Along with the popularity of environmental protection concepts, the environmental treatment of water pollution attracts widespread attention, among which, the research on Bi-based semiconductor photocatalytic degradat...Along with the popularity of environmental protection concepts, the environmental treatment of water pollution attracts widespread attention, among which, the research on Bi-based semiconductor photocatalytic degradation technology has made great progress. However, the development of such bismuth-based composites still remains a challenging task due to difficult recovery and low catalytic efficiency. Herein, a novel CC/BiPO4</sub>/Bi2</sub>WO6</sub> composite was successfully synthesized through two-step hydrothermal method using activated flexible carbon cloth as a substrate. The results of the photocatalytic degradation experiments showed that the obtained CC/BiPO<sub>4</sub>/Bi<sub>2</sub>WO<sub>6</sub> composites can degrade 92.1% RhB in 60 min under UV-visible light irradiation, which was much higher than that of unloaded BiPO4</sub> (24.4%) and BiPO4</sub>/Bi2</sub>WO6</sub> (52.9%), exhibiting a better adsorption-photocatalytic degradation performance than BiPO4</sub> and BiPO4</sub>/Bi2</sub>WO6</sub>. Photoluminescence spectra indicated that the improved photocatalytic activity was due to the more effective inhibition of photogenerated carrier complexation. Furthermore, the radical capture experiments confirmed that h<sup>+</sup>, ·OH and O<sub>2</sub>-</sup> were the main active substances in the photocatalytic degradation process of RhB by the CC/BiPO4</sub>/Bi2</sub>WO6</sub> composites. More importantly, the prepared CC/BiPO4</sub>/Bi2</sub>WO6</sub> composite had a simple separation process and good recycling stability, and its photocatalytic degradation efficiency can still reach 53.3% after six cycles of RhB degradation. .展开更多
The InVO4-TiO2 nano-crystalline photocatalyst was prepared by sol-gel method and characterized by DRS, FTIR, Raman and XRD. The photocatalytic activities of the prepared sample were investigated by photocatalytic degr...The InVO4-TiO2 nano-crystalline photocatalyst was prepared by sol-gel method and characterized by DRS, FTIR, Raman and XRD. The photocatalytic activities of the prepared sample were investigated by photocatalytic degradation of ethylene in the gaseous phase under visible light irradiation (λ>450 nm). The results indicate that both of pure TiO2 and InVO4 or their simple mixture show no photocatalytic activities for degradation of ethylene under visible light irradiation. However, as-synthesized InVO4-TiO2 catalyzes the degradation of ethylene into CO2 under visible light irradiation. In addition, the interaction between InVO4 and TiO2 results in some structural distortion to all the crystal forms of TiO2 in as-synthesized catalyst InVO4-TiO2.展开更多
文摘Along with the popularity of environmental protection concepts, the environmental treatment of water pollution attracts widespread attention, among which, the research on Bi-based semiconductor photocatalytic degradation technology has made great progress. However, the development of such bismuth-based composites still remains a challenging task due to difficult recovery and low catalytic efficiency. Herein, a novel CC/BiPO4</sub>/Bi2</sub>WO6</sub> composite was successfully synthesized through two-step hydrothermal method using activated flexible carbon cloth as a substrate. The results of the photocatalytic degradation experiments showed that the obtained CC/BiPO<sub>4</sub>/Bi<sub>2</sub>WO<sub>6</sub> composites can degrade 92.1% RhB in 60 min under UV-visible light irradiation, which was much higher than that of unloaded BiPO4</sub> (24.4%) and BiPO4</sub>/Bi2</sub>WO6</sub> (52.9%), exhibiting a better adsorption-photocatalytic degradation performance than BiPO4</sub> and BiPO4</sub>/Bi2</sub>WO6</sub>. Photoluminescence spectra indicated that the improved photocatalytic activity was due to the more effective inhibition of photogenerated carrier complexation. Furthermore, the radical capture experiments confirmed that h<sup>+</sup>, ·OH and O<sub>2</sub>-</sup> were the main active substances in the photocatalytic degradation process of RhB by the CC/BiPO4</sub>/Bi2</sub>WO6</sub> composites. More importantly, the prepared CC/BiPO4</sub>/Bi2</sub>WO6</sub> composite had a simple separation process and good recycling stability, and its photocatalytic degradation efficiency can still reach 53.3% after six cycles of RhB degradation. .
文摘The InVO4-TiO2 nano-crystalline photocatalyst was prepared by sol-gel method and characterized by DRS, FTIR, Raman and XRD. The photocatalytic activities of the prepared sample were investigated by photocatalytic degradation of ethylene in the gaseous phase under visible light irradiation (λ>450 nm). The results indicate that both of pure TiO2 and InVO4 or their simple mixture show no photocatalytic activities for degradation of ethylene under visible light irradiation. However, as-synthesized InVO4-TiO2 catalyzes the degradation of ethylene into CO2 under visible light irradiation. In addition, the interaction between InVO4 and TiO2 results in some structural distortion to all the crystal forms of TiO2 in as-synthesized catalyst InVO4-TiO2.
基金Project(51102025)supported by the National Natural Science Foundation of ChinaProject(14JJ7040)supported by Natural Science Foundation of Hunan Province,ChinaProject(2014GH561172)supported by China Torch Program
