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Experimental evaluation of the salt dissolution in inter-salt shale oil reservoirs
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作者 YANG Zhengming LI Ruishan +4 位作者 LI Haibo LUO Yutian CHEN Ting GAO Tiening ZHANG Yapu 《Petroleum Exploration and Development》 2020年第4期803-809,共7页
By using salt dissolution experiment,imbibition experiment and high temperature and high pressure nuclear magnetic resonance(NMR)on-line test,the evaluation methods for salt dissolution of inter salt shale oil-bearing... By using salt dissolution experiment,imbibition experiment and high temperature and high pressure nuclear magnetic resonance(NMR)on-line test,the evaluation methods for salt dissolution of inter salt shale oil-bearing cores were established,and the effects of salt dissolution on spontaneous imbibition and permeability were analyzed.The intensity of salt dissolution is quantitatively evaluated by comparing the signal quantity and distribution characteristics of T2 spectrum(transverse relaxation time)measured at different times.In salt dissolution experiment,salt in the core is gradually dissolved as the injected water is continuously immersed in the core.The spontaneous imbibition experiment of inter-salt shale oil-bearing core can be divided into three stages:strong imbibition and weak salt dissolution,strong salt dissolution promoting imbibition,and weak salt dissolution and weak imbibition.The salt dissolution in spontaneous imbibition is very obvious,and the salt dissolution contributes more than 60%of recovery.The micro-pore structure in different cross sections or different parts of inter-salt shale oil-bearing core isn’t uniform,and the pore volume,porosity and permeability increase after salt dissolution. 展开更多
关键词 shale oil salt dissolution IMBIBITION physical simulation nuclear magnetic resonance
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Identification and evaluation of shale oil micromigration and its petroleum geological significance 被引量:2
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作者 HU Tao JIANG Fujie +10 位作者 PANG Xiongqi LIU Yuan WU Guanyun ZHOU Kuo XIAO Huiyi JIANG Zhenxue LI Maowen JIANG Shu HUANG Liliang CHEN Dongxia MENG Qingyang 《Petroleum Exploration and Development》 SCIE 2024年第1期127-140,共14页
Taking the Lower Permian Fengcheng Formation shale in Mahu Sag of Junggar Basin,NW China,as an example,core observation,test analysis,geological analysis and numerical simulation were applied to identify the shale oil... Taking the Lower Permian Fengcheng Formation shale in Mahu Sag of Junggar Basin,NW China,as an example,core observation,test analysis,geological analysis and numerical simulation were applied to identify the shale oil micro-migration phenomenon.The hydrocarbon micro-migration in shale oil was quantitatively evaluated and verified by a self-created hydrocarbon expulsion potential method,and the petroleum geological significance of shale oil micro-migration evaluation was determined.Results show that significant micro-migration can be recognized between the organic-rich lamina and organic-poor lamina.The organic-rich lamina has strong hydrocarbon generation ability.The heavy components of hydrocarbon preferentially retained by kerogen swelling or adsorption,while the light components of hydrocarbon were migrated and accumulated to the interbedded felsic or carbonate organic-poor laminae as free oil.About 69% of the Fengcheng Formation shale samples in Well MY1 exhibit hydrocarbon charging phenomenon,while 31% of those exhibit hydrocarbon expulsion phenomenon.The reliability of the micro-migration evaluation results was verified by combining the group components based on the geochromatography effect,two-dimension nuclear magnetic resonance analysis,and the geochemical behavior of inorganic manganese elements in the process of hydrocarbon migration.Micro-migration is a bridge connecting the hydrocarbon accumulation elements in shale formations,which reflects the whole process of shale oil generation,expulsion and accumulation,and controls the content and composition of shale oil.The identification and evaluation of shale oil micro-migration will provide new perspectives for dynamically differential enrichment mechanism of shale oil and establishing a“multi-peak model in oil generation”of shale. 展开更多
关键词 shale oil micro-migration identification micro-migration evaluation Junggar Basin Mahu Sag Lower Permian Fengcheng Formation hydrocarbon expulsion potential method
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Geologic characteristics,exploration and production progress of shale oil and gas in the United States:An overview
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作者 MCMAHON T P LARSON T E +1 位作者 ZHANG T SHUSTER M 《Petroleum Exploration and Development》 SCIE 2024年第4期925-948,共24页
We present a systematic summary of the geological characteristics,exploration and development history and current state of shale oil and gas in the United States.The hydrocarbon-rich shales in the major shale basins o... We present a systematic summary of the geological characteristics,exploration and development history and current state of shale oil and gas in the United States.The hydrocarbon-rich shales in the major shale basins of the United States are mainly developed in six geological periods:Middle Ordovician,Middle-Late Devonian,Early Carboniferous(Middle-Late Mississippi),Early Permian,Late Jurassic,and Late Cretaceous(Cenomanian-Turonian).Depositional environments for these shales include intra-cratonic basins,foreland basins,and passive continental margins.Paleozoic hydrocarbon-rich shales are mainly developed in six basins,including the Appalachian Basin(Utica and Marcellus shales),Anadarko Basin(Woodford Shale),Williston Basin(Bakken Shale),Arkoma Basin(Fayetteville Shale),Fort Worth Basin(Barnett Shale),and the Wolfcamp and Leonardian Spraberry/Bone Springs shale plays of the Permian Basin.The Mesozoic hydrocarbon-rich shales are mainly developed on the margins of the Gulf of Mexico Basin(Haynesville and Eagle Ford)or in various Rocky Mountain basins(Niobrara Formation,mainly in the Denver and Powder River basins).The detailed analysis of shale plays reveals that the shales are different in facies and mineral components,and"shale reservoirs"are often not shale at all.The United States is abundant in shale oil and gas,with the in-place resources exceeding 0.246×10^(12)t and 290×10^(12)m^(3),respectively.Before the emergence of horizontal well hydraulic fracturing technology to kick off the"shale revolution",the United States had experienced two decades of exploration and production practices,as well as theory and technology development.In 2007-2023,shale oil and gas production in the United States increased from approximately 11.2×10^(4)tons of oil equivalent per day(toe/d)to over 300.0×10^(4)toe/d.In 2017,the shale oil and gas production exceeded the conventional oil and gas production in the country.In 2023,the contribution from shale plays to the total U.S.oil and gas production remained above 60%.The development of shale oil and gas has largely been driven by improvements in drilling and completion technologies,with much of the recent effort focused on“cube development”or“co-development”.Other efforts to improve productivity and efficiency include refracturing,enhanced oil recovery,and drilling of“U-shaped”wells.Given the significant resources base and continued technological improvements,shale oil and gas production will continue to contribute significant volumes to total U.S.hydrocarbon production. 展开更多
关键词 United States shale oil shale gas shale reservoirs unconventional reservoirs oil and gas production resource assessment
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“Component flow”conditions and its effects on enhancing production of continental medium-to-high maturity shale oil
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作者 ZHAO Wenzhi BIAN Congsheng +8 位作者 LI Yongxin LIU Wei QIN Bing PU Xiugang JIANG Jianlin LIU Shiju GUAN Ming DONG Jin SHEN Yutan 《Petroleum Exploration and Development》 SCIE 2024年第4期826-838,共13页
Based on the production curves,changes in hydrocarbon composition and quantities over time,and production systems from key trial production wells in lacustrine shale oil areas in China,fine fraction cutting experiment... Based on the production curves,changes in hydrocarbon composition and quantities over time,and production systems from key trial production wells in lacustrine shale oil areas in China,fine fraction cutting experiments and molecular dynamics numerical simulations were conducted to investigate the effects of changes in shale oil composition on macroscopic fluidity.The concept of“component flow”for shale oil was proposed,and the formation mechanism and conditions of component flow were discussed.The research reveals findings in four aspects.First,a miscible state of light,medium and heavy hydrocarbons form within micropores/nanopores of underground shale according to similarity and intermiscibility principles,which make components with poor fluidity suspended as molecular aggregates in light and medium hydrocarbon solvents,such as heavy hydrocarbons,thereby decreasing shale oil viscosity and enhancing fluidity and outflows.Second,small-molecule aromatic hydrocarbons act as carriers for component flow,and the higher the content of gaseous and light hydrocarbons,the more conducive it is to inhibit the formation of larger aggregates of heavy components such as resin and asphalt,thus increasing their plastic deformation ability and bringing about better component flow efficiency.Third,higher formation temperatures reduce the viscosity of heavy hydrocarbon components,such as wax,thereby improving their fluidity.Fourth,preservation conditions,formation energy,and production system play important roles in controlling the content of light hydrocarbon components,outflow rate,and forming stable“component flow”,which are crucial factors for the optimal compatibility and maximum flow rate of multi-component hydrocarbons in shale oil.The component flow of underground shale oil is significant for improving single-well production and the cumulative ultimate recovery of shale oil. 展开更多
关键词 continental facies pure shale type shale oil medium-to-high maturity shale oil micro-nanopores multi-component hydrocarbons component flow similarity and intermiscibility molecular aggregate
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CO_(2)flooding in shale oil reservoir with radial borehole fracturing for CO_(2)storage and enhanced oil recovery
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作者 Jia-Cheng Dai Tian-Yu Wang +3 位作者 Jin-Tao Weng Kang-Jian Tian Li-Ying Zhu Gen-Sheng Li 《Petroleum Science》 SCIE EI CAS CSCD 2024年第1期519-534,共16页
This study introduces a novel method integrating CO_(2)flooding with radial borehole fracturing for enhanced oil recovery and CO_(2)underground storage,a solution to the limited vertical stimulation reservoir volume i... This study introduces a novel method integrating CO_(2)flooding with radial borehole fracturing for enhanced oil recovery and CO_(2)underground storage,a solution to the limited vertical stimulation reservoir volume in horizontal well fracturing.A numerical model is established to investigate the production rate,reservoir pressure field,and CO_(2)saturation distribution corresponding to changing time of CO_(2)flooding with radial borehole fracturing.A sensitivity analysis on the influence of CO_(2)injection location,layer spacing,pressure difference,borehole number,and hydraulic fractures on oil production and CO_(2)storage is conducted.The CO_(2)flooding process is divided into four stages.Reductions in layer spacing will significantly improve oil production rate and gas storage capacity.However,serious gas channeling can occur when the spacing is lower than 20 m.Increasing the pressure difference between the producer and injector,the borehole number,the hydraulic fracture height,and the fracture width can also increase the oil production rate and gas storage rate.Sensitivity analysis shows that layer spacing and fracture height greatly influence gas storage and oil production.Research outcomes are expected to provide a theoretical basis for the efficient development of shale oil reservoirs in the vertical direction. 展开更多
关键词 shale oil Radial borehole fracturing Embedded discrete fracture model Enhanced oil recovery Carbon storage
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Development characteristics and controlling factors of fractures in lacustrine shale and their geological significance for evaluating shale oil sweet spots in the third member of the Shahejie Formation in the Qikou Sag, Bohai Bay Basin
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作者 Xu Zeng Tao Yang +5 位作者 Jian-Wei Feng Cong-Sheng Bian Ming Guan Wei Liu Bing-Cheng Guo Jin Dong 《Petroleum Science》 SCIE EI CAS CSCD 2024年第2期791-805,共15页
Natural fractures are critical for shale oil and gas enrichment and development. Due to the extremely high heterogeneity of shale, the factors controlling the formation of internal fractures, especially horizontal fra... Natural fractures are critical for shale oil and gas enrichment and development. Due to the extremely high heterogeneity of shale, the factors controlling the formation of internal fractures, especially horizontal fractures, remain controversial. In this study, we integrate thin section analysis and microcomputed tomography(CT) data from several lacustrine shale samples from the third member(Es3) of the Shahejie Formation, Qikou Sag, Bohai Bay Basin, to assess the fractures in detail. The goal is to reveal the development characteristics, controlling factors, and geological significance for evaluating sweet spots in a shale oil play. The fractures in the Es3contain high-angle structural and horizontal bed-parallel fractures that are mostly shear and extensional. Various factors influence fracture development,including lithofacies, mineral composition, organic matter content, and the number of laminae. Structural fractures occur predominantly in siltstone, whereas bed-parallel fractures are abundant in laminated shale and layered mudstone. A higher quartz content results in higher shale brittleness, causing fractures, whereas the transformation between clay minerals contributes to the development of bedparallel fractures. Excess pore pressure due to hydrocarbon generation and expulsion during thermal advance can cause the formation of bed-parallel fractures. The density of the bed-parallel and structural fractures increases with the lamina density, and the bed-parallel fractures are more sensitive to the number of laminae. The fractures are critical storage spaces and flow conduits and are indicative of sweet spots. The laminated shale in the Es3with a high organic matter content contains natural fractures and is an organic-rich, liquid-rich, self-sourced shale play. Conversely, the siltstone, massive mudstone, and argillaceous carbonate lithofacies contain lower amounts of organic matter and do not have bed-parallel fractures. However, good reservoirs can form in these areas when structural fractures are present and the source, and storage spaces are separated. 展开更多
关键词 FRACTURES Development characteristics Controlling factors shale oil Sweet spot
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Effect of thermal maturation and organic matter content on oil shale fracturing
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作者 Fatemeh Saberi Mahboubeh Hosseini‑Barzi 《International Journal of Coal Science & Technology》 EI CAS CSCD 2024年第2期16-34,共19页
The Pabdeh Formation represents organic matter enrichment in some oil fields,which can be considered a source rock.This study is based on the Rock–Eval,Iatroscan,and electron microscopy imaging results before and aft... The Pabdeh Formation represents organic matter enrichment in some oil fields,which can be considered a source rock.This study is based on the Rock–Eval,Iatroscan,and electron microscopy imaging results before and after heating the samples.We discovered this immature shale that undergoes burial and diagenesis,in which organic matter is converted into hydro-carbons.Primary migration is the process that transports hydrocarbons in the source rock.We investigated this phenomenon by developing a model that simulates hydrocarbon generation and fluid pressure during kerogen-to-hydrocarbon conversion.Microfractures initially formed at the tip/edge of kerogen and were filled with hydrocarbons,but as catagenesis progressed,the pressure caused by the volume increase of kerogen decreased due to hydrocarbon release.The transformation of solid kerogen into low-density bitumen/oil increased the pressure,leading to the development of damage zones in the source rock.The Pabdeh Formation’s small porethroats hindered effective expulsion,causing an increase in pore fluid pressure inside the initial microfractures.The stress accumulated due to hydrocarbon production,reaching the rock’s fracture strength,further contributed to damage zone development.During the expansion process,microfractures preferentially grew in low-strength pathways such as lithology changes,laminae boundaries,and pre-existing microfractures.When the porous pressure created by each kerogen overlapped,individual microfractures interconnected,forming a network of microfractures within the source rock.This research sheds light on the complex interplay between temperature,hydrocarbon generation,and the development of expulsion fractures in the Pabdeh Formation,providing valuable insights for understanding and optimizing hydrocarbon extraction in similar geological settings. 展开更多
关键词 oil shale MICROFRACTURE Hydrocarbon generation Organic matter Thermal maturation Primary migration
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Experiment of dynamic seepage of tight/shale oil under matrix fracture coupling
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作者 DU Meng YANG Zhengming +10 位作者 LYU Weifeng LI Zhongcheng WANG Guofeng CHEN Xinliang QI Xiang YAO Lanlan ZHANG Yuhao JIA Ninghong LI Haibo CHANG Yilin HUO Xu 《Petroleum Exploration and Development》 SCIE 2024年第2期403-415,共13页
A physical simulation method with a combination of dynamic displacement and imbibition was established by integrating nuclear magnetic resonance(NMR)and CT scanning.The microscopic production mechanism of tight/shale ... A physical simulation method with a combination of dynamic displacement and imbibition was established by integrating nuclear magnetic resonance(NMR)and CT scanning.The microscopic production mechanism of tight/shale oil in pore throat by dynamic imbibition and the influencing factors on the development effect of dynamic imbibition were analyzed.The dynamic seepage process of fracking-soaking-backflow-production integration was simulated,which reveals the dynamic production characteristics at different development stages and their contribution to enhancing oil recovery(EOR).The seepage of tight/shale reservoirs can be divided into three stages:strong displacement and weak imbibition as oil produced rapidly by displacement from macropores and fractures,weak displacement and strong imbibition as oil produced slowly by reverse imbibition from small pores,and weak displacement and weak imbibition at dynamic equilibrium.The greater displacement pressure results in the higher displacement recovery and the lower imbibition recovery.However,if the displacement pressure is too high,the injected water is easy to break through the front and reduce the recovery degree.The higher the permeability,the greater the imbibition and displacement recovery,the shorter the time of imbibition balance,and the higher the final recovery.The fractures can effectively increase the imbibition contact area between matrix and water,reduce the oil-water seepage resistance,promote the oil-water displacement between matrix and fracture,and improve the oil displacement rate and recovery of the matrix.The soaking after fracturing is beneficial to the imbibition replacement and energy storage of the fluid;also,the effective use of the carrying of the backflow fluid and the displacement in the mining stage is the key to enhancing oil recovery. 展开更多
关键词 tight oil shale oil physical simulation nuclear magnetic resonance CT scanning dynamic imbibition production performance EOR
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Hydrodynamic resistance of pore–throat structures and its effect on shale oil apparent permeability
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作者 Wendong Wang Qian Zhang +3 位作者 Jilong Xu Da Zheng Lifeng Liu Yuliang Su 《International Journal of Coal Science & Technology》 EI CAS CSCD 2024年第2期101-110,共10页
Oil transport is greatly affected by heterogeneous pore–throat structures present in shale.It is therefore very important to accurately characterize pore–throat structures.Additionally,it remains unclear how pore–t... Oil transport is greatly affected by heterogeneous pore–throat structures present in shale.It is therefore very important to accurately characterize pore–throat structures.Additionally,it remains unclear how pore–throat structures affect oil transport capacity.In this paper,using finite element(FE)simulation and mathematical modeling,we calculated the hydrodynamic resistance for four pore–throat structure.In addition,the influence of pore throat structure on shale oil permeability is analyzed.According to the results,the hydrodynamic resistance of different pore throat structures can vary by 300%.The contribution of additional resistance caused by streamline bending is also in excess of 40%,even without slip length.Fur-thermore,Pore–throat structures can affect apparent permeability by more than 60%on the REV scale,and this influence increases with heterogeneity of pore size distribution,organic matter content,and organic matter number.Clearly,modeling shale oil flow requires consideration of porous–throat structure and additional resistance,otherwise oil recovery and flow capacity may be overestimated. 展开更多
关键词 Pore–throat structure Hydrodynamic resistance Apparent permeability REV-scale shale oil
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Development review and the prospect of oil shale in-situ catalysis conversion technology
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作者 Li Wang Chen-Hao Gao +2 位作者 Rui-Ying Xiong Xiao-Jun Zhang Ji-Xiang Guo 《Petroleum Science》 SCIE EI CAS CSCD 2024年第2期1385-1395,共11页
As an unconventional resource, oil shale possesses abundant reserves and significant potential for industrial applications. The rational and efficient development of oil shale resources holds immense importance in red... As an unconventional resource, oil shale possesses abundant reserves and significant potential for industrial applications. The rational and efficient development of oil shale resources holds immense importance in reducing national energy demand. In-situ catalytic technology, characterized by its high efficiency, low pollution, and minimal energy consumption, represents a key direction for future oil shale development. This paper provides a comprehensive review of research progress in in-situ oil shale mining technology, oil shale pyrolysis catalysts, the pyrolysis mechanism of kerogen, and the compatibility of different heating processes and catalysts. Furthermore, the paper proposes future research directions and prospects for oil shale in-situ catalytic technology, including reservoir modification, highefficiency catalyst synthesis, injection processes, and high-efficiency heating technology. These insights serve as valuable technical references for the advancement of oil shale in-situ catalytic technology. 展开更多
关键词 oil shale In-situ catalytic technology Pyrolysis catalyst Kerogen pyrolysis mechanism
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Permeability Estimation of Shale Oil Reservoir with Laboratory-derived Data: A Case Study of the Chang 7 Member in Ordos Basin
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作者 Zhang Lin Gao Li +3 位作者 Ba Jing Zhang Meng-Bo José M.Carcione Liu Wei-Hua 《Applied Geophysics》 SCIE CSCD 2024年第3期440-455,616,共17页
The shale oil reservoir within the Yanchang Formations of Ordos Basin harbors substantial oil and gas resources and has recently emerged as the primary focus of unconventional oil and gas exploration and development.D... The shale oil reservoir within the Yanchang Formations of Ordos Basin harbors substantial oil and gas resources and has recently emerged as the primary focus of unconventional oil and gas exploration and development.Due to its complex pore and throat structure,pronounced heterogeneity,and tight reservoir characteristics,the techniques for conventional oil and gas exploration and production face challenges in comprehensive implementation,also indicating that as a vital parameter for evaluating the physical properties of a reservoir,permeability cannot be effectively estimated.This study selects 21 tight sandstone samples from the Q area within the shale oil formations of Ordos Basin.We systematically conduct the experiments to measure porosity,permeability,ultrasonic wave velocities,and resistivity at varying confining pressures.Results reveal that these measurements exhibit nonlinear changes in response to effective pressure.By using these experimental data and effective medium model,empirical relationships between P-and S-wave velocities,permeability and resistivity and effective pressure are established at logging and seismic scales.Furthermore,relationships between P-wave impedance and permeability,and resistivity and permeability are determined.A comparison between the predicted permeability and logging data demonstrates that the impedance–permeability relationship yields better results in contrast to those of resistivity–permeability relationship.These relationships are further applied to the seismic interpretation of shale oil reservoir in the target layer,enabling the permeability profile predictions based on inverse P-wave impedance.The predicted results are evaluated with actual production data,revealing a better agreement between predicted results and logging data and productivity. 展开更多
关键词 shale oil reservoir P-wave impedance RESISTIVITY PERMEABILITY rock physics experiment
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Mechanical characteristics and reservoir stimulation mechanisms of the Gulong shale oil reservoirs, the northern Songliao Basin
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作者 Si-Wei Meng Jia-Ping Tao +6 位作者 Tian-Jiao Li Dong-Xu Li Su-Ling Wang Liu Yang Xin Liu Li-Hao Liang He Liu 《Petroleum Science》 SCIE EI CAS CSCD 2024年第3期2023-2036,共14页
Shale oil of the Qingshankou Formation of the Gulong Sag,the northern Songliao Basin,represents the first attempt at large-scale development of pure-shale-type shale oil in China.By integrating the multiscale refined ... Shale oil of the Qingshankou Formation of the Gulong Sag,the northern Songliao Basin,represents the first attempt at large-scale development of pure-shale-type shale oil in China.By integrating the multiscale refined reservoir characterization with macro-micro-scale mechanical testing,it is clarified that the Gulong shale is characterized by high clay mineral content,high rock plasticity,highly-developed bedding,and prominent mechanical anisotropy.A three-dimensional(3D)fracture propagation model of hydraulic fracturing was built for the Gulong shale,which fully captures the hydraulic fracture distribution pattern affected by the high bedding density,in-situ stress,and fracturing treatment parameters.Our research showed that due to influences of bedding,hydraulic fracturing in the Gulong shale forms a complex fracture morphology featuring the main fracture with multiple perpendicular branches that have different lengths(like the outdoor directional TV antenna);however,the vertical propagation of fractures is inhibited,and the fracture height is commonly less than 10 m.The limited stimulated reservoir volume(SRV)is the main problem facing the fracturing stimulation of the Gulong shale oil.Bedding density has vital effects on fracture morphology,so case-specific fracturing designs shall be developed for shale intervals with different bedding development degrees.For reservoirs with welldeveloped bedding,it is suggested to properly increase the perforation cluster spacing and raise the volume and proportions of viscous fluids of the pad,so as to effectively promote vertical fracture propagation and improve reservoir stimulation performance.This study integrates multi-scale fine reservoir characterization and macro-micro-scale mechanical testing,as well as the construction and numerical simulation of hydraulic fracturing models for high-density layered shale reservoirs,providing a new approach and methodological framework for the fracturing research of high-density layered shale reservoirs. 展开更多
关键词 shale oil Hydraulic fracturing High bedding density Fracture propagation model
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Numerical evaluations on the fluid production in the in-situ conversion of continental shale oil reservoirs
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作者 Zhao-Bin Zhang Maryelin Josefina Briceno Montilla +3 位作者 Shou-Ding Li Xiao Li Jian-Peng Xing Yan-Zhi Hu 《Petroleum Science》 SCIE EI CAS CSCD 2024年第4期2485-2501,共17页
In-situ conversion presents a promising technique for exploiting continental oil shale formations,characterized by highly fractured organic-rich rock.A 3D in-situ conversion model,which incorporates a discrete fractur... In-situ conversion presents a promising technique for exploiting continental oil shale formations,characterized by highly fractured organic-rich rock.A 3D in-situ conversion model,which incorporates a discrete fracture network,is developed using a self-developed thermal-flow-chemical(TFC)simulator.Analysis of the model elucidates the in-situ conversion process in three stages and defines the transformation of fluids into three distinct outcomes according to their end stages.The findings indicate that kerogen decomposition increases fluid pressure,activating fractures and subsequently enhancing permeability.A comprehensive analysis of activated fracture permeability and heating power reveals four distinct production modes,highlighting that increasing heating power correlates with higher cumulative fluid production.Activated fractures,with heightened permeability,facilitate the mobility of heavy oil toward production wells but hinder its cracking,thereby limiting light hydrocarbon production.Additionally,energy efficiency research demonstrates the feasibility of the in-situ conversion in terms of energy utilization,especially when considering the surplus energy from high-fluctuation energy sources such as wind and solar power to provide heating. 展开更多
关键词 In-situ conversion Continental shale oil Natural fracture network TFC model
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Formation,evolution,reconstruction of black shales and their influence on shale oil and gas resource
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作者 Shi-zhen Li Qiu-chen Xu +11 位作者 Mu Liu Guo-heng Liu Yi-fan Li Wen-yang Wang Xiao-guang Yang Wei-bin Liu Yan-fei An Peng Sun Tao Liu Jiang-hui Ding Qian-chao Li Chao-gang Fang 《China Geology》 CAS CSCD 2024年第3期551-585,共35页
Black shales are important products of material cycling and energy exchange among the lithosphere,atmosphere,hydrosphere,and biosphere.They are widely distributed throughout geological history and provide essential en... Black shales are important products of material cycling and energy exchange among the lithosphere,atmosphere,hydrosphere,and biosphere.They are widely distributed throughout geological history and provide essential energy and mineral resources for the development of human society.They also record the evolution process of the earth and improve the understanding of the earth.This review focuses on the diagenesis and formation mechanisms of black shales sedimentation,composition,evolution,and reconstruction,which have had a significant impact on the formation and enrichment of shale oil and gas.In terms of sedimentary environment,black shales can be classified into three types:Marine,terrestrial,and marine-terrestrial transitional facies.The formation processes include mechanisms such as eolian input,hypopycnal flow,gravity-driven and offshore bottom currents.From a geological perspective,the formation of black shales is often closely related to global or regional major geological events.The enrichment of organic matter is generally the result of the interaction and coupling of several factors such as primary productivity,water redox condition,and sedimentation rate.In terms of evolution,black shales have undergone diagenetic evolution of inorganic minerals,thermal evolution of organic matter and hydrocarbon generation,interactions between organic matter and inorganic minerals,and pore evolution.In terms of reconstruction,the effects of fold deformation,uplift and erosion,and fracturing have changed the stress state of black shale reservoirs,thereby having a significant impact on the pore structure.Fluid activity promotes the formation of veins,and have changed the material composition,stress structure,and reservoir properties of black shales.Regarding resource effects,the deposition of black shales is fundamental for shale oil and gas resources,the evolution of black shales promotes the shale oil and gas formation and storage,and the reconstruction of black shales would have caused the heterogeneous distribution of oil and gas in shales.Exploring the formation mechanisms and interactions of black shales at different scales is a key to in-depth research on shale formation and evolution,as well as the key to revealing the mechanism controlling shale oil and gas accumulation.The present records can reveal how these processes worked in geological history,and improve our understanding of the coupling mechanisms among regional geological events,black shales evolution,and shale oil and gas formation and enrichment. 展开更多
关键词 Black shales shale oil and gas Resource effects Sedimentary environment Sedimentary process Organic matter accumulation Diagenetic evolution Thermal evolution Organic matter and inorganic minerals Tectonic reconstruction oil and gas exploration engineering VEINS Fluid activity
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The occurrence characteristics of oil in shales matrix from organic geochemical screening data and pore structure properties:An experimental study Author links open overlay panel
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作者 Zi-Zhi Lin Jun-Qian Li +8 位作者 Shuang-Fang Lu Qin-Hong Hu Peng-Fei Zhang Jun-Jie Wang Qi Zhi Hong-Sheng Huang Na Yin Yue Wang Tian-Chen Ge 《Petroleum Science》 SCIE EI CAS CSCD 2024年第1期1-13,共13页
The occurrence characteristics of shale oil are of great significance to the movability of shale oil.In this study,the occurrence characteristics of oil in the shale matrix at Funing Formation shale in Subei Basin wer... The occurrence characteristics of shale oil are of great significance to the movability of shale oil.In this study,the occurrence characteristics of oil in the shale matrix at Funing Formation shale in Subei Basin were quantitatively evaluated by organic geochemistry and microscopic pore structure characterization experiments.The Multiple Isothermal Stages Pyrolysis(MIS)experiment results show that the content of total oil,adsorbed oil,and free oil in the shales are 3.15-11.25 mg/g,1.41-4.95 mg/g,and 1.74-6.51 mg/g,respectively.among which the silicon-rich shale has the best oil-bearing.The relative content of free oil shows an increasing trend in pores with pore diameters greater than 3 nm.When the relative content of free oil reaches 100%,the pore size of silicon-rich shale is about 200 nm,while that of calcium-rich shale,clay-rich shale,and siliceous mixed shale is about 10 nm.The occurrence law of adsorbed oil is opposite to that of free oil,which indicates that shale oil will occur in the pores and fractures in a free state in a more extensive pore size range(>200 nm).This study also enables us to further understand the occurrence characteristics of shale oil under the interaction of occurrence state and occurrence space. 展开更多
关键词 shale oil Occurrence characteristics Sequential solvent extraction Low-temperature nitrogen adsorption Funing Formation Dongtai Depression
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Extractable and kerogen-bound hopanoids from typical Eocene oil shales in China
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作者 Changbo Zhai Zhirong Zhang +2 位作者 John K.Volkman Hong Lu Yan'e Chen 《Energy Geoscience》 EI 2024年第2期171-179,共9页
This study conducted a comparative analysis of extractable hopanoid hydrocarbons and those released via stepwise pyrolysis of typical Eocene immature oil shales in China,namely the Huadian,Maoming,and Fushun shales.Bo... This study conducted a comparative analysis of extractable hopanoid hydrocarbons and those released via stepwise pyrolysis of typical Eocene immature oil shales in China,namely the Huadian,Maoming,and Fushun shales.Both the Huadian and Maoming shales exhibit immature indicators in extractable and kerogen-bound hopanoids(notably,high abundance of C_(29)to C_(32)17β,21β-hopanes and unsaturated hopenes).In contrast,the Fushun oil shale's hopanoids from extracts and pyrolyzates suggest a higher maturity level.The absence of neohopenes in the pyrolyzates of the shales underpins that the kerogenbound hopanoid skeletons resist rearrangement.However,the Huadian oil shale's asymmetric distribution of C_(29)and C_(30)hopenes and neohopenes hints at the presence of an additional source.Novel unsaturated hopenes,such as hop-20(21)-enes,identified in pyrolyzates of the three kerogens at various pyrolysis temperatures,reveal the occurrence of double bonds in kerogen-bound hopanoid skeletons without methyl rearrangements.The absence of hop-20-(21)-ene in extracts suggests that it might act as an intermediate of these novel hopenes during the epimerization of hopanoid skeletons within kerogen.The extractable and pyrolytic hopanoids'stereochemical alignment indicates that epimerization may occur in both ring systems and alkyl side chains of kerogen-bound hopanoid skeletons.Sequential stepwise pyrolysis proves to be a quick screening method for geological hopanoids without causing any significant alteration to the original skeletons even when cracking multiple covalent bonds is necessary. 展开更多
关键词 Hopanoid HOPANE Hopene Neohopene Stepwise pyrolysis KEROGEN Eocene oil shale
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Shale oil recovery by CO_(2)injection in Jiyang Depression,Bohai Bay Basin,East China
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作者 LI Yang ZHU Yangwen +8 位作者 LI Zongyang JIANG Tingxue XUE Zhaojie SHEN Ziqi XIAO Pufu YU Hongmin CHENG Ziyan ZHAO Qingmin ZHANG Qingfu 《Petroleum Exploration and Development》 SCIE 2024年第4期981-992,共12页
Laboratory experiments,numerical simulations and fracturing technology were combined to address the problems in shale oil recovery by CO_(2)injection.The laboratory experiments were conducted to investigate the displa... Laboratory experiments,numerical simulations and fracturing technology were combined to address the problems in shale oil recovery by CO_(2)injection.The laboratory experiments were conducted to investigate the displacement mechanisms of shale oil extraction by CO_(2)injection,and the influences of CO_(2)pre-pad on shale mechanical properties.Numerical simulations were performed about influences of CO_(2)pre-pad fracturing and puff-n-huff for energy replenishment on the recovery efficiency.The findings obtained were applied to the field tests of CO_(2)pre-pad fracturing and single well puff-n-huff.The results show that the efficiency of CO_(2)puff-n-huff is affected by micro-and nano-scale effect,kerogen,adsorbed oil and so on,and a longer soaking time in a reasonable range leads to a higher exploitation degree of shale oil.In the"injection+soaking"stage,the exploitation degree of heavy hydrocarbons is enhanced by CO_(2)through its effects of solubility-diffusion and mass-transfer.In the"huff"stage,crude oil in large pores is displaced by CO_(2)to surrounding larger pores or bedding fractures and finally flows to the production well.The injection of CO_(2)pre-pad is conducive to keeping the rock brittle and reducing the fracture breakdown pressure,and the CO_(2)is liable to filter along the bedding surface,thereby creating a more complex fracture.Increasing the volume of CO_(2)pre-pad can improve the energizing effect,and enhance the replenishment of formation energy.Moreover,the oil recovery is more enhanced by CO_(2)huff-n-puff with the lower shale matrix permeability,the lower formation pressure,and the larger heavy hydrocarbon content.The field tests demonstrate a good performance with the pressure maintained well after CO_(2)pre-pad fracturing,the formation energy replenished effectively after CO_(2)huff-n-puff in a single well,and the well productivity improved. 展开更多
关键词 shale oil carbon dioxide pre-pad fracturing huff-n-puff for energy replenishment laboratory experiment field test recovery efficiency enhanced oil recovery
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Optimization method of fracturing fluid volume intensity for SRV fracturing technique in shale oil reservoir based on forced imbibition:A case study of well X-1 in Biyang Sag of Nanxiang Basin,China
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作者 JIANG Tingxue SHEN Ziqi +6 位作者 WANG Liangjun QI Zili XIAO Bo QIN Qiuping FAN Xiqun WANG Yong QU Hai 《Petroleum Exploration and Development》 SCIE 2024年第3期674-683,共10页
An optimization method of fracturing fluid volume strength was introduced taking well X-1 in Biyang Sag of Nanxiang Basin as an example.The characteristic curves of capillary pressure and relative permeability were ob... An optimization method of fracturing fluid volume strength was introduced taking well X-1 in Biyang Sag of Nanxiang Basin as an example.The characteristic curves of capillary pressure and relative permeability were obtained from history matching between forced imbibition experimental data and core-scale reservoir simulation results and taken into a large scale reservoir model to mimic the forced imbibition behavior during the well shut-in period after fracturing.The optimization of the stimulated reservoir volume(SRV)fracturing fluid volume strength should meet the requirements of estimated ultimate recovery(EUR),increased oil recovery by forced imbibition and enhancement of formation pressure and the fluid volume strength of fracturing fluid should be controlled around a critical value to avoid either insufficiency of imbibition displacement caused by insufficient fluid amount or increase of costs and potential formation damage caused by excessive fluid amount.Reservoir simulation results showed that SRV fracturing fluid volume strength positively correlated with single-well EUR and an optimal fluid volume strength existed,above which the single-well EUR increase rate kept decreasing.An optimized increase of SRV fracturing fluid volume and shut-in time would effectively increase the formation pressure and enhance well production.Field test results of well X-1 proved the practicality of established optimization method of SRV fracturing fluid volume strength on significant enhancement of shale oil well production. 展开更多
关键词 shale oil horizontal well volume fracturing forced imbibition fracturing fluid intensity parameter optimization
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Iteration and evaluation of shale oil development technology for continental rift lake basins
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作者 SUN Huanquan WANG Haitao +8 位作者 YANG Yong LYU Qi ZHANG Feng LIU Zupeng LYU Jing CHEN Tiancheng JIANG Tingxue ZHAO Peirong WU Shicheng 《Petroleum Exploration and Development》 SCIE 2024年第4期993-1008,共16页
By benchmarking with the iteration of drilling technology,fracturing technology and well placement mode for shale oil and gas development in the United States and considering the geological characteristics and develop... By benchmarking with the iteration of drilling technology,fracturing technology and well placement mode for shale oil and gas development in the United States and considering the geological characteristics and development difficulties of shale oil in the Jiyang continental rift lake basin,East China,the development technology system suitable for the geological characteristics of shale oil in continental rift lake basins has been primarily formed through innovation and iteration of the development,drilling and fracturing technologies.The technology system supports the rapid growth of shale oil production and reduces the development investment cost.By comparing it with the shale oil development technology in the United States,the prospect of the shale oil development technology iteration in continental rift lake basins is proposed.It is suggested to continuously strengthen the overall three-dimensional development,improve the precision level of engineering technology,upgrade the engineering technical indicator system,accelerate the intelligent optimization of engineering equipment,explore the application of complex structure wells,form a whole-process integrated quality management system from design to implementation,and constantly innovate the concept and technology of shale oil development,so as to promote the realization of extensive,beneficial and high-quality development of shale oil in continental rift lake basins. 展开更多
关键词 shale oil continental rift lake basin Jiyang Depression DRILLING FRACTURING DEVELOPMENT technology iteration PROSPECT
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Shale oil production predication based on an empirical modelconstrained CNN-LSTM
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作者 Qiang Zhou Zhengdong Lei +4 位作者 Zhewei Chen Yuhan Wang Yishan Liu Zhenhua Xu Yuqi Liu 《Energy Geoscience》 EI 2024年第2期232-239,共8页
Accurately predicting the production rate and estimated ultimate recovery(EUR)of shale oil wells is vital for efficient shale oil development.Although numerical simulations provide accurate predictions,their high time... Accurately predicting the production rate and estimated ultimate recovery(EUR)of shale oil wells is vital for efficient shale oil development.Although numerical simulations provide accurate predictions,their high time,data,and labor demands call for a swifter,yet precise,method.This study introduces the DuongeCNNeLSTM(D-C-L)model,which integrates a convolutional neural network(CNN)with a long short-term memory(LSTM)network and is grounded on the empirical Duong model for physical constraints.Compared to traditional approaches,the D-C-L model demonstrates superior precision,efficiency,and cost-effectiveness in predicting shale oil production. 展开更多
关键词 shale oil Production prediction D-C-L Physical constraint
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