"Carbon peaking and carbon neutrality"is an essential national strategy,and the geological storage and utilization of CO_(2)is a hot issue today.However,due to the scarcity of pure CO_(2)gas sources in China..."Carbon peaking and carbon neutrality"is an essential national strategy,and the geological storage and utilization of CO_(2)is a hot issue today.However,due to the scarcity of pure CO_(2)gas sources in China and the high cost of CO_(2)capture,CO_(2)-rich industrial waste gas(CO_(2)-rich IWG)is gradually emerging into the public's gaze.CO_(2)has good adsorption properties on shale surfaces,but acidic gases can react with shale,so the mechanism of the CO_(2)-rich IWG-water-shale reaction and the change in reservoir properties will determine the stability of geological storage.Therefore,based on the mineral composition of the Longmaxi Formation shale,this study constructs a thermodynamic equilibrium model of water-rock reactions and simulates the regularity of reactions between CO_(2)-rich IWG and shale minerals.The results indicate that CO_(2)consumed 12%after reaction,and impurity gases in the CO_(2)-rich IWG can be dissolved entirely,thus demonstrating the feasibility of treating IWG through water-rock reactions.Since IWG inhibits the dissolution of CO_(2),the optimal composition of CO_(2)-rich IWG is 95%CO_(2)and 5%IWG when CO_(2)geological storage is the main goal.In contrast,when the main goal is the geological storage of total CO_(2)-rich IWG or impurity gas,the optimal CO_(2)-rich IWG composition is 50%CO_(2)and 50%IWG.In the CO_(2)-rich IWG-water-shale reaction,temperature has less influence on the water-rock reaction,while pressure is the most important parameter.SO2 has the greatest impact on water-rock reaction in gas.For minerals,clay minerals such as illite and montmorillonite had a significant effect on water-rock reaction.The overall reaction is dominated by precipitation and the volume of the rock skeleton has increased by 0.74 cm3,resulting in a decrease in shale porosity,which enhances the stability of CO_(2)geological storage to some extent.During the reaction between CO_(2)-rich IWG-water-shale at simulated temperatures and pressures,precipitation is the main reaction,and shale porosity decreases.However,as the reservoir water content increases,the reaction will first dissolve and then precipitate before dissolving again.When the water content is less than 0.0005 kg or greater than 0.4 kg,it will lead to an increase in reservoir porosity,which ultimately reduces the long-term geological storage stability of CO_(2)-rich IWG.展开更多
Preparation of ceramsite from solid waste based on the sintering process is a new technology and had a high efficiency in improving producing capability, decreasing consumption of liquefied petroleum gas (LPG), and re...Preparation of ceramsite from solid waste based on the sintering process is a new technology and had a high efficiency in improving producing capability, decreasing consumption of liquefied petroleum gas (LPG), and recovering waste heat of flue gas. An experiment sintering gangue ceramsite was conducted in a 25 kg scale sintering pot with a 100 cm height. The combustion characteristics, phase transformation, and the release profile of SO_(2)^(*) (SO and/or SO_(2)) and NO_(x)^(*) (N_(2)O, NO, and/or NO_(2)) of gangue ceramsite during the sintering process were studied by X-ray diffraction analysis, X-ray fluorescence spectrometry, thermogravimetry–differential thermogravimetry–differential scanning calorimetry, and measurement of physical properties of ceramsite and gas components of flue gas. The results showed that the gangue ceramsite had excellent properties, and its compressive strength and water absorption were 8.2–9.6 MPa and 8.9%–9.8%, respectively, far exceeding the requirement of standard (GB/T 17431.1–2010). The ignition temperature of gangue ceramsite was 443 ℃, and the ignition loss was 14.60 mass% at 1000 ℃. Kaolinite and calcite disappeared at 600 and 800 ℃, respectively. Albite disappeared and mullite formed at 1000 ℃. Two peaks of SO_(2)^(*) emissions emerged in the range of 311–346 mg m^(-3) near 500 ℃ of upper layer ceramsite and 420–489 mg m^(-3) near 1000 ℃ of lower layer ceramsite, respectively. NO_(x)^(*) emissions peak emerged in the range of 227–258 mg m^(-3) near 550 ℃ of the upper layer ceramsite, which was related to the oxidation of sulfide and the combustion of LPG. Gangue is a direct heat source for sintering of ceramsite as well. During sintering process, the heat of flue gas above and below 400 ℃ accounts for 55.9% and 30.0% of the all-output heat, respectively, and was potentially used for producing waste-heat steam or electricity as by-products and drying raw materials during its own initial sintering process, which can realize combined mass and heat utilization for the gangue and further reduce the cost of sintered gangue ceramsite.展开更多
基金The work was supported by the National Natural Science Foundation of China(No.52074316)PetroChina Company Limited(No.2019E-2608).
文摘"Carbon peaking and carbon neutrality"is an essential national strategy,and the geological storage and utilization of CO_(2)is a hot issue today.However,due to the scarcity of pure CO_(2)gas sources in China and the high cost of CO_(2)capture,CO_(2)-rich industrial waste gas(CO_(2)-rich IWG)is gradually emerging into the public's gaze.CO_(2)has good adsorption properties on shale surfaces,but acidic gases can react with shale,so the mechanism of the CO_(2)-rich IWG-water-shale reaction and the change in reservoir properties will determine the stability of geological storage.Therefore,based on the mineral composition of the Longmaxi Formation shale,this study constructs a thermodynamic equilibrium model of water-rock reactions and simulates the regularity of reactions between CO_(2)-rich IWG and shale minerals.The results indicate that CO_(2)consumed 12%after reaction,and impurity gases in the CO_(2)-rich IWG can be dissolved entirely,thus demonstrating the feasibility of treating IWG through water-rock reactions.Since IWG inhibits the dissolution of CO_(2),the optimal composition of CO_(2)-rich IWG is 95%CO_(2)and 5%IWG when CO_(2)geological storage is the main goal.In contrast,when the main goal is the geological storage of total CO_(2)-rich IWG or impurity gas,the optimal CO_(2)-rich IWG composition is 50%CO_(2)and 50%IWG.In the CO_(2)-rich IWG-water-shale reaction,temperature has less influence on the water-rock reaction,while pressure is the most important parameter.SO2 has the greatest impact on water-rock reaction in gas.For minerals,clay minerals such as illite and montmorillonite had a significant effect on water-rock reaction.The overall reaction is dominated by precipitation and the volume of the rock skeleton has increased by 0.74 cm3,resulting in a decrease in shale porosity,which enhances the stability of CO_(2)geological storage to some extent.During the reaction between CO_(2)-rich IWG-water-shale at simulated temperatures and pressures,precipitation is the main reaction,and shale porosity decreases.However,as the reservoir water content increases,the reaction will first dissolve and then precipitate before dissolving again.When the water content is less than 0.0005 kg or greater than 0.4 kg,it will lead to an increase in reservoir porosity,which ultimately reduces the long-term geological storage stability of CO_(2)-rich IWG.
基金support of the Shendong Buertai Colliery and Shandong ECON Energy Saving Technology Co.,Ltd on experimentssupport from the National Key R&D Program Project(Grant No.2019YFC1905705)is greatly acknowledged.
文摘Preparation of ceramsite from solid waste based on the sintering process is a new technology and had a high efficiency in improving producing capability, decreasing consumption of liquefied petroleum gas (LPG), and recovering waste heat of flue gas. An experiment sintering gangue ceramsite was conducted in a 25 kg scale sintering pot with a 100 cm height. The combustion characteristics, phase transformation, and the release profile of SO_(2)^(*) (SO and/or SO_(2)) and NO_(x)^(*) (N_(2)O, NO, and/or NO_(2)) of gangue ceramsite during the sintering process were studied by X-ray diffraction analysis, X-ray fluorescence spectrometry, thermogravimetry–differential thermogravimetry–differential scanning calorimetry, and measurement of physical properties of ceramsite and gas components of flue gas. The results showed that the gangue ceramsite had excellent properties, and its compressive strength and water absorption were 8.2–9.6 MPa and 8.9%–9.8%, respectively, far exceeding the requirement of standard (GB/T 17431.1–2010). The ignition temperature of gangue ceramsite was 443 ℃, and the ignition loss was 14.60 mass% at 1000 ℃. Kaolinite and calcite disappeared at 600 and 800 ℃, respectively. Albite disappeared and mullite formed at 1000 ℃. Two peaks of SO_(2)^(*) emissions emerged in the range of 311–346 mg m^(-3) near 500 ℃ of upper layer ceramsite and 420–489 mg m^(-3) near 1000 ℃ of lower layer ceramsite, respectively. NO_(x)^(*) emissions peak emerged in the range of 227–258 mg m^(-3) near 550 ℃ of the upper layer ceramsite, which was related to the oxidation of sulfide and the combustion of LPG. Gangue is a direct heat source for sintering of ceramsite as well. During sintering process, the heat of flue gas above and below 400 ℃ accounts for 55.9% and 30.0% of the all-output heat, respectively, and was potentially used for producing waste-heat steam or electricity as by-products and drying raw materials during its own initial sintering process, which can realize combined mass and heat utilization for the gangue and further reduce the cost of sintered gangue ceramsite.
