to data recording,storage,processing,monitoring of the beam intensity and energy,and visualization of various spectra.In comparison to the conventional resonance nuclear reaction system,the key technique is the precise synchronization of the detected counts with the actual scanning voltage(or probing laser frequency).The functions of the system were tested by measuring the hyperfine structure spectra of stable calcium(e.g.,^(40)Ca^(+))and radioactive potassium(e.g.,^(38)K)in the bunched and continuous modes,respectively.This system will be routinely applied and further improved in subsequent laser spectroscopy experiments on unstable isotopes at the Beijing Radioactive Ion-beam Facility(BRIF).

Numerical studies of isotopic selective photoionization of ytterbium in a three-step ionization scheme

Selective photoionization of ytterbium isotope is studied numerically based on a three-step photoionization scheme,4f^(14)6s^(21)S_0(0 cm^(-1))→4f~(14)6s6p~3P_1(17992.008 cm^(-1))→(4f~(13)6s~26p)(7/2,3/2)_2(35196.98 cm^(-1))→auto-ionization state(52353 cm^(-1))→Yb^(+),by the density matrix theory with the consideration of atomic hyperfine structures and magnetic sublevels.To examine the physical model,the numerical isotopic abundance of ytterbium is compared with that from mass spectroscopy experiment,showing that they are in good agreement with each other.The excitation process and ionization process of ytterbium,especially for odd isotopes,are discussed and analyzed in detail on this basis.The effects of frequency detuning,power densities,spectral bandwidths,polarization of two excitation lasers,and atomic Doppler broadening on the total ionization yield and isotopic abundance are investigated numerically and the optimal excitation conditions for~(176)Yb enrichment are identified semi-quantitatively.

Characterization of Fe_3Si-based coatings on low silicon steel by pulsed Nd:YAG laser cladding

The Fe3Si based coating was produced on the Fe-1 Si steel surface by a pulsed Nd：YAG （yttrium aluminum garnet） laser. Its phase constitution and microstructure were characterized by using X-ray diffraction （XRD）, optical microscope （OM）, and field emission scanning electron microscope （FESEM） with associated energy dispersive spectroscopy （EDS） and transmission electron microscopy （TEM）. The hyperfine structure of the coating was studied by Mrssbauer spectra （MS） and the magnetic property was also measured at room temperature by a vibrating sample magnetometer （VSM）. The obtained coating is pore and crack-free with dense microstructure and high Si content. The metallurgical bonding between the coating and the substrate was realized. The microstructure of the coating is typical fine dendrites. The major phase was confirmed by XRD and TEM to be the ordering D03 structured Fe3Si phase. In addition, there were smaller amounts of the Fe5Si3 phase and the γ-Fe phase in the coating. Compared with the substrate, the laser cladding coating has a lower saturation magnetization and a higher coercive force. The poor magnetic property might be because of rapid solidification microstructure and phase constitution in the coating.

Variation of the Observed Widths of La I Lines with the Energy of the Upper Excited Levels, Demonstrated on Previously Unknown Energy Levels

We performed systematic laser spectroscopic investigations of La I spectral lines, using optogalvanic detection. Sixteen previously unknown even parity levels, having energies between 40,300 and 44,300 cm-1, are reported. These levels classify altogether 67 lines, not listed in spectral tables. The new levels were found due to the observation of the depopulation of the lower levels of the excited transitions. We found a remarkable variation of the observed widths of single hyperfine structure components dependent on the energy of the upper excited levels. Some levels having energies higher than 43,000 cm-1 appear to have a very high ionization probability.

Measurement of niobium reaction rate for material surveillance tests in fast reactors

A highly accurate and precise technique for measurement of the 93 Nb(n,n’)93m Nb reaction rate was established for the material surveillance tests,etc.in fast reactors.The self-absorption effect on the measurement of the characteristic X-rays emitted by 93m Nb was decreased by the dissolution and evaporation to dryness of niobium dosimeter.A highly precise count of the number of 93 Nb atoms was obtained by measuring the niobium solution concentration using inductively coupled plasma mass spectrometry.X-rays of 93m Nb were measured accurately by means of comparing the X-ray intensity of irradiated niobium solution with that of the solution in which stable 93 Nb was added.The difference between both intensities indicates the effect of 182 Ta,which is generated from an impurity tantalum,and the intensity of X-rays from 93m Nb was evaluated.Measurement error of the 93 Nb(n,n’)93m Nb reaction rate was reduced to be less than 4%,which was equivalent to the other reaction rate errors of dosimeters used for Joyo dosimetry.In addition,an advanced technique using Resonance Ionization Mass Spectrometry was proposed for the precise measurement of 93m Nb yield,and 93m Nb will be resonance-ionized selectively by discriminating the hyperfine splitting of the atomic energy levels between 93 Nb and 93m Nb at high resolution.

MOSSBAUER STUDY ON REDUCIBILITY OF SUPPORTED Eu_2O_3

The reduction process of Eu2O3 on TiO2 and other supports is investigated in detail by Mossbauer spectroscopy. The reducibility of Eu2O3 is greatly enhanced when it is supported on a surface of support. This is due to the solid-solid interaction between the oxide and the support.

Spectrally selective optical pumping in Doppler-broadened cesium atoms

The D1 line spectrally selective pumping process in Doppler-broadened cesium is analyzed by solving the optical Bloch equations. The process, described by a three-level model with the A scheme, shows that the saturation intensity of broadened atoms is three orders of magnitude larger than that of resting atoms. The 丨Fg = 3） →丨Fe = 4） resonance pumping can result in the ground state丨Fg = 4, mF = 4） sublevel having a maximum population of 0.157 and the population difference would be about 0.01 in two adjacent magnetic sublevels of the hyperfine （HF） state Fg = 4. To enhance the anisotropy in the ground state, we suggest employing dichromatic optical HF pumping by adding a laser to excite D1 line 丨Fg = 4） → 丨Fe = 3） transition, in which the cesium magnetometer sensitivity increases by half a magnitude and is unaffected by the nonlinear Zeeman effect even in Earth＇s average magnetic field.

ESR Study of the Reaction Between Cp_2Ti(CO)_2 and Cp_2TiBr_2

Introduction Floriani and Fachinetti have proposed that （Cp;TiCl）;can be prepared by the reaction between Cp;TiCl;and Cp;Ti（CO）;. We extended the method to the preparation of （Cp;TiBr）;and characterized an active intermediate by ESR method.

New Levels of the Pr Atom with Almost Similar Energies

A Fourier transform （FT） spectrum of praseodymium （Pr） extending from UV to IR was investigated. Hyperfine （hf） structures of unclassified lines with sufficiently high signal to noise ratio （SNR） were analyzed and some new levels were found. We present these new levels in this work. Some of the new levels have energies almost equal to the energies of already known or other new levels, distinguished either by different values of angular momentum J or by their parity.

Spectra of charmed and bottom baryons with hyperfine interaction

Up to now, the excited charmed and bottom baryon states have still not been well studied experimentally or theoretically. In this paper, we predict the mass of Ωb, the only L=0 baryon state which has not been observed, to be 6069.2 MeV. The spectra of charmed and bottom baryons with the orbital angular momentum L= 1 are studied in two popular constituent quark models, the Goldstone boson exchange （GBE） model and the one gluon exchange （OGE） hyperfine interaction model. Inserting the latest experimental data from the ＂Review of Particle Physics＂, we find that in the GBE model, there exist some multiplets （∑c（b）, ≡c（b） and Ωc（b）） in which the total spin of the three quarks in their lowest energy states is 3/2, but in the OGE model there is no such phenomenon. This is the most important difference between the GBE and OGE models. These results can be tested in the near future. We suggest more efforts to study the excited charmed and bottom baryons both theoretically and experimentally, not only for the abundance of baryon spectra, but also for determining which hyperfine interaction model best describes nature.

Rydberg electromagnetically induced transparency in^(40)K ultracold Fermi gases

We report the measurement of the electromagnetically induced transparency(EIT)with Rydberg states in ultracold^(40)K Fermi gases,which is obtained through a two-photon process with the ladder scheme.Rydberg–EIT lines are obtained by measuring the atomic losses instead of the transmitted probe beam.Based on the laser frequency stabilization locking to the superstable cavity,we study the Rydberg–EIT line shapes for the 37s and 35d states.We experimentally demonstrate the significant change in the Rydberg–EIT spectrum by changing the principal quantum number of the Rydberg state(n=37/52 and l=0).Moreover,the transparency peak position shift is observed,which may be induced by the interaction of the Rydberg atoms.This work provides a platform to explore many interesting behaviors involving Rydberg states in ultracold Fermi gases.