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Decoupled water electrolysis:Flexible strategy for pure hydrogen production with small voltage inputs
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作者 Kexin Zhou Jiahui Huang +3 位作者 Daili Xiang Aijiao Deng Jialei Du Hong Liu 《Journal of Energy Chemistry》 SCIE EI CAS CSCD 2024年第7期340-356,共17页
Hydrogen gas is widely regarded as an ideal green energy carrier and a potential alternative to fossil fuels for coping with the aggravating energy crisis and environmental pollution.Currently,the vast majority of the... Hydrogen gas is widely regarded as an ideal green energy carrier and a potential alternative to fossil fuels for coping with the aggravating energy crisis and environmental pollution.Currently,the vast majority of the world's hydrogen is produced by reforming fossil fuels;however,this hydrogen-making technology is not sustainable or environmentally friendly because ofits high energy consumption and large carbon emissions.Renewables-driven water splitting(2H_(2)0-2H_(2)+0_(2))becomes an extensively studied scheme for sustain-able hydrogen production.Conventional water electrolysis requires an input voltage higher than 1.23 V and forms a gas mixture of H_(2)/O_(2),which results in high electricity consumption,potential safety hazards,and harmful reactive oxygen species.By virtue of the auxiliary redox mediators(RMs)as the robust H^(+)/e^(-)reservoir,decoupled electrolysis splits water at a much lower potential and evolves O_(2)(H_(2)O+RMS_(ox)-O_(2)+H-RMS_(red))and H_(2)(H-RMS_(red)-H_(2)+RMS_(ox))at separate times,rates,and spaces,thus pro-ducing the puretarget hydrogen gas safely.Decoupled electrolysis has accelerated the development ofwater electrolysis technology for H_(2) production.However,itis still lack of a comprehensive and in-depth review in this field based on different types of RMs.This review highlights the basic principles and critical progress of this emerging water electrolysis mode over the past decade.Several representative examples are then dis-played in detail according to the differences in the RMs.The rational choice and design of RMs have also been emphasized.Subsequently,novel applications of decoupled water splitting are briefly discussed,including the manufacture of valuable chemicals,Cl_(2) production,pollutant degradation,and other half-reactions in artificial photosynthesis.Finally,thekey characteristics and disadvantages of each type of mediator are sum-marized in depth.In addition,we present an outlook for future directions in decoupled water splitting.Thus,the flexibility in the design of mediators provides huge space for improving this electrochemical technology.@2024 Science Press and Dalian Institute of Chemical Physics,Chinese Academy of Sciences.Published by ELSEVIER B.V.and Science Press.All rights reserved. 展开更多
关键词 Hydrogen production Conventional water splitting Decoupled water splitting Redox mediators Biomimetics
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Classification and technical target of water electrolysis for hydrogen production
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作者 Kahyun Ham Sooan Bae Jaeyoung Lee 《Journal of Energy Chemistry》 SCIE EI CAS CSCD 2024年第8期554-576,I0012,共24页
Continuous efforts are underway to reduce carbon emissions worldwide in response to global climate change.Water electrolysis technology,in conjunction with renewable energy,is considered the most feasible hydrogen pro... Continuous efforts are underway to reduce carbon emissions worldwide in response to global climate change.Water electrolysis technology,in conjunction with renewable energy,is considered the most feasible hydrogen production technology based on the viable possibility of large-scale hydrogen production and the zero-carbon-emission nature of the process.However,for hydrogen produced via water electrolysis systems to be utilized in various fields in practice,the unit cost of hydrogen production must be reduced to$1/kg H_(2).To achieve this unit cost,technical targets for water electrolysis have been suggested regarding components in the system.In this paper,the types of water electrolysis systems and the limitations of water electrolysis system components are explained.We suggest guideline with recent trend for achieving this technical target and insights for the potential utilization of water electrolysis technology. 展开更多
关键词 water electrolysis Hydrogen production Technical target ELECTROCHEMISTRY
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Gas-Water Production of a Continental Tight-Sandstone Gas Reservoir under Different Fracturing Conditions
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作者 Yan Liu Tianli Sun +1 位作者 Bencheng Wang Yan Feng 《Fluid Dynamics & Materials Processing》 EI 2024年第6期1165-1180,共16页
A numerical model of hydraulic fracture propagation is introduced for a representative reservoir(Yuanba continental tight sandstone gas reservoir in Northeast Sichuan).Different parameters are considered,i.e.,the inte... A numerical model of hydraulic fracture propagation is introduced for a representative reservoir(Yuanba continental tight sandstone gas reservoir in Northeast Sichuan).Different parameters are considered,i.e.,the interlayer stress difference,the fracturing discharge rate and the fracturing fluid viscosity.The results show that these factors affect the gas and water production by influencing the fracture size.The interlayer stress difference can effectively control the fracture height.The greater the stress difference,the smaller the dimensionless reconstruction volume of the reservoir,while the flowback rate and gas production are lower.A large displacement fracturing construction increases the fracture-forming efficiency and expands the fracture size.The larger the displacement of fracturing construction,the larger the dimensionless reconstruction volume of the reservoir,and the higher the fracture-forming efficiency of fracturing fluid,the flowback rate,and the gas production.Low viscosity fracturing fluid is suitable for long fractures,while high viscosity fracturing fluid is suitable for wide fractures.With an increase in the fracturing fluid viscosity,the dimensionless reconstruction volume and flowback rate of the reservoir display a non-monotonic behavior,however,their changes are relatively small. 展开更多
关键词 Tight sandstone gas reservoir fracture propagation flowback rate gas production law water production law influencing factor
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Pt nanoclusters modified porous g-C_(3)N_(4)nanosheets to significantly enhance hydrogen production by photocatalytic water reforming of methanol
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作者 Yi-Fei Liang Jin-Rong Lu +2 位作者 Shang-Kun Tian Wen-Quan Cui Li Liu 《Chinese Journal of Chemical Engineering》 SCIE EI CAS CSCD 2024年第2期40-50,共11页
For the use of green hydrogen energy,it is crucial to have efficient photocatalytic activity for hydrogen generation by water reforming of methanol under mild conditions.Much attention has been paid to gC_(3)N_(4)as a... For the use of green hydrogen energy,it is crucial to have efficient photocatalytic activity for hydrogen generation by water reforming of methanol under mild conditions.Much attention has been paid to gC_(3)N_(4)as a promising photocatalyst for the generation of hydrogen.To improve the separation of photogenerated charge,porous nanosheet g-C_(3)N_(4)was modified with Pt nanoclusters(Pt/g-C_(3)N_(4))through impregnation and following photo-induced reduction.This catalyst showed excellent photocatalytic activity of water reforming of methanol fo r hydrogen production with a 17.12 mmol·g^(-1)·h^(-1)rate at room temperature,which was 311 times higher than that of the unmodified g-C_(3)N_(4).The strong interactions of Pt-N in Pt/g-C_(3)N_(4)constructed effective electron transfer channels to promote the separation of photogenerated electrons and holes effectively.In addition,in-situ infrared spectroscopy was used to investigate the intermediates of the hydrogen production reaction,which proved that methanol and water eventually turn into H_(2)and CO_(2)via formaldehyde and formate.This study provides insights for understanding the photocatalytic hydrogen production in the water reforming of methanol. 展开更多
关键词 water reforming of methanol Photocatalysis g-C_(3)N_(4) Pt nanoclusters Hydrogen production
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Progress in manipulating spin polarization for solar hydrogen production
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作者 Qian Yang Xin Tong Zhiming Wang 《Materials Reports(Energy)》 EI 2024年第1期43-57,共15页
Photocatalytic and photoelectrochemical water splitting using semiconductor materials are effective approaches for converting solar energy into hydrogen fuel.In the past few years,a series of photocatalysts/photoelect... Photocatalytic and photoelectrochemical water splitting using semiconductor materials are effective approaches for converting solar energy into hydrogen fuel.In the past few years,a series of photocatalysts/photoelectrocatalysts have been developed and optimized to achieve efficient solar hydrogen production.Among various optimization strategies,the regulation of spin polarization can tailor the intrinsic optoelectronic properties for retarding charge recombination and enhancing surface reactions,thus improving the solar-to-hydrogen(STH)efficiency.This review presents recent advances in the regulation of spin polarization to enhance spin polarized-dependent solar hydrogen evolution activity.Specifically,spin polarization manipulation strategies of several typical photocatalysts/photoelectrocatalysts(e.g.,metallic oxides,metallic sulfides,non-metallic semiconductors,ferroelectric materials,and chiral molecules)are described.In the end,the critical challenges and perspectives of spin polarization regulation towards future solar energy conversion are briefly provided. 展开更多
关键词 Spin polarization Solar energy conversion Photocatalytic hydrogen production Photoelectrochemical water splitting
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Water diversion and agricultural production:Evidence from China 被引量:1
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作者 YANG Rui XU Hang 《Journal of Integrative Agriculture》 SCIE CAS CSCD 2023年第4期1244-1257,共14页
Water diversion can alleviate water shortages caused by the uneven distribution of water resources.China’s Southto-North Water Diversion Project(SNWD)is the largest water diversion project worldwide.Based on the pref... Water diversion can alleviate water shortages caused by the uneven distribution of water resources.China’s Southto-North Water Diversion Project(SNWD)is the largest water diversion project worldwide.Based on the prefecturelevel data of China’s Huang-Huai-Hai Plain from 2000 to 2020,this study employs an empirical strategy of Differencesin-Differences(DID)to analyze the impact of SNWD on agricultural production.The results show that SNWD has significantly increased agricultural production,measured by the agricultural value added.The estimated results of the benchmark model remain robust when the contemporaneous policy is addressed,an alternative outcome is used,subsamples are estimated,and alternative estimation techniques are employed.This study argues that the potential impact mechanism may be that SNWD significantly increases the acreage for cash crops but reduces that for grain crops.Heterogeneity analysis shows that in prefectures with high temperature or land potential,SNWD’s impact on agricultural value added is relatively low.In contrast,in areas with prolonged sunshine or high slopes,SNWD’s impact on agricultural value added is relatively large.Given the low added value of grain crops,the government should consider strengthening food security by subsidizing water supply to sustain grain production. 展开更多
关键词 South-to-North water Diversion Project agricultural production Differences-in-Differences China
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Sand Production Prediction and Safe Differential Pressure Determination in a Deepwater Gas Field
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作者 Hao Qiu Yi Wu +5 位作者 Min Wen Xuesong Xing Zening Hou Nan Ma Zizhen Zhang Rui Zhang 《Fluid Dynamics & Materials Processing》 EI 2023年第3期579-592,共14页
Sand production is a critical issue during the development of offshore oil and gas fields.Certain gas fields(e.g.the AB gas field)have high porosity and high permeability,and with water at the bottom of the reservoir,... Sand production is a critical issue during the development of offshore oil and gas fields.Certain gas fields(e.g.the AB gas field)have high porosity and high permeability,and with water at the bottom of the reservoir,the risk of sand production greatly increases at high differential pressures.Based on reservoir properties,geological conditions,production requirements,and well logging data,in this study an ultrasonic time difference method,a B index method,and a S index method are used together with a model of rock mass failure(accounting for water influx and pressure depletion)to qualitatively predict sand production.The results show that considered sample gas field has an overall high risk of sand production.The critical differential pressure(CDP)without water influx is in the range of 1.40 to 2.35 MPa,the CDP after water influx is from 0.60 to 1.41MPa.The CDP under pressure depletion is in the range of 1.20 to 1.92 MPa.The differential pressure charts of sand production are plotted,and the safe differential pressure windows with or without water influx are obtained.The model calculation results and the experimental results are consistent with the field production data,which indicates that the implemented prediction method could be taken as a reference for sand production prediction in similar deep water gas fields. 展开更多
关键词 Sand production differential pressure water influx pressure depletion
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Effects of the Produced Water from a Sour Oilfield in South Kuwait on the Production Tubing
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作者 Feras Al Salem Vijo Poulose +3 位作者 Kazuyuki Kawamura Arata Nakamura Hakim Saibi Thies Thiemann 《Journal of Water Resource and Protection》 2023年第7期358-375,共18页
Kuwaiti oil production faces a growing challenge in the increasing quantities of produced water generated in the production of oil. The high water cut of the produced fluid from the wells and the high salinity of the ... Kuwaiti oil production faces a growing challenge in the increasing quantities of produced water generated in the production of oil. The high water cut of the produced fluid from the wells and the high salinity of the produced water lead to significant degradation of subsurface equipment, specifically the production tubing. Debris generated through the degradation of the inner part of the tubing becomes a constituent of the scaling that deposits in the tubing and blocks the flow of the production fluid, inducing higher maintenance costs. This paper looks at the characteristics of the scaling in regard to the produced water and outlines the economic impact of the produced water induced degradation of the tubing structure. 展开更多
关键词 Produced water SCALING production Tubing Corrosion SEM-EDS WD-XRF XPS
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Ultralow-voltage hydrogen production and simultaneous Rhodamine B beneficiation in neutral wastewater
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作者 Xiang Peng Song Xie +8 位作者 Shijian Xiong Rong Li Peng Wang Xuming Zhang Zhitian Liu Liangsheng Hu Biao Gao Peter Kelly Paul K.Chu 《Journal of Energy Chemistry》 SCIE EI CAS CSCD 2023年第6期574-582,I0013,共10页
Electrocatalytic water splitting for hydrogen production is hampered by the sluggish oxygen evolution reaction(OER)and large power consumption and replacing the OER with thermodynamically favourable reactions can impr... Electrocatalytic water splitting for hydrogen production is hampered by the sluggish oxygen evolution reaction(OER)and large power consumption and replacing the OER with thermodynamically favourable reactions can improve the energy conversion efficiency.Since iron corrodes easily and even self-corrodes to form magnetic iron oxide species and generate corrosion currents,a novel strategy to integrate the hydrogen evolution reaction(HER)with waste Fe upgrading reaction(FUR)is proposed and demonstrated for energy-efficient hydrogen production in neutral media.The heterostructured MoSe_(2)/MoO_(2) grown on carbon cloth(MSM/CC)shows superior HER performance to that of commercial Pt/C at high current densities.By replacing conventional OER with FUR,the potential required to afford the anodic current density of 10 m A cm^(-2)decreases by 95%.The HER/FUR overall reaction shows an ultralow voltage of 0.68 V for 10 m A cm^(-2)with a power equivalent of 2.69 k Wh per m^(3)H_(2).Additionally,the Fe species formed at the anode extract the Rhodamine B(Rh B)pollutant by flocculation and also produce nanosized magnetic powder and beneficiated Rh B for value-adding applications.This work demonstrates both energy-saving hydrogen production and pollutant recycling without carbon emission by a single system and reveals a new direction to integrate hydrogen production with environmental recovery to achieve carbon neutrality. 展开更多
关键词 Energy-saving hydrogen production Hydrogen evolution reaction Neutral water splitting MoSe_(2)/MoO_(2)heterostructure Environmental recovery
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Strong electronic coupling of CoNi and N-doped-carbon for efficient urea-assisted H2 production at a large current density 被引量:1
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作者 Guangfu Qian Jinli Chen +3 位作者 Wenjie Jiang Tianqi Yu Kexin Tan Shibin Yin 《Carbon Energy》 SCIE EI CAS CSCD 2023年第12期187-199,共13页
Exploiting efficient urea oxidation reaction(UOR)and hydrogen evolution reaction(HER)catalysts are significant for energy-saving H2 production through urea-assisted water electrolysis,but it is still challenging.Herei... Exploiting efficient urea oxidation reaction(UOR)and hydrogen evolution reaction(HER)catalysts are significant for energy-saving H2 production through urea-assisted water electrolysis,but it is still challenging.Herein,carbon-encapsulated CoNi coupled with CoNiMoO(CoNi@CN-CoNiMoO)is prepared by solvothermal method and calcination to enhance the activity/stability of urea-assisted water electrolysis at large current density.It exhibits good activity for UOR(E10/1,000=1.29/1.40 V)and HER(E-10/-1000=-45/-245 mV)in 1.0 M KOH+0.5 M urea solution.For the UOR||HER system,CoNi@CN-CoNiMoO only needs 1.58 V at 500 mA cm-2 and shows good stability.Density functional theory calculation suggests that the strong electronic interaction at the interface between NiCo alloy and N-doping-carbon layers can optimize the adsorption/desorption energy of UOR/HER intermediates and accelerate the water dissociation,which can expedite urea decomposition and Volmer step,thus increasing the UOR and HER activity,respectively.This work provides a new solution to design UOR/HER catalysts for H2 production through urea-assisted water electrolysis. 展开更多
关键词 carbon-encapsulated structure catalyst hydrogen production large current density urea-assisted water electrolysis
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Raising on Water Stocking Density Reduces Geese Reproductive Performances via Water Bacteria and Lipopolysaccharide Contaminations in “Geese-Fish” Production System 被引量:23
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作者 JIANG Dan-li LIU Li +3 位作者 WANG Cong-li CHEN Fang SUN Ai-dong SHI Zhen-dan 《Agricultural Sciences in China》 CAS CSCD 2011年第9期1459-1466,共8页
This study was carried out to unravel the mechanism of reductions in production performances in high stocking density geese flocks during summer months in "geese-fish" production system. Experiment 1 observed the wa... This study was carried out to unravel the mechanism of reductions in production performances in high stocking density geese flocks during summer months in "geese-fish" production system. Experiment 1 observed the water bacterial growth, lipopolysaccharde concentrations in water and geese blood, and geese reproductive performances from summer to winter, in two flocks with varying on water stocking densities. Results showed that counts of total bacteria, Escherichia coli and Salmonella in water, as well as water and geese plasma LPS concentrations, exhibited a tendency decreasing from the highest levels in summer, to intermediate levels in autumn, and to the lowest values in winter. Such seasonal decreases in bacteria and LPS concentrations were associated with similar seasonal decreases in embryo mortality during incubation. In addition, embryos dead or showing development retardation by day 25 of incubation contained copious LPS in allantoic fluid, in contrast to the negligible amount in normal developing embryos. Raising on water stocking density elevated bacteria counts, LPS concentrations in water and geese plasma, and decreased egg fertility but increased embryo mortality during incubation. In experiment 2, exogenous LPS treatment to the geese depressed egg laying, reduced egg hatchability, caused sickness behavior in the goslings hatched. In experiment 3, exogenous LPS directly administered to day 8 and 18 embryos during incubation dose dependently increased mortality and decreased hatchability, and caused sickness behavior in the goslings hatched. It is concluded that the raising on water geese stocking density stimulates pathogenic bacteria growth in water, which via LPS contamination impaires embryo development in incubation and therefore reduces geese reproductive performance and gosling quality during the hot summer months. 展开更多
关键词 water bacteria growth LIPOPOLYSACCHARIDE production performances GEESE
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Impacts of Climate Change on Water and Agricultural Production in Ten Large River Basins in China 被引量:17
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作者 WANG Jin-xia HUANG Ji-kun YAN Ting-ting 《Journal of Integrative Agriculture》 SCIE CAS CSCD 2013年第7期1267-1278,共12页
The overall goal of this paper is to examine impacts of climate change on water supply and demand balance and their consequences on agricultural production in ten river basins in China. To realize this goal, China Wat... The overall goal of this paper is to examine impacts of climate change on water supply and demand balance and their consequences on agricultural production in ten river basins in China. To realize this goal, China Water Simulation Model (CWSM) is used to analyze three alternative climate scenarios (A1B, A2 and B2). The results show that the impacts of climate change on water supply and demand balance differ largely among alternative scenarios. While significant impacts of climate change on water balance will occur under the A1B scenario, the impacts of climate change under the A2 and B2 scenarios will be marginal. Under the A1B scenario, the water shortage in the river basins located in the northern China will become more serious, particularly in Liaohe and Haihe river basins, but the other river basins in the southern China will improve their water balance situations. Despite larger impacts of climate change on water balance in the northern China, its impacts on total crops' production will be moderate if farmers would be able to reallocate water among crops and adjust irrigated and rainfed land. The paper concludes with some policy implications. 展开更多
关键词 climate change water supply and demand agricultural production IMPACTS
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Optimum Design and Global Analysis of Flexible Jumper for An Innovative Subsurface Production System in Ultra-Deep Water 被引量:5
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作者 黄一 甄兴伟 +1 位作者 张崎 王文华 《China Ocean Engineering》 SCIE EI CSCD 2014年第2期239-247,共9页
The study focuses on the flexible jumper issue of Subsurface Tension Leg Production (STLP) system concept, which is considered as a competing alternative system to support well completion devices and rigid risers in... The study focuses on the flexible jumper issue of Subsurface Tension Leg Production (STLP) system concept, which is considered as a competing alternative system to support well completion devices and rigid risers in ultra-deep water for offshore petroleum production. The paper presents analytical and numerical approaches for the optimum design and global analysis of the flexible jumper. Criteria using catenary concept are developed to define the critical length for optimum design. Based on the criteria, detailed hydrodynamic analyses including quasi-static analysis, modal analysis, and dynamic analysis are performed. Modal analysis with respect to the quasi-static analysis shows that the existence of resonant modes requires special consideration. The results of dynamic analysis confirm the effectiveness of the de-coupled effect from the jumper on STLP system. The approaches developed in the study also have wide application prospect in reference to the optimum design and analysis of any Hybrid Riser (HR) concept. 展开更多
关键词 subsurface production system flexible jumper dynamic analysis ultra-deep water
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Hydrogen production by glycerol reforming in supercritical water over Ni/MgO-ZrO_2 catalyst 被引量:2
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作者 Qihai Liu Liewen Liao +1 位作者 Zili Liu Xinfa Dong 《Journal of Energy Chemistry》 SCIE EI CAS CSCD 2013年第4期665-670,共6页
Nano ZrO2 and MgO-ZrO2 were prepared by a self-assembly route and were employed as the support for Ni catalysts used in hydrogen production from glycerol reforming in supercritical water (SCW). The reforming experim... Nano ZrO2 and MgO-ZrO2 were prepared by a self-assembly route and were employed as the support for Ni catalysts used in hydrogen production from glycerol reforming in supercritical water (SCW). The reforming experiments were conducted in a tubular fixed-bed flow reactor over a temperature range of 600-800 ℃. The influences of process variables such as temperature, contact time, and water to glycerol ratio on hydrogen yield were investigated and the catalysts were charactered by ICP, BET, XRD and SEM. The results showed that high hydrogen yield was obtained from glycerol by reforming in supercritical water over the Ni/MgO-ZrO2 catalysts in a short contact time. The MgO in the catalyst showed significant promotion effect for hydrogen production likely due to the formation of the alkaline active site. Even when the glycerol feed concentration was up to 45 wt%, glycerol was completely gasified and transfered to the gas products containing hydrogen, carbon dioxide, and methane along with small amounts of carbon monoxide. At a diluted feed concentration of 5 wt%, near theoretical yield of 7 mole of H2/mol of glycerol could be obtained. 展开更多
关键词 hydrogen production glycerol remforming supercritical water MgO modification Ni/ZrO2 catalysts
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The Effect of Water Saving and Production Increment by Drip Irrigation Schedules 被引量:2
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作者 QIUYuan-feng LUOJin-yao MENGGe 《Wuhan University Journal of Natural Sciences》 CAS 2004年第4期493-497,共5页
Drip irrigation system can achieve high uniformity. When the system is designed for uniformity coefficient equal or more than 70%, the water application in the field can be expressed as a normal distribution and furth... Drip irrigation system can achieve high uniformity. When the system is designed for uniformity coefficient equal or more than 70%, the water application in the field can be expressed as a normal distribution and further simplified to a linear distribution. This paper will describe the irrigation scheduling parameters, percent of deficit, application efficiency and coefficient of variation by simple mathematical model. Using this effective model and the irrigation application, the total yield affected by the total water application for different uniformity of irrigation application can be determined. More over, this paper uses the cost of water, price of yield, uniformity of the drip irrigation system, crop response to water application and environmental concerns of pollution and contamination to determine the optimal irrigation schedule. A case study shows that the optimal irrigation schedule can achieve the effect of water saving and production increment compared with the conventional irrigation schedule in which the whole field is fully irrigated. Key words drip irrigation - linear cumulative frequency curve - optimal irrigation schedule - water saving - production increment CLC number TV 139.1 Foundation item: Supported by the National Natural Science Foundation of China (59379407)Biography: QIU Yuan-feng (1973-), male, Ph. D, research direction: water saving irrigation theory and techniques. 展开更多
关键词 drip irrigation linear cumulative frequency curve optimal irrigation schedule water saving production increment
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Production characteristics and displacement mechanisms of infilling polymer-surfactant-preformed particle gel flooding in post-polymer flooding reservoirs:A review of practice in Ng3 block of Gudao Oilfield
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作者 Zhi-Bin An Kang Zhou +1 位作者 De-Jun Wu Jian Hou 《Petroleum Science》 SCIE EI CAS CSCD 2023年第4期2354-2371,共18页
The pilot test of infilling polymer-surfactant-preformed particle gel(PPG)flooding has been successfully implemented after polymer flooding in Ng3 block of Gudao Oilfield in China.However,the production characteristic... The pilot test of infilling polymer-surfactant-preformed particle gel(PPG)flooding has been successfully implemented after polymer flooding in Ng3 block of Gudao Oilfield in China.However,the production characteristics and displacement mechanisms are still unclear,which restricts its further popularization and application.Aiming at this problem,this paper firstly analyzes the production performance of the pilot test and proposed four response types according to the change of water cut curves,including W-type,U-type,V-type response,and no response.Furthermore,the underlying reasons of these four types are analyzed from the aspects of seepage resistance and sweep efficiency.The overall sweep efficiency of gradual-rising W-type,gradual-decreasing W-type,and early V-type response increases from 0.81 to 0.93,0.55 to 0.89,and 0.94 to 1,respectively.And the sum of seepage resistance along the connection line between production well and injection well for U-type and delayed V-type response increases from 0.0994 to 0.2425,and 0.0677 to 0.1654,respectively.Then,the remaining oil distribution after polymer flooding is summarized into four types on the basis of production and geological characteristics,namely disconnected remaining oil,streamline unswept remaining oil,rhythm remaining oil,and interlayer-controlled remaining oil.Furthermore,the main displacement mechanisms for each type are clarified based on the dimensionless seepage resistance and water absorption profile.Generally,improving connectivity by well pattern infilling is the most important for producing disconnected remaining oil.The synergistic effect of well pattern infilling and polymer-surfactant-PPG flooding increases the dimensionless seepage resistance of water channeling regions and forces the subsequent injected water to turn to regions with streamline unswept remaining oil.The improvement of the water absorption profile by polymer-surfactant-PPG flooding and separated layer water injection contributes to displacing rhythm remaining oil and interlayer-controlled remaining oil.Finally,the paper analyzes the relationships between the remaining oil distribution after polymer flooding and production characteristics of infilling polymer-surfactant-PPG flooding.The study helps to deepen the understanding of infilling polymer-surfactant-PPG flooding and has reference significance for more commercial implementations in the future. 展开更多
关键词 Infilling polymer-surfactant-PPG flooding production characteristics Displacement mechanisms Dimensionless seepage resistance water absorption profile
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Hydrophilic bi-functional B-doped g-C_(3)N_(4) hierarchical architecture for excellent photocatalytic H_(2)O_(2) production and photoelectrochemical water splitting 被引量:5
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作者 Yang Ding Soumyajit Maitra +8 位作者 Chunhua Wang Runtian Zheng Meiyu Zhang Tarek Barakat Subhasis Roy Jing Liu Yu Li Tawfique Hasan Bao-Lian Su 《Journal of Energy Chemistry》 SCIE EI CAS CSCD 2022年第7期236-247,I0007,共13页
Graphitic carbon nitride(g-C_(3)N_(4))has attracted great interest in photocatalysis and photoelectrocatalysis.However,their poor hydrophilicity poses a great challenge for their applications in aqueous environment.He... Graphitic carbon nitride(g-C_(3)N_(4))has attracted great interest in photocatalysis and photoelectrocatalysis.However,their poor hydrophilicity poses a great challenge for their applications in aqueous environment.Here,we demonstrate synthesis of a hydrophilic bi-functional hierarchical architecture by the assembly of B-doped g-C_(3)N_(4)nanoplatelets.Such hierarchical B-doped g-C_(3)N_(4)material enables full utilization of their highly enhanced visible light absorption and photogenerated carrier separation in aqueous medium,leading to an excellent photocatalytic H_(2)O_(2)production rate of 4240.3μM g^(-1)h^(-1),2.84,2.64 and 2.13 times higher than that of the bulk g-C_(3)N_(4),g-C_(3)N_(4)nanoplatelets and bulk B doped g-C_(3)N_(4),respectively.Photoanodes based on these hierarchical architectures can generate an unprecedented photocurrent density of 1.72 m A cm^(-2)at 1.23 V under AM 1.5 G illumination for photoelectrochemical water splitting.This work makes a fundamental improvement towards large-scale exploitation of highly active,hydrophilic and stable metal-free g-C_(3)N_(4)photocatalysts for various practical applications. 展开更多
关键词 Boron doping HYDROPHILICITY Hierarchically assembled architectures Photocatalytic H_(2)O_(2)production Photoelectrocatalytic water splitting
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A conformal titanyl phosphate amorphous overlayer for enhancing photoelectrochemical hydrogen peroxide production
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作者 Jaekyum Kim Young Eun Kim +8 位作者 Minyeong Je Won Tae Hong Chang-Lyoul Lee Tae-Hoon Kim Sung Min Cho Chang Hyuck Choi Heechae Choi Woo-Seok Choe Jung Kyu Kim 《Journal of Energy Chemistry》 SCIE EI CAS CSCD 2023年第11期399-408,I0009,共11页
Photoelectrochemical(PEC)H_(2)O_(2)production through water oxidation reaction(WOR)is a promising strategy,however,designing highly efficient and selective photoanode materials remains challenging due to competitive r... Photoelectrochemical(PEC)H_(2)O_(2)production through water oxidation reaction(WOR)is a promising strategy,however,designing highly efficient and selective photoanode materials remains challenging due to competitive reaction pathways.Here,for highly enhanced PEC H_(2)O_(2)production,we present a conformal amorphous titanyl phosphate(a-TP)overlayer on nanoparticulate TiO_(2)surfaces,achieved via lysozyme-molded in-situ surface reforming.The a-TP overlayer modulates surface adsorption energies for reaction intermediates,favoring WOR for H_(2)O_(2)production over the competing O_(2)evolution reaction.Our density functional theory calculations reveal that a-TP/TiO_(2)exhibits a substantial energy uphill for the O·*formation pathway,which disfavors O_(2)evolution but promotes H_(2)O_(2)production.Additionally,the a-TP overlayer strengthens the built-in electric field,resulting in favorable kinetics.Consequently,a-TP/TiO_(2)exhibits 3.7-fold higher Faraday efficiency(FE)of 63%at 1.76 V vs.reversible hydrogen electrode(RHE)under 1 sun illumination,compared to bare TiO_(2)(17%),representing the highest FE among TiO_(2)-based WOR H_(2)O_(2)production systems.Employing the a-TP overlayer constitutes a promising strategy for controlling reaction pathways and achieving efficient solar-to-chemical energy conversion. 展开更多
关键词 Solar H_(2)O_(2) production in-situ surface reforming Titanyl phosphate Amorphous overlayer Reaction pathway control
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MOF-Like 3D Graphene-Based Catalytic Membrane Fabricated by One-Step Laser Scribing for Robust Water Purification and Green Energy Production 被引量:2
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作者 Xinyu Huang Liheng Li +11 位作者 Shuaifei Zhao Lei Tong Zheng Li Zhuiri Peng Runfeng Lin Li Zhou Chang Peng Kan-Hao Xue Lijuan Chen Gary J.Cheng Zhu Xiong Lei Ye 《Nano-Micro Letters》 SCIE EI CAS CSCD 2022年第11期48-61,共14页
Increasing both clean water and green energy demands for survival and development are the grand challenges of our age.Here,we successfully fabricate a novel multifunctional 3D graphene-based catalytic membrane(3D-GCM)... Increasing both clean water and green energy demands for survival and development are the grand challenges of our age.Here,we successfully fabricate a novel multifunctional 3D graphene-based catalytic membrane(3D-GCM)with active metal nanoparticles(AMNs)loading for simultaneously obtaining the water purification and clean energy generation,via a“green”one-step laser scribing technology.The as-prepared 3D-GCM shows high porosity and uniform distribution with AMNs,which exhibits high permeated fluxes(over 100 L m^(−2) h^(−1))and versatile super-adsorption capacities for the removal of tricky organic pollutants from wastewater under ultra-low pressure-driving(0.1 bar).After adsorption saturating,the AMNs in 3D-GCM actuates the advanced oxidization process to self-clean the fouled membrane via the catalysis,and restores the adsorption capacity well for the next time membrane separation.Most importantly,the 3D-GCM with the welding of laser scribing overcomes the lateral shear force damaging during the long-term separation.Moreover,the 3D-GCM could emit plentiful of hot electrons from AMNs under light irradiation,realizing the membrane catalytic hydrolysis reactions for hydrogen energy generation.This“green”precision manufacturing with laser scribing technology provides a feasible technology to fabricate high-efficient and robust 3D-GCM microreactor in the tricky wastewater purification and sustainable clean energy production as well. 展开更多
关键词 3D graphene Laser scribing Catalytic membrane water purification Hydrogen production
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Responses of water productivity to irrigation and N supply for hybrid maize seed production in an arid region of Northwest China 被引量:3
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作者 RAN Hui KANG Shaozhong +4 位作者 LI Fusheng DU Taisheng DING Risheng LI Sien TONG Ling 《Journal of Arid Land》 SCIE CSCD 2017年第4期504-514,共11页
Water and nitrogen(N) are generally two of the most important factors in determining the crop productivity. Proper water and N managements are prerequisites for agriculture sustainable development in arid areas. Fie... Water and nitrogen(N) are generally two of the most important factors in determining the crop productivity. Proper water and N managements are prerequisites for agriculture sustainable development in arid areas. Field experiments were conducted to study the responses of water productivity for crop yield(WP_(Y-ET)) and final biomass(WP_(B-ET)) of film-mulched hybrid maize seed production to different irrigation and N treatments in the Hexi Corridor, Northwest China during April to September in 2013 and also during April to September in 2014. Three irrigation levels(70%–65%, 60%–55%, and 50%–45% of the field capacity) combined with three N rates(500, 400, and 300 kg N/hm^2) were tested in 2013. The N treatments were adjusted to 500, 300, and 100 kg N/hm^2 in 2014. Results showed that the responses of WP_(Y-ET) and WP_(B-ET) to different irrigation amounts were different. WP_(Y-ET) was significantly reduced by lowering irrigation amounts while WP_(B-ET) stayed relatively insensitive to irrigation amounts. However, WP_(Y-ET) and WP_(B-ET) behaved consistently when subjected to different N treatments. There was a slight effect of reducing N input from 500 to 300 kg/hm^2 on the WP_(Y-ET) and WP_(B-ET), however, when reducing N input to 100 kg/hm^2, the values of WP_(Y-ET) and WP_(B-ET) were significantly reduced. Water is the primary factor and N is the secondary factor in determining both yield(Y) and final biomass(B). Partial factor productivity from applied N(PFP_N) was the maximum under the higher irrigation level and in lower N rate(100–300 kg N/hm^2) in both years(2013 and 2014). Lowering the irrigation amount significantly reduced evapotranspiration(ET), but ET did not vary with different N rates(100–500 kg N/hm^2). Both Y and B had robust linear relationships with ET, but the correlation between B and ET(R^2=0.8588) was much better than that between Y and ET(R^2=0.6062). When ET increased, WP_(Y-ET) linearly increased and WP_(B-ET) decreased. Taking the indices of Y, B, WP_(Y-ET), WP_(B-ET) and PFP_N into account, a higher irrigation level(70%–65% of the field capacity) and a lower N rate(100–300 kg N/hm^2) are recommended to be a proper irrigation and N application strategy for plastic film-mulched hybrid maize seed production in arid Northwest China. 展开更多
关键词 water use efficiency water stress nitrogen use efficiency evapotranspiration water productivity for yield water productivity for biomass arid region
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