Two new baccharane-type glycosides(1 and 2), together with seven known baccharane-type glycosides (3u9) hosenkoside A, hosenkoside B, hosenkoside C, hosenkoside F, hosenkoside M, hosenkoside K and hosenko- side G ...Two new baccharane-type glycosides(1 and 2), together with seven known baccharane-type glycosides (3u9) hosenkoside A, hosenkoside B, hosenkoside C, hosenkoside F, hosenkoside M, hosenkoside K and hosenko- side G were isolated from the dried seeds of Impatientis balsamina L. The new baccharane-type glycosides were identified as honsenkol A-3-O-β-D-glucopyranosyl-26-O-p-D-glucopyranosyl-28-O-β-D-glucopyranosyl-O-β-D- glucopyranosyl(1) and (3S,4R,17R,20S)17-hydrroxy-3-O-β-D-xylopyranose(12)-β-D-glucopyranosyl-26-O-β-D- glucopyranosyl-28-O-β-D-glucopyranosyl-21,24-epoxybaccharane(2), respectively, by spectroscopic methods, in- cluding NMR(1D and 2D), IR and HR-ESI-MS. Compounds 1 and 2 were evaluated for in vitro inhibitory activity against the cell lines. Compound 2 with a new baccharane skeleton had anti-hepatic fibrosis activity against A375 cells in bioassay results, which means the new compounds have potential value in antitumor applications.展开更多
Two new tetrahydronaphthalenes,lα,2α-diol-4α-ethoxy-1,2,3,4-tetrahydronaphthalene(1) and 1a,2a,4β-triol-1,2,3,4- tetrahydronaphthalene(2),were isolated from the stem of Impatiens balsamina L.Their structures were ...Two new tetrahydronaphthalenes,lα,2α-diol-4α-ethoxy-1,2,3,4-tetrahydronaphthalene(1) and 1a,2a,4β-triol-1,2,3,4- tetrahydronaphthalene(2),were isolated from the stem of Impatiens balsamina L.Their structures were elucidated by various spectroscopic methods.展开更多
The samples of pueraria lobata ohwi were digested by HNO3 + HClO4.contents of the next trace elements Fe,Zn,Cu,Mn,Ca,Mg,Co,Cr,Ni,Cd,Pb and Al in the bloom,base,stem,and leaf of Impatiens balsamina have been determined...The samples of pueraria lobata ohwi were digested by HNO3 + HClO4.contents of the next trace elements Fe,Zn,Cu,Mn,Ca,Mg,Co,Cr,Ni,Cd,Pb and Al in the bloom,base,stem,and leaf of Impatiens balsamina have been determined by Flame Atomic Absorption method.The result show that the recovery is about 97.5%-103.2%,and the RSD<2.7%,with good accuracy and precision.The order of the content of the trace elements of high to low is as follows:leaf>stem>bloom>base.The importance of essential trace elements Zn,Fe,Mn,Cu for human each has a higher content.In addition,toxic trace elements such as lead,arsenic and cadmium are also found.展开更多
基金Supported by the National Natural Science Foundation of China(No. 81173602).
文摘Two new baccharane-type glycosides(1 and 2), together with seven known baccharane-type glycosides (3u9) hosenkoside A, hosenkoside B, hosenkoside C, hosenkoside F, hosenkoside M, hosenkoside K and hosenko- side G were isolated from the dried seeds of Impatientis balsamina L. The new baccharane-type glycosides were identified as honsenkol A-3-O-β-D-glucopyranosyl-26-O-p-D-glucopyranosyl-28-O-β-D-glucopyranosyl-O-β-D- glucopyranosyl(1) and (3S,4R,17R,20S)17-hydrroxy-3-O-β-D-xylopyranose(12)-β-D-glucopyranosyl-26-O-β-D- glucopyranosyl-28-O-β-D-glucopyranosyl-21,24-epoxybaccharane(2), respectively, by spectroscopic methods, in- cluding NMR(1D and 2D), IR and HR-ESI-MS. Compounds 1 and 2 were evaluated for in vitro inhibitory activity against the cell lines. Compound 2 with a new baccharane skeleton had anti-hepatic fibrosis activity against A375 cells in bioassay results, which means the new compounds have potential value in antitumor applications.
文摘Two new tetrahydronaphthalenes,lα,2α-diol-4α-ethoxy-1,2,3,4-tetrahydronaphthalene(1) and 1a,2a,4β-triol-1,2,3,4- tetrahydronaphthalene(2),were isolated from the stem of Impatiens balsamina L.Their structures were elucidated by various spectroscopic methods.
文摘The samples of pueraria lobata ohwi were digested by HNO3 + HClO4.contents of the next trace elements Fe,Zn,Cu,Mn,Ca,Mg,Co,Cr,Ni,Cd,Pb and Al in the bloom,base,stem,and leaf of Impatiens balsamina have been determined by Flame Atomic Absorption method.The result show that the recovery is about 97.5%-103.2%,and the RSD<2.7%,with good accuracy and precision.The order of the content of the trace elements of high to low is as follows:leaf>stem>bloom>base.The importance of essential trace elements Zn,Fe,Mn,Cu for human each has a higher content.In addition,toxic trace elements such as lead,arsenic and cadmium are also found.