Block piezoelectric ceramics(PZTs)are often used in impact igniters to provide activation energy for electric initiators.Under the action of strong impact stress,PZTs release electric energy accompanied by crack initi...Block piezoelectric ceramics(PZTs)are often used in impact igniters to provide activation energy for electric initiators.Under the action of strong impact stress,PZTs release electric energy accompanied by crack initiation,propagation and crushing.At present,the electrical output performance of PZTs in projectile is usually calculated by quasi-static piezoelectric equation without considering the dynamic effect caused by strong impact and the influence of crack propagation on material properties.So the ignition parameters are always not accurately predicted.To tackle this,a PZT dynamic damage constitutive model considering crack propagation is established based on the dynamic impact test and the crack propagation theory of brittle materials.The model is then embedded into the ABAQUS subroutine and used to simulate the electromechanical response of the impact igniter during the impact of a small caliber projectile on the target.Meanwhile,the experiments of projectile with impact igniter impact on the target are carried out.The comparison between experimental and numerical simulation results show that the established dynamic damage model can effectively predict the dynamic electromechanical response of PZTs in the missile service environment.展开更多
In the extreme conditions of high altitude,low temperature,low pressure,and high speed,the aircraft engine is prone to flameout and difficult to start secondary ignition,which makes reliable ignition of combustion cha...In the extreme conditions of high altitude,low temperature,low pressure,and high speed,the aircraft engine is prone to flameout and difficult to start secondary ignition,which makes reliable ignition of combustion chamber at high altitude become a worldwide problem.To solve this problem,a kind of multichannel plasma igniter with round cavity is proposed in this paper,the three-channel and five-channel igniters are compared with the traditional ones.The discharge energy of the three igniters was compared based on the electric energy test and the thermal energy test,and ignition experiments was conducted in the simulated high-altitude environment of the component combustion chamber.The results show that the recessed multichannel plasma igniter has higher discharge energy than the conventional spark igniter,which can increase the conversion efficiency of electric energy from 26%to 43%,and the conversion efficiency of thermal energy from 25%to 73%.The recessed multichannel plasma igniter can achieve greater spark penetration depth and excitation area,which both increase with the increase of height.At the same height,the inlet flow helps to increase the penetration depth of the spark.The recessed multichannel plasma igniter can widen the lean ignition boundary,and the maximum enrichment percentage of lean ignition boundary can reach 31%.展开更多
High-temperature ignition is essential for the ignition and combustion of energetic metal fuels, including aluminum and magnesium particles which are protected by their high- melting-temperature oxides. A plasma torch...High-temperature ignition is essential for the ignition and combustion of energetic metal fuels, including aluminum and magnesium particles which are protected by their high- melting-temperature oxides. A plasma torch characterized by an ultrahigh-temperature plasma plume fulfills such high-temperature ignition conditions. A new steam plasma igniter is designed and successfully validated by aluminum power ignition and combustion tests. The steam plasma rapidly stabilizes in both plasma and steam jet modes. Parametric investigation of the steam plasma jet is conducted in terms of arc strength. A high-speed camera and an oscilloscope method visualize the discharge characteristics, and optical emission spectroscopy measures the thermochemical properties of the plasma jet. The diatomic molecule OH fitting method, the Boltzmann plot method, and short exposure capturing with an intensified charge coupled device record the axial distributions of the rotational gas temperature, excitation temperature, and OH radical distribution, respectively. The excitation temperature at the nozzle tip is near 5500 K, and the gas temperature is 5400 K.展开更多
Relighting of jet engines at high altitudes is very difficult because of the high velocity, low pressure, and low tempera- ture of the inlet airflow. Successful ignition needs sufficient ignition energy to generate a ...Relighting of jet engines at high altitudes is very difficult because of the high velocity, low pressure, and low tempera- ture of the inlet airflow. Successful ignition needs sufficient ignition energy to generate a spark kernel to induce a so-called critical flame initiation radius. However, at high altitudes with high-speed inlet airflow, the critical flame initiation radius becomes larger; therefore, traditional ignition technologies such as a semiconductor igniter (SI) become infeasible for use in high-altitude relighting of jet engines. In this study, to generate a large spark kernel to achieve successful ignition with high-speed inlet airflow, a new type of multichannel plasma igniter (MCPI) is proposed. Experiments on the electrical char- acteristics of the MCPI and SI were conducted under normal and sub-atmospheric pressures (P = 10-100 kPa). Ignition experiments for the MCPI and SI with a kerosene/air mixture in a triple-swirler combustor under different velocities of inlet airflow (60-110 m/s), with a temperature of 473 K at standard atmospheric pressure, were investigated. Results show that the MCPI generates much more arc discharge energy than the SI under a constant pressure; for example, the MCPI generated 6.93% and 16.05 % more arc discharge energy than that of the SI at 30 kPa and 50 kPa, respectively. Compared to the SI, the MCPI generates a larger area and height of plasma heating zone, and induces a much larger initial spark kernel. Furthermore, the lean ignition limit of the MCPI and SI decreases with an increase in the velocity of the inlet airflow, and the maximum velocity of inlet airflow where the SI and MCPI can achieve successful and reliable ignition is 88.7 m/s and 102.2 m/s, respectively. Therefore, the MCPI has the advantage of achieving successful ignition with high-speed inlet airflow and extends the average ignition speed boundary of the kerosene/air mixture by 15.2%.展开更多
The electrical characteristics of an alternating current (AC) plasma igniter were investigated for a working gas of air at atmospheric pressure. The discharge voltage and current were measured in air in both breakdo...The electrical characteristics of an alternating current (AC) plasma igniter were investigated for a working gas of air at atmospheric pressure. The discharge voltage and current were measured in air in both breakdown and stable combustion processes, respectively, and the current-zero phenomena, voltage-current (V-I) characteristics were studied for different working gas flow rates. The results indicated that the working gas between anode and cathode could be ionized to generate gas discharge when the voltage reached 8 kV, and the maximum current was 33.36 A. When the current came to zero, current-zero phenomena appeared with duration of 2 #s. At the current-zero moment, dynamic resistance between electrodes became extremely high, and the maximum value could reach 445 kf~, which was the main factor to restrain the current. With increasing working gas flow rates, the gradient of V-I characteristic curves was increased, as was the dynamic resistance. At a constant driven power, the discharge voltage increased.展开更多
At present, aero-engines face a major need to widen the ignition envelope. In order to provide a technical support to expand the high altitude ignition envelope of aero-engines, in this article we propose a novel igni...At present, aero-engines face a major need to widen the ignition envelope. In order to provide a technical support to expand the high altitude ignition envelope of aero-engines, in this article we propose a novel ignition technology, i.e., "precombustion plasma jet ignition technology". In this paper, we also design a pre-combustion plasma jet igniter. Its discharge characteristics, jet characteristics, and ignition effects are studied. The results show that increasing the equivalent ratio of jet gas can enhance the discharge stability and increase the duty cycle. At the same time, it can reduce working power and energy consumption. The increase of equivalent ratio in jet gas can enhance the length and ignition area of plasma jet.In the process of ignition, the pre-combustion plasma jet igniter has obvious advantages, suchn as shortening the ignition delay time and enlarging the ignition boundary. When the airflow velocity is 39.11 m/s and the inlet air temperature is80℃, compared with the spark igniter and the air plasma jet igniter, the pre-combustion plasma jet igniter has an ignition boundary that is expanded by 319.8% and 55.7% respectively.展开更多
Stable combustion in an afterburner can help increase the thrust of the engine in a short time,thereby improving the maneuverability of a fighter.To improve the ignition performance of an afterburner,a twin-duct ignit...Stable combustion in an afterburner can help increase the thrust of the engine in a short time,thereby improving the maneuverability of a fighter.To improve the ignition performance of an afterburner,a twin-duct ignition platform was designed to study the performance of a gliding arc plasma igniter in close-to-real afterburner conditions.The research was carried out by a combination of experiments and simulations.The working environment of the igniter was explored through a numerical simulation.The results showed that the airflow ejected from the radiating holes formed a swirling sheath,which increased the anti-interference ability of the airflow jet.The influence of the pressure difference between the inlet and outlet of the igniter(Δp),the flow rate outside the igniter outlet(W_(2)),and the installation angle(α)on the singlecycle discharge energy(E)as well as the maximum arc length(L)were studied through experiments.Three stages were identified:the airflow breakdown stage,the arc evolution stage,and the arc fracture stage.E and L increased by 107.3%and 366.2%,respectively,withΔp increasing from 10 to 70 Torr.The relationship between L andΔp obtained by data fitting is L=3-2.47/(1+(Δp/25)^(4)).The relationship of L at differentαis L_(α=0°)>(L_(α=45°)and L_(α=135°))>L_(α=180°)>L_(α=90°).E and L decrease by 18.2%and 37.3%,respectively,whenΔp=45 Torr and W_(2) is increased from 0 to 250 l min^(-1).展开更多
Plasma ignition technology has delivered good performance in the aerospace industry. In this study, a pre-combustion plasma jet igniter was designed, and its characteristics were examined from three aspects: the morph...Plasma ignition technology has delivered good performance in the aerospace industry. In this study, a pre-combustion plasma jet igniter was designed, and its characteristics were examined from three aspects: the morphology, temperature, and discharge characteristics and process of ignition. Images of the OH distribution were obtained by using an OH Planar Laser-Induced Fluorescence(OH-PLIF) experimental system. Results have shown that the proposed plasma jet had a higher OH concentration, longer length, and larger area than those of a traditional igniter. The stability of discharge of the igniter was improved as the equivalence ratio φ was increased, and reducing gas flow reduced the pulsation of the plasma jet. When the input current was increased from 15A to 35 A, the highest average temperature increased from 5127 K to 7987 K. An increase in the equivalence ratio reduced the region of arc ionization, but expanded the regions of the core combustion reaction and the outer flame. Herein, this study has obtained a deep understanding of the jet and ignition law and developed a new idea for the application of plasma in the ignition field.A pre-combustion plasma jet igniter can significantly improve the efficiency of ignition and shorten the ignition process compared with a traditional igniter.展开更多
Exploding foil initiator(EFI)is a kind of advanced device for initiating explosives,but its function is unstable when it comes to directly igniting pyrotechnics.To solve the problem,this research aims to reveal the ig...Exploding foil initiator(EFI)is a kind of advanced device for initiating explosives,but its function is unstable when it comes to directly igniting pyrotechnics.To solve the problem,this research aims to reveal the ignition mechanism of EFIs directly igniting pyrotechnics.An oscilloscope,a photon Doppler velocimetry,and a plasma spectrum measurement system were employed to obtain information of electric characteristics,impact pressure,and plasma temperature.The results of the electric characteristics and the impact pressure were inconsistent with ignition results.The only thing that the ignition success tests had in common was that their plasma all had a relatively long period of high-temperature duration(HTD).It eventually concludes that the ignition mechanism in this research is the microconvection heat transfer rather than the shock initiation,which differs from that of exploding foil initiators detonating explosives.Furthermore,the methods for evaluating the ignition success of semiconductor bridge initiators are not entirely applicable to the tests mentioned in this paper.The HTD is the critical parameter for judging the ignition success,and it is influenced by two factors:the late time discharge and the energy of the electric explosion.The longer time of the late time discharge and the more energy of the electric explosion,the easier it is to expand the HTD,which improves the probability of the ignition success.展开更多
Relight of jet engines at high altitude is difficult due to the relatively low pressure and temperature of inlet air.The penetration of initial flame kernel affects the ignition probability in the turbine engine combu...Relight of jet engines at high altitude is difficult due to the relatively low pressure and temperature of inlet air.The penetration of initial flame kernel affects the ignition probability in the turbine engine combustor greatly.In order to achieve successful ignition at high altitude,a deeper penetration of initial flame kernel should be generated.In this study,a Gliding Arc Plasma Jet Igniter(GAPJI)is designed to induce initial flame kernel with deeper penetration to achieve successful ignition at high altitude.The ignition performance of the GAPJI was demonstrated in a model combustor.It was found that GAPJI can generate plasma with deeper penetration up to 30.5 mm than spark igniter with 22.1 mm.The discharge power of GAPJI was positively correlated with flow rate of the carrier gas,approaching 200 W in average.Ignition experiments show that GAPJI has the advantage of extending the lean ignition limit.With GAPJI,the lean ignition limit of the combustor is 0.02 at 0 km,which is 55.6%less than that with spark igniter(0.045).The evolution of flame morphology was observed to explore the development of the flame kernel.It is shown that the advantage of a high penetration and continuous releasing energy can accelerate the ignition process and enhance combustion.展开更多
A plasma jet ignition technology was studied for aeroengine combustor.The advantages of compact stnucture and advanced performance of air-cooled plasma jet igniter had been tested and verified in the opening test.The ...A plasma jet ignition technology was studied for aeroengine combustor.The advantages of compact stnucture and advanced performance of air-cooled plasma jet igniter had been tested and verified in the opening test.The plasma jet igniter could produce a continuous plasma jet,stable and reliable ignition.The influence factors of plasma jet ignition aerodynamic and structure were studied in the opening test.Continuous plasma jet was closely related to inlet pressure and flow,simultaneously to the igniter nozzle geometry and throat size.Based on the stable continuous plasma jet,some methods were explored in order to reduce plasma output power,optimize the structure design,and improve the thermal protective.The plasma jet igniter applied to aeroengine combustor was identified initially.For combustion chamber with the igniter,altitude ignition performance were experimented for the inlet pressure of plasma ignition from 10 kPa to 50 kPa,the flow of plasma jet not more than 0.20 g/s,and energy output of ignition from 800 W to 1500 W.The test results were compared with that of conventional aeroengine high energy ignition system.The results show that the plasma jet igniter is better than the conventional one.展开更多
The arc ignition system based on charring polymers has advantages of simple structure,low ignition power consumption and multiple ignitions,which bringing it broadly application prospect in hybrid propulsion system of...The arc ignition system based on charring polymers has advantages of simple structure,low ignition power consumption and multiple ignitions,which bringing it broadly application prospect in hybrid propulsion system of micro/nano satellite.However,charring polymers alone need a relatively high input voltage to achieve pyrolysis and ignition,which increases the burden and cost of the power system of micro/nano satellite in practical application.Adding conductive substance into charring polymers can effectively decrease the conducting voltage which can realize low voltage and low power consumption repeated ignition of arc ignition system.In this paper,a charring conductive polymer ignition grain with a cavity geometry in precombustion chamber,which is composed of PLA and multiwall carbon nanotubes(MWCNT)was proposed.The detailed ignition processes were analyzed and two different ignition mechanisms in the cavity of charring conductive polymers were revealed.The ignition characteristics of charring conductive polymers were also investigated at different input voltages,ignition grain structures,ignition locations and injection schemes in a visual ignition combustor.The results demonstrated that the ignition delay and external energy required for ignition were inversely correlated with the voltages applied to ignition grain.Moreover,the incremental depth of cavity shortened the ignition delay and external energy required for ignition while accelerated the propagation of flame.As the depth of cavity increased from 2 to 6 mm(at 50 V),the time of flame propagating out of ignition grain changed from 235.6 to 108 ms,and values of mean ignition delay time and mean external energy required for ignition decreased from 462.8 to 320 ms and 16.2 to 10.75 J,respectively.The rear side of the cavity was the ideal ignition position which had a shorter ignition delay and a faster flame propagation speed in comparison to other ignition positions.Compared to direct injection scheme,swirling injection provided a more favorable flow field environment in the cavity,which was beneficial to ignition and initial flame propagation,but the ignition position needed to be away from the outlet of swirling injector.At last,the repeated ignition characteristic of charring conductive polymers was also investigated.The ignition delay time and external energy required for ignition decreased with repeated ignition times but the variation was decreasing gradually.展开更多
Energetic Semiconductor bridge(ESCB)based on reactive multilayered films(RMFs)has a promising application in the miniature and intelligence of initiator and pyrotechnics device.Understanding the ignition enhancement m...Energetic Semiconductor bridge(ESCB)based on reactive multilayered films(RMFs)has a promising application in the miniature and intelligence of initiator and pyrotechnics device.Understanding the ignition enhancement mechanism of RMFs on semiconductor bridge(SCB)during the ignition process is crucial for the engineering and practical application of advanced initiator and pyrotechnics devices.In this study,a one-dimensional(1D)gas-solid two-phase flow ignition model was established to study the ignition process of ESCB to charge particles based on the reactivity of Al/MoO_(3) RMFs.In order to fully consider the coupled exothermic between the RMFs and the SCB plasma during the ignition process,the heat release of chemical reaction in RMFs was used as an internal heat source in this model.It is found that the exothermal reaction in RMFs improved the ignition performance of SCB.In the process of plasma rapid condensation with heat release,the product of RMFs enhanced the heat transfer process between the gas phase and the solid charge particle,which accelerated the expansion of hot plasma,and heated the solid charge particle as well as gas phase region with low temperature.In addition,it made up for pressure loss in the gas phase.During the plasma dissipation process,the exothermal chemical reaction in RMFs acted as the main heating source to heat the charge particle,making the surface temperature of the charge particle,gas pressure,and gas temperature rise continuously.This result may yield significant advantages in providing a universal ignition model for miniaturized ignition devices.展开更多
Incorporating aluminum metal-organic frameworks(Al-MOFs)as energetic additives for solid fuels presents a promising avenue for enhancing combustion performance.This study explores the potential benefits of Al-MOF(MIL-...Incorporating aluminum metal-organic frameworks(Al-MOFs)as energetic additives for solid fuels presents a promising avenue for enhancing combustion performance.This study explores the potential benefits of Al-MOF(MIL-53(Al))energetic additive on the combustion performance of hydroxyl-terminated polybutadiene(HTPB)fuel.The HTPB-MOF fuel samples were manufactured using the vacuum-casting technique,followed by a comprehensive evaluation of their ignition and combustion properties using an opposed flow burner(OFB)setup utilizing gaseous oxygen as an oxidizer.To gauge the effectiveness of Al-MOFs as fuel additives,their impact is compared with that of nano-aluminum(nAl),another traditional additive in HTPB fuel.The results indicate that the addition of 15%(mass fraction)nAl into HTPB resulted in the shortest ignition delay time(136 ms),demonstrating improved ignition performance compared to pure HTPB(273 ms).The incorporation of Al-MOF in HTPB also reduced ignition delay times to 227 ms and 189 ms,respectively.Moreover,under high oxidizer mass flux conditions(79—81 kg/(m^(2)s)),HTPB fuel with 15%nAl exhibited a substantial 83.2%increase in regression rate compared to the baseline HTPB fuel,highlighting the positive influence of nAl on combustion behavior.In contrast,HTPB-MOF with a 15%Al-MOF additive showed a 32.7%increase in regression rate compared to pure HTPB.These results suggest that HTPB-nAl outperforms HTPB-MOF in terms of regression rates,indicating a more vigorous and rapid burning behavior.展开更多
Understanding the response of solid combustibles under high radiant fluxes is critical in predicting the thermal damage from extreme scenarios.Unlike the more moderate radiant fluxes in conventional hydrocarbon fires,...Understanding the response of solid combustibles under high radiant fluxes is critical in predicting the thermal damage from extreme scenarios.Unlike the more moderate radiant fluxes in conventional hydrocarbon fires,extreme events such as strong explosion,concentrated sunlight and directed energy can generate dynamic radiant fluxes at the MW/m^(2) level,creating a unique threat to materials.This study investigates the pyrolysis and spontaneous ignition behaviors of corrugated cardboard by using both experimental and numerical methods,under 10-cm dynamic high radiant fluxes ranging from 0.2 to 1.25 MW/m^(2) for 10 s.The spontaneous ignition process at dynamic high radiant fluxes was recorded and quantified.Two ignition modes were found at the critical radiant flux of 0.4 MW/m^(2),namely hot-gas spontaneous ignition and hot-residue piloted ignition.The latter is not the focus of this paper due to its extremely small probability of occurrence.The research reveals that the increase in flux intensity induces shorter delay times for both pyrolysis and ignition,lower ignition energy density,along with a corresponding rise in the critical mass flux and surface temperature at ignition moment.The simulation results are generally aligned with the experimental findings,despite some divergences may be attributed to model simplifications and parameter assumptions.The work contributes to a deeper insight into material behavior under extreme radiation,with valuable implications for fire safety and hazard assessment.展开更多
Copper-based azide(Cu(N_(3))2 or CuN_(3),CA)chips synthesized by in-situ azide reaction and utilized in miniaturized explosive systems has become a hot research topic in recent years.However,the advantages of in-situ ...Copper-based azide(Cu(N_(3))2 or CuN_(3),CA)chips synthesized by in-situ azide reaction and utilized in miniaturized explosive systems has become a hot research topic in recent years.However,the advantages of in-situ synthesis method,including small size and low dosage,bring about difficulties in quantitative analysis and differences in ignition capabilities of CA chips.The aim of present work is to develop a simplified quantitative analysis method for accurate and safe analysis of components in CA chips to evaluate and investigate the corresponding ignition ability.In this work,Cu(N_(3))2 and CuN_(3)components in CA chips were separated through dissolution and distillation by utilizing the difference in solubility and corresponding content was obtained by measuring N_(3)-concentration through spectrophotometry.The spectrophotometry method was optimized by studying influencing factors and the recovery rate of different separation methods was studied,ensuring the accuracy and reproducibility of test results.The optimized method is linear in range from 1.0-25.0 mg/L,with a correlation coefficient R^(2)=0.9998,which meets the requirements of CA chips with a milligram-level content test.Compared with the existing ICP method,component analysis results of CA chips obtained by spectrophotometry are closer to real component content in samples and have satisfactory accuracy.Moreover,as its application in miniaturized explosive systems,the ignition ability of CA chips with different component contents for direct ink writing CL-20 and the corresponding mechanism was studied.This study provided a basis and idea for the design and performance evaluation of CA chips in miniaturized explosive systems.展开更多
Investigating the ignition response of nitrate ester plasticized polyether(NEPE) propellant under dynamic extrusion loading is of great significant at least for two cases. Firstly, it helps to understand the mechanism...Investigating the ignition response of nitrate ester plasticized polyether(NEPE) propellant under dynamic extrusion loading is of great significant at least for two cases. Firstly, it helps to understand the mechanism and conditions of unwanted ignition inside charged propellant under accident stimulus.Secondly, evaluates the risk of a shell crevice in a solid rocket motor(SRM) under a falling or overturning scene. In the present study, an innovative visual crevice extrusion experiment is designed using a dropweight apparatus. The dynamic responses of NEPE propellant during extrusion loading, including compaction and compression, rapid shear flow into the crevice, stress concentration, and ignition reaction, have been firstly observed using a high-performance high-speed camera. The ignition reaction is observed in the triangular region of the NEPE propellant sample above the crevice when the drop weight velocity was 1.90 m/s. Based on the user material subroutine interface UMAT provided by finite element software LS-DYNA, a viscoelastic-plastic model and dual ignition criterion related to plastic shear dissipation are developed and applied to the local ignition response analysis under crevice extrusion conditions. The stress concentration occurs in the crevice location of the propellant sample, the shear stress is relatively large, the effective plastic work is relatively large, and the ignition reaction is easy to occur. When the sample thickness decreases from 5 mm to 2.5 mm, the shear stress increases from 22.3 MPa to 28.6 MPa, the critical value of effective plastic work required for ignition is shortened from 1280 μs to 730 μs, and the triangular area is easily triggering an ignition reaction. The propellant sample with a small thickness is more likely to stress concentration, resulting in large shear stress and effective work, triggering an ignition reaction.展开更多
This review article provides overall understanding of stainless,environment-friendly,and nonflammable Mg alloys(SEN alloys)recently developed at the Korea Institute of Materials Science.SEN alloys are produced by addi...This review article provides overall understanding of stainless,environment-friendly,and nonflammable Mg alloys(SEN alloys)recently developed at the Korea Institute of Materials Science.SEN alloys are produced by adding small amounts of Ca and Y(each<1 wt%)into commercial Mg–Al based alloys,resulting in exceptional ignition and corrosion resistances and impressive mechanical properties.Their main advantages of SEN alloys are as follows.(1)A dense multi-oxide layer of SEN alloys comprising MgO,CaO,and Y_(2)O_(3) impedes the outward dispersion of Mg vapor and the inward penetration of O_(2) during oxidation,thereby enhancing the oxidation and ignition resistances.(2)The presence of Ca-and Y-based second-phase particles in SEN alloys can enhance their corrosion resistance because Ca-containing particles prevent the spread of corrosion,and the replacement of Al-containing particles with less noble ones containing Y(e.g.,Al–Mn–Y or Al–Y particles)retards corrosion.(3)The addition of minor amounts of Ca and Y renders excellent mechanical properties due to improved strengthening effects.These enhanced properties are attributed to more pronounced dynamic recrystallization and grain refining behaviors caused by the second-phase particles during extrusion.(4)Despite the presence of various types of second-phase particles,the fatigue properties of SEN9 alloys are similar to those of commercial AZ91 alloys.(5)Simultaneous introduction of Ca and Y suppresses the formation of Mg17Al12 discontinuous precipitates during aging,leading to the enhanced elongation of aged SEN alloys.(6)Adding mischmetal into the SEN9 alloy leads to a six-fold enhancement in extrudability.Consequently,the studies conducted on SEN alloys demonstrate their excellent ignition and corrosion resistances and mechanical properties,which broaden the industrial applications of Mg alloys by addressing their inherent weaknesses.展开更多
To enhance the catalytic activity of copper ferrite(CuFe_(2)O_(4))nanoparticle and promote its application as combustion catalyst,a low-cost silicon dioxide(SiO_(2))carrier was employed to construct a novel CuFe_(2)O_...To enhance the catalytic activity of copper ferrite(CuFe_(2)O_(4))nanoparticle and promote its application as combustion catalyst,a low-cost silicon dioxide(SiO_(2))carrier was employed to construct a novel CuFe_(2)O_(4)/SiO_(2)binary composites via solvothermal method.The phase structure,morphology and catalytic activity of CuFe_(2)O_(4)/SiO_(2)composites were studied firstly,and thermal decomposition,combustion and safety performance of ammonium perchlorate(AP)and 1,3,5-trinitroperhydro-1,3,5-triazine(RDX)with it affecting were then systematically analyzed.The results show that CuFe_(2)O_(4)/SiO_(2)composite can remarkably either advance the decomposition peak temperature of AP and RDX,or reduce the apparent activation energy at their main decomposition zone.Moreover,the flame propagation rate of RDX was promoted by about 2.73 times with SiO_(2)content of 3 wt%,and safety property of energetic component was also improved greatly,in which depressing the electrostatic discharge sensitivity of pure RDX by about 1.89 times.In addition,the effective range of SiO_(2)carrier content in the binary catalyst is found to be 3 to 5 wt%.Therefore,SiO_(2)opens a new insight on the design of combustion catalyst carrier and will promote the application of CuFe_(2)O_(4)catalyst in solid propellant.展开更多
In the double-cone ignition schemes(DCIS), the deuterium–tritium target shell is ablated and compressed by a highpower nanosecond laser in Au-cones to generate plasmas. Under the actions of spherically symmetric comp...In the double-cone ignition schemes(DCIS), the deuterium–tritium target shell is ablated and compressed by a highpower nanosecond laser in Au-cones to generate plasmas. Under the actions of spherically symmetric compression and acceleration along the Au cone, they will be ejected out of the cone mouth and collide with each other. The plasmas experience conversion from kinetic energy to internal energy at the vertex of the geometric center of two Au cones that are symmetric to each other, because of which high-density fusion plasmas are preheated. This key physical process has undergone experimental verification on the Shenguang-II upgraded facility in China. Apparently, the improvement and optimization of the velocity of plasmas in hypersonic jet flow at the cone mouth are crucial for the success of the DCIS. In the DCIR7 experiment of the Shenguang-II upgraded facility, a velocity yield of approximately 130–260 km/s was achieved for the plasmas at the cone mouth, with a result of nearly 300 km/s based on numerical simulation. In this paper, theoretical analysis is performed as regards the process, in which target shells are ablated and compressed by laser to generate highvelocity plasmas ejected through jet flow. Based on this analysis, the formula for the velocity of plasmas in supersonic jet flow at the cone mouth is proposed. This study also provides measures that are more effective for improving the kinetic energy of plasmas and optimizing energy conversion efficiency, which can serve as theoretical references for the adjustment and optimization of processes in subsequent experiments.展开更多
基金supported by the National Natural Science Foundation of China(Grant No.12172232)the project of Key Laboratory of Impact and Safety Engineering(Ningbo University,China)+1 种基金Ministry of Education(CJ202206)supported by the scientific research support plan of introducing high-level talents from Shenyang Ligong University。
文摘Block piezoelectric ceramics(PZTs)are often used in impact igniters to provide activation energy for electric initiators.Under the action of strong impact stress,PZTs release electric energy accompanied by crack initiation,propagation and crushing.At present,the electrical output performance of PZTs in projectile is usually calculated by quasi-static piezoelectric equation without considering the dynamic effect caused by strong impact and the influence of crack propagation on material properties.So the ignition parameters are always not accurately predicted.To tackle this,a PZT dynamic damage constitutive model considering crack propagation is established based on the dynamic impact test and the crack propagation theory of brittle materials.The model is then embedded into the ABAQUS subroutine and used to simulate the electromechanical response of the impact igniter during the impact of a small caliber projectile on the target.Meanwhile,the experiments of projectile with impact igniter impact on the target are carried out.The comparison between experimental and numerical simulation results show that the established dynamic damage model can effectively predict the dynamic electromechanical response of PZTs in the missile service environment.
基金National Natural Science Foundation of China(Grant No.91641204).
文摘In the extreme conditions of high altitude,low temperature,low pressure,and high speed,the aircraft engine is prone to flameout and difficult to start secondary ignition,which makes reliable ignition of combustion chamber at high altitude become a worldwide problem.To solve this problem,a kind of multichannel plasma igniter with round cavity is proposed in this paper,the three-channel and five-channel igniters are compared with the traditional ones.The discharge energy of the three igniters was compared based on the electric energy test and the thermal energy test,and ignition experiments was conducted in the simulated high-altitude environment of the component combustion chamber.The results show that the recessed multichannel plasma igniter has higher discharge energy than the conventional spark igniter,which can increase the conversion efficiency of electric energy from 26%to 43%,and the conversion efficiency of thermal energy from 25%to 73%.The recessed multichannel plasma igniter can achieve greater spark penetration depth and excitation area,which both increase with the increase of height.At the same height,the inlet flow helps to increase the penetration depth of the spark.The recessed multichannel plasma igniter can widen the lean ignition boundary,and the maximum enrichment percentage of lean ignition boundary can reach 31%.
基金supported by the Defense Acquisition Program Administration and Agency for Defense Development under the contract UD110095CDsupported by the Advanced Research Center Program(NRF-2013R1A5A1073861) through the National Research Foundation of Korea(NRF) grant funded by the Korean government(MSIP) contracted through the Advanced Space Propulsion Research Center at Seoul National University
文摘High-temperature ignition is essential for the ignition and combustion of energetic metal fuels, including aluminum and magnesium particles which are protected by their high- melting-temperature oxides. A plasma torch characterized by an ultrahigh-temperature plasma plume fulfills such high-temperature ignition conditions. A new steam plasma igniter is designed and successfully validated by aluminum power ignition and combustion tests. The steam plasma rapidly stabilizes in both plasma and steam jet modes. Parametric investigation of the steam plasma jet is conducted in terms of arc strength. A high-speed camera and an oscilloscope method visualize the discharge characteristics, and optical emission spectroscopy measures the thermochemical properties of the plasma jet. The diatomic molecule OH fitting method, the Boltzmann plot method, and short exposure capturing with an intensified charge coupled device record the axial distributions of the rotational gas temperature, excitation temperature, and OH radical distribution, respectively. The excitation temperature at the nozzle tip is near 5500 K, and the gas temperature is 5400 K.
基金Project supported by the National Natural Science Foundation of China(Grant Nos.91541120,11472306,51336011,and 91641204)
文摘Relighting of jet engines at high altitudes is very difficult because of the high velocity, low pressure, and low tempera- ture of the inlet airflow. Successful ignition needs sufficient ignition energy to generate a spark kernel to induce a so-called critical flame initiation radius. However, at high altitudes with high-speed inlet airflow, the critical flame initiation radius becomes larger; therefore, traditional ignition technologies such as a semiconductor igniter (SI) become infeasible for use in high-altitude relighting of jet engines. In this study, to generate a large spark kernel to achieve successful ignition with high-speed inlet airflow, a new type of multichannel plasma igniter (MCPI) is proposed. Experiments on the electrical char- acteristics of the MCPI and SI were conducted under normal and sub-atmospheric pressures (P = 10-100 kPa). Ignition experiments for the MCPI and SI with a kerosene/air mixture in a triple-swirler combustor under different velocities of inlet airflow (60-110 m/s), with a temperature of 473 K at standard atmospheric pressure, were investigated. Results show that the MCPI generates much more arc discharge energy than the SI under a constant pressure; for example, the MCPI generated 6.93% and 16.05 % more arc discharge energy than that of the SI at 30 kPa and 50 kPa, respectively. Compared to the SI, the MCPI generates a larger area and height of plasma heating zone, and induces a much larger initial spark kernel. Furthermore, the lean ignition limit of the MCPI and SI decreases with an increase in the velocity of the inlet airflow, and the maximum velocity of inlet airflow where the SI and MCPI can achieve successful and reliable ignition is 88.7 m/s and 102.2 m/s, respectively. Therefore, the MCPI has the advantage of achieving successful ignition with high-speed inlet airflow and extends the average ignition speed boundary of the kerosene/air mixture by 15.2%.
基金supported by National Natural Science Foundation of China(Nos.50776100,51106179)
文摘The electrical characteristics of an alternating current (AC) plasma igniter were investigated for a working gas of air at atmospheric pressure. The discharge voltage and current were measured in air in both breakdown and stable combustion processes, respectively, and the current-zero phenomena, voltage-current (V-I) characteristics were studied for different working gas flow rates. The results indicated that the working gas between anode and cathode could be ionized to generate gas discharge when the voltage reached 8 kV, and the maximum current was 33.36 A. When the current came to zero, current-zero phenomena appeared with duration of 2 #s. At the current-zero moment, dynamic resistance between electrodes became extremely high, and the maximum value could reach 445 kf~, which was the main factor to restrain the current. With increasing working gas flow rates, the gradient of V-I characteristic curves was increased, as was the dynamic resistance. At a constant driven power, the discharge voltage increased.
基金Project supported by the National Natural Science Foundation of China(Grant Nos.51776223 and 91741112)
文摘At present, aero-engines face a major need to widen the ignition envelope. In order to provide a technical support to expand the high altitude ignition envelope of aero-engines, in this article we propose a novel ignition technology, i.e., "precombustion plasma jet ignition technology". In this paper, we also design a pre-combustion plasma jet igniter. Its discharge characteristics, jet characteristics, and ignition effects are studied. The results show that increasing the equivalent ratio of jet gas can enhance the discharge stability and increase the duty cycle. At the same time, it can reduce working power and energy consumption. The increase of equivalent ratio in jet gas can enhance the length and ignition area of plasma jet.In the process of ignition, the pre-combustion plasma jet igniter has obvious advantages, suchn as shortening the ignition delay time and enlarging the ignition boundary. When the airflow velocity is 39.11 m/s and the inlet air temperature is80℃, compared with the spark igniter and the air plasma jet igniter, the pre-combustion plasma jet igniter has an ignition boundary that is expanded by 319.8% and 55.7% respectively.
基金supported by National Science and Technology Major Project (No. 2017-Ⅲ-0007-0033)
文摘Stable combustion in an afterburner can help increase the thrust of the engine in a short time,thereby improving the maneuverability of a fighter.To improve the ignition performance of an afterburner,a twin-duct ignition platform was designed to study the performance of a gliding arc plasma igniter in close-to-real afterburner conditions.The research was carried out by a combination of experiments and simulations.The working environment of the igniter was explored through a numerical simulation.The results showed that the airflow ejected from the radiating holes formed a swirling sheath,which increased the anti-interference ability of the airflow jet.The influence of the pressure difference between the inlet and outlet of the igniter(Δp),the flow rate outside the igniter outlet(W_(2)),and the installation angle(α)on the singlecycle discharge energy(E)as well as the maximum arc length(L)were studied through experiments.Three stages were identified:the airflow breakdown stage,the arc evolution stage,and the arc fracture stage.E and L increased by 107.3%and 366.2%,respectively,withΔp increasing from 10 to 70 Torr.The relationship between L andΔp obtained by data fitting is L=3-2.47/(1+(Δp/25)^(4)).The relationship of L at differentαis L_(α=0°)>(L_(α=45°)and L_(α=135°))>L_(α=180°)>L_(α=90°).E and L decrease by 18.2%and 37.3%,respectively,whenΔp=45 Torr and W_(2) is increased from 0 to 250 l min^(-1).
基金co-supported by the National Natural Science Foundation of China(No.52306123)the Postdoctoral Science Foundation,China(No.2023M734277)the Natural Science Basic Research Program of Shaanxi,China(No.2021JQ-046)。
文摘Plasma ignition technology has delivered good performance in the aerospace industry. In this study, a pre-combustion plasma jet igniter was designed, and its characteristics were examined from three aspects: the morphology, temperature, and discharge characteristics and process of ignition. Images of the OH distribution were obtained by using an OH Planar Laser-Induced Fluorescence(OH-PLIF) experimental system. Results have shown that the proposed plasma jet had a higher OH concentration, longer length, and larger area than those of a traditional igniter. The stability of discharge of the igniter was improved as the equivalence ratio φ was increased, and reducing gas flow reduced the pulsation of the plasma jet. When the input current was increased from 15A to 35 A, the highest average temperature increased from 5127 K to 7987 K. An increase in the equivalence ratio reduced the region of arc ionization, but expanded the regions of the core combustion reaction and the outer flame. Herein, this study has obtained a deep understanding of the jet and ignition law and developed a new idea for the application of plasma in the ignition field.A pre-combustion plasma jet igniter can significantly improve the efficiency of ignition and shorten the ignition process compared with a traditional igniter.
文摘Exploding foil initiator(EFI)is a kind of advanced device for initiating explosives,but its function is unstable when it comes to directly igniting pyrotechnics.To solve the problem,this research aims to reveal the ignition mechanism of EFIs directly igniting pyrotechnics.An oscilloscope,a photon Doppler velocimetry,and a plasma spectrum measurement system were employed to obtain information of electric characteristics,impact pressure,and plasma temperature.The results of the electric characteristics and the impact pressure were inconsistent with ignition results.The only thing that the ignition success tests had in common was that their plasma all had a relatively long period of high-temperature duration(HTD).It eventually concludes that the ignition mechanism in this research is the microconvection heat transfer rather than the shock initiation,which differs from that of exploding foil initiators detonating explosives.Furthermore,the methods for evaluating the ignition success of semiconductor bridge initiators are not entirely applicable to the tests mentioned in this paper.The HTD is the critical parameter for judging the ignition success,and it is influenced by two factors:the late time discharge and the energy of the electric explosion.The longer time of the late time discharge and the more energy of the electric explosion,the easier it is to expand the HTD,which improves the probability of the ignition success.
基金co-supported by the National Natural Science Foundation of China (Nos. 51807204 and 91941301)the Postdoctoral Research Foundation of China (No. 2019M663719)the National Science and Technology Major Project, China (No. 2017-Ⅲ-0007-0033)
文摘Relight of jet engines at high altitude is difficult due to the relatively low pressure and temperature of inlet air.The penetration of initial flame kernel affects the ignition probability in the turbine engine combustor greatly.In order to achieve successful ignition at high altitude,a deeper penetration of initial flame kernel should be generated.In this study,a Gliding Arc Plasma Jet Igniter(GAPJI)is designed to induce initial flame kernel with deeper penetration to achieve successful ignition at high altitude.The ignition performance of the GAPJI was demonstrated in a model combustor.It was found that GAPJI can generate plasma with deeper penetration up to 30.5 mm than spark igniter with 22.1 mm.The discharge power of GAPJI was positively correlated with flow rate of the carrier gas,approaching 200 W in average.Ignition experiments show that GAPJI has the advantage of extending the lean ignition limit.With GAPJI,the lean ignition limit of the combustor is 0.02 at 0 km,which is 55.6%less than that with spark igniter(0.045).The evolution of flame morphology was observed to explore the development of the flame kernel.It is shown that the advantage of a high penetration and continuous releasing energy can accelerate the ignition process and enhance combustion.
基金The study is all supported by Aviation Science Foundation of Aviation Industry Corporation of Chinathe authors are grateful to the participants of Shenyang Engine Research Institute of China for their help.
文摘A plasma jet ignition technology was studied for aeroengine combustor.The advantages of compact stnucture and advanced performance of air-cooled plasma jet igniter had been tested and verified in the opening test.The plasma jet igniter could produce a continuous plasma jet,stable and reliable ignition.The influence factors of plasma jet ignition aerodynamic and structure were studied in the opening test.Continuous plasma jet was closely related to inlet pressure and flow,simultaneously to the igniter nozzle geometry and throat size.Based on the stable continuous plasma jet,some methods were explored in order to reduce plasma output power,optimize the structure design,and improve the thermal protective.The plasma jet igniter applied to aeroengine combustor was identified initially.For combustion chamber with the igniter,altitude ignition performance were experimented for the inlet pressure of plasma ignition from 10 kPa to 50 kPa,the flow of plasma jet not more than 0.20 g/s,and energy output of ignition from 800 W to 1500 W.The test results were compared with that of conventional aeroengine high energy ignition system.The results show that the plasma jet igniter is better than the conventional one.
基金the Fundamental Research Funds for the Central Universities(Grant No.30920041102)National Natural Science Foundation of China(Grant No.11802134).
文摘The arc ignition system based on charring polymers has advantages of simple structure,low ignition power consumption and multiple ignitions,which bringing it broadly application prospect in hybrid propulsion system of micro/nano satellite.However,charring polymers alone need a relatively high input voltage to achieve pyrolysis and ignition,which increases the burden and cost of the power system of micro/nano satellite in practical application.Adding conductive substance into charring polymers can effectively decrease the conducting voltage which can realize low voltage and low power consumption repeated ignition of arc ignition system.In this paper,a charring conductive polymer ignition grain with a cavity geometry in precombustion chamber,which is composed of PLA and multiwall carbon nanotubes(MWCNT)was proposed.The detailed ignition processes were analyzed and two different ignition mechanisms in the cavity of charring conductive polymers were revealed.The ignition characteristics of charring conductive polymers were also investigated at different input voltages,ignition grain structures,ignition locations and injection schemes in a visual ignition combustor.The results demonstrated that the ignition delay and external energy required for ignition were inversely correlated with the voltages applied to ignition grain.Moreover,the incremental depth of cavity shortened the ignition delay and external energy required for ignition while accelerated the propagation of flame.As the depth of cavity increased from 2 to 6 mm(at 50 V),the time of flame propagating out of ignition grain changed from 235.6 to 108 ms,and values of mean ignition delay time and mean external energy required for ignition decreased from 462.8 to 320 ms and 16.2 to 10.75 J,respectively.The rear side of the cavity was the ideal ignition position which had a shorter ignition delay and a faster flame propagation speed in comparison to other ignition positions.Compared to direct injection scheme,swirling injection provided a more favorable flow field environment in the cavity,which was beneficial to ignition and initial flame propagation,but the ignition position needed to be away from the outlet of swirling injector.At last,the repeated ignition characteristic of charring conductive polymers was also investigated.The ignition delay time and external energy required for ignition decreased with repeated ignition times but the variation was decreasing gradually.
基金supported by the National Natural Science Foundation of China(Grant Nos.22275092,52102107 and 52372084)the Fundamental Research Funds for the Central Universities(Grant No.30923010920)。
文摘Energetic Semiconductor bridge(ESCB)based on reactive multilayered films(RMFs)has a promising application in the miniature and intelligence of initiator and pyrotechnics device.Understanding the ignition enhancement mechanism of RMFs on semiconductor bridge(SCB)during the ignition process is crucial for the engineering and practical application of advanced initiator and pyrotechnics devices.In this study,a one-dimensional(1D)gas-solid two-phase flow ignition model was established to study the ignition process of ESCB to charge particles based on the reactivity of Al/MoO_(3) RMFs.In order to fully consider the coupled exothermic between the RMFs and the SCB plasma during the ignition process,the heat release of chemical reaction in RMFs was used as an internal heat source in this model.It is found that the exothermal reaction in RMFs improved the ignition performance of SCB.In the process of plasma rapid condensation with heat release,the product of RMFs enhanced the heat transfer process between the gas phase and the solid charge particle,which accelerated the expansion of hot plasma,and heated the solid charge particle as well as gas phase region with low temperature.In addition,it made up for pressure loss in the gas phase.During the plasma dissipation process,the exothermal chemical reaction in RMFs acted as the main heating source to heat the charge particle,making the surface temperature of the charge particle,gas pressure,and gas temperature rise continuously.This result may yield significant advantages in providing a universal ignition model for miniaturized ignition devices.
文摘Incorporating aluminum metal-organic frameworks(Al-MOFs)as energetic additives for solid fuels presents a promising avenue for enhancing combustion performance.This study explores the potential benefits of Al-MOF(MIL-53(Al))energetic additive on the combustion performance of hydroxyl-terminated polybutadiene(HTPB)fuel.The HTPB-MOF fuel samples were manufactured using the vacuum-casting technique,followed by a comprehensive evaluation of their ignition and combustion properties using an opposed flow burner(OFB)setup utilizing gaseous oxygen as an oxidizer.To gauge the effectiveness of Al-MOFs as fuel additives,their impact is compared with that of nano-aluminum(nAl),another traditional additive in HTPB fuel.The results indicate that the addition of 15%(mass fraction)nAl into HTPB resulted in the shortest ignition delay time(136 ms),demonstrating improved ignition performance compared to pure HTPB(273 ms).The incorporation of Al-MOF in HTPB also reduced ignition delay times to 227 ms and 189 ms,respectively.Moreover,under high oxidizer mass flux conditions(79—81 kg/(m^(2)s)),HTPB fuel with 15%nAl exhibited a substantial 83.2%increase in regression rate compared to the baseline HTPB fuel,highlighting the positive influence of nAl on combustion behavior.In contrast,HTPB-MOF with a 15%Al-MOF additive showed a 32.7%increase in regression rate compared to pure HTPB.These results suggest that HTPB-nAl outperforms HTPB-MOF in terms of regression rates,indicating a more vigorous and rapid burning behavior.
基金the Presidential Foundation of CAEP(Grant No.YZJJZQ2023008)the National Natural Science Foundation of China(Grant No.NSFC 12372342)for financial support of this work.
文摘Understanding the response of solid combustibles under high radiant fluxes is critical in predicting the thermal damage from extreme scenarios.Unlike the more moderate radiant fluxes in conventional hydrocarbon fires,extreme events such as strong explosion,concentrated sunlight and directed energy can generate dynamic radiant fluxes at the MW/m^(2) level,creating a unique threat to materials.This study investigates the pyrolysis and spontaneous ignition behaviors of corrugated cardboard by using both experimental and numerical methods,under 10-cm dynamic high radiant fluxes ranging from 0.2 to 1.25 MW/m^(2) for 10 s.The spontaneous ignition process at dynamic high radiant fluxes was recorded and quantified.Two ignition modes were found at the critical radiant flux of 0.4 MW/m^(2),namely hot-gas spontaneous ignition and hot-residue piloted ignition.The latter is not the focus of this paper due to its extremely small probability of occurrence.The research reveals that the increase in flux intensity induces shorter delay times for both pyrolysis and ignition,lower ignition energy density,along with a corresponding rise in the critical mass flux and surface temperature at ignition moment.The simulation results are generally aligned with the experimental findings,despite some divergences may be attributed to model simplifications and parameter assumptions.The work contributes to a deeper insight into material behavior under extreme radiation,with valuable implications for fire safety and hazard assessment.
基金the financial support provided by the National Natural Science Foundation of China(Grant No.11872013).
文摘Copper-based azide(Cu(N_(3))2 or CuN_(3),CA)chips synthesized by in-situ azide reaction and utilized in miniaturized explosive systems has become a hot research topic in recent years.However,the advantages of in-situ synthesis method,including small size and low dosage,bring about difficulties in quantitative analysis and differences in ignition capabilities of CA chips.The aim of present work is to develop a simplified quantitative analysis method for accurate and safe analysis of components in CA chips to evaluate and investigate the corresponding ignition ability.In this work,Cu(N_(3))2 and CuN_(3)components in CA chips were separated through dissolution and distillation by utilizing the difference in solubility and corresponding content was obtained by measuring N_(3)-concentration through spectrophotometry.The spectrophotometry method was optimized by studying influencing factors and the recovery rate of different separation methods was studied,ensuring the accuracy and reproducibility of test results.The optimized method is linear in range from 1.0-25.0 mg/L,with a correlation coefficient R^(2)=0.9998,which meets the requirements of CA chips with a milligram-level content test.Compared with the existing ICP method,component analysis results of CA chips obtained by spectrophotometry are closer to real component content in samples and have satisfactory accuracy.Moreover,as its application in miniaturized explosive systems,the ignition ability of CA chips with different component contents for direct ink writing CL-20 and the corresponding mechanism was studied.This study provided a basis and idea for the design and performance evaluation of CA chips in miniaturized explosive systems.
基金National Natural Science Foundation of China(U22B20131)State Key Laboratory of Explosion Science and Technology(QNKT23-10)for supporting this project.
文摘Investigating the ignition response of nitrate ester plasticized polyether(NEPE) propellant under dynamic extrusion loading is of great significant at least for two cases. Firstly, it helps to understand the mechanism and conditions of unwanted ignition inside charged propellant under accident stimulus.Secondly, evaluates the risk of a shell crevice in a solid rocket motor(SRM) under a falling or overturning scene. In the present study, an innovative visual crevice extrusion experiment is designed using a dropweight apparatus. The dynamic responses of NEPE propellant during extrusion loading, including compaction and compression, rapid shear flow into the crevice, stress concentration, and ignition reaction, have been firstly observed using a high-performance high-speed camera. The ignition reaction is observed in the triangular region of the NEPE propellant sample above the crevice when the drop weight velocity was 1.90 m/s. Based on the user material subroutine interface UMAT provided by finite element software LS-DYNA, a viscoelastic-plastic model and dual ignition criterion related to plastic shear dissipation are developed and applied to the local ignition response analysis under crevice extrusion conditions. The stress concentration occurs in the crevice location of the propellant sample, the shear stress is relatively large, the effective plastic work is relatively large, and the ignition reaction is easy to occur. When the sample thickness decreases from 5 mm to 2.5 mm, the shear stress increases from 22.3 MPa to 28.6 MPa, the critical value of effective plastic work required for ignition is shortened from 1280 μs to 730 μs, and the triangular area is easily triggering an ignition reaction. The propellant sample with a small thickness is more likely to stress concentration, resulting in large shear stress and effective work, triggering an ignition reaction.
基金supported by the Materials and Components Technology Development Program(No.20024843)funded by the Ministry of Trade,Industry&Energy(MOTIE,South Korea)by the National Research Council of Science&Technology(NST)grant(No.CRC23011-000)funded by the Korea government(MSIT).
文摘This review article provides overall understanding of stainless,environment-friendly,and nonflammable Mg alloys(SEN alloys)recently developed at the Korea Institute of Materials Science.SEN alloys are produced by adding small amounts of Ca and Y(each<1 wt%)into commercial Mg–Al based alloys,resulting in exceptional ignition and corrosion resistances and impressive mechanical properties.Their main advantages of SEN alloys are as follows.(1)A dense multi-oxide layer of SEN alloys comprising MgO,CaO,and Y_(2)O_(3) impedes the outward dispersion of Mg vapor and the inward penetration of O_(2) during oxidation,thereby enhancing the oxidation and ignition resistances.(2)The presence of Ca-and Y-based second-phase particles in SEN alloys can enhance their corrosion resistance because Ca-containing particles prevent the spread of corrosion,and the replacement of Al-containing particles with less noble ones containing Y(e.g.,Al–Mn–Y or Al–Y particles)retards corrosion.(3)The addition of minor amounts of Ca and Y renders excellent mechanical properties due to improved strengthening effects.These enhanced properties are attributed to more pronounced dynamic recrystallization and grain refining behaviors caused by the second-phase particles during extrusion.(4)Despite the presence of various types of second-phase particles,the fatigue properties of SEN9 alloys are similar to those of commercial AZ91 alloys.(5)Simultaneous introduction of Ca and Y suppresses the formation of Mg17Al12 discontinuous precipitates during aging,leading to the enhanced elongation of aged SEN alloys.(6)Adding mischmetal into the SEN9 alloy leads to a six-fold enhancement in extrudability.Consequently,the studies conducted on SEN alloys demonstrate their excellent ignition and corrosion resistances and mechanical properties,which broaden the industrial applications of Mg alloys by addressing their inherent weaknesses.
基金the National Nature Science Foundation of China(Grant Nos.21673178,22105160)the Natural Science Foundation of Shaanxi Province(Grant No.2023-JC-ZD-07)+1 种基金the Foundation of Key Laboratory of Defense Science and technology(Grant No.6142603032213)the Key Science and Technology Innovation Team of Shaanxi Province(Grant No.2022TD-33).
文摘To enhance the catalytic activity of copper ferrite(CuFe_(2)O_(4))nanoparticle and promote its application as combustion catalyst,a low-cost silicon dioxide(SiO_(2))carrier was employed to construct a novel CuFe_(2)O_(4)/SiO_(2)binary composites via solvothermal method.The phase structure,morphology and catalytic activity of CuFe_(2)O_(4)/SiO_(2)composites were studied firstly,and thermal decomposition,combustion and safety performance of ammonium perchlorate(AP)and 1,3,5-trinitroperhydro-1,3,5-triazine(RDX)with it affecting were then systematically analyzed.The results show that CuFe_(2)O_(4)/SiO_(2)composite can remarkably either advance the decomposition peak temperature of AP and RDX,or reduce the apparent activation energy at their main decomposition zone.Moreover,the flame propagation rate of RDX was promoted by about 2.73 times with SiO_(2)content of 3 wt%,and safety property of energetic component was also improved greatly,in which depressing the electrostatic discharge sensitivity of pure RDX by about 1.89 times.In addition,the effective range of SiO_(2)carrier content in the binary catalyst is found to be 3 to 5 wt%.Therefore,SiO_(2)opens a new insight on the design of combustion catalyst carrier and will promote the application of CuFe_(2)O_(4)catalyst in solid propellant.
基金Project supported by the Strategic Priority Research Program of Chinese Academy of Sciences (Grant Nos. XDA25051000 and XDA 25010100)。
文摘In the double-cone ignition schemes(DCIS), the deuterium–tritium target shell is ablated and compressed by a highpower nanosecond laser in Au-cones to generate plasmas. Under the actions of spherically symmetric compression and acceleration along the Au cone, they will be ejected out of the cone mouth and collide with each other. The plasmas experience conversion from kinetic energy to internal energy at the vertex of the geometric center of two Au cones that are symmetric to each other, because of which high-density fusion plasmas are preheated. This key physical process has undergone experimental verification on the Shenguang-II upgraded facility in China. Apparently, the improvement and optimization of the velocity of plasmas in hypersonic jet flow at the cone mouth are crucial for the success of the DCIS. In the DCIR7 experiment of the Shenguang-II upgraded facility, a velocity yield of approximately 130–260 km/s was achieved for the plasmas at the cone mouth, with a result of nearly 300 km/s based on numerical simulation. In this paper, theoretical analysis is performed as regards the process, in which target shells are ablated and compressed by laser to generate highvelocity plasmas ejected through jet flow. Based on this analysis, the formula for the velocity of plasmas in supersonic jet flow at the cone mouth is proposed. This study also provides measures that are more effective for improving the kinetic energy of plasmas and optimizing energy conversion efficiency, which can serve as theoretical references for the adjustment and optimization of processes in subsequent experiments.