Effects of acid-rock reaction on physical properties during CO_(2)-rich industrial waste gas(CO_(2)-rich IWG)injection in shale reservoirs

"Carbon peaking and carbon neutrality"is an essential national strategy,and the geological storage and utilization of CO_(2)is a hot issue today.However,due to the scarcity of pure CO_(2)gas sources in China and the high cost of CO_(2)capture,CO_(2)-rich industrial waste gas(CO_(2)-rich IWG)is gradually emerging into the public's gaze.CO_(2)has good adsorption properties on shale surfaces,but acidic gases can react with shale,so the mechanism of the CO_(2)-rich IWG-water-shale reaction and the change in reservoir properties will determine the stability of geological storage.Therefore,based on the mineral composition of the Longmaxi Formation shale,this study constructs a thermodynamic equilibrium model of water-rock reactions and simulates the regularity of reactions between CO_(2)-rich IWG and shale minerals.The results indicate that CO_(2)consumed 12%after reaction,and impurity gases in the CO_(2)-rich IWG can be dissolved entirely,thus demonstrating the feasibility of treating IWG through water-rock reactions.Since IWG inhibits the dissolution of CO_(2),the optimal composition of CO_(2)-rich IWG is 95%CO_(2)and 5%IWG when CO_(2)geological storage is the main goal.In contrast,when the main goal is the geological storage of total CO_(2)-rich IWG or impurity gas,the optimal CO_(2)-rich IWG composition is 50%CO_(2)and 50%IWG.In the CO_(2)-rich IWG-water-shale reaction,temperature has less influence on the water-rock reaction,while pressure is the most important parameter.SO2 has the greatest impact on water-rock reaction in gas.For minerals,clay minerals such as illite and montmorillonite had a significant effect on water-rock reaction.The overall reaction is dominated by precipitation and the volume of the rock skeleton has increased by 0.74 cm3,resulting in a decrease in shale porosity,which enhances the stability of CO_(2)geological storage to some extent.During the reaction between CO_(2)-rich IWG-water-shale at simulated temperatures and pressures,precipitation is the main reaction,and shale porosity decreases.However,as the reservoir water content increases,the reaction will first dissolve and then precipitate before dissolving again.When the water content is less than 0.0005 kg or greater than 0.4 kg,it will lead to an increase in reservoir porosity,which ultimately reduces the long-term geological storage stability of CO_(2)-rich IWG.

Research status and application of artificial intelligence large models in the oil and gas industry

This article elucidates the concept of large model technology,summarizes the research status of large model technology both domestically and internationally,provides an overview of the application status of large models in vertical industries,outlines the challenges and issues confronted in applying large models in the oil and gas sector,and offers prospects for the application of large models in the oil and gas industry.The existing large models can be briefly divided into three categories:large language models,visual large models,and multimodal large models.The application of large models in the oil and gas industry is still in its infancy.Based on open-source large language models,some oil and gas enterprises have released large language model products using methods like fine-tuning and retrieval augmented generation.Scholars have attempted to develop scenario-specific models for oil and gas operations by using visual/multimodal foundation models.A few researchers have constructed pre-trained foundation models for seismic data processing and interpretation,as well as core analysis.The application of large models in the oil and gas industry faces challenges such as current data quantity and quality being difficult to support the training of large models,high research and development costs,and poor algorithm autonomy and control.The application of large models should be guided by the needs of oil and gas business,taking the application of large models as an opportunity to improve data lifecycle management,enhance data governance capabilities,promote the construction of computing power,strengthen the construction of“artificial intelligence+energy”composite teams,and boost the autonomy and control of large model technology.

Risk Assessment Index System of Natural Gas Industrial Chain in China

This paper establishes a risk assessment index system for the natural gas industrial chain. China＇s natural gas industrial chain is entering a stage of rapid growth. In order to guarantee healthy development of the natural gas industrial chain, it is urgent to establish a risk alert system, which is based on a risk assessment index system. First of all, the risks of the natural gas industrial chain are defined in the paper; then the risk factors are analyzed according to the present status of the natural gas industrial chain, and five categories of risk factors are summarized： resource risk, transport risk, marketing risk, risk of unbalanced chain links, and environment risk. The paper presents the principles of the risk assessment index system. The natural gas industrial chain risk assessment index system is established with four levels and forty-six risk indices.

Scenario analysis on abating industrial process greenhouse gas emissions from adipic acid production in China

Adipic acid is an important petrochemical product,and its production process emits a high concentration of greenhouse gas N_2 O.This paper aims to provide quantitative references for relevant authorities to formulate greenhouse gas control roadmaps.The forecasting method of this paper is consistent with the published national inventory in terms of caliber.Based on the N_2 O abatement technical parameters of adipic acid and the production trend,this paper combines the scenario analysis and provides a measurement of comprehensive N_2 O abatement effect of the entire industry in China.Four future scenarios are assumed.The baseline scenario(BAUS) is a frozen scenario.Three emission abatement scenarios(ANAS,SNAS,and ENAS) are assumed under different strength of abatement driving parameters.The results show that China's adipic acid production process can achieve increasingly significant N_2 O emission abatement effects.Compared to the baseline scenario,by 2030,the N_2 O emission abatements of the three emission abatement scenarios can reach 207-399 kt and the emission abatement ratios can reach 32.5%-62.6%.By 2050,the N_2 O emission abatements for the three emission abatement scenarios can reach 387-540 kt and the emission abatement ratios can reach 71.4%-99.6%.

Review on the challenges and strategies in oil and gas industry's transition towards carbon neutrality in China

In light of carbon-neutral pledge, the oil and gas industry has been facing several critical new challenges in China. The current status and new challenges in terms of market mechanism reform, supply-consumption balance and key technology innovation in China's oil and gas industry are reviewed in the present study, and new strategies and roadmaps are proposed to cope with the challenges. The study found that (i) the oil and gas market faces challenges such as incomplete pricing mechanisms, unclear subject rights, and the lack of recognition and trading of carbon assets. (ii) the trade-off between short-term supply security and long-term low-carbon supply is the most critical issue. (iii) in addition to typical challenges such as immature technology and lack of funding support, the unclear multiple technology coupling development mode also poses problems for the low-carbon transformation of the oil and gas industry. To address these new challenges, comprehensive strategies and roadmaps for China's oil and gas industry towards carbon neutrality are proposed and discussed in the aspects of participating in market transactions, restructuring production and consumption, deploying key technology innovations, and planning enterprise strategies. The present study is expected to provide a blueprint for the future development of China's oil and gas industry towards carbon neutrality.

Empirical Investigation of Treatment of Sour Gas by Novel Technology: Energy Optimization

The sour gas sweetening is one of the main processes in gas industries. Gas sweetening is done through chemical processes. Therefore, it requires high cost and energy. The results show that increasing the operating temperature increases the mass transfer coefficient and increases the mass transfer rate. Theoretical and experimental data show that sulfur removal in 4.5 W magnetic field is desirable. The increase in sulfur removal percentage in the magnetic field of 4.5 W and 6.75 W is about 16.4% and 15.2%, respectively. According to the obtained results, the effect of temperature increase from 18.8°C to 23.4°C is more evident than the effect of temperature change from 23.4°C to 32.2°C. Because more thermal energy is needed to provide higher temperatures. Therefore, the temperature of 23.4°C is reported as the optimal temperature. The results of this research show that the percentage of sulfur removal is also high at this temperature.

Problems and Strategies of China’s Natural Gas Industry

Although significant progress in China＇s natural gas industry has been made since the adoption of the ＂Eighth Five-Year Plan＂（from 1991 to 1995）, some problems still exist in the aspects of gas resources, exploitation, utilization and macromanagement, and hinder a further development of the natural gas industry. A series of strategies for solving the problems was put forward, including accurate orientation of the natural gas industry, strengthening the construction of gas transmission and distribution networks, comprehensive exploitation policies for ＂integration of up-and-downstream＂, government-supported gas-preferential policies, construction of the gas market frameworks and devoting strong effort to the new market development.

Fuzzy logic applied to value of information assessment in oil and gas projects

The concept of value of information(VOI)has been widely used in the oil industry when making decisions on the acquisition of new data sets for the development and operation of oil fields.The classical approach to VOI assumes that the outcome of the data acquisition process produces crisp values,which are uniquely mapped onto one of the deterministic reservoir models representing the subsurface variability.However,subsurface reservoir data are not always crisp;it can also be fuzzy and may correspond to various reservoir models to different degrees.The classical approach to VOI may not,therefore,lead to the best decision with regard to the need to acquire new data.Fuzzy logic,introduced in the 1960 s as an alternative to the classical logic,is able to manage the uncertainty associated with the fuzziness of the data.In this paper,both classical and fuzzy theoretical formulations for VOI are developed and contrasted using inherently vague data.A case study,which is consistent with the future development of an oil reservoir,is used to compare the application of both approaches to the estimation of VOI.The results of the VOI process show that when the fuzzy nature of the data is included in the assessment,the value of the data decreases.In this case study,the results of the assessment using crisp data and fuzzy data change the decision from"acquire"the additional data(in the former)to"do not acquire"the additional data(in the latter).In general,different decisions are reached,depending on whether the fuzzy nature of the data is considered during the evaluation.The implications of these results are significant in a domain such as the oil and gas industry(where investments are huge).This work strongly suggests the need to define the data as crisp or fuzzy for use in VOI,prior to implementing the assessment to select and define the right approach.

Current Status and Development Trend of Natural Gas Industry in China

In China, the proven reserves of natural gas is 3.86 trillion cubic meters (tcm). This figure will quite possibly increase at a high speed in the future. At present, the annual production of natural gas has exceeded 34 billion cubic meters (bcm), which, likewise, will rise sharply. The pipeline construction has basically taken shape, which will be gradually perfected. And the gas consumption market is in the startup stage, which will be rapidly expanded in the quite near future.

Risk Matrix as a Tool for Risk Analysis in Underwater Operations in the Oil and Gas Industry

The study is a cross-sectional design assessment of the likelihood, frequency and severity of hazards associated with underwater operations in the Niger Delta. Five oil and gas companies were used for this study selected by a purposive method given that they had the highest number of workers involved in underwater operations. A sample size of 418 was computed to which the questionnaires were administered with response rate of 95.93%. Data analyses were carried out to cover descriptive statistics, analysis of variance and Pearsonal correlation coefficients. The 4 by 4 risk assessment matrix for the likelihood and consequences showed that 8 out of 20 underwater hazards were categorized as having very high risk according to their risk ratings. The eight hazards categorized based on their risk IDs were H01, H03, H04, H08, H10, H11, H12, and H15. The 4 by 4 risk matrix for frequency and consequences revealed that two hazards (Piracy & bandit attack/kidnapping (H01) and Other main vessels/heavy object dropping or falling load/collision (H08)) were identified to be of very high risk.

Contract Labor and the Right to Freedom of Association in the Oil and Gas Industry in Nigeria

Contract labor is one of several terms, which are widely used to describe work arrangements, which do not fall within the traditional definition of employment. Contracting out services and getting employees through contractors have become widespread practice by many employers because it helps them to cut cost since these contractors could often supply these workers more cheaply and efficiently. Labor rights and standards are sometimes seen as sacrificial lambs on the altar of competitive edge by companies due to the perception that they constitute ＂costs＂ which if eliminated or reduced to the barest minimum, will impact positively on the ability of companies to compete favorably in the global market and consequent improvement of their balance sheets, to the joy of shareholders. Contract work is increasingly becoming the norm in Nigeria＇s oil and gas industry as companies undergo restructuring, concentration on core activities and modifications in work organization and technology. These factors certainly affect traditional employment relations and the exercise of freedom of association and collective bargaining rights inherent in them. Contract workers now make up about 60% of the workforce in the industry and they are denied the right to organize into Unions. The denial of this right has resulted in exploitation of these workers. This paper seeks to examine the adequacy of labor law governing trade unionism in Nigeria in ensuring the right of contract workers to freedom of association, as well as its conformity to international labor standards. It is argued that Nigerian labor laws need to be enforced to ensure that this category of workers benefits from this right. In addition a proposal is made for a law reform which will define contract labor and provide a legal framework for the regulation and protection of contract workers in Nigeria in order to guarantee their right to unionize and enable them to improve their rights at work.

Current Situation and the Outlook of China＇s Natural Gas Industry

Core indicators of China’s natural gas industry in 2016In 2016,China produced 132.82 bcm of natural gas and 1.61bcm of coal-to-gas,production amounts that were 1.5%and 15.8%higher than those of the previous year,respectively.The imported gas volume was 38.34bcm through pipeline(up 9.0%from the previous year)and 33.74 bcm via LNG facilities(up 30.6%from

NATURAL GAS INDUSTRY

Natural Gas Industry(NGI)i is an only scien-tific and technological periodical in China which comprehensively reports natural gas industry and approved by the State Scientific and Technolog-ical Commission and the Satate News Publishing Office.It is undertaken by Sichuan Petroleum Ad-ministration situated in the land of plenty,which has the longest history and abundant experiences in natural gas exploration and development,and pos-sesses the highest yield of gas at present.

BRIGHT PROSPECT OF CHINA'S NATURAL GAS INDUSTRY

Sino-IEAConferenceonNaturalGasindustrywasheldinBeijing,duringNovember9-10,1999.ItwascosponsoredbyStateDevelopmentPlanningCommission,StatePetroleumandChemicalindustryBureauandInternationalEnergyAgency(IEA),incollaborationwithChinaNationalPetroleumCorp...

Analysis on the Characteristics of Environmental Kuznets Curve and Assessment of Air Quality in Qingdao City

[Objective] The aim was to analyze the characteristics of environmental Kuznets curve (EKC) and assess air quality in Qingdao City. [Method] The EKC characteristics of Qingdao from 1996 to 2008 were studied based on air pollutant discharge indices, air pollution indices and economic data from the environmental quality reports and statistics yearbooks of Qingdao, and the air quality of Qingdao City was assessed. [Result] With the increase of GDP per capita, the total discharge of industrial waste gases improved remarkably, and its EKC showed inverted U type. Meanwhile, the discharge of SO2, industrial fumes and industrial dusts decreased on the whole, and the EKC of sulfur dioxide and industrial fumes was close to inverted N type. In addition, air pollution composite index also showed decrease trend, and its EKC showed inverted N type. In recent 13 years, the concentration of SO2, particles and NO2 in ambient air of Qingdao City showed decrease trend on the whole, especially particles. In addition, PM10 has replaced SO2 as the primary pollutant since 2001, and air pollution type has changed from coal smoke pollution to mixed mode pollution of coal smoke and motor vehicle. The mitigation of air pollution in Qingdao City could be attributed to the implementation of industrial waste gas management by the governments of Qingdao City. [Conclusion] The study could provide theoretical foundations for the establishment of environmental policies in Qingdao City.

Mississippi River Delta: Land Subsidence and Coastal Erosion

The Mississippi River Delta is a major center for transportation, industry, human population and ecosystem services. Critical areas included energy production, navigation, fisheries, flood protection of coastal communities, and restoration of damaged habitats. Complex environmental management in a great river system requires broad-base complex science, engineering and monitoring. A major national and state objective has become the restoration of the Mississippi River Delta that is threatened by subsidence, flooding, storm surges, compaction, oil extraction and gas extraction. The primary objectives of the paper are to document the landscape and geological properties of the Mississippi River Delta which have contributed to the successful resource and economic development of a historically-rich region of North America and to document the natural resource and environmental risks to the Mississippi River Delta. Economic and urban development of the Mississippi River Delta by the oil and gas industry and creation of levees by the USACE has contributed to land subsidence problems. Environmental challenges include land subsidence as a result of the pumping of vast amounts of oil and gas, the lack of sediment deposition in the Mississippi River Delta as a result of a system of levees, coastal erosion impacts of hurricanes, disposal of untreated and treated wastewater, periodic flooding and water pollution.