Heat transfer enhanced inorganic phase change material compositing carbon nanotubes for battery thermal management and thermal runaway propagation mitigation

Developing technologies that can be applied simultaneously in battery thermal management(BTM)and thermal runaway(TR)mitigation is significant to improving the safety of lithium-ion battery systems.Inorganic phase change material(PCM)with nonflammability has the potential to achieve this dual function.This study proposed an encapsulated inorganic phase change material(EPCM)with a heat transfer enhancement for battery systems,where Na_(2)HPO_(4)·12H_(2)O was used as the core PCM encapsulated by silica and the additive of carbon nanotube(CNT)was applied to enhance the thermal conductivity.The microstructure and thermal properties of the EPCM/CNT were analyzed by a series of characterization tests.Two different incorporating methods of CNT were compared and the proper CNT adding amount was also studied.After preparation,the battery thermal management performance and TR propagation mitigation effects of EPCM/CNT were further investigated on the battery modules.The experimental results of thermal management tests showed that EPCM/CNT not only slowed down the temperature rising of the module but also improved the temperature uniformity during normal operation.The peak battery temperature decreased from 76℃to 61.2℃at 2 C discharge rate and the temperature difference was controlled below 3℃.Moreover,the results of TR propagation tests demonstrated that nonflammable EPCM/CNT with good heat absorption could work as a TR barrier,which exhibited effective mitigation on TR and TR propagation.The trigger time of three cells was successfully delayed by 129,474 and 551 s,respectively and the propagation intervals were greatly extended as well.

Hydrochemical characteristics and the ecological effect of algal carbonic anhydrase in carbon cycle in the Taiyuan section of Fenhe River

Water scarcity and pollution pose a threat to the sustainable development of cities and society.Therefore,it is crucial to analyze the hydrochemical characteristics and carbon dynamics of waterdeficient areas.Taking the Taiyuan section of Fenhe River as the research object,we systematically explored the hydrochemical characteristics of surface water and its evolutionary processes,as well as the ecological effect of algal carbonic anhydrase in carbon cycle using the hydrochemical evolution method and correlation analysis.The ternary diagram demonstrates that the main water chemical type in Fenhe River was SO^(2-)_(4)·Cl^(-)-Na^(+).The Gibbs and end-member diagrams of each ion display that the chemical composition of surface water was mainly controlled by silicate decomposition.The chemical ions originated mainly from dissolution of some minerals,such as plagioclase,halite,dolomite,calcite,and gypsum.The diatoms had a lower CO_(2)requirement because they exhibited a higher abundance at a lower partial pressure of CO_(2)(p CO_(2)).However,high CO_(2)concentration had a positive effect on cyanobacteria,which reduced the active transport of HCO_(3)^(-),saved the energy needed for this part of active transport,and indirectly improved the overall photosynthetic efficiency of algae.Carbonic anhydrase(CA)activity was significantly negatively correlated with p CO_(2)and positively correlated with HCO_(3)^(-)concentration,indicating that CA in water promoted the conversion of CO_(2)to HCO_(3)^(-).The HCO_(3)^(-)generated from this process continued to participate in the erosion of silicate rocks,sequestering CO_(2)in the form of Ca CO_(3),which has a non-negligible impact on the carbon sink in the Fenhe River.These consequences may have important implications for the biogeochemical cycling occurring in urban water.

Inorganic Carbon Utilization in Some Marine Phytoplankton Species

In order to learn the ways and possible utilization mechanisms of dissolved inorganic carbon (DIC) in marine phytoplankton species under carbon-replete or -limited conditions, the activity of extracellular carbonic anhydrase (CA) was assayed in different pH, CO 2 and DIC concentrations. Extracellular CA in Amphidinium carterae and Prorocentrum minimum was detected under carbon-replete conditions, while in Melosira sp., Phaeodactylum tricornutum, Skeletonema costatum, Thalassiosira rotula, Emiliania huxleyi and Pleurochrysis carterae, CA activity was assayed under conditions of carbon limitation. No CA activity was found even under carbon-limited conditions in Chaetoceros compressus, Glenodinium foliaceum, Coccolithus pelagicus, Gephrocapsa oceanica and Heterosigma akashiwo. In species without extracellular CA activity, the direct HCO - 3 uptake was investigated using a pH drift technique and the anion exchange inhibitor 4′4′-diisothiocyanatostilbene-2,2-disulfonic acid (DIDS) in a closed system. The result showed that direct HCO - 3 transport might occur by an anion exchange mechanism in species Coc. pelagicus and G. oceanica. Of the 13 species investigated, only H. akashiwo did not have the potential for direct uptake or extracellular CA-catalyzed HCO - 3 utilization.

Photosynthetic Responses to Inorganic Carbon in Ulva lactuca Under Aquatic and Aerial States

Intertidal macroalgae experience continual alternation of photosynthesis between aquatic state at high tide and aerial state at low tide. The comparative photosynthetic responses to inorganic carbon were investigated in the common intertidal macroalga Ulva lactuca L. along the coast of Shantou between aquatic and aerial state. The inorganic carbon dissolved in seawater at present could fully (at 10 ℃ or 20 ℃) or nearly (at 30 ℃) saturate the aquatic photosynthesis of U. lactuca . However, the aerial photosynthesis was limited by current ambient atmospheric CO 2 level, and such a limitation was more severe at higher temperature (20-30 ℃) than at lower temperature (10 ℃). The carbon_saturated maximal photosynthesis of U. lactuca under aerial state was much greater than that under aquatic state at 10 ℃ and 20 ℃, while the maximal photosynthesis under both states was similar at 30 ℃. The aerial values of K m (CO 2) for photosynthesis were higher than the aquatic values. On the contrary, the values of apparent photosynthetic CO 2 conductance under aerial state were considerably lower than that under aquatic state. It was concluded that the increase of atmospheric CO 2 would enhance the primary productivity of U. lactuca through stimulating the photosynthesis under aerial state during low tide.

Effect of inorganic carbon on anaerobic ammonium oxidation enriched in sequencing batch reactor

The present lab-scale research reveals the enrichment of anaerobic ammonium oxidation microorganism from methanogenic anaerobic granular sludge and the effect of inorganic carbon(sodium bicarbonate)on anaerobic ammonium oxidation.The enrichment of anammox bacteria was carried out in a 7.0-L sequencing batch reactor(SBR)and the effect of bicarbonate on anammox was conducted in a 3.0-L SBR.Research results,especially the biomass,showed first signs of anammox activity after 54 d cultivation with synthetic wast...

Lower Triassic Inorganic Carbon Isotope Excursion in Chaohu, Anhui Province, China

This paper reports a Lower Triassic inorganic carbon isotope profile from the North Pingdingshan Section in Chaohu, Anhui Province, China, which was situated in a deep part of the Lower Yangtze carbonate ramp. The δ ( 13 C) excursion shows two periods from the Permian Triassic boundary to the lower Spathian substage, corresponding to the ecosystem undergoing evolution and recovery after the end Permian mass extinction and related events. The first period starts at the δ ( 13 C) depletion caused by the mass extinction and evolves with a gradual δ ( 13 C) increase resulting from the development of some disaster taxa during the Induan. The strong Smithian δ ( 13 C) depletion in the second period might be formed by the collapse of the disaster ecosystem and the biotic recovery occurred with the explosive increase of bioproductivity in the Spathian. Thus the δ ( 13 C) excursion in the Lower Triassic expresses patterns of biotic evolution and recovery during the erratic ecosystem that followed the great end Permian mass extinction.

Stable isotopic composition of riverine dissolved inorganic carbon of the Xijiang River Inner Estuary

For researching the spatio-temporal variation of the stable isotopic composition of the riverine dissolved inorganic carbon（DIC）,we had carried out a survey throughout the hydrologic year during which theδ^13CDIC of the surface water and its physicochemical parameter were examined along the Xijiang River Inner Estuarine waterway from September 2006 to June 2007.There was a striking seasonal variation on the averageδ^13CDIC,as the averageδ^13CDIC in summer（-13.91‰）or autumn（-13.09‰）was much less than those in spring（-11.71‰）or winter（-12.26‰）.The riverineδ13C DIC was controlled by decomposed condition of the riverine organic matter linking the seasonal variation of the physicochemical parameter in the surface water according to the correlation analysis which indicated notable relations betweenδ^13CDIC and water temperature（p=0.000;r=-0.569）or betweenδ^13CDIC and oxide-reduction potential（p=0.000;r=0.646）.The striking positive correlation between δ^13CDIC and the sampling distance happened in the summer rainy season,while striking negative correlation happened in the spring dry season,indicating that river-sea interaction influenced water physicochemical parameters and controlled the riverine DIC property in the survey waterway.In view of the riverineδ^13CDIC decreasing for the decomposition of the terrestrial organic matter in the rainy season in summer and increasing for the briny invaded zone extending in the spring dry season along the waterway from the Makou gauging station to the Modaomen outlet,theδ^13CDIC spatio-temporal variation was closely related to the geographical environment of the Xijiang drainage basin.

The Effects of Estuarine Processes on the Fluxes of Inorganic and Organic Carbon in the Yellow River Estuary

Riverine carbon flux is an important component of the global carbon cycle. The spatial and temporal variations of organic and inorganic carbon were examined during both dry and wet seasons in the Yellow River estuary. Concentrations of dissolved organic carbon （DOC） and dissolved inorganic carbon （DIC） in the Yellow River during dry seasons were higher than those during wet seasons. The effective concentrations of DOC （CDOC＊） were higher than the observed DOC at zero salinity. This input of DOC in the Yellow River estuary was due to sediment desorption processes in low salinity regions. In contrast to DOC, the effective concen- trations of DIC were 10% lower than the DIC measured at freshwater end, and the loss of DIC was caused by CaCO3 precipitation in low salinity region, Particulate organic carbon （POC） and particulate inorganic carbon （PIC） contents of the particles stabilized to constant values （0.5%：t：0.05% and 1.8%--0.2%, respectively） within the turbidity maximum zone （TMZ） and showed no noticeable seasonal variations. A rapid drop of PIC and rise of POC occurred simultaneously outside the TMZ due to an intense dilution of riv- erine inorganic-rich particles being transported into a pool of aquatic organic-poor particles outside the TMZ. Annually, the Yellow River transported 6.95× 10^5 t of DIC, 0.64× 10^5 t of DOC, 78.58× 10^5 t of PIC and 2.29× 10^5 t of POC to the sea.

Damming effects on dissolved inorganic carbon in different kinds of reservoirs in Jialing River,Southwest China

To assess the effects of river damming on dissolved inorganic carbon in the Jialing River, a total of 40 water samples, including inflow, outflow, and stratified water in four cascade reservoirs(Tingzikou, Xinzheng,Dongxiguan, Caojie) were collected in January and July,2016. The major cations, anions, and δ^(13)C_(DIC) values were analyzed. It was found that the dissolved compositions are dominated by carbonate weathering, while sulfuric acids may play a relatively important role during carbonate weathering and increasing DIC concentration. Different reservoirs had variable characteristics of water physiochemical stratification. The DIC concentrations of reservoir water were lower in summer than those in winter due to the dilute effects and intensive aquatic photosynthesis, as well as imported tributaries. The δ^(13)C_(DIC) values in Tingzikou Reservoir were higher during summer than those in winter,which indicated that intensive photosynthesis increased the δ^(13)C_(DIC) values in residual water, but a similar trend was not obvious in other reservoirs. Except for in Xinzheng Reservoir, the δ^(13)C_(DIC) values in inflow and outflow reservoir water were lower than those in the surface water of stratified sampling in summer. For stratified sampling, it could be found that, in summer, the Tingzikou Reservoir δ^(13)C_(DIC) values significantly decreased with water depthdue to the anaerobic breakdown of organic matter. The significant correlation(p<0.01 or 0.05) between the DIC concentrations, the δ^(13)C_(DIC) values and anthropogenic species(Na^++K^+, Cl~–, SO_4^(2-) and NO_3^-) showed that the isotope composition of DIC can be a useful tracer of contaminants. In total, Tingzikou Reservoir showed lacustrine features, Xinzheng Reservoir and Dongxiguan Reservoir had "transitional'' features, and Caojie Reservoir had a total of "fluvial'' features. Generally, cascade reservoirs in the Jialing River exhibited natural river features rather than typical lake features due to characteristics of reservoir water in physiochemical stratification, spatiotemporal variations of DIC concentrations and isotopic compositions. It is evident that the dissolved inorganic carbon dynamics of natural rivers had been partly remolded by dam building.

Inorganic Carbon Parameters Responding to Summer Hypoxia Outside the Changjiang Estuary and the Related Implications

The eutrophication, hypoxia and coastal acidification are attracting more and more attention. In this study, inorganic carbon parameters, including dissolved inorganic carbon （DIC）, total alkalinity （TA） and calculated partial pressure of CO2 （pCO2）, obtained from a summer cruise in August, 2009, were used to investigate their integrated response to biological processes accompanying the oxygen depletion in the areas off the Changjiang Estuary. According to the observations, the typical hypoxia occurred in the bottom water just outside the Changjiang Estuary with Dissolved Oxygen （DO） lower than 2.00 mg L^-1. The biological uptake in the surface water and the decomposition of organic matter in the bottom water were fully coupled with each other. The high concentration of Chl_a （Chl_a = 10.9μgL^-1） and DO （9.25 mgL^-1）, profoundly decreased DIC concentration 0828 μmolkg^-1） and elevated pH （8.42） was observed in the surface water. The correspondingly increased DIC and depletion of oxygen were observed in the bottom water. The semi-quantitative analysis proved that the locally-produced phytoplankton, determined by primary productivity, was deposited to the bottom and contributed about 76% of total amount of the organic carbon decomposition in the bottom. However, in the bottom hypoxia （DO = 2.05 mgL^-1） area observed in the Southern Zhejiang coastal water, the responding patterns of inorganic carbon parameters deviated from the previous one. The expanding of Changjiang Diluted Water （CDW）, the adding of Hangzhou Bay water （with high DIC concentration） and Coastal Current together modify the DIC background value in this area, and the local degeneration and upwelling process may also help to offset the local DIC removed by net biological uptake in surface water. In addition when the mixing occurring in autumn, which may break the summer stratification, the excess release of high DIC in the bottom water to the subsurface water could have an important influence on coastal acidification and the CO2 uptake capacity in this area.

Soil resource availability impacts microbial response to organic carbon and inorganic nitrogen inputs

Impacts of newly added organic carbon （C） and inorganic nitrogen （N） on the microbial utilization of soil organic matter are important in determining the future C balance of terrestrial ecosystems. We examined microbial responses to cellulose and ammonium nitrate additions in three soils with very different C and N availability. These soils included an organic soil（ 14.2% total organic C, with extremely high extractable N and low labile C）, a forest soi1（4.7% total organic C, with high labile C and extremely low extractable N）, and a grassland soil（1.6% total organic C, with low extractable N and labile C）. While cellulose addition alone significantly enhanced microbial respiration and biomass C and N in the organic and grassland soils, it accelerated only the microbial respiration in the highly-N limited forest soil. These results indicated that when N was not limited, C addition enhanced soil respiration by stimulating both microbial growth and their metabolic activity, New C inputs lead to elevated C release in all three soils, and the magnitude of the enhancement was higher in the organic and grassland soils than the forest soil. The addition of cellulose plus N to the forest and grassland soils initially increased the microbial biomass and respiration rates, but decreased the rates as time progressed. Compared to cellulose addition alone, cellulose plus N additions increased the total C-released in the grassland soil, but not in the forest soil. The enhancement of total C- released induced by C and N addition was less than 50% of the added-C in the forest soil after 96 d of incubation, in contrast to 87.5% and 89.0% in the organic and grassland soils. These results indicate that indigenous soil C and N availability substantially impacts the allocation of organic C for microbial biomass growth and/or respiration, potentially regulating the turnover rates of the new organic C inputs.

Photochemical production of dissolved inorganic carbon from suwannee river humic acid

The photochemical mineralization of dissolved organic carbon(DOC) to dissolved inorganic carbon(DIC) is a key process in carbon cycling.Using a Suntest CPS solar simulator,Suwannee River humic acid(SRHA) was photooxidated to examine the effects of O2 levels,the wavelength of incident light,and the concentration of Fe on the photoproduction of DIC.Increasing the O2 abundance enhanced photodegradation of SRHA.The rate of DIC photoproduction under air saturation in the first 24 h(4.40 μmol/(L h)) was increased by a factor of 1.56 under O2 saturation,but fell by only 36% under N2 saturation.To evaluate the relative importance of UV-B,UV-A,and visible radiation in the photodegradation,we examined the above process using Mylar-d films and UF-3 and UF-4 plexiglass filters.The results indicated that the UV-B,UV-A and visible wavelengths accounted for 31.8%,32.6% and 25.6%,respectively,of DIC production with simulated sunlight irradiation.The above results also indicated that photoproduction of DIC could take place in natural water at depths greater than those that UV light can reach.When 20 μmol/L desferrioxamine mesylate(DFOM,a strong Fe complexing ligand) was added,the rate of DIC photoproduction fell to 55.6% that of the original SRHA samples with 5.46 μmol/L Fe.

Sources of dissolved inorganic carbon in rivers from the Changbaishan area, an active volcanic zone in North Eastern China

Major elements and carbon isotopes of dissolved inorganic carbon(DIC)have been measured in the waters of Changbaishan mountain,a volcanic area in northeastern China,between June and September 2016 to decipher the origin of the CO_2 involved in chemical weathering reactions.Spatial variations of major elements ratios measured in water samples can be explained by a change of the chemical composition of the volcanic rocks between the volcanic cone(trachytes)and the basaltic shield as evidenced by the variations in the composition of these rocks.Hence,DIC results from the neutralization of CO_2 by silicate rocks.DIC concentrations vary from 0.3 to 2.5 mmol/L and carbon isotopic compositions of DIC measured in rivers vary from-14.2‰to 3.5‰.At a first order,the DIC transported by rivers is derived from the chemical weathering’s consumption of CO_2 with a magmatic origin,enriched in^(13)C(-5%)and biogenic soil CO_2 with lower isotopic compositions.The highest δ^(13)C values likely result from C isotopes fractionation during CO_2 degassing in rivers.A mass balance based on carbon isotopes suggest that the contribution of magmatic CO_2 varied from less than 20%to more than 70%.Uncertainties in this calculation associated with CO_2 degassing in rivers are difficult to quantify,and the consequence of CO_2 degassing would be an overestimation of the contribution of DIC derived from the neutralization of magmatic CO_2 by silicate rocks.

Pitfalls of acid leaching method for determining organic and inorganic carbon contents in marine sediments

Organic and inorganic carbon contents of marine sediments are important to reconstruct marine productivity,global carbon cycle, and climate change. A proper method to separate and determine organic and inorganic carbons is thus of great necessity. Although the best method is still disputable, the acid leaching method is widely used in many laboratories because of its ease-of-use and high accuracy. The results of the elemental analysis of sediment trap samples reveal that organic and inorganic carbon contents cannot be obtained using the acid leaching method, causing an infinitely amplified error when the carbon content of the decarbonated sample is 12%±1% according to a mathematical derivation. Acid fumigation and gasometric methods are used for comparison, which indicates that other methods can avoid this problem in organic carbon analysis. For the first time, this study uncovers the pitfalls of the acid leaching method, which limits the implication in practical laboratory measurement, and recommends alternative solutions of organic/inorganic carbon determination in marine sediments.

Distribution of Dissolved Inorganic Carbon (DIC) and Its Related Parameters in Seawater of the North Yellow Sea and off the Qingdao Coast in October, 2007

Data on the distribution of dissolved inorganic carbon (DIC) were obtained from two cruises in the North Yellow Sea (NYS) and off the Qingdao Coast (QC) in October, 2007. Carbonate parameters were calculated. The concentrations of DIC are from 1.896-2.229 mmolL-1 in the NYS and from 1.939-2.032 mmolL-1 off the QC. In the southwest of the NYS, DIC in the upper layers decreases from the north of the SP (Shandong Peninsula) shelf to the center of the NYS; whereas in the lower layers DIC increases from the north of the SP shelf to the center of the NYS and South Yellow Sea. In the northeast of the NYS, DIC in all layers in- creases from the YR (Yalu River) estuary to the centre of the NYS. The distribution of DIC in NYS can be used as an indicator of Yellow Sea Cold Water Mass (YSCWM). Air-sea CO2 fluxes were calculated using three models and the results suggest that both the NYS and the QC waters are potential sources of atmospheric CO2 in October.

Hierarchical responses of soil organic and inorganic carbon dynamics to soil acidification in a dryland agroecosystem,China

Soil acidification is a major global issue of sustainable development for ecosystems. The increasing soil acidity induced by excessive nitrogen （N） fertilization in farmlands has profoundly impacted the soil carbon dynamics. However, the way in which changes in soil pH regulating the soil carbon dynamics in a deep soil profile is still not well elucidated. In this study, through a 12-year field N fertilization experiment with three N fertilizer treatments （0, 120, and 240 kg N/（hm-2·a）） in a dryland agroecosystem of China, we explored the soil pH changes over a soil profile up to a depth of 200 cm and determined the responses of soil organic carbon （SOC） and soil inorganic carbon （SIC） to the changed soil pH. Using a generalized additive model, we identified the soil depth intervals with the most powerful statistical relationships between changes in soil pH and soil carbon dynamics. Hierarchical responses of SOC and SIC dynamics to soil acidification were found. The results indicate that the changes in soil pH explained the SOC dynamics well by using a non-linear relationship at the soil depth of 0-80 cm （P=0.006）, whereas the changes in soil pH were significantly linearly correlated with SIC dynamics at the 100-180 cm soil depth （P=0.015）. After a long-term N fertilization in the experimental field, the soil pH value decreased in all three N fertilizer treatments. Furthermore, the declines in soil pH in the deep soil layer （100-200 cm） were significantly greater （P=0.035） than those in the upper soil layer （0-80 cm）. These results indicate that soil acidification in the upper soil layer can transfer excess protons to the deep soil layer, and subsequently, the structural heterogeneous responses of SOC and SIC to soil acidification were identified because of different buffer capacities for the SOC and SIC. To better estimate the effects of soil acidification on soil carbon dynamics, we suggest that future investigations for soil acidification should be extended to a deeper soil depth, e.g., 200 cm.

The influence of macronitrogen (NO_3^- and NH_4^+) addition with U lva pertusa on dissolved inorganic carbon system

The influence of macronitrogen （NO3 and NH＋） addition with Ulva pertusa on dissolved inorganic carbon system in seawater was studied. The results indicate that p（C02） and HCO3 concentration decrease significantly, while pH and CO32- concentration increase significantly. When the con- centration of NO3 was less than 71 μmol/dm3 or NH4＋ was less than 49.7μmol/dm3, dissolved inorganic carbon （DIC） absorption rates by Ulva pertusa generally increased with the increasing of nitrogen concentration. The DIC decreased 151 μmol/dm3 with the addition of 71 μmol/dm3 NO3 and decreased 232 μmol/dm3 with the addition of 49.7 μmol/dm3 NH＋ after the experiment compared with DIC measured without nitrogen addition. A significant negative-correlation was found between Ac（DIC） and growth rate （#） of Ulva pertusa （r =- 0.91, P 〈0.000 1, n=11）. NH＋ had more influence on the species of inorganic carbon system than NO3.

Forms and functions of inorganic carbon in the Jiaozhou Bay sediments

Inorganic carbon forms and their influencing factors, mutual transformation and contribution to carbon cycling in the Jiaozhou Bay sediments were discussed. The results show that inorganic carbon in sediments could be divided into five forms： NaCl form, NH3-H20 form, NaOH form, NH20H-HCl form and HCI form. Thereinto, NH2OH.HCl form and HCl form account for more than 70% of total inorganic carbon. There was close relationship among every form of inorganic carbon and their correlativity was clearly different with different sedimentary environment except the similar strong positive correlation among NH-OH-HCl form, HCl form and total inorganic carbon in all regions of the Jiaozhou Bay. All forms of inorganic carbon were influenced by organic carbon, pH, Eh, Es, nitrogen and phosphorus in sediments, but their influence had different characteristics in different regions. Every form of inorganic carbon transformed into each other continuously during early diagenesis of sediments and the common phenomenon was that NaCl form, NH3-H2O form, NaOH form and NH2OH-HCl form might transform into steady HCl form. NaCl form, NH3-H2O form, NaOH form and NH2OH-HCl form could participate in carbon recycle and they are potential carbon source; HCl form may be buried for a long time in sediments, and it may be one of the final resting places of atmospheric C02. Inorganic carbon which entered into sediments was about 4.98× 1010 g in the Jiaozhou Bay every year, in which about 1.47×1010 g of inorganic carbon might be buried for a long time and about 3.51 × 1010 g of inorganic carbon might return into seawater and take part in carbon recycling.

Iron and inorganic carbon in Liaodong Gulf sediments of Bohai Sea in China

Iron in seawater is an essential trace metal for phytoplankton that plays an important role in the marine carbon cycle. But most studies focused on oceanic iron fertilization in high nutrient low chlorophyll （HNLC） seawaters. A study of inorganic carbon （IC） forms and its influencing factors was presented in Liaodong Gulf sediments, and especially the influence of iron was discussed in detail. Inorganic carbon in Liaodong Gulf sediments was divided into five forms： NaCl, NH3·H2O, NaOH, NH2OH·HCl and HCl. The concentration of NaCl and NaOH forms were similar and they only occupied the minority of total inorganic carbon （TIC）. However, NH3 ·H2O, NH2OH · HCl and HCl forms were the principal forms of TIC and accounted for more than 80% of TIC. Especially, the percentage of NH3·H2O form was much higher than that in the Changjiang River Estuary and Jiaozhou Bay sediments. All forms of inorganic carbon were influenced by organic carbon, pore water, iron, pH, redox potential （Eh） and sulfur potential（Es） in sediments, moreover, the influences had different characteristics for different IC forms. However, the redox reactions of iron affected mainly active IC forms. Iron had little effect on NH2OH· HCl and HCl forms of IC which were influenced mainly by pH. Iron had a stronger influence on NaCl, NaOH and NH3· H2O forms of IC ; the influence of Fe^2＋ was higher than Fe^3＋ and its effect on NH3 ·H2O form was stronger than on NaCl and NaOH forms.

Distributions of dissolved inorganic carbon and total alkalinity in the Western Arctic Ocean

The third Chinese National Arctic Research Expedition （3rd CHINARE-Arctic in 2008） was carried out from July to September 2008. During the survey, numerous sea water samples were taken for CO2 parameter measurement （including total alkalinity TA and total dissolved inorganic carbon DIC）.The distribution of COs parameters in the Western Arctic Ocean was determined, and the controlling factors are addressed. The ranges of summertime TA, normalized TA （nTA）, DIC and normalized DIC （nDIC） in the surface seawater were 1 757 2 229 umol.kg 1 2 383-2 722 umol.kg-1, 1 681 2 034 pmol.kg 1, 2 119--2 600 umol.kg-1, respectively. Because of dilution from ice meltwater, the surface TA and DIC concentrations were relatively low. TA in the upper 100 m to the south of 78°N had good correlation with salinity, showing a conservative behavior. The distribution followed the seawater-river mixing line at salinity 〉30, then followed the seawater mixing line （diluted by river water to salinity = 30） with the ice meltwater. The DIC distribution in the Chukchi Sea was dominated by biological production or respiration of organic matter, whereas conservative mixing dominated the mixed layer TA distribution in the ice-free Canada Basin.