The natural gas hydrate has been regarded as an important future green energy.Significant progress on the hydrate exploitation has been made,but some challenges are still remaining.In order to enhance the hydrate expl...The natural gas hydrate has been regarded as an important future green energy.Significant progress on the hydrate exploitation has been made,but some challenges are still remaining.In order to enhance the hydrate exploitation efficiency,a significant understanding of the effective thermal conductivity(ETC)of the hydrate-bearing sediment has become essential,since it directly controls the heat and mass transfer behaviors,and thereby determines the stability of hydrate reservoir and production rate.In this study,the effective thermal conductivities of various hydrate-bearing sediments were in-situ measured and studied.The impacts of temperature,particle size and type of sediment were investigated.The effective thermal conductivities of the quartz sand sediments before and after hydrate formation were in-situ measured.The results show the weak negative correlation of effective thermal conductivity of the quartz sand sediment on the temperature before and after the hydrate formation.The effective thermal conductivity of the hydrate-bearing sediment decreases with the increase of particle size of the sediment.The dominant effect of the type of porous medium on the characteristics of the effective thermal conductivity of hydrate-bearing sediment was highlighted.The results indicate that both the effective thermal conductivities of hydrate-bearing quartz sand sediment and hydrate-bearing silicon carbide sediment are weakly negatively correlated with temperature,but the effective thermal conductivity of hydrate-bearing clay sediment is weakly positively dependent on the temperature.In addition,the values of the effective thermal conductivities of various hydrate-bearing sediments are in the order of hydrate-bearing silicon carbide sediment>hydrate-bearing quartz sand sediment>hydrate-bearing clay sediment.These findings could suggest that the intrinsic thermal conductivity of porous medium could control the characteristics of effective thermal conductivity of hydrate-bearing sediment.展开更多
In order to explore the thermal conductivity of the natural poly-mineral rock,numerical tests of rock models with randomly-distributed components were conducted and compared with each other.Elaborately designed Monte ...In order to explore the thermal conductivity of the natural poly-mineral rock,numerical tests of rock models with randomly-distributed components were conducted and compared with each other.Elaborately designed Monte Carlo method was adopted to ingratiate the requirement of the random characteristics of grain size and the grains＇spatial distribution.This requirement was fulfilled by clustering the randomly generated unstructured tetrahedral elements in full three dimensions.Natural rocks are consisted of randomly distributed crystal particles or intergranular minerals.Our primary results verify that the thermal conductivity of the rock is strongly sensitive to the ingredients＇ volume fraction and their spatial distribution.Furthermore,we proved that,in order to reduce the measurement error to a reasonable range,the numerical specimen must be large enough or include sufficient number of mineral particles.Our numerical test results are in accordance with a variety of empirical formulas which are currently employed in petrology.展开更多
An improved test rig providing both the heat and cold source was used to perform thermal response test(TRT), and the line source model was used for data analysis. The principle of determining the temperature differenc...An improved test rig providing both the heat and cold source was used to perform thermal response test(TRT), and the line source model was used for data analysis. The principle of determining the temperature difference between the inlet and outlet of test well can keep the heating or cooling rate constant, along with a reduced size of test rig. Among the influencial factors of the line source model, the temperature difference was determined as the most important, which agreed with the test results. When the gravel was taken as the backfill material, the soil thermal conductivities of heating and cooling at the test place were 1.883 W/(m·K) and 1.754 W/(m·K), respectively, and the deviation of TRT between heating and cooling soil was 6.8%. In the case of fine sand, the thermal conductivities of heating and cooling were 1.541 W/(m·K) and 1.486 W/(m·K), respectively, and the corresponding deviation was 6%. It was also concluded that different velocities of water had less influence on TRT than the temperature difference.展开更多
A series of stearates with different rare-earth ion were investigated as thermal stabilizers for rigid PVC at 180 ℃ in air. Their stabilizing efficiency was based on measuring the rate of dehydrochlorination. The res...A series of stearates with different rare-earth ion were investigated as thermal stabilizers for rigid PVC at 180 ℃ in air. Their stabilizing efficiency was based on measuring the rate of dehydrochlorination. The resulted revealed the higher stabilizing efficiency of the investigated rare-earth stearates as thermal stabilizers for rigid PVC compared with the thermal stabilizers for industry: calcium stearate, zinc stearate, butyl stannum mercaptide, phosphite esters, β-diketone and epoxidized sunflower oil. This was well illustrated by longer incubation period (T_S) values and lower rate of dehydrochlorination. The stable efficiency was affected by the nature of rare-earth element's individual electronic shell. The mechanism for the stabilizing effect of rare-earth stearates was proposed. The result was experimentally proved based on IR spectrum.展开更多
Thermal performance was the most important factor in the development of borehole heat exchanger utilizing geothermal energy.The thermal performance was affected by many different design parameters,such as configuratio...Thermal performance was the most important factor in the development of borehole heat exchanger utilizing geothermal energy.The thermal performance was affected by many different design parameters,such as configuration type and borehole size of geothermal heat exchanger.These eventually determined the operation and cost efficiency of the geothermal heat exchanger system.The main purpose of this work was to assess the thermal performance of geothermal heat exchanger with variation of borehole sizes and numbers of U-tubes inside a borehole.For this,a thermal response test rig was established with line-source theory.The thermal response test was performed with in-line variable input heat source.Effective thermal conductivity and thermal resistance were obtained from the measured data.From the measurement,the effective thermal conductivity is found to have similar values for twopair type(4 U-tubes)and three-pair type(6 U-tubes)borehole heat exchanger systems indicating similar heat transfer ability.Meanwhile,the thermal resistance shows lower value for the three-pair type compared to the two-pair type.Measured data based resistance have lower value compared to computed result from design programs.Overall comparison finds better thermal performance for the three-pair type,however,fluctuating temperature variation indicates complex flow behavior inside the borehole and requires further study on flow characteristics.展开更多
Since first establishing thermal measurement techniques for micrometer-scale wires,various methods have been devised and improved upon.However,the uncertainty of different measurements on the same sample has not yet b...Since first establishing thermal measurement techniques for micrometer-scale wires,various methods have been devised and improved upon.However,the uncertainty of different measurements on the same sample has not yet been discussed.In this work,a round robin test was performed to compare the thermal conductivity and thermal diffusivity measurement methods for a fine metal wire.The tested material was a pure gold wire,with a diameter of 30μm.The wire was cut into certain lengths and distributed to four institutions using five different measurement methods:the direct current(DC)self-heating method,the DC heating T-type method,the 3ωmethod for thermal conductivity,the scanning laser heating alternating current(AC)method,and the spot periodic heating radiation thermometry method for thermal diffusivity.After completing the measurements,the reported thermal conductivity and thermal diffusivity at room temperature,i.e.,317 W·m^(-1)·K^(-1)and 128×10^(-6)m^(2)·s^(-1),respectively,were adopted as references for comparison with the measurement results.The advantages and disadvantages of each method are described in terms of the effect of electrical and thermal junctions fabricated on a wire,such as an electrode,a thermocouple,and a heat bath.The knowledge obtained from the tested methods will be useful for selecting and designing a measurement technique for various wire-like materials.展开更多
Thermal performance is the most important factor in the development of a borehole heat exchanger utilizing geothermal energy.The thermal performance is affected by many different design parameters and different operat...Thermal performance is the most important factor in the development of a borehole heat exchanger utilizing geothermal energy.The thermal performance is affected by many different design parameters and different operating conditions such as bleeding.This eventually determines the operation and cost efficiency of the borehole heat exchanger system.The thermal performance of an open standing column well (SCW) type geothermal heat exchanger was assessed under the influence of bleeding.For this,a thermal response test rig was established with line-source theory.The test rig also had a bleeding function by releasing fluid while taking additional underground water through the heat exchanger.The thermal response test was performed with an additional constant input heat source.Effective thermal conductivity and thermal resistance were obtained from the measured data.From the measurement,the effective thermal conductivity is found to have 1.47 times higher value when bleeding is applied.The thermal resistance also increases by 1.58 times compared to a non-bleeding case.This trend indicates enhanced heat transfer in the SCW type heat exchanger with a bleeding function.Bleeding,therefore,could be an effective method of achieving a high heat transfer rate in the SCW type heat exchanger with sufficient underground water supply.展开更多
基金This work was supported by the National Natural Science Foundation of China(U19B2005,21808238,U20B6005,22127812)the National Key Research and Development Program of China(2021YFC2800902).
文摘The natural gas hydrate has been regarded as an important future green energy.Significant progress on the hydrate exploitation has been made,but some challenges are still remaining.In order to enhance the hydrate exploitation efficiency,a significant understanding of the effective thermal conductivity(ETC)of the hydrate-bearing sediment has become essential,since it directly controls the heat and mass transfer behaviors,and thereby determines the stability of hydrate reservoir and production rate.In this study,the effective thermal conductivities of various hydrate-bearing sediments were in-situ measured and studied.The impacts of temperature,particle size and type of sediment were investigated.The effective thermal conductivities of the quartz sand sediments before and after hydrate formation were in-situ measured.The results show the weak negative correlation of effective thermal conductivity of the quartz sand sediment on the temperature before and after the hydrate formation.The effective thermal conductivity of the hydrate-bearing sediment decreases with the increase of particle size of the sediment.The dominant effect of the type of porous medium on the characteristics of the effective thermal conductivity of hydrate-bearing sediment was highlighted.The results indicate that both the effective thermal conductivities of hydrate-bearing quartz sand sediment and hydrate-bearing silicon carbide sediment are weakly negatively correlated with temperature,but the effective thermal conductivity of hydrate-bearing clay sediment is weakly positively dependent on the temperature.In addition,the values of the effective thermal conductivities of various hydrate-bearing sediments are in the order of hydrate-bearing silicon carbide sediment>hydrate-bearing quartz sand sediment>hydrate-bearing clay sediment.These findings could suggest that the intrinsic thermal conductivity of porous medium could control the characteristics of effective thermal conductivity of hydrate-bearing sediment.
基金supported by the National Science and Technology Project (No. Si-noProbe-07)National Basic Research Program of China (No. 2008cb425701)+1 种基金National Natural Science Foundation of China (No. 40774049)Institute of Earthquake Science,China Earthquake Administration,who provided us with the support from the collaborative project named as "Pre-study of several issues of testing ground for numerical forecast earthquakes in North China"
文摘In order to explore the thermal conductivity of the natural poly-mineral rock,numerical tests of rock models with randomly-distributed components were conducted and compared with each other.Elaborately designed Monte Carlo method was adopted to ingratiate the requirement of the random characteristics of grain size and the grains＇spatial distribution.This requirement was fulfilled by clustering the randomly generated unstructured tetrahedral elements in full three dimensions.Natural rocks are consisted of randomly distributed crystal particles or intergranular minerals.Our primary results verify that the thermal conductivity of the rock is strongly sensitive to the ingredients＇ volume fraction and their spatial distribution.Furthermore,we proved that,in order to reduce the measurement error to a reasonable range,the numerical specimen must be large enough or include sufficient number of mineral particles.Our numerical test results are in accordance with a variety of empirical formulas which are currently employed in petrology.
基金Supported by the National Natural Science Foundation of China(No.41272263)
文摘An improved test rig providing both the heat and cold source was used to perform thermal response test(TRT), and the line source model was used for data analysis. The principle of determining the temperature difference between the inlet and outlet of test well can keep the heating or cooling rate constant, along with a reduced size of test rig. Among the influencial factors of the line source model, the temperature difference was determined as the most important, which agreed with the test results. When the gravel was taken as the backfill material, the soil thermal conductivities of heating and cooling at the test place were 1.883 W/(m·K) and 1.754 W/(m·K), respectively, and the deviation of TRT between heating and cooling soil was 6.8%. In the case of fine sand, the thermal conductivities of heating and cooling were 1.541 W/(m·K) and 1.486 W/(m·K), respectively, and the corresponding deviation was 6%. It was also concluded that different velocities of water had less influence on TRT than the temperature difference.
文摘A series of stearates with different rare-earth ion were investigated as thermal stabilizers for rigid PVC at 180 ℃ in air. Their stabilizing efficiency was based on measuring the rate of dehydrochlorination. The resulted revealed the higher stabilizing efficiency of the investigated rare-earth stearates as thermal stabilizers for rigid PVC compared with the thermal stabilizers for industry: calcium stearate, zinc stearate, butyl stannum mercaptide, phosphite esters, β-diketone and epoxidized sunflower oil. This was well illustrated by longer incubation period (T_S) values and lower rate of dehydrochlorination. The stable efficiency was affected by the nature of rare-earth element's individual electronic shell. The mechanism for the stabilizing effect of rare-earth stearates was proposed. The result was experimentally proved based on IR spectrum.
基金Project financially supported by the Second Stage of Brain Korea 21 Projects and Changwon National University,Korea
文摘Thermal performance was the most important factor in the development of borehole heat exchanger utilizing geothermal energy.The thermal performance was affected by many different design parameters,such as configuration type and borehole size of geothermal heat exchanger.These eventually determined the operation and cost efficiency of the geothermal heat exchanger system.The main purpose of this work was to assess the thermal performance of geothermal heat exchanger with variation of borehole sizes and numbers of U-tubes inside a borehole.For this,a thermal response test rig was established with line-source theory.The thermal response test was performed with in-line variable input heat source.Effective thermal conductivity and thermal resistance were obtained from the measured data.From the measurement,the effective thermal conductivity is found to have similar values for twopair type(4 U-tubes)and three-pair type(6 U-tubes)borehole heat exchanger systems indicating similar heat transfer ability.Meanwhile,the thermal resistance shows lower value for the three-pair type compared to the two-pair type.Measured data based resistance have lower value compared to computed result from design programs.Overall comparison finds better thermal performance for the three-pair type,however,fluctuating temperature variation indicates complex flow behavior inside the borehole and requires further study on flow characteristics.
文摘Since first establishing thermal measurement techniques for micrometer-scale wires,various methods have been devised and improved upon.However,the uncertainty of different measurements on the same sample has not yet been discussed.In this work,a round robin test was performed to compare the thermal conductivity and thermal diffusivity measurement methods for a fine metal wire.The tested material was a pure gold wire,with a diameter of 30μm.The wire was cut into certain lengths and distributed to four institutions using five different measurement methods:the direct current(DC)self-heating method,the DC heating T-type method,the 3ωmethod for thermal conductivity,the scanning laser heating alternating current(AC)method,and the spot periodic heating radiation thermometry method for thermal diffusivity.After completing the measurements,the reported thermal conductivity and thermal diffusivity at room temperature,i.e.,317 W·m^(-1)·K^(-1)and 128×10^(-6)m^(2)·s^(-1),respectively,were adopted as references for comparison with the measurement results.The advantages and disadvantages of each method are described in terms of the effect of electrical and thermal junctions fabricated on a wire,such as an electrode,a thermocouple,and a heat bath.The knowledge obtained from the tested methods will be useful for selecting and designing a measurement technique for various wire-like materials.
基金Project supported by the Second Stage of Brain Korea 21 Projects and Changwon National University in2011-2012
文摘Thermal performance is the most important factor in the development of a borehole heat exchanger utilizing geothermal energy.The thermal performance is affected by many different design parameters and different operating conditions such as bleeding.This eventually determines the operation and cost efficiency of the borehole heat exchanger system.The thermal performance of an open standing column well (SCW) type geothermal heat exchanger was assessed under the influence of bleeding.For this,a thermal response test rig was established with line-source theory.The test rig also had a bleeding function by releasing fluid while taking additional underground water through the heat exchanger.The thermal response test was performed with an additional constant input heat source.Effective thermal conductivity and thermal resistance were obtained from the measured data.From the measurement,the effective thermal conductivity is found to have 1.47 times higher value when bleeding is applied.The thermal resistance also increases by 1.58 times compared to a non-bleeding case.This trend indicates enhanced heat transfer in the SCW type heat exchanger with a bleeding function.Bleeding,therefore,could be an effective method of achieving a high heat transfer rate in the SCW type heat exchanger with sufficient underground water supply.
