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Co-Production of High-Grade Dissolving Pulp,Furfural,and Lignin from Eucalyptus via Extremely Low Acid Pretreatment and Pulping Technologies and Catalysis 被引量:1
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作者 Chengxiang Li Yue Wu +3 位作者 Chunhui Zhang Yao Liu Qixuan Lin Junli Ren 《Journal of Renewable Materials》 SCIE EI 2023年第6期2555-2574,共20页
Hemicellulose and lignin are not reasonably utilized during the dissolved pulp preparation process.This work aimed to propose a process for the co-production of dissolving pulp,furfural,and lignin from eucalyptus.High... Hemicellulose and lignin are not reasonably utilized during the dissolved pulp preparation process.This work aimed to propose a process for the co-production of dissolving pulp,furfural,and lignin from eucalyptus.High-grade dissolving pulp was prepared from eucalyptus using a combination of extremely low acid(ELA)pretreatment,Kraft cooking,and elementary chlorine-free(ECF)bleaching.The obtained pre-hydrolysate was catalytic conversion into furfural in a biphasic system,and lignin during Kraft cooking and ECF was recovered.The process condition was discussed as well as the mass flow direction.The results showed that ELA pretreatment could effectively remove 80.1%hemicellulose.Compared with traditional hydrothermal pretreatment,the ELA pretreatment significantly increased the xylose yield from 5.05 to 14.18 g/L at 170℃ for 2 h,which had practical significance for furfural production.The 82.7%furfural yield and 82.9%furfural selectivity were obtained from xylose-rich pre-hydrolysate using NaCl as a phase modifier in a biphasic system with 4-methyl-2-pentanone(MIBK)as an organic phase by ion exchange resin catalysts at 190℃ for 2 h.Subsequently,the pretreated eucalyptus was subjected to Kraft cooking,and the optimal alkali amount was 14%.Then,the Kraft pulp was bleached using the O-D1-EP-D_(2) sequence,and dissolving pulp was obtained with an ISO brightness of 86.0%,viscosity of 463 mL/g,andα-cellulose content of 95.4%.The Kraft lignin which has a potential application was investigated by 2D-HSQC NMR and 31P NMR.The results showed that the S/G ratio of Kraft lignin was 1.93,and the content of phenolic hydroxyl groups was 2.53 mmol/g.Moreover,based on the above proposed process,30.5 g dissolving pulp,5.5 g furfural,and 21.2 g lignin per 100 g eucalyptus chips(oven dry)were produced.This research will provide new catalysis and pulping technical routes for dissolving pulp,furfural,and Kraft lignin products,which are in great demand in the chemical industry. 展开更多
关键词 EUCALYPTUS extremely low acid pretreatment dissolving pulp FURFURAL kraft lignin
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A review of physicochemical properties of dissolved organic carbon and its impact over mountain glaciers 被引量:1
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作者 NIU Hewen CHEN Mengxue +5 位作者 KANG Shichang SHUKLA Tanuj QIN Huili GAO Wanni HUANG Shihai ZHANG Fu 《Journal of Mountain Science》 SCIE CSCD 2024年第1期1-19,共19页
Investigating the characteristics and transformation of water-soluble carbonaceous matter in the cryosphere regions is important for understanding biogeochemical process in the earth system.Water-soluble carbonaceous ... Investigating the characteristics and transformation of water-soluble carbonaceous matter in the cryosphere regions is important for understanding biogeochemical process in the earth system.Water-soluble carbonaceous matter is a heterogeneous mixture of organic compounds that is soluble in aquatic environments.Despite its importance,we still lack systematic understanding for dissolved organic carbon(DOC)in several aspects including exact chemical composition and physical interactions with microorganisms,glacier meltwater.This review presents the chemical composition and physical properties of glacier DOC deposited through anthropogenic emission,terrestrial,and biogenic sources.We present the molecular composition of DOC and its effect over snow albedo and associated radiative forcings.Results indicate that DOC in snow/ice is made up of aromatic protein-like species,fulvic acid-like materials,and humic acid-like materials.Light-absorbing impurities in surface snow and glacier ice cause considerable albedo reduction and the associated radiative forcing is definitely positive.Water-soluble carbonaceous matter dominated the carbon transport in the high-altitude glacial area.Owing to prevailing global warming and projected increase in carbon emission,the glacial DOC is expected to release,which will have strong underlying impacts on cryosphere ecosystem.The results of this work have profound implications for better understanding the carbon cycle in high altitude cryosphere regions.A new compilation of globally distributed work is required,including large-scale measurements of glacial DOC over high-altitude cryosphere regions,to overcome and address the scientific challenges to constrain climate impacts of light-absorbing impurities related processes in Earth system and climate models. 展开更多
关键词 Mountain glaciers dissolved organic carbon Molecular composition Radiative forcing
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Development, Application and Prospect of Dissolving Microneedles
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作者 Juan YAN Chaoguo SUN +3 位作者 Yanjing LI Yuchen CUI Dongfang SHI Suohui ZHANG 《Agricultural Biotechnology》 CAS 2023年第1期55-60,共6页
In recent years, as a new transdermal drug delivery method, microneedle transdermal drug delivery technology accelerates the absorption of drugs through micron pores, which has been widely used in the field of medicin... In recent years, as a new transdermal drug delivery method, microneedle transdermal drug delivery technology accelerates the absorption of drugs through micron pores, which has been widely used in the field of medicine and cosmetics. Dissolving microneedles have the characteristics of good biocompatibility and fast dissolution speed, which attract more and more researchers’ attention and research. In this paper, the concept, properties and preparation methods of dissolving microneedles as well as the research status of dissolving microneedles in the field of medicine and cosmetics in recent years were summarized and prospected, so as to enable researchers to have a clearer and comprehensive understanding of dissolving microneedles and prospect the application and development prospects of dissolving microneedles in the industry. 展开更多
关键词 dissolving microneedles Medicine MAKEUP DEVELOPMENT APPLICATION
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Recent progress on nanomaterial-based electrochemical dissolved oxygen sensors
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作者 Shaoqi Zhang Tao Liu +1 位作者 Zhenyu Chu Wanqin Jin 《Chinese Journal of Chemical Engineering》 SCIE EI CAS CSCD 2024年第4期103-119,共17页
Dissolved oxygen(DO)usually refers to the amount of oxygen dissolved in water.In the environment,medicine,and fermentation industries,the DO level needs to be accurate and capable of online monitoring to guide the pre... Dissolved oxygen(DO)usually refers to the amount of oxygen dissolved in water.In the environment,medicine,and fermentation industries,the DO level needs to be accurate and capable of online monitoring to guide the precise control of water quality,clinical treatment,and microbial metabolism.Compared with other analytical methods,the electrochemical strategy is superior in its fast response,low cost,high sensitivity,and portable device.However,an electrochemical DO sensor faces a trade-off between sensitivity and long-term stability,which strongly limits its practical applications.To solve this problem,various advanced nanomaterials have been proposed to promote detection performance owing to their excellent electrocatalysis,conductivity,and chemical stability.Therefore,in this review,we focus on the recent progress of advanced nanomaterial-based electrochemical DO sensors.Through the comparison of the working principles on the main analysis techniques toward DO,the advantages of the electrochemical method are discussed.Emphasis is placed on recently developed nanomaterials that exhibit special characteristics,including nanostructures and preparation routes,to benefit DO determination.Specifically,we also introduce some interesting research on the configuration design of the electrode and device,which is rarely introduced.Then,the different requirements of the electrochemical DO sensors in different application fields are included to provide brief guidance on the selection of appropriate nanomaterials.Finally,the main challenges are evaluated to propose future development prospects and detection strategies for nanomaterial-based electrochemical sensors. 展开更多
关键词 NANOMATERIAL dissolved oxygen Electrochemical sensor NANOSTRUCTURES Detection principles
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Dissolvable temporary barrier:a novel paradigm for flexible hydrogel patterning in organ-on-a-chip models
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作者 Ding Wang Qinyu Li +5 位作者 Chenyang Zhou Zhangjie Li Kangyi Lu Yijun Liu Lian Xuan Xiaolin Wang 《Bio-Design and Manufacturing》 SCIE EI CAS CSCD 2024年第2期153-166,共14页
A combination of hydrogels and microfluidics allows the construction of biomimetic three-dimensional(3D)tissue models in vitro,which are also known as organ-on-a-chipmodels.The hydrogel patterningwith awell-controlled... A combination of hydrogels and microfluidics allows the construction of biomimetic three-dimensional(3D)tissue models in vitro,which are also known as organ-on-a-chipmodels.The hydrogel patterningwith awell-controlled spatial distribution is typically achieved by embedding sophisticated microstructures to act as a boundary.However,these physical barriers inevitably expose cells/tissues to a less physiologically relevant microenvironment than in vivo conditions.Herein,we present a novel dissolvable temporary barrier(DTB)strategy that allows robust and flexible hydrogel patterning with great freedom of design and desirable flow stimuli for cellular hydrogels.The key aspect of this approach is the patterning of a water-soluble rigid barrier as a guiding path for the hydrogel using stencil printing technology,followed by a barrier-free medium perfusion after the dissolution of the DTB.Single and multiple tissue compartments with different geometries can be established using either straight or curved DTB structures.The effectiveness of this strategy is further validated by generating a 3D vascular network through vasculogenesis and angiogenesis using a vascularized microtumor model.As a new proof-of-concept in vasculature-on-a-chip,DTB enables seamless contact between the hydrogel and the culture medium in closed microdevices,which is an improved protocol for the fabrication ofmultiorgan chips.Therefore,we expect it to serve as a promising paradigm for organ-on-a-chip devices for the development of tumor vascularization and drug evaluation in the future preclinical studies. 展开更多
关键词 dissolvable temporary barrier Hydrogel patterning Microfluidics Organ-on-a-chip Vascularization
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A numerical model study on the spatial and temporal variabilities of dissolved oxygen in Qinzhou Bay of the northern Beibu Gulf
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作者 Gaolei Cheng Shiqiu Peng +1 位作者 Bin Yang Dongliang Lu 《Acta Oceanologica Sinica》 SCIE CAS CSCD 2024年第6期49-59,共11页
Oxygen facilitates the breakdown of the organic material to provide energy for life.The concentration of dissolved oxygen(DO) in the water must exceed a certain threshold to support the normal metabolism of marine org... Oxygen facilitates the breakdown of the organic material to provide energy for life.The concentration of dissolved oxygen(DO) in the water must exceed a certain threshold to support the normal metabolism of marine organisms.Located in the northern B eibu Gulf,Qinzhou B ay receives abundant freshwater and nutrients from several rivers which significantly influence the level of the dissolved oxygen.However,the spatial-temporal variations of DO as well as the associated driving mechanisms have been rarely studied through field observations.In this study,a three-dimension al coupled physical-biogeochemical model is used to investigate the spatial and seasonal variations of the DO and the associated driving mechanisms in Qinzhou B ay.The validation against observations indicates that the model can capture the seasonal and inter-annual variability of the DO concentration with the range of 5-10 mg/L.Sensitivity experiments show that the river discharges,winds and tides play crucial roles in the seasonal variability of the DO by changing the vertical mixing and stratification of the water column and the circulation pattern.In winter,the tide and wind forces have strong effects on the DO distribution by enhancing the vertical mixing,especially near the bay mouth.In summer,the river discharges play a dominant role in the DO distribution by inhibiting the vertical water exchange and delivering more nutrients to the Bay,which increases the DO depletion and results in lower DO on the bottom of the estuary salt wedge.These findings can contribute to the preservation and management of the coastal environment in the northern Beibu Gulf. 展开更多
关键词 river plume dissolved oxygen STRATIFICATION physical-biological model
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Molecular investigation into the transformation of recalcitrant dissolved organic sulfur in refinery sour water during stripping process
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作者 Yu-Guo Li Chen He +2 位作者 Chun-Mao Chen Fan Liu Quan Shi 《Petroleum Science》 SCIE EI CAS CSCD 2024年第3期2112-2119,共8页
Refinery sour water primarily originates from the tops of towers in various units and coker condensate,and cannot be discharged directly to a wastewater treatment plant due to high levels of chemical oxygen demand(COD... Refinery sour water primarily originates from the tops of towers in various units and coker condensate,and cannot be discharged directly to a wastewater treatment plant due to high levels of chemical oxygen demand(COD)and organic sulfur contents.Even after the recovery of H_(2)S from the sour water by the stripping process,the effluent still contains a high concentration of dissolved organic sulfur(DOS),which can have a huge bad influence.While chemical composition of dissolved organic matter(DOM)in refinery wastewater has been extensively studied,the investigation of recalcitrant DOS from sour waters remains unclear.In the present study,chemical composition of sour water DOMs(especially DOS)was investigated using fluorescence spectroscopy(excitation-emission matrix,EEM)and mass spectrometry,including gas chromatography-mass spectrometry(GC-MS)and high-resolution Orbitrap MS.The GC-MS and EEM results showed that volatile and low-aromaticity compounds were effectively removed during the stripping process,while compounds with high hydrophilicity and humification degree were found to be more recalcitrant.The Orbitrap MS results showed that weak-polar oxygenated sulfur compounds were easier to be removed than oxygenated compounds.However,the effluent still contained significant amounts of sulfur-containing compounds with multiple sulfur atoms,particularly in the form of highly unsaturated and aromatic compounds.The Orbitrap MS/MS results of CHOS-containing compounds from the effluent indicate that the sulfur atoms may exist as sulfonates,disulfide bonds,thioethers.Understanding the composition and structure of sour water DOS is crucial for the development of effective treatment processes that can target polysulfide compounds and minimize their impact on the environment. 展开更多
关键词 Molecular transformation dissolved organic sulfur Stripping process Refinery sourwater Orbitrap MS
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Inter-annual variations of dissolved oxygen and hypoxia off the northern Changjiang River(Yangtze River) Estuary in summer from 1997 to 2014
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作者 Anqi Liu Feng Zhou +6 位作者 Xiao Ma Qiang Zhao Guanghong Liao Yuntao Zhou Di Tian Xiaobo Ni Ruibin Ding 《Acta Oceanologica Sinica》 SCIE CAS CSCD 2024年第6期119-130,共12页
Hypoxia off the Changjiang River Estuary has been the subject of much attention,yet systematic observations have been lacking,resulting in a lack of knowledge regarding its long-term change and drivers.By revisiting t... Hypoxia off the Changjiang River Estuary has been the subject of much attention,yet systematic observations have been lacking,resulting in a lack of knowledge regarding its long-term change and drivers.By revisiting the repeated surveys of dissolved oxygen(DO) and other relevant hydrographic parameters along the section from the Changjiang River Estuary to the Jeju-do in the summer from 1997 to 2014,rather different trends were revealed for the dual low-DO cores.The nearshore low-DO core,located close to the river mouth and relatively stable,shows that hypoxia has become more severe with the lowest DO descen ding at a rate of -0.07 mg/(L·a) and the thickness of low-DO zone rising at a rate of 0.43 m/a.The offshore core,centered around 40-m isobath but moving back and forth between 123.5°-125°E,shows large fluctuations in the minimum DO concentration,with the thickness of low-DO zone falling at a rate of -1.55 m/a.The probable factors affecting the minimum DO concentration in the two regions also vary.In the nearshore region,the decreasing minimum DO is driven by the increase in both stratification and primary productivity,with the enhanced extension of the Changjiang River Diluted Water(CDW) strengthening stratification.In the offshore region,the fluctuating trend of the minimum DO concentration indicates that both DO loss and DO supplement are distinct.The DO loss is primarily attributed to bottom apparent oxygen utilization caused by the organic matter decay and is also relevant to the advection of low-DO water from the nearshore region.The DO supplement is primarily due to weakened stratification.Our analysis also shows that the minimum DO concentration in the nearshore region was extremely low in 1998,2003,2007 and 2010,related to El Ni?o signal in these summers. 展开更多
关键词 dissolved oxygen low-DO Changjiang River Estuary interannual variations DUAL-CORE
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Straw mulching alters the composition and loss of dissolved organic matter in farmland surface runoff by inhibiting the fragmentation of soil small macroaggregates
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作者 Shanshan Cai Lei Sun +7 位作者 Wei Wang Yan Li Jianli Ding Liang Jin Yumei Li Jiuming Zhang Jingkuan Wang Dan Wei 《Journal of Integrative Agriculture》 SCIE CAS CSCD 2024年第5期1703-1717,共15页
Straw mulching is a widespread practice for reducing the soil carbon loss caused by erosion.However,the effects of straw mulching on dissolved organic matter(DOM)runoff loss from black soil are not well studied.How st... Straw mulching is a widespread practice for reducing the soil carbon loss caused by erosion.However,the effects of straw mulching on dissolved organic matter(DOM)runoff loss from black soil are not well studied.How straw mulching affects the composition and loss of runoff DOM by changing soil aggregates remains largely unclear.Here,a straw mulching treatment was compared to a no mulching treatment(as a control)on sloping farmland with black soil erosion in Northeast China.We divided the soil into large macroaggregates(>2 mm),small macroaggregates(0.25-2 mm),and microaggregates(<0.25 mm).After five rain events,the effects of straw mulching on the concentration(characterized by dissolved organic carbon(DoC)and composition(analyzed by fluorescence spectroscopy)of runoff and soil aggregate DOM were studied.The results showed that straw mulching reduced the runoff amount by 54.7%.Therefore,although straw mulching increased the average DOc concentration in runoff,it reduced the total runoff DOM loss by 48.3%.The composition of runoff DOM is similar to that of soil,as both contain humic-like acid and protein-like components.With straw mulching treatment,the protein-like components in small macroaggregates accumulated and the protein-like components in runoff declined with rain events.Fluorescence spectroscopy technology may help in understanding the hydrological paths of rain events by capturing the dynamic changes of runoff and soil DOM characteristics.A variation partitioning analysis(VPA)indicated that the DOM concentration and composition of microaggregates explained 68.2%of the change in runoff DOM from no mulching plots,while the change in runoff DOM from straw mulching plots was dominated by small macroaggregates at a rate of 55.1%.Taken together,our results demonstrated that straw mulching reduces the fragmentation of small macroaggregates and the loss of microaggregates,thus effecting DOM compositions in soil and reducing the DOM loss in runoff.These results provide a theoretical basis for reducing carbon loss in sloping farmland. 展开更多
关键词 dissolved organic matter black soil surface runoff AGGREGATES fluorescence spectrum
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The impact of typhoons on the biogeochemistry of dissolved organic matter in eutrophic bays in northwestern South China Sea
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作者 Xuan Lu Qibin Lao +3 位作者 Fajin Chen Guangzhe Jin Chunqing Chen Qingmei Zhu 《Acta Oceanologica Sinica》 SCIE CAS CSCD 2024年第6期15-31,共17页
Highly productive estuaries facilitate intense decomposition of dissolved organic matter(DOM) as a carbon source.However,the specific impacts of typhoons on DOM decomposition in eutrophic bays remain unclear.To addres... Highly productive estuaries facilitate intense decomposition of dissolved organic matter(DOM) as a carbon source.However,the specific impacts of typhoons on DOM decomposition in eutrophic bays remain unclear.To address this issue,we investigated the spectral characteristics of DOM before and after Typhoon Ewiniar in Zhanjiang B ay,a eutrophic semi-enclosed bay in the northwestern South China Sea.The results revealed that intense microbial decomposition of DOM occurred during the pre-typhoon period because high nutrient inputs facilitated the mobilization of DOM in the bay.However,the intrusion of external seawater induced by the typhoon diluted the nutrient levels in Zhanjiang B ay,reducing the impact of microbial decomposition on DOM during the post-typhoon perio d.Nevertheless,the net addition of DOM occurred in Zhanjiang Bay during the post-typhoon period,possibly because of the decomposition of particulate organic matter(POM) and desorption of particulate matter.In addition,an increase in apparent oxygen utilization,a decrease in DO saturation and the reduced level of Chl a indicated that organic matter(OM) decomposition was enhanced and OM decomposition shifted to POM decomposition in Zhanjiang Bay after the typhoon.Overall,our study highlighted the shift in the intense OM decomposition from DOM to POM decomposition before and after typhoons in eutrophic bays,providing new insights into the response of typhoons to biogeo chemistry. 展开更多
关键词 dissolved organic matter optical analyses decomposition TYPHOON northwestern South China Sea
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Impact of transparent exopolymer particles on the dynamics of dissolved organic carbon in the Amundsen Sea,Antarctica
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作者 HU Ji XUE Siyou +6 位作者 ZHAO Jun LI Dong ZHANG Haifeng YU Peisong ZHANG Cai YANG Xufeng PAN Jianming 《Advances in Polar Science》 CSCD 2024年第1期123-131,共9页
The Southern Ocean is an important carbon sink pool and plays a critical role in the global carbon cycling.The Amundsen Sea was reported to be highly productive in inshore area in the Southern Ocean.In order to invest... The Southern Ocean is an important carbon sink pool and plays a critical role in the global carbon cycling.The Amundsen Sea was reported to be highly productive in inshore area in the Southern Ocean.In order to investigate the influence of transparent exopolymer particles(TEP)on the behavior of dissolved organic carbon(DOC)in this region,a comprehensive study was conducted,encompassing both open water areas and highly productive polynyas.It was found that microbial heterotrophic metabolism is the primary process responsible for the production of humic-like fluorescent components in the open ocean.The relationship between apparent oxygen utilization and the two humic-like components can be accurately described by a power-law function,with a conversion rate consistent with that observed globally.The presence of TEP was found to have little impact on this process.Additionally,the study revealed the accumulation of DOC at the sea surface in the Amundsen Sea Polynya,suggesting that TEP may play a critical role in this phenomenon.These findings contribute to a deeper understanding of the dynamics and surface accumulation of DOC in the Amundsen Sea Polynya,and provide valuable insights into the carbon cycle in this region. 展开更多
关键词 dissolved organic matter chromophoric dissolved organic matter excitation-emission matrix coupled with parallel factor analysis transparent exopolymer particles Amundsen Sea ANTARCTICA
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Exploration of the Existence Forms and Patterns of Dissolved Oxygen Molecules in Water
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作者 Hewei Yuan Yaozhong Zhang +7 位作者 Xiaolu Huang Xiwu Zhang Jinjin Li Yufeng Huang Kun Li Haotian Weng Yang Xu Yafei Zhang 《Nano-Micro Letters》 SCIE EI CAS CSCD 2024年第10期337-349,共13页
The structure of liquid water is primarily composed of three-dimensional networks of water clusters formed by hydrogen bonds,and dis-solved oxygen is one of the most important indicators for assessing water qual-ity.I... The structure of liquid water is primarily composed of three-dimensional networks of water clusters formed by hydrogen bonds,and dis-solved oxygen is one of the most important indicators for assessing water qual-ity.In this work,distilled water with different concentration of dissolved oxygen were prepared,and a clear negative correlation between the size of water clus-ters and dissolved oxygen concentration was observed.Besides,a phenomenon of rapid absorption and release of oxygen at the water interfaces was unveiled,suggesting that oxygen molecules predominantly exist at the interfaces of water clusters.Oxygen molecules can move rapidly through the interfaces among water clusters,allowing dissolved oxygen to quickly reach a saturation level at certain partial pressure of oxygen and temperature.Further exploration into the mechanism by molecular dynamics simulations of oxygen and water clusters found that oxygen molecules can only exist stably at the interfaces among water clusters.A semi-empirical formula relating the average number of water molecules in a cluster(n)to ^(17)O NMR half-peak width(W)was summarized:n=0.1 W+0.85.These findings provide a foundation for exploring the structure and properties of water. 展开更多
关键词 Water clusters dissolved oxygen ^(17)O NMR Molecular dynamics simulation
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Impacts of Water-Sediment Regulation Scheme on Chromophoric Dissolved Organic Matter in the Lower Yellow River
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作者 LIU Xiao JIANG Xueyan +2 位作者 LIU Qian SUI Juanjuan ZOU Li 《Journal of Ocean University of China》 CAS CSCD 2024年第2期455-466,共12页
As a river with more than 3000 reservoirs in its watershed,the Yellow River has been affected by dams not only on the sediment load,but also on the water quality.Water-sediment regulation scheme(WSRS),which has been c... As a river with more than 3000 reservoirs in its watershed,the Yellow River has been affected by dams not only on the sediment load,but also on the water quality.Water-sediment regulation scheme(WSRS),which has been carried out annually in the Yellow River since 2002,is a typical human activity affecting river water quality.Chromophoric dissolved organic matter(CDOM)in river is susceptible to changes in ecological and environmental conditions as well as human activities.Here,we report variations in dissolved organic carbon concentrations,compositions and sources of CDOM in time series samples in the lower Yellow River during WSRS.In addition,a parallel factor fluorescence analysis(PARAFAC)method is applied to identify different fluorescent components in water samples during WRSR,showing four major components including tryptophan-like component(C1),microbial humic-like component(C2),terrestrial humic-like component(C3)and tyrosine-like component(C4).In general,C1 increased after water regulation,while C2 and C3 increased after sediment regulation,indicating that the water and sediment released by the dam have different effects on CDOM compositions.Under the impacts of the dam,source of CDOM in the lower Yellow River is mainly autochthonous related to microbial activities,and is regulated by the terrestrial input during WSRS period.Sediment resuspension inhibits microbial activities and reduces the production of autochthonous CDOM.Overall,human activities especially WSRS,as exemplified here,significantly alter the quality and quantity of CDOM in the lower Yellow River,affecting CDOM dynamics and biogeochemical processes in the estuarine environment. 展开更多
关键词 chromophoric dissolved organic matter(CDOM) water-sediment regulation scheme(WSRS) Yellow River optical properties
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Dissolved Organic Matter Features of Three Adjacent Eastern Mediterranean Urbanized Watersheds
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作者 Nour Abboud Elias Michel Maatouk +1 位作者 Zeinab Matar Veronique Kazpard 《Open Journal of Modern Hydrology》 CAS 2024年第3期153-173,共21页
Landscape urbanization broadly affects ecosystems in coastal watersheds, but, until now, the influence of nonpoint source urban inputs on dissolved organic matter (DOM) amount, composition, and source is poorly unders... Landscape urbanization broadly affects ecosystems in coastal watersheds, but, until now, the influence of nonpoint source urban inputs on dissolved organic matter (DOM) amount, composition, and source is poorly understood. To understand how DOM composition varied with urbanization, fluorescence excitation-emission matrices (EEMs) were determined for urban and non-urban waters from upstream to downstream sites along three adjacent coastal watersheds that flow into the Mediterranean Sea. Two humic DOM fluorescent components (humic-like and fulvic-like peaks) and two proteinic components (tyrosine-like and tryptophane-like peaks) were identified by EEM fluorescence. The results indicated that urbanization had an important influence on DOM concentration and composition, with urban waters having a high degree of DOM variation due to different land uses surrounding each body of water. Urban waters show a higher DOM fluorescence index (FI), the highest fluorescence intensity of protein-like manifested also by BIX values, and a lower value of the humification index (HIX) than non-urban waters which were dominated by allochthonous inputs. In addition, the EEM was compared in dry and wet season where higher DOM amounts and FI appeared in summer due to autochthonous production coming from algae growth compared to allochthonous input from rainfall dominated in wet season. The concentration of DOC increased from upstream to downstream for the three rivers, especially Beirut River. The increase in DOC values was observed in both dry and wet seasons by 39 and 19 times respectively compared to upstream (0.93 - 0.91 mgC/L). 展开更多
关键词 dissolved Organic Matter DOM EEM Fluorescence Spectroscopy Autochthonous/Allochthonous DOM Urbanization Upstream/Downstream Wet/Dry Season
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Study of Total Dissolved Solids (TDS) Concentrations Factor of SWCC Al-Khobar Plant Seawater Intakes
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作者 Ahmed Al-Kubaish Jamal Salama Waleed Al-Jurayan 《Computational Water, Energy, and Environmental Engineering》 2024年第1期1-12,共12页
This study presents a significant contribution to the field of water quality assessment and sustainable water management practices. By evaluating the levels of total dissolved solids (TDS) in seawater intakes within A... This study presents a significant contribution to the field of water quality assessment and sustainable water management practices. By evaluating the levels of total dissolved solids (TDS) in seawater intakes within Al-Khobar desalination production system, the study addresses a crucial aspect of water treatment and environmental impact assessment. The findings provide valuable insights into the variations and trends of TDS levels across different phases of the system, highlighting the importance of monitoring and management strategies. The study provided both gravimetric total dissolved solids (TDS) and electrical conductivity (EC) measurements to analyze TDS calculation factor and evaluate measurement accuracy. Results revealed significant variations in TDS levels across the sampling locations, with phase-2 exhibiting higher levels and greater fluctuations. Phase-3 displayed similar trends but with lower TDS levels, while phase-4 showed slightly different behavior with higher average TDS levels. EC measurements demonstrated a strong correlation with TDS, providing a reliable estimation. However, additional methods such as gravimetric analysis should be employed to confirm TDS measurements. The findings contribute to understanding water quality in the Al-Khobar desalination system, aiding in monitoring, management, and decision-making processes for water treatment and environmental impact assessment. The study enhances the credibility of water quality assessments and supports sustainable water management practices. 展开更多
关键词 Total dissolved Solids CONDUCTIVITY Seawater DESALINATION
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Impacts of Climate Change on Seawater Temperature and Total Dissolved Solids: Challenges and Sustainable Solutions for Reverse Osmosis Desalination in the Arabian Gulf Region
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作者 Ahmed Al Kubaish Jamal Salama 《Computational Water, Energy, and Environmental Engineering》 2024年第1期86-93,共8页
This article examines the influence of seawater temperature and total dissolved solids (TDS) on reverse osmosis (RO) desalination in the Arabian Gulf region, with a focus on the impact of climate change. The study hig... This article examines the influence of seawater temperature and total dissolved solids (TDS) on reverse osmosis (RO) desalination in the Arabian Gulf region, with a focus on the impact of climate change. The study highlights the changes in seawater temperature and TDS levels over the years and discusses their effects on the efficiency and productivity of RO desalination plants. It emphasizes the importance of monitoring TDS levels and controlling seawater temperature to optimize water production. The article also suggests various solutions, including intensive pre-treatment, development of high-performance membranes, exploration of alternative water sources, and regulation of discharges into the Gulf, to ensure sustainable water supply in the face of rising TDS levels and seawater temperature. Further research and comprehensive monitoring are recommended to understand the implications of these findings and develop effective strategies for the management of marine resources in the Arabian Gulf. 展开更多
关键词 Climate Change TEMPERATURE Reverse Osmosis Seawater Total dissolved Solids DESALINATION
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STUDY ON THE MECHANISM OF NYLON 6, 6 DISSOLVING PROCESS USING CaCl_2/MeOH AS THE SOLVENT 被引量:9
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作者 孙本惠 《Chinese Journal of Polymer Science》 SCIE CAS CSCD 1994年第1期57-65,共9页
A discussion of the mechanism of nylon 6, 6 dissolving process using CaCl_2/MeOH as the sol-vent is presented. The calcium chloride forms a complex compound with nylon 6, 6 by breakingthe hydrogen bonds. The melting p... A discussion of the mechanism of nylon 6, 6 dissolving process using CaCl_2/MeOH as the sol-vent is presented. The calcium chloride forms a complex compound with nylon 6, 6 by breakingthe hydrogen bonds. The melting point of the CaCl_2 --nylon 6, 6 complex was found to be reducedby 91K relative to the pure nylon 6, 6 polymer. The role of methanol is somewhat similar to acatalyst. The results demonstrate that the complexation of a Lewis acid (CaCl_2) and a Lewis base(nylon 6, 6) can be used to probe intermolecular interactions such as hydrogen bonding in polymers, to modify the polymer properties and mediate its solubility and processing. 展开更多
关键词 dissolving mechanism CaCl_2/MeOH solvent POLYAMIDE COMPLEX
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Numerical Modelling of Dissolving and Driving Exploitation of Potash Salt in the Qarhan Playa——A Coupled Model of Reactive Solute Transport and Chemical Equilibrium in a Multi-component Underground Brine System 被引量:10
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作者 LI Wenpeng LIU Zhenying 《Acta Geologica Sinica(English Edition)》 SCIE CAS CSCD 2008年第5期1070-1082,共13页
Firstly, the macroscopic chemical equilibrium state of a series of chemical reactions between intercrystal brine and its media salt layer (salt deposit) in Qarhan Salt Lake was studied by using the Pitzer theory. Th... Firstly, the macroscopic chemical equilibrium state of a series of chemical reactions between intercrystal brine and its media salt layer (salt deposit) in Qarhan Salt Lake was studied by using the Pitzer theory. The concept of macroscopic solubility product and its relation with accumulated ore dissolving ratio were presented, which are used in the numerical model of dissolving and driving exploitation of potassium salt in Qarhan Salt Lake. And secondly, with a model forming idea of transport model for reacting solutes in the multi-component fresh groundwater system in porous media being a reference, a two-dimensional transport model coupled with a series of chemical reactions in a multi-component brine porous system (salt deposits) was developed by using the Pitzer theory. Meanwhile, the model was applied to model potassium/magnesium transport in Qarhan Salt Lake in order to study the transfer law of solid and liquid phases in the dissolving and driving process and to design the optimal injection/abstraction strategy for dissolving and capturing maximum Potassium/ Magnesium in the mining of salt deposits in Qarhan Salt Lake. 展开更多
关键词 salt lake macroscopic solubility product transport model of reacting solutes dissolving and driving exploitation
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Dissolving of Nb and Ti carbonitride precipitates in microalloyed steels 被引量:8
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作者 Wenjin Nie, Shanwu Yang, Shaoqiang Yuan, and Xinlai HeMaterials Science and Engineering School, University of Science and Technology Beijing, Beijing 100083, China 《Journal of University of Science and Technology Beijing》 CSCD 2003年第5期78-80,共3页
The dissolving behaviour of Nb and Ti carbonitride precipitates inmicroalloyed steels during isothermal holding at 1300℃ was investigated by Transmission electronmicroscopy (TEM) and energy dispersion x-ray spectrum ... The dissolving behaviour of Nb and Ti carbonitride precipitates inmicroalloyed steels during isothermal holding at 1300℃ was investigated by Transmission electronmicroscopy (TEM) and energy dispersion x-ray spectrum (EDX). It was found that all precipitates inNb-Ti microalloyed steel are (Nb, Ti)(C, N). With holding time increasing, the atomic ratio of Nb/Tiin precipitates decrease gradually. These precipitates still existe even after holding for 48 h at1300℃ while Nb(C, N) precipitates dissolve away in Nb microalloyed steel only after 4 h at the sametemperature. These results show that formation and thermostability of precipitates are considerablyinfluenced by interaction between Nb and Ti. 展开更多
关键词 dissolving (Nb Ti)(C N) TEM EDX
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Upgrading Paper-grade Softwood Kraft Pulp to Dissolving Pulp by Cold Caustic Extraction 被引量:6
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作者 Chao Tian QingXian Miao +1 位作者 LinQiang Zheng YongHao Ni 《Paper And Biomaterials》 2016年第1期31-37,共7页
Cold caustic extraction has potential applications in the production of dissolving-grade pulps due to its ability to selectively remove hemicellulose from lignocellulosic materials. In this study,we demonstrate the co... Cold caustic extraction has potential applications in the production of dissolving-grade pulps due to its ability to selectively remove hemicellulose from lignocellulosic materials. In this study,we demonstrate the conversion of paper-grade kraft pulp into dissolving pulp by a single-stage cold caustic extraction. Under the extraction conditions of 12 wt% NaOH lye,11% pulp consistency,a temperature of 35℃,and 2 h,a paper-grade softwood kraft pulp was purified to high-grade dissolving pulp with 97. 1% α-cellulose content,1. 2% pentosane content,and narrowed molecular weight distribution. The resulting extraction filtrate was concentrated by nano-filtration to obtain the hemicellulose content of 59. 0 g / L,while the permeate was a clear Na OH solution with 10. 9 wt% concentration. A process configuration was also proposed,integrating this cold caustic extraction process with existing pulp and paper production and multi-purpose utilization of the extraction filtrate. 展开更多
关键词 cold caustic extraction dissolving pulp Α-CELLULOSE membrane filtration HEMICELLULOSE
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