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Factors influencing in-situ leaching of uranium mining in a sandstone deposit in Shihongtan, Northwest China 被引量:2
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作者 LIU Jin-hui SUN Zhan-xue +1 位作者 SHI Wei-jun ZHOU Yi-peng 《Journal of Groundwater Science and Engineering》 2015年第1期16-20,共5页
The Shihongtan uranium deposit in northwest China is a sandstone-type deposit suitable for alkaline in-situ leaching exploitation of uranium. Alkaline leaching tends to result in CaCO3 precipitation there by affecting... The Shihongtan uranium deposit in northwest China is a sandstone-type deposit suitable for alkaline in-situ leaching exploitation of uranium. Alkaline leaching tends to result in CaCO3 precipitation there by affecting the porosity of the ore-bearing aquifer. CaCO3 deposits can also block pumping and injection holes if the formulation parameters of the leaching solution are not well controlled. However, controlling these parameters to operate the in-situ leaching process is challenging. Our study demonstrates that the dissolved uranium concentration in the leaching solution increases as HCO3-concentration increases. Therefore, the most suitable HCO3-concentration to use as leaching solution is defined by the boundary value of the HCO3-concentration that controls CaCO3 dissolution-precipitation. That is, the dissolution and precipitation of calcite is closely related to pH, Ca2+ and HCO3-concentration. The pH and Ca2+ concentration are the main factors limiting HCO3-concentration in the leaching solution. The higher the pH and Ca2+ concentration, the lower the boundary value of HCO3-concentration, and therefore the more unfavorable to in-situ leaching of uranium. 展开更多
关键词 Sandstone-type uranium deposit in-situ leaching Boundary value Saturation index
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Quantifying the impact of mineralogical heterogeneity on reactive transport modeling of CO_(2)+O_(2) in-situ leaching of uranium 被引量:1
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作者 Yun Yang Wenjie Qiu +5 位作者 Zhengbang Liu Jian Song Jianfeng Wu Zhi Dou Jinguo Wang Jichun Wu 《Acta Geochimica》 EI CAS CSCD 2022年第1期50-63,共14页
CO_(2)+O_(2) in-situ leaching(ISL)of sandstonetype uranium ore represents the third generation of solution mining in China.In this study,reactive transport modeling of the interaction between hydrodynamic and geochemi... CO_(2)+O_(2) in-situ leaching(ISL)of sandstonetype uranium ore represents the third generation of solution mining in China.In this study,reactive transport modeling of the interaction between hydrodynamic and geochemical reactions is performed to enable better prediction and regulation of the CO_(2)+O_(2) in-situ leaching process of uranium.Geochemical reactions between mining solutions and rock,and the kinetic uranium dissolution controlled by O_(2)(aq)and bicarbonate(HCO_(3)-)are considered in the CO_(2)+O_(2) ISL reactive transport model of a typical sandstone-hosted uranium ore deposit in northern China.The reactive leaching of uranium is most sensitive to the spatial distribution of the mineralogical properties of the uranium deposit.Stochastic geostatistical models are used to represent the uncertainty on the spatial distribution of mineral grades.A Monte Carlo analysis was also performed to simulate the uranium production variability over an entire set of geostatistical realizations.The ISL stochastic simulation performed with the selected geostatistical realizations approximates the uranium production variability well.The simulation results of the ISL reactive transport model show that the extent of the uranium plume is highly dependent on mineralogical heterogeneity.The uncertainty analysis suggests the effect of uranium grade heterogeneity was found to be important to improve the accurate capture of the uncertainty.This study provides guidance for the accurate simulation and dynamic regulation of the CO_(2)+O_(2) leaching process of uranium at the scale of large mining areas. 展开更多
关键词 in-situ leaching Reactive transport HETEROGENEITY Stochastic geostatistical model Monte Carlo analysis Uranium grade
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Study on treatment of wastewater from acid in-situ leaching of uranium ore with sulfate reducing bacteria
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作者 Qingliang WANG 《Chinese Journal Of Geochemistry》 EI CAS 2006年第B08期180-180,共1页
关键词 SRB 废水处理 地下水 铀矿 硫酸盐
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Study on synergistic leaching of potassium and phosphorus from potassium feldspar and solid waste phosphogypsum via coupling reactions
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作者 Chao Li Shizhao Wang +3 位作者 Yunshan Wang Xuebin An Gang Yang Yong Sun 《Chinese Journal of Chemical Engineering》 SCIE EI CAS CSCD 2024年第1期117-129,共13页
To achieve the resource utilization of solid waste phosphogypsum(PG)and tackle the problem of utilizing potassium feldspar(PF),a coupled synergistic process between PG and PF is proposed in this paper.The study invest... To achieve the resource utilization of solid waste phosphogypsum(PG)and tackle the problem of utilizing potassium feldspar(PF),a coupled synergistic process between PG and PF is proposed in this paper.The study investigates the features of P and F in PG,and explores the decomposition of PF using hydrofluoric acid(HF)in the sulfuric acid system for K leaching and leaching of P and F in PG.The impact factors such as sulfuric acid concentration,reaction temperature,reaction time,material ratio(PG/PF),liquid–solid ratio,PF particle size,and PF calcination temperature on the leaching of P and K is systematically investigated in this paper.The results show that under optimal conditions,the leaching rate of K and P reach more than 93%and 96%,respectively.Kinetics study using shrinking core model(SCM)indicates two significant stages with internal diffusion predominantly controlling the leaching of K.The apparent activation energies of these two stages are 11.92 kJ·mol^(-1)and 11.55 kJ·mol^(-1),respectively. 展开更多
关键词 PHOSPHOGYPSUM Potassium feldspar Coupling reaction leaching Waste treatment Kinetics
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Selective leaching of lithium from spent lithium-ion batteries using sulfuric acid and oxalic acid
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作者 Haijun Yu Dongxing Wang +6 位作者 Shuai Rao Lijuan Duan Cairu Shao Xiaohui Tu Zhiyuan Ma Hongyang Cao Zhiqiang Liu 《International Journal of Minerals,Metallurgy and Materials》 SCIE EI CAS CSCD 2024年第4期688-696,共9页
Traditional hydrometallurgical methods for recovering spent lithium-ion batteries(LIBs)involve acid leaching to simultaneously extract all valuable metals into the leachate.These methods usually are followed by a seri... Traditional hydrometallurgical methods for recovering spent lithium-ion batteries(LIBs)involve acid leaching to simultaneously extract all valuable metals into the leachate.These methods usually are followed by a series of separation steps such as precipitation,extraction,and stripping to separate the individual valuable metals.In this study,we present a process for selectively leaching lithium through the synergistic effect of sulfuric and oxalic acids.Under optimal leaching conditions(leaching time of 1.5 h,leaching temperature of 70°C,liquid-solid ratio of 4 mL/g,oxalic acid ratio of 1.3,and sulfuric acid ratio of 1.3),the lithium leaching efficiency reached89.6%,and the leaching efficiencies of Ni,Co,and Mn were 12.8%,6.5%,and 21.7%.X-ray diffraction(XRD)and inductively coupled plasma optical emission spectrometer(ICP-OES)analyses showed that most of the Ni,Co,and Mn in the raw material remained as solid residue oxides and oxalates.This study offers a new approach to enriching the relevant theory for selectively recovering lithium from spent LIBs. 展开更多
关键词 selective leaching oxalic acid sulfuric acid spent lithium-ion batteries
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Effect of Saline Water on Soil Acidity, Alkalinity and Nutrients Leaching in Sandy Loamy Soil in Rwamagana Bella Flower Farm, Rwanda
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作者 Abel Mwubahaman Wali Umaru Garba +3 位作者 Hussein Bizimana Jean de Dieu Bazimenyera Eric Derrick Bugenimana Jean Nepomuscene Nsengiyumva 《Agricultural Sciences》 2024年第1期15-35,共21页
The necessity to saline and sodic waters is sometimes used for irrigating agricultural activities under certain circumstances, but it is important to note that the use of these waters comes with specific consideration... The necessity to saline and sodic waters is sometimes used for irrigating agricultural activities under certain circumstances, but it is important to note that the use of these waters comes with specific considerations and limitations. One way to decrease undesirable effects of sodic waters on the physical and chemical properties of soils is to apply organic and chemical amendments within the soil. This study aimed to assess the effectiveness of saline water on soil acidity, alkalinity and nutrients leaching in sandy loamy soil at Bella flower farm, in Rwamagana District, Rwanda. The water used was from the Muhazi Lake which is classified as Class I (Saline water quality). Column leaching experiments using treated soils were then conducted under saturated conditions. The soil under experimental was first analyzed for its textural classification, soil properties and is classified as sandy loamy soil. The t-test was taken at 1%, 5% and 10% levels of statistical significance compared to control soil. The results indicated that the application of saline water to soils caused an increase in some soil nutrients like increase of Phosphorus (P), Potassium (K<sup>+</sup>), Magnesium (Mg2<sup>+</sup>), Sulphur (S), CN ratio and Sodium (Na<sup>+</sup>) and decreased soil texture, physical and chemical properties and remained soil nutrients. Consequently, the intensive addition of saline water leachates to soil in PVC pipes led to decreased of soil EC through leaching and a raiser Soluble Sodium Percentage (SSP). The rate of saline water application affected the increase accumulation of SAR and Na% in the top soil layers. The study indicated that saline water is an inefficient amendment for sandy soil with saline water irrigation. The study recommends further studies with similar topic with saline water irrigation, as it accentuated the alkalinity levels. 展开更多
关键词 NUTRIENTS leaching Saline Water Soil Acidity Soil Alkalinity
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Extraction of Valuable Metals from Titanium-bearing Blast Furnace Slag by Acid Leaching
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作者 刘燕 CHEN Xuegui +2 位作者 MAO Shuaidong XIAO Yadong LI Jiacong 《Journal of Wuhan University of Technology(Materials Science)》 SCIE EI CAS CSCD 2024年第2期376-385,共10页
To realize the resource utilization of the valuable metals in the titanium-containing blast furnace slag,the process route of “hydrochloric acid leaching-electrolysis-carbonization and carbon dioxide capture-preparat... To realize the resource utilization of the valuable metals in the titanium-containing blast furnace slag,the process route of “hydrochloric acid leaching-electrolysis-carbonization and carbon dioxide capture-preparation of calcium carbonate” was proposed.In this study,the influences of process conditions on the leaching rates of calcium,magnesium,aluminum,and iron and the phases of the leaching residue were investigated for the leaching process.The experimental results show that the HCl solution could selectively leach the elements from the titanium-containing blast furnace slag.The better leaching conditions are the HCl solution concentration of 4 mol/L,the leaching time of 30 min,the ratio of liquid volume to solid gas of 10 mL/g,and the stirring paddle speed of 300 r/min.Under the conditions,the leaching rates of calcium,magnesium,aluminum,and iron can reach 85.87%,73.41%,81.35%,and 59.08%,and the leaching rate of titanium is 10.71%.The iron and the aluminum are removed from the leachate to obtain iron-aluminum water purification agents,and the magnesium is removed from the leachate to obtain magnesium hydroxide.The leaching residue phase is dominated by perovskite,followed by magnesium silicate and tricalcium aluminate,and the titaniumrich material could be obtained from the leaching residue by desiliconization. 展开更多
关键词 titanium-containing blast furnace slag acid leaching valuable metals comprehensive utilization
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Recovery of Li, Ni, Co and Mn from spent lithium-ion batteries assisted by organic acids: Process optimization and leaching mechanism
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作者 Liuyi Ren Bo Liu +5 位作者 Shenxu Bao Wei Ding Yimin Zhang Xiaochuan Hou Chao Lin Bo Chen 《International Journal of Minerals,Metallurgy and Materials》 SCIE EI CAS CSCD 2024年第3期518-530,共13页
The proper recycling of spent lithium-ion batteries(LIBs)can promote the recovery and utilization of valuable resources,while also negative environmental effects resulting from the presence of toxic and hazardous subs... The proper recycling of spent lithium-ion batteries(LIBs)can promote the recovery and utilization of valuable resources,while also negative environmental effects resulting from the presence of toxic and hazardous substances.In this study,a new environmentally friendly hydro-metallurgical process was proposed for leaching lithium(Li),nickel(Ni),cobalt(Co),and manganese(Mn)from spent LIBs using sulfuric acid with citric acid as a reductant.The effects of the concentration of sulfuric acid,the leaching temperature,the leaching time,the solid-liquid ratio,and the reducing agent dosage on the leaching behavior of the above elements were investigated.Key parameters were optimized using response surface methodology(RSM)to maximize the recovery of metals from spent LIBs.The maxim-um recovery efficiencies of Li,Ni,Co,and Mn can reach 99.08%,98.76%,98.33%,and 97.63%.under the optimized conditions(the sulfuric acid concentration was 1.16 mol/L,the citric acid dosage was 15wt%,the solid-liquid ratio was 40 g/L,and the temperature was 83℃ for 120 min),respectively.It was found that in the collaborative leaching process of sulfuric acid and citric acid,the citric acid initially provided strong reducing CO_(2)^(-),and the transition metal ions in the high state underwent a reduction reaction to produce transition metal ions in the low state.Additionally,citric acid can also act as a proton donor and chelate with lower-priced transition metal ions,thus speeding up the dissolution process. 展开更多
关键词 spent lithium-ion batteries leaching response surface methodology sulfuric acid citric acid
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Preparation of sodium molybdate from molybdenum concentrate by microwave roasting and alkali leaching
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作者 Fengjuan Zhang Chenhui Liu +2 位作者 Srinivasakannan Chandrasekar Yingwei Li Fuchang Xu 《International Journal of Minerals,Metallurgy and Materials》 SCIE EI CSCD 2024年第1期91-105,共15页
The preparation process of sodium molybdate has the disadvantages of high energy consumption,low thermal efficiency,and high raw material requirement of molybdenum trioxide,in order to realize the green and efficient ... The preparation process of sodium molybdate has the disadvantages of high energy consumption,low thermal efficiency,and high raw material requirement of molybdenum trioxide,in order to realize the green and efficient development of molybdenum concentrate resources,this paper proposes a new process for efficient recovery of molybdenum from molybdenum concentrate and preparation of sodium molybdate by microwave-enhanced roasting and alkali leaching.Thermodynamic analysis indicated the feasibility of oxidation roasting of molybdenum concentrate.The effects of roasting temperature,holding time,and power-to-mass ratio on the oxidation product and leaching product sodium molybdate (Na_(2)MoO_(4)·2H_(2)O) were investigated.Under the optimal process conditions:roasting temperature of 700℃,holding time of 110 min,and power-to-mass ratio of 110 W/g,the molybdenum state of existence was converted from MoS_(2) to Mo O3.The process of preparing sodium molybdate by alkali leaching of molybdenum calcine was investigated,the optimal leaching conditions include a solution concentration of 2.5 mol/L,a liquid-to-solid ratio of 2 mL/g,a leaching temperature of 60℃,and leaching solution termination at pH 8.The optimum conditions result in a leaching rate of sodium molybdate of 96.24%.Meanwhile,the content of sodium molybdate reaches 94.08wt%after leaching and removing impurities.Iron and aluminum impurities can be effectively separated by adjusting the pH of the leaching solution with sodium carbonate solution.This research avoids the shortcomings of the traditional process and utilizes the advantages of microwave metallurgy to prepare high-quality sodium molybdate,which provides a new idea for the highvalue utilization of molybdenum concentrate. 展开更多
关键词 molybdenum metallurgy microwave oxidation roasting removing impurities sodium hydroxide leaching
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Evaluating the fractionation of ion-adsorption rare earths for in-situ leaching and metallogenic mechanism 被引量:4
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作者 Qiuhua Xu Lifeng Yang +5 位作者 Dashan Wang Xiao Hou Yuanyuan Sun Xuezhen Zhou Xinmu Zhou Yongxiu Li 《Journal of Rare Earths》 SCIE EI CAS CSCD 2018年第12期1333-1341,共9页
The fractionation of ion adsorption rare earths(IAREs) along the depth in a shaft of a deposit at Dajishan,Jiangxi, China was comparatively evaluated using the partition values(PVs) and relative fractionation values(R... The fractionation of ion adsorption rare earths(IAREs) along the depth in a shaft of a deposit at Dajishan,Jiangxi, China was comparatively evaluated using the partition values(PVs) and relative fractionation values(RFVs) of the leached rare earths(REs). It is found that both PVs and RFVs can objectively reflect the migration and fractionation of REs, but RE content and abrasion pH could not. However, the RFVs can provide more information to quantitatively evaluating the migration and fractionation characteristics of REs along the selected direction and region than PVs could, which is of significance for designing the optimal procedures of in-situ leaching based on the determined flow direction of injecting solution. It is demonstrated that the migration of Ce, Pr, and Nd along the depth direction is inert, and that of REs post Sm and Y is active. Meanwhile, the migration of La shows region characteristics which is active in the upper and inert in lower region. More interesting, the dependence of RFVs on atomic number of REs displays a tetrad group variation trend. However, the fractionation of REs among clay minerals with different particle sizes is not evident, especially for the clay in the bottom region. These results indicate that the migration and fractionation of REs not only are dominated by the adsorption of their hydrated ions, but also rely on their hydrolysis tendency, which provide information for understanding the metallogenic mechanism of IAREs. 展开更多
关键词 Ion-adsorption rare earth in-situ leaching FRACTIONATION METALLOGENIC
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Comprehensive utilization of complex rubidium ore resources:Mineral dissociation and selective leaching of rubidium and potassium 被引量:2
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作者 Quankuang Zhang Baozhong Ma +2 位作者 Chengyan Wang Yongqiang Chen Wenjuan Zhang 《International Journal of Minerals,Metallurgy and Materials》 SCIE EI CAS CSCD 2023年第5期857-867,共11页
Currently,the process of extracting rubidium from ores has attracted a great deal of attention due to the increasing application of rubidium in high-technology field.A novel process for the comprehensive utilization o... Currently,the process of extracting rubidium from ores has attracted a great deal of attention due to the increasing application of rubidium in high-technology field.A novel process for the comprehensive utilization of rubidium ore resources is proposed in this paper.The process consists mainly of mineral dissociation,selective leaching,and desilication.The results showed that the stable silicon–oxygen tetrahedral structure of the rubidium ore was completely disrupted by thermal activation and the mineral was completely dissociated,which was conducive to subsequent selective leaching.Under the optimal conditions,extractions of 98.67% Rb and 96.23%K were obtained by leaching the rubidium ore.Moreover,the addition of a certain amount of activated Al(OH)_(3) during leaching can effectively inhibit the leaching of silicon.In the meantime,the leach residue was sodalite,which was successfully synthesized to zeolite A by hydrothermal conversion.The proposed process provided a feasible strategy for the green extraction of rubidium and the sustainable utilization of various resources. 展开更多
关键词 RUBIDIUM mineral dissociation selective leaching zeolite A DESILICATION
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An insight on the mechanism of efficient leaching of vanadium from vanadium shale induced by microwave-generated hot spots 被引量:2
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作者 Sheng Li Yimin Zhang +1 位作者 Yizhong Yuan Pengcheng Hu 《International Journal of Minerals,Metallurgy and Materials》 SCIE EI CAS CSCD 2023年第2期293-302,共10页
Microwave heating can rapidly and uniformly raise the temperature and accelerate the reaction rate.In this paper,microwave heating was used to improve the acid leaching,and the mechanism was investigated via microscop... Microwave heating can rapidly and uniformly raise the temperature and accelerate the reaction rate.In this paper,microwave heating was used to improve the acid leaching,and the mechanism was investigated via microscopic morphology analysis and numerical simulation by COMSOL Multiphysics software.The effects of the microwave power,leaching temperature,CaF_(2) dosage,H_(2)SO_(4) concentration,and leaching time on the vanadium recovery were investigated.A vanadium recovery of 80.66%is obtained at a microwave power of 550 W,leaching temperature of 95℃,CaF_(2) dosage of 5wt%,H_(2)SO_(4) concentration of 20vol%,and leaching time of 2.5 h.Compared with conventional leaching technology,the vanadium recovery increases by 6.18%,and the leaching time shortens by 79.17%.More obvious pulverization of shale particles and delamination of mica minerals happen in the microwave-assisted leaching process.Numerical simulation results show that the temperature of vanadium shales increases with an increase in electric field(E-field).The distributions of E-field and temperature among vanadium shale particles are relatively uniform,except for the higher content at the contact position of the particles.The analysis results of scaleup experiments and leaching experiments indicate high-temperature hot spots in the process of microwave-assisted leaching,and the local high temperature destroys the mineral structure and accelerates the reaction rate. 展开更多
关键词 vanadium shale microwave-assisted leaching hot spots numerical simulation
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Occurrence,leaching behavior,and detoxification of heavy metal Cr in coal gasification slag 被引量:1
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作者 Jiangshan Qu Jianbo Zhang +7 位作者 Huiquan Li Shaopeng Li Da Shi Ruiqi Chang Wenfen Wu Ganyu Zhu Chennian Yang Chenye Wang 《Chinese Journal of Chemical Engineering》 SCIE EI CAS CSCD 2023年第6期11-19,共9页
Coal gasification slag(CGS)is a type of solid waste produced during coal gasification,in which heavy metals severely restrict its resource utilization.In this work,the mineral occurrence and distribution of typical he... Coal gasification slag(CGS)is a type of solid waste produced during coal gasification,in which heavy metals severely restrict its resource utilization.In this work,the mineral occurrence and distribution of typical heavy metal Cr in CGS is investigated.The leaching behavior of Cr under different conditions is studied in detail.Acid leaching-selective oxidation-coprecipitation method is proposed based on the characteristics of Cr in CGS.The detoxification of Cr in CGS is realized,and the detoxification mechanism is clarified.Results show that Cr is highly enriched in CGS.The speciation of Cr is mainly residual fraction(74.47%-86.12%),which is combined with amorphous aluminosilicate.Cr^(3+)and Cr^(6+)account for 90.93%-94.82%and 5.18%-9.07%of total Cr,respectively.High acid concentration and high liquid-solid ratio are beneficial to destroy the lattice structure of amorphous aluminosilicate,thus improving the leaching efficiency of Cr,which can reach 97.93%under the optimal conditions.Acid leaching-selective oxidation-coprecipitation method can realize the detoxification of Cr in CGS.Under the optimal conditions,the removal rates of Fe^(3+)and Cr^(3+)in the leaching solution are 80.99%-84.79%and 70.58%-71.69%,respectively,while the loss rate of Al^(3+)is only 1.10%-3.35%.Detoxification slag exists in the form of Fe-Cr coprecipitation(Fe_(1-x)Cr_xOOH),which can be used for smelting.The detoxification acid leaching solution can be used to prepare inorganic polymer composite coagulant poly-aluminum chloride(PAC).This study can provide theoretical and data guidance for detoxification of heavy metal Cr in CGS and achieve resource utilization of coal gasification solid waste. 展开更多
关键词 Coal gasification slag Heavy metal DISTRIBUTIONS leaching DETOXIFICATION PRECIPITATION
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基于遗传算法和蚁群算法的LEACH改进协议
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作者 徐巍 钟宇超 余成成 《无线电工程》 2024年第1期199-205,共7页
针对无线传感器网络低功耗自适应集簇分层(Low Energy Adaptive Clustering Hierarchy,LEACH)路由协议因能耗不均衡导致节点过早死亡的问题,提出了一种基于遗传算法和蚁群算法改进的LEACH路由协议。在分簇阶段,通过遗传算法选举合理的... 针对无线传感器网络低功耗自适应集簇分层(Low Energy Adaptive Clustering Hierarchy,LEACH)路由协议因能耗不均衡导致节点过早死亡的问题,提出了一种基于遗传算法和蚁群算法改进的LEACH路由协议。在分簇阶段,通过遗传算法选举合理的簇头节点并根据节点的分布划分簇群;在数据传输阶段,通过蚁群算法使簇头节点尽可能选择能量充足且距离较短的路径进行数据传输。仿真结果表明,与传统的分簇路由协议LEACH和LEACH-C相比,改进算法可以使网络的能量消耗更加均衡,并延长网络的生命周期。 展开更多
关键词 低功耗自适应集簇分层协议 节点能耗 分簇 遗传算法 蚁群算法
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Recovery of Li_(2)CO_(3)and FePO_(4)from spent LiFePO_(4)by coupling technics of isomorphic substitution leaching and solvent extraction 被引量:1
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作者 Yong Niu Xiaowu Peng +4 位作者 Jinfeng Li Yuze Zhang Fugen Song Dong Shi Lijuan Li 《Chinese Journal of Chemical Engineering》 SCIE EI CAS CSCD 2023年第2期306-315,共10页
Efficient and low-cost recycling of spent lithium iron phosphate(LiFePO_(4),LFP)batteries has become an inevitable trend.In this study,an integrated closed-loop recycling strategy including isomorphic substitution lea... Efficient and low-cost recycling of spent lithium iron phosphate(LiFePO_(4),LFP)batteries has become an inevitable trend.In this study,an integrated closed-loop recycling strategy including isomorphic substitution leaching and solvent extraction process for spent LFP was proposed.An inexpensive FeCl_(3)was used as leaching agent to directly substitute Fe^(2+)from LFP.99%of Li can be rapidly leached in just 30 min,accompanied by 98%of FePO_(4)precipitated in lixivium.The tri-n-butyl phosphate(TBP)-sulfonated kerosene(SK)system was applied to extract Li from lixivium through a twelve-stage countercurrent process containing synchronous extraction and stepwise stripping of Li^(+)and Fe^(3+).80.81%of Li can be selectively enriched in stripping liquor containing 3.059 mol·L^(-1)of Li^(+)under optimal conditions.And the Fe stripping liquor was recovered for LFP re-leaching,of which,Fe^(2+)was oxidized to Fe^(3+)by appropriate H_(2)O_(2).Raffinate and lixivium were concentrated and entered into extraction process to accomplished closeloop recycling process.Overall,the results suggest that more than 99%of Li was recovered.FeCl_(3)holding in solution was directly regenerated without any pollutant emission.The sustainable mothed would be an alternative candidate for total element recycling of spent LFP batteries with industrial potential. 展开更多
关键词 Spent LiFePO_(4) leaching lithium Extraction STRIPPING RECOVERY
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Reclamation of CO_(2) sodium silicate used sands by steam leaching
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作者 Ji-jun Lu Wei He +1 位作者 Lei Yang Hua-fang Wang 《China Foundry》 SCIE EI CAS CSCD 2023年第6期537-544,共8页
The bond film on the surface of the CO_(2) sodium silicate used sands is not easy to decompose,therefore,it is difficult to reclaim used sands.A new reclamation method of CO_(2) sodium silicate used sands was develope... The bond film on the surface of the CO_(2) sodium silicate used sands is not easy to decompose,therefore,it is difficult to reclaim used sands.A new reclamation method of CO_(2) sodium silicate used sands was developed by steam leaching,which can reduce the water consumption of reclamation and improve the removal effect of sodium silicate bond film.Firstly,the leaching effect of the sodium silicate sands after 20/200/400/600/800/1,000°C heat preservation treatment was simulated.Furthermore,the influence of the leaching time on the removal effect of the sodium silicate bond film was studied.Finally,the casting properties of the reclaimed sands after the leaching reclamation treatment were tested.The results show for simulated used sands after 30 min of steam leaching,the removal ratio of the alkali exceeds 84.1%,the removal ratio of silicate is 86.2%,and the removal ratio of carbonate is 93.6%.The removal rate of alkali,silicate and carbonate is relatively low in the leaching time of 30-50 min.Considering the reclamation effect and cost,the leaching time is controlled in 30 min.Water consumption is only 60%of the mass of used sands for 30 min steam leaching,while it is 200%for wet reclamation.Morphological analysis shows that most of the hazardous substances in the used sands are removed in 30 min steam leaching,and the reclaimed sands surface after steam leaching in 50 min is as smooth as new sands.After 30 min of steam leaching,the alkali removal effect of the factory used sands can reach 81.5%,the water consumption by the steam leaching reclamation is 58%of the mass of the used sand,which is similar to the result of simulated used sands.The performance of reclaimed sands obtained after 30 min steam leaching is better than that of new sands when the amount of sodium silicate added is 6%of the mass of the reclaimed sands and the CO_(2) blowing time is 15 s:the 24 h ultimate compressive strength of reclaimed sands is 5.6 MPa(equated with new sands),and the collapsibility compressive strength is 5.2 MPa,which is lower than the collapsibility compressive strength of new sands(7.7 MPa).This indicates that the reclamation of CO_(2) sodium silicate used sands by steam leaching is a feasible method. 展开更多
关键词 sodium silicate sands steam leaching simulated temperature RECLAMATION
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Fabrication of Porous Polycaprolactone/Carboxymethylcellulose Scaffolds by using Salt Leaching Technique
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作者 NOPPADOL Sriputtha FASAI Wiwatwongwana NATTAWIT Promma 《Journal of Wuhan University of Technology(Materials Science)》 SCIE EI CAS CSCD 2023年第2期455-459,共5页
The purpose of this work was to fabricate three-dimensional porous scaffolds by using the salt leaching technique.This technique is simple and it does not need the pressure or dislike expensive equipment.The study sel... The purpose of this work was to fabricate three-dimensional porous scaffolds by using the salt leaching technique.This technique is simple and it does not need the pressure or dislike expensive equipment.The study selected polycaprolactone blended with carboxymethylcellulose that is the additive.The ratios of them were derived from mixture design in Minitab program that was 98/2(P1),93.5/6.5(P2),89/11(P3),84.5/15.5(P4),and 80/20(P5),respectively.The scanning electron microscopy(SEM)was applied to assess the physical properties and the pore size dimension of the scaffold from SEM micrographs.The results of SEM present the scaffolds happened interconnected porous structures that are found in all of the P1-P5 samples.The pore size dimension of all sample scaffolds is in the range of 264.11-348.28μm.Whereas the largest and the smallest of pore size are the sample of P3 and P2,respectively,while the porosity ranges from 98.06%-98.88%that the sample of P5 is the greatest and the sample of P4 is the slightly lowest.In conclusion,the blended PCL/CMC scaffolds P1-P5 were formed by salt leaching technique suitable to use in tissue engineering application.However,the amount of CMC blended with PCL should be reasonable in order to adjust the hydrophilic of the scaffold. 展开更多
关键词 polycaprolactone(PCL) carboxymethylcellulose(CMC) salt leaching tissue engineering scaffolds
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Correlation Evaluation of Ion Adsorption-Based Rare Earth Leaching Performance Based on Zeta Potential Drop Leaching
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作者 Xunhe Li Zhengxiong Ding +3 位作者 Sengbiao Zeng Yanzhu Liu Dongping Li Yongxiu Li 《Journal of Materials Science and Chemical Engineering》 2023年第11期28-47,共20页
Rare earth elements are indispensable raw materials for advanced aero-engines, special optical materials, and high-performance electronic products. With the development of the social economy, the global demand for rar... Rare earth elements are indispensable raw materials for advanced aero-engines, special optical materials, and high-performance electronic products. With the development of the social economy, the global demand for rare earth resources is increasing, and rare earths have become a key metal for the development of new industries and frontier technologies that are highly valued both at home and abroad. Ion-adsorbed rare earth ores are an important source of rare earths, so the efficient green leaching of ion-adsorbed rare earths is important. Researchers found that the selection of an efficient green leaching agent for ion-adsorbed rare earths is based on the zeta potential of tailing clay minerals in addition to leaching efficiency, and both zeta potential and leaching ion concentration are related to mineral acidity and alkalinity, and the pH of tailing water suspension is a direct indicator of environmental water quality requirements. Therefore, the efficiency of the leaching process is closely integrated with the environmental evaluation, and the characteristics and correlation of the changes in zeta potential, pH, conductivity and pollutant concentration of the pulp of clay mineral content during the leaching process of ore leaching and tailings aqueous electrolyte solution leaching are studied by evaluating the leaching system, and a set of correlation leaching efficiency and environmental impact evaluation method is established based on the results of the above analysis, which is of scientific development of ion adsorption rare earth resources. It has important theoretical significance and practical application value. 展开更多
关键词 Ion Adsorption Rare Earth Ph Value Zeta Potential the leaching Efficiency
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Assessment of the Greenhouse Gas Footprint and Environmental Impact of CO_(2)and O_(2)in situ Uranium Leaching
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作者 YANG Yun ZUO Jinsong +5 位作者 QIU Wenjie WU Jichun QUE Weimin ZHOU Genmao LIU Zhengbang WU Jianfeng 《Acta Geologica Sinica(English Edition)》 SCIE CAS CSCD 2023年第3期986-994,共9页
Under the new development philosophy of carbon peaking and carbon neutrality,CO_(2)and O_(2)in situ leaching(ISL)has been identified as a promising technique for uranium mining in China,not only because it solves carb... Under the new development philosophy of carbon peaking and carbon neutrality,CO_(2)and O_(2)in situ leaching(ISL)has been identified as a promising technique for uranium mining in China,not only because it solves carbon dioxide utilization and sequestration,but it also alleviates the environmental burden.However,significant challenges exist in assessment of CO_(2)footprint and water-rock interactions,due to complex geochemical processes.Herein this study conducts a three-dimensional,multicomponent reactive transport model(RTM)of a field-scale CO_(2)and O_(2)ISL process at a typical sandstone-hosted uranium deposit in Songliao Basin,China.Numerical simulations are performed to provide new insight into quantitative interpretation of the greenhouse gas(CO_(2))footprint and environmental impact(SO_(4)^(2–))of the CO_(2)and O_(2)ISL,considering the potential chemical reaction network for uranium recovery at the field scale.RTM results demonstrate that the fate of the CO_(2)could be summarized as injected CO_(2)dissolution,dissolved CO_(2)mineralization and storage of CO_(2)as a gas phase during the CO_(2)and O_(2)ISL process.Furthermore,compared to acid ISL,CO_(2)and O_(2)ISL has a potentially smaller environmental footprint,with 20%of SO_(4)^(2–)concentration in the aquifer.The findings improve our fundamental understanding of carbon utilization in a long-term CO_(2)and O_(2)ISL system and provide important environmental implications when considering complex geochemical processes. 展开更多
关键词 in situ leaching of uranium reactive transport modeling geochemical process CO_(2)utilization
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Leaching Fraction (LF) of Irrigation Water for Saline Soils Using Machine Learning
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作者 Rab Nawaz Bashir Imran Sarwar Bajwa +4 位作者 Muhammad Waseem Iqbal Muhammad Usman Ashraf Ahmed Mohammed Alghamdi Adel ABahaddad Khalid Ali Almarhabi 《Intelligent Automation & Soft Computing》 SCIE 2023年第5期1915-1930,共16页
Soil salinity is a serious land degradation issue in agriculture.It is a major threat to agriculture productivity.Extra irrigation water is applied to leach down the salts from the root zone of the plants in the form ... Soil salinity is a serious land degradation issue in agriculture.It is a major threat to agriculture productivity.Extra irrigation water is applied to leach down the salts from the root zone of the plants in the form of a Leaching fraction(LF)of irrigation water.For the leaching process to be effective,the LF of irriga-tion water needs to be adjusted according to the environmental conditions and soil salinity level in the form of Evapotranspiration(ET)rate.The relationship between environmental conditions and ET rate is hard to be defined by a linear relationship and data-driven Machine learning(ML)based decisions are required to determine the calibrated Evapotranspiration(ETc)rate.ML-assisted ETc is pro-posed to adjust the LF according to the ETc and soil salinity level.A regression model is proposed to determine the ETc rate according to the prevailing tempera-ture,humidity,and sunshine,which would be used to determine the smart LF according to the ETc and soil salinity level.The proposed model is trained and tested against the Blaney Criddle method of Reference evapotranspiration(ETo)determination.The validation of the model from the test dataset reveals the accu-racy of the ML model in terms of Root mean squared errors(RMSE)are 0.41,Mean absolute errors(MAE)are 0.34,and Mean squared errors(MSE)are 0.28 mm day-1.The applications of the proposed solution in a real-time environ-ment show that the LF by the proposed solution is more effective in reducing the soil salinity as compared to the traditional process of leaching. 展开更多
关键词 leaching fraction saline soil EVAPOTRANSPIRATION machine learning calibrated evapotranspiration artificial intelligence blaney criddle method
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