The mixed spinel ferrite system Mg0.95Mn0.05Fe2-2xTizxO4 （0 ≤x ≤ 0.7） was synthesized by the conventional solid-state reaction technique. The effect of Ti^4＋ doping was studied by using the Moessbauer spectroscop...The mixed spinel ferrite system Mg0.95Mn0.05Fe2-2xTizxO4 （0 ≤x ≤ 0.7） was synthesized by the conventional solid-state reaction technique. The effect of Ti^4＋ doping was studied by using the Moessbauer spectroscopy measurements at room temperature. From the analysis of the Moessbauer spectra, it is observed that s-electron density, electric field gradient （EFG）, quadrupole coupling constant （QCC） and the net hyperfine magnetic fields acting on the Moessbauer nuclei-FeA^3＋ and FeB^3＋ change with the increase of Ti^4＋ doping in Mg0.95Mn0.05Fe2O4. The hyperfine magnetic field decreases with the increase of Ti^4＋ doping.展开更多
We perform the ab initio calculation for obtaining the density of states and magnetic properties of ZrFe2 Laves phase compound based on the method of augmented plane waves plus local orbital The results indicate that ...We perform the ab initio calculation for obtaining the density of states and magnetic properties of ZrFe2 Laves phase compound based on the method of augmented plane waves plus local orbital The results indicate that the ferromagnetic state is more stable than the paramagnetic one, but with a slightly larger volume. The 3d - 4d exchange interactions between Fe and Zr electrons lead to the antiparallel coupling for Fe 3d and Zr 4d states, which is responsible for the ferrimagnetic ordering of the compound. The resulting magnetic moment of about 1.98μB for Fe is spatially localized near the Fe site, while around Zr a small but extended negative spin states causes a moment of about -0.44 μB. Moreover, the resulting magnetic moments with the generalized gradient approximation are more consistent with experimental values than that of the local-spin density approximation.展开更多
Y1.6Ca1.4V 0.45Sn0.5Fe4.05O12 is irradiated by 0.56 GeV carbon ion. The irradiation effect is investigated by Mossbauer spectroscopy. The irradiation results in an isotropic distribution of the hyperfine magnetic fiel...Y1.6Ca1.4V 0.45Sn0.5Fe4.05O12 is irradiated by 0.56 GeV carbon ion. The irradiation effect is investigated by Mossbauer spectroscopy. The irradiation results in an isotropic distribution of the hyperfine magnetic field. The hyperfine magnetic fields decrease after the irradiation due to the change of supertransferred field. After the irradiation, the chain Fe(a)-oxygen-Fe(d) become longer and it leads to decrease of the supertransferred field.展开更多
Ⅰ. EXPERIMENT9Crl8 ball-bearing stainless steel has the following composition:C, 1 wt%; Cr, 18 wt%; Mn, 0.1 wt%; Si, 0.8 wt%; S, 0.03 wt%; P, 0.03 wt%, besides Fe. Its abilities of antichemical erosion and antielectr...Ⅰ. EXPERIMENT9Crl8 ball-bearing stainless steel has the following composition:C, 1 wt%; Cr, 18 wt%; Mn, 0.1 wt%; Si, 0.8 wt%; S, 0.03 wt%; P, 0.03 wt%, besides Fe. Its abilities of antichemical erosion and antielectrical-chemical erosion are due to the high content of Cr in it. In order to obtain high hardness and high wear resistance, higher content of C is included. Si is in展开更多
基金Project supported by the Second Stage of Brain Korea 21 ProjectProject(RTI04-01-03) supported by the Regional Technology Innovation Program of the Ministry of Knowledge Economy (MKE),Korea
文摘The mixed spinel ferrite system Mg0.95Mn0.05Fe2-2xTizxO4 （0 ≤x ≤ 0.7） was synthesized by the conventional solid-state reaction technique. The effect of Ti^4＋ doping was studied by using the Moessbauer spectroscopy measurements at room temperature. From the analysis of the Moessbauer spectra, it is observed that s-electron density, electric field gradient （EFG）, quadrupole coupling constant （QCC） and the net hyperfine magnetic fields acting on the Moessbauer nuclei-FeA^3＋ and FeB^3＋ change with the increase of Ti^4＋ doping in Mg0.95Mn0.05Fe2O4. The hyperfine magnetic field decreases with the increase of Ti^4＋ doping.
基金Supported by the Natural Science Foundation of Shandong Province under Grant Nos Y2002D9 and Y2004A10, and the Doctoral Foundation of Jinan University under Grant No B0632.
文摘We perform the ab initio calculation for obtaining the density of states and magnetic properties of ZrFe2 Laves phase compound based on the method of augmented plane waves plus local orbital The results indicate that the ferromagnetic state is more stable than the paramagnetic one, but with a slightly larger volume. The 3d - 4d exchange interactions between Fe and Zr electrons lead to the antiparallel coupling for Fe 3d and Zr 4d states, which is responsible for the ferrimagnetic ordering of the compound. The resulting magnetic moment of about 1.98μB for Fe is spatially localized near the Fe site, while around Zr a small but extended negative spin states causes a moment of about -0.44 μB. Moreover, the resulting magnetic moments with the generalized gradient approximation are more consistent with experimental values than that of the local-spin density approximation.
文摘Y1.6Ca1.4V 0.45Sn0.5Fe4.05O12 is irradiated by 0.56 GeV carbon ion. The irradiation effect is investigated by Mossbauer spectroscopy. The irradiation results in an isotropic distribution of the hyperfine magnetic field. The hyperfine magnetic fields decrease after the irradiation due to the change of supertransferred field. After the irradiation, the chain Fe(a)-oxygen-Fe(d) become longer and it leads to decrease of the supertransferred field.
基金Project supported by the National Natural Science Foundation of China
文摘Ⅰ. EXPERIMENT9Crl8 ball-bearing stainless steel has the following composition:C, 1 wt%; Cr, 18 wt%; Mn, 0.1 wt%; Si, 0.8 wt%; S, 0.03 wt%; P, 0.03 wt%, besides Fe. Its abilities of antichemical erosion and antielectrical-chemical erosion are due to the high content of Cr in it. In order to obtain high hardness and high wear resistance, higher content of C is included. Si is in
