期刊文献+
共找到5篇文章
< 1 >
每页显示 20 50 100
Inorganic matter in rice husk derived carbon and its effect on the capacitive performance
1
作者 Wanlu Li Meruyert Nazhipkyzy Teresa J.Bandosz 《Journal of Energy Chemistry》 SCIE EI CAS CSCD 2021年第6期639-649,I0016,共12页
Porous carbons were obtained from rice husk using two different chemical activation methods and they were investigated as supercapacitors.Their properties were studied using X-ray photoelectron spectroscopy,thermal an... Porous carbons were obtained from rice husk using two different chemical activation methods and they were investigated as supercapacitors.Their properties were studied using X-ray photoelectron spectroscopy,thermal analysis,potentiometric titration,and nitrogen adsorption isotherm.The specific capacitance measured in both H_(2) SO_(4) and KOH electrolytes in two-electrode cell was up to-150 F/g.The activation method used affected the resulting carbons’features.As expected,the dependence of the capacitance on porosity was found.The ash content reached 36 wt.%and that inorganic mater blocked some pores and limited their accessibility to electrolyte ions and increased the charge transfer resistance.Nevertheless,the main ash constituents such as CaCO_(3),MgCO_(3),Ca_(3)(PO_(4))2(or P_(2)O_(5)),and Fe-and Zn-containing species did not affect the specific capacitance to a large extent.Especially SiO2,even in a relatively large amount(~20 wt.%)T did not play a detrimental role in the capacitance behavior.The results showed that in spite of a high ash content,carbon can exhibit a good capacitive performance provided that it has a favorable porosity and is rich in sp_(2) configurations. 展开更多
关键词 inorganic matter Capacitive performance SIO2 CARBONATES Pore accessibility
下载PDF
Quantum chemical investigation on photodegradation mechanisms of sulfamethoxypyridazine with dissolved inorganic matter and hydroxyl radical 被引量:3
2
作者 Shaheen Shah Ce Hao 《Journal of Environmental Sciences》 SCIE EI CAS CSCD 2017年第7期85-92,共8页
Sulfamethoxypyridazine(SMP) is one of the commonly used sulfonamide antibiotics(SAs).SAs are mainly studied to undergo triplet-sensitized photodegradation in water under natural sunlight with other coexisting aqua... Sulfamethoxypyridazine(SMP) is one of the commonly used sulfonamide antibiotics(SAs).SAs are mainly studied to undergo triplet-sensitized photodegradation in water under natural sunlight with other coexisting aquatic environmental organic pollutants.In this work,SMP was selected as a representative of SAs.We studied the mechanisms of triplet-sensitized photodegradation of SMP and the influence of selected dissolved inorganic matter,i.e.,anions(Br^-,Cl^-,and NO^-_3) and cations ions(Ca^(2+),Mg^(2+),and Zn^(2+)) on SMP photodegradation mechanism by quantum chemical methods.In addition,the degradation mechanisms of SMP by hydroxyl radical(OH·) were also investigated.The creation of SO_2 extrusion product was accessed with two different energy pathways(pathway-1 and pathway-2) by following two steps(step-I and step-II) in the tripletsensitized photodegradation of SMP.Due to low activation energy,the pathway-1 was considered as the main pathway to obtain SO_2 extrusion product.Step-II of pathway-1 was measured to be the rate-limiting step(RLS) of SMP photodegradation mechanism and the effect of the selected anions and cations was estimated for this step.All selected anions and cations promoted photodegradation of SMP by dropping the activation energy of pathway-1.The estimated low activation energies of different degradation pathways of SMP with OH·radical indicate that OH·radical is a very powerful oxidizing agent for SMP degradation via attack through benzene derivative and pyridazine derivative ring. 展开更多
关键词 Sulfamethoxypyridazine Photodegradation mechanism Dissolved inorganic matter Hydroxyl radical DFT
原文传递
Formation,evolution,reconstruction of black shales and their influence on shale oil and gas resource
3
作者 Shi-zhen Li Qiu-chen Xu +11 位作者 Mu Liu Guo-heng Liu Yi-fan Li Wen-yang Wang Xiao-guang Yang Wei-bin Liu Yan-fei An Peng Sun Tao Liu Jiang-hui Ding Qian-chao Li Chao-gang Fang 《China Geology》 CAS CSCD 2024年第3期551-585,共35页
Black shales are important products of material cycling and energy exchange among the lithosphere,atmosphere,hydrosphere,and biosphere.They are widely distributed throughout geological history and provide essential en... Black shales are important products of material cycling and energy exchange among the lithosphere,atmosphere,hydrosphere,and biosphere.They are widely distributed throughout geological history and provide essential energy and mineral resources for the development of human society.They also record the evolution process of the earth and improve the understanding of the earth.This review focuses on the diagenesis and formation mechanisms of black shales sedimentation,composition,evolution,and reconstruction,which have had a significant impact on the formation and enrichment of shale oil and gas.In terms of sedimentary environment,black shales can be classified into three types:Marine,terrestrial,and marine-terrestrial transitional facies.The formation processes include mechanisms such as eolian input,hypopycnal flow,gravity-driven and offshore bottom currents.From a geological perspective,the formation of black shales is often closely related to global or regional major geological events.The enrichment of organic matter is generally the result of the interaction and coupling of several factors such as primary productivity,water redox condition,and sedimentation rate.In terms of evolution,black shales have undergone diagenetic evolution of inorganic minerals,thermal evolution of organic matter and hydrocarbon generation,interactions between organic matter and inorganic minerals,and pore evolution.In terms of reconstruction,the effects of fold deformation,uplift and erosion,and fracturing have changed the stress state of black shale reservoirs,thereby having a significant impact on the pore structure.Fluid activity promotes the formation of veins,and have changed the material composition,stress structure,and reservoir properties of black shales.Regarding resource effects,the deposition of black shales is fundamental for shale oil and gas resources,the evolution of black shales promotes the shale oil and gas formation and storage,and the reconstruction of black shales would have caused the heterogeneous distribution of oil and gas in shales.Exploring the formation mechanisms and interactions of black shales at different scales is a key to in-depth research on shale formation and evolution,as well as the key to revealing the mechanism controlling shale oil and gas accumulation.The present records can reveal how these processes worked in geological history,and improve our understanding of the coupling mechanisms among regional geological events,black shales evolution,and shale oil and gas formation and enrichment. 展开更多
关键词 Black shales Shale oil and gas Resource effects Sedimentary environment Sedimentary process Organic matter accumulation Diagenetic evolution Thermal evolution Organic matter and inorganic minerals Tectonic reconstruction Oil and gas exploration engineering VEINS Fluid activity
下载PDF
hale gas reservoir modeling and production evaluation considering complex gas transport mechanisms and dispersed distribution of kerogen 被引量:3
4
作者 Jie Zeng Jishan Liu +3 位作者 Wai Li Yee-Kwong Leong Derek Elsworth Jianchun Guo 《Petroleum Science》 SCIE CAS CSCD 2021年第1期195-218,共24页
Stimulated shale reservoirs consist of kerogen,inorganic matter,secondary and hydraulic fractures.The dispersed distribution of kerogen within matrices and complex gas flow mechanisms make production evaluation challe... Stimulated shale reservoirs consist of kerogen,inorganic matter,secondary and hydraulic fractures.The dispersed distribution of kerogen within matrices and complex gas flow mechanisms make production evaluation challenging.Here we establish an analytical method that addresses kerogen-inorganic matter gas transfer,dispersed kerogen distribution,and complex gas flow mechanisms to facilitate evaluating gas production.The matrix element is defined as a kerogen core with an exterior inorganic sphere.Unlike most previous models,we merely use boundary conditions to describe kerogen-inorganic matter gas transfer without the instantaneous kerogen gas source term.It is closer to real inter-porosity flow conditions between kerogen and inorganic matter.Knudsen diffusion,surface diffusion,adsorption/desorption,and slip corrected flow are involved in matrix gas flow.Matrix-fracture coupling is realized by using a seven-region linear flow model.The model is verified against a published model and field data.Results reveal that inorganic matrices serve as a major gas source especially at early times.Kerogen provides limited contributions to production even under a pseudo-steady state.Kerogen properties’influence starts from the late matrix-fracture inter-porosity flow regime,while inorganic matter properties control almost all flow regimes except the early-mid time fracture linear flow regime.The contribution of different linear flow regions is also documented. 展开更多
关键词 Analytical solution Shale gas reservoir Well performance Kerogen and inorganic matter
下载PDF
Comparison of inorganic chemical compositions of atmospheric TSP,PM10 and PM2.5 in northern and southern Chinese coastal cities 被引量:3
5
作者 Yiding Ma Zongshuang Wang +5 位作者 Yufei Tan Shu Xu Shaofei Kong Gang Wu Xuefang Wu Hong Li 《Journal of Environmental Sciences》 SCIE EI CAS CSCD 2017年第5期339-353,共15页
To compare the inorganic chemical compositions of TSP(total suspended paniculate),PM10(particulate matter with an aerodynamic diameter less than 10 μm) and PM2.5(particulate matter with an aerodynamic diameter l... To compare the inorganic chemical compositions of TSP(total suspended paniculate),PM10(particulate matter with an aerodynamic diameter less than 10 μm) and PM2.5(particulate matter with an aerodynamic diameter less than 2.5 μm) in southern and northern cities in China,atmospheric particles were synchronously collected in Dalian(the northern city)and Xiamen(the southern city) in spring and autumn of 2004.The mass concentrations,twenty-three elements and nine soluble ions were assessed.The results show that in Dalian,the mass concentrations of Mg,Al,Ca,Mn and Fe in spring were 4.0-10.1,2.6-8.0,4.1-12,1.2-3.6 and 2.9-7.9 times higher,respectively,than those in Xiamen.The dust storm influence is more obvious in Dalian in spring.However,in Xiamen,heavy metals accounted for 13.9%-17.9%of TSP,while heavy metals contributed to 5.5%-9.3%of TSP in Dalian.These concentrations suggest that heavy metal pollution in Xiamen was more serious.In addition,the concentrations of Na+,Cl-,Ca2+ and Mg2+ were higher in Dalian due to the influence of marine aerosol,construction activities and soil dust.The NO3-/SO42- ratios in Dalian(0.25-0.49) were lower than those in Xiamen(0.51-0.62),indicating that the contributions of vehicle emission to particles in Xiamen were higher.Coefficient of divergence values was higher than 0.40,implying that the inorganic chemical composition profiles for the particles of Dalian and Xiamen were quite different from each other. 展开更多
关键词 Particulate matter inorganic chemical compositions Differences Dalian city Xiamen city
原文传递
上一页 1 下一页 到第
使用帮助 返回顶部