Controlled synthesis is central to obtaining polymers with accurate structures and excellent performances.Recent research in the controlled synthesis of polymers has focused on optimizing monomers,initiation systems,a...Controlled synthesis is central to obtaining polymers with accurate structures and excellent performances.Recent research in the controlled synthesis of polymers has focused on optimizing monomers,initiation systems,and reaction conditions.The satisfactory sequence,topological structure,and dispersity have been achieved to satisfy the growing demand for functional polymers.This re-view summarizes the selection of monomers of various types and structures,the innovation of initiation systems,and the optimiza-tion of reaction conditions in the controlled synthesis of polymers and discusses their challenges and opportunities.展开更多
基金supported by the National Key Research and Development Program(Nos.2022YFC2603500,2021YFC2400600)the National Natural Science Foundation of China(Nos.52273158,U21A2099,52022095,52073280,51973216)+2 种基金the Science and Technology Development Program of Jjilin Province(Nos.20220204018YY,20210509005RQ,20210504001GH,20200404182YY)the Special Project for City-Academy Scientific and Technological Innovation Cooperation of Changchun(No.21SH14)the Youth Innovation Promotion Association of the Chinese Academy of Sciences(No.2019230).
文摘Controlled synthesis is central to obtaining polymers with accurate structures and excellent performances.Recent research in the controlled synthesis of polymers has focused on optimizing monomers,initiation systems,and reaction conditions.The satisfactory sequence,topological structure,and dispersity have been achieved to satisfy the growing demand for functional polymers.This re-view summarizes the selection of monomers of various types and structures,the innovation of initiation systems,and the optimiza-tion of reaction conditions in the controlled synthesis of polymers and discusses their challenges and opportunities.
